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1. 发明授权

US08012458B2 Rare-earth amidate coordination compounds 失效
标题翻译：稀土酰胺配位化合物
公开(公告)号：US08012458B2
公开(公告)日：2011-09-06
申请号：US11759973
申请日：2007-06-08
申请人： Damien F. Reardon
发明人： Damien F. Reardon
IPC分类号： A61B5/055 , G01N33/20
CPC分类号： C22B3/002 , C07F5/003 , C07F9/5345 , C22B59/00 , Y02P10/234
摘要： The invention is directed to a lanthamide chelate composition having a lanthamide, a charged amidate ligand, and a mono- or bidentate neutrally charged coordination compound, the composition being represented by structure I or structure II wherein Ln3+ designates lanthamide, R1 is alkyl, aryl, or heteroaryl; R2 is alkyl, aminoalkyl, aryl or heteroaryl; M is a neutrally charged monodentate coordination compound, M′ is a neutrally charged bidentate coordination compound, a=1 or 2; and wherein M and M′ comprise N, S, or O. It extends to the process of making the composition.
摘要翻译：本发明涉及具有花生酰胺，带电荷的酰胺化物配体和单或双齿中性带电配位化合物的花生酰胺螯合物组合物，该组合物由结构I或结构II表示，其中Ln3 +表示花氨酰胺，R1是烷基，芳基，或杂芳基; R2是烷基，氨基烷基，芳基或杂芳基; M是中性充电单齿配位化合物，M'是中性充电二齿配位化合物，a = 1或2; 并且其中M和M'包括N，S或O.它延伸到制备组合物的过程中。

2. 发明申请

US20050211955A1 Cesium and strontium extraction using a mixed extractant solvent including crown ether and calixarene extractants 失效
标题翻译：使用包括冠醚和杯芳烃萃取剂的混合萃取剂溶剂进行铯和锶萃取
公开(公告)号：US20050211955A1
公开(公告)日：2005-09-29
申请号：US10808039
申请日：2004-03-23
申请人： David Meikrantz , Terry Todd , Catherine Riddle , Jack Law , Dean Peterman , Bruce Mincher , Christopher McGrath , John Baker
发明人： David Meikrantz , Terry Todd , Catherine Riddle , Jack Law , Dean Peterman , Bruce Mincher , Christopher McGrath , John Baker
IPC分类号： C22B3/26 , C22B26/00 , C22B60/02 , C23G5/00
CPC分类号： C22B3/002 , C22B26/00 , Y02P10/234
摘要： A mixed extractant solvent including calix[4]arene-bis-(tert-octylbenzo)-crown-6 (“BOBCalixC6”), 4′,4′,(5′)-di-(t-butyldicyclo-hexano)-18-crown-6 (“DtBu18C6”), and at least one modifier dissolved in a diluent. The mixed extractant solvent may be used to remove cesium and strontium from an acidic solution. The DtBu18C6 may be present from approximately 0.01 M to approximately 0.4M, such as from approximately 0.086 M to approximately 0.108 M. The modifier may be 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol (“Cs-7SB”) and may be present from approximately 0.01M to approximately 0.8M. In one embodiment, the mixed extractant solvent includes approximately 0.15M DtBu18C6, approximately 0.007M BOBCalixC6, and approximately 0.75M Cs-7SB modifier dissolved in an isoparaffinic hydrocarbon diluent. The mixed extractant solvent may form an organic phase in an extraction system that also includes an aqueous phase. Methods of extracting cesium and strontium as well as strontium alone are also disclosed.
摘要翻译：混合萃取剂溶剂包括杯[4]芳烃双 - （叔辛基苯并） - 起始-6（“BOBCalixC6”），4'，4'，（5'） - 二 - （叔丁基二环己基） -crown-6（“DtBu18C6”）和溶解在稀释剂中的至少一种改性剂。混合的萃取剂溶剂可用于从酸性溶液中除去铯和锶。 DtBu18C6可以为约0.01M至约0.4M，例如约0.086M至约0.108M。改性剂可为1-（2,2,3,3-四氟丙氧基）-3-（4-仲 - 丁基苯氧基）-2-丙醇（“Cs-7SB”），并且可以以约0.01M至约0.8M存在。在一个实施方案中，混合萃取剂溶剂包括溶解在异链烷烃稀释剂中的约0.15M DtBu18C6，约0.007M BOBCalixC6和约0.75M Cs-7SB改性剂。混合的萃取剂溶剂可以在还包含水相的萃取系统中形成有机相。还公开了提取铯和锶以及单独的锶的方法。

3. 发明申请

US20030108464A1 Method for separating metal ions 失效
公开(公告)号：US20030108464A1
公开(公告)日：2003-06-12
申请号：US10316923
申请日：2002-12-12
申请人： National Inst. for Research in Inorganic Materials
发明人： Yu Komatsu , Shigekazu Tsurubou
IPC分类号： C22B026/20
CPC分类号： B01J39/04 , C22B3/002 , C22B26/20 , Y02P10/234
摘要： A method for separating metal ions, which comprises adding a selective capturing agent to an aqueous solution containing plural types of metal ions, said selective capturing agent being a cyclic compound and forming a complex with metal ions having ion radii suitable for the size of the ring alone, so that unnecessary metal ions are held by the selective capturing agent in the aqueous solution, and bringing said aqueous solution into contact with an ion exchange solid phase so as to transport desired metal ions alone to the solid phase.

4. 发明授权

US06511603B1 Alkaline earth cation extraction from acid solution 有权
标题翻译：从酸溶液中提取碱土阳离子
公开(公告)号：US06511603B1
公开(公告)日：2003-01-28
申请号：US09695126
申请日：2000-10-24
申请人： Mark Dietz , E. Philip Horwitz
发明人： Mark Dietz , E. Philip Horwitz
IPC分类号： C02F126
CPC分类号： B01J45/00 , C02F1/26 , C02F2101/006 , C22B3/002 , C22B26/20 , Y02P10/234 , Y10S423/14 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： An extractant medium for extracting alkaline earth cations from an aqueous acidic sample solution is described as are a method and apparatus for using the same. The separation medium is free of diluent, free-flowing and particulate, and comprises a Crown ether that is a 4,4′(5′)[C4-C8-alkylcyclohexano]18-Crown-6 dispersed on an inert substrate material.
摘要翻译：作为使用该酸性溶液的方法和装置，还描述了从酸性样品溶液水溶液中提取碱土金属阳离子的萃取介质。分离介质不含稀释剂，自由流动和颗粒，并且包含分散在惰性基材上的4,4'（5'）[C4-C8-烷基环己烷] 18-冠-6的冠醚。

5. 发明授权

US08715598B2 Method for the purification of radium from different sources 有权
标题翻译：从不同来源净化镭的方法
公开(公告)号：US08715598B2
公开(公告)日：2014-05-06
申请号：US13441803
申请日：2012-04-06
申请人： Eva Kabai , Josue M. Moreno Bermudez , Richard Henkelmann , Andreas Türler
发明人： Eva Kabai , Josue M. Moreno Bermudez , Richard Henkelmann , Andreas Türler
IPC分类号： C01F13/00
CPC分类号： C22B60/00 , C22B3/002 , C22B13/04 , C22B26/20 , G21G1/001 , G21G2001/0094 , Y02P10/234
摘要： The invention is directed to a method for the purification of Radium, in particular 226Ra, for target preparation for an essentially pure 225Ac production from available radioactive sources, using an extraction chromatography in order to separate chemically similar elements such as Ba, Sr, and Pb from the desired Ra; wherein said extraction chromatography has an extractant system on the basis of a crown ether. The invention is related to a method for recycling of 226Ra, for target preparation for 225Ac production from radium sources irradiated with accelerated protons (p,2n), after separation of the produced 225Ac. In this method a combination of the above extraction chromatography and a cation exchange chromatography is used. The obtained 226Ra is essentially free of the following chemical contaminants consisting of Ag, Al, As, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, K, Li, Mg, Mn, Na, Ni, Pb, Sr, V, Zn, and Ba.
摘要翻译：本发明涉及一种用于纯化镭（特别是226Ra）的方法，用于使用提取色谱从化学上类似的元素如Ba，Sr和Pb分离用于从可用的放射源制备基本上纯的225Ac产物的目标制备从所需的Ra; 其中所述提取色谱法具有基于冠醚的萃取剂体系。本发明涉及一种用于回收226Ra的方法，用于在分离产生的225Ac之后，用加速质子（p，2n）照射的镭源进行225Ac生产的目标制备。在该方法中，使用上述提取色谱和阳离子交换层析的组合。得到的226Ra基本上不含由Ag，Al，As，Be，Bi，Ca，Cd，Co，Cr，Cu，Fe，Ga，K，Li，Mg，Mn，Na，Ni，Pb组成的以下化学污染物，Sr，V，Zn和Ba。

6. 发明授权

US08153087B2 Method for the purification of radium from different sources 有权
标题翻译：从不同来源净化镭的方法
公开(公告)号：US08153087B2
公开(公告)日：2012-04-10
申请号：US12398346
申请日：2009-03-05
申请人： Eva Kabai , Josue Manuel Moreno Bermudez , Richard Henkelmann , Andreas Turler
发明人： Eva Kabai , Josue Manuel Moreno Bermudez , Richard Henkelmann , Andreas Turler
IPC分类号： C01F13/00
CPC分类号： C22B60/00 , C22B3/002 , C22B13/04 , C22B26/20 , G21G1/001 , G21G2001/0094 , Y02P10/234
摘要： The present application is directed to a method for the purification of Radium, in particular 226Ra, for target preparation for an essentially pure 225Ac production from available radioactive sources, using an extraction chromatography in order to separate chemically similar elements such as Ba, Sr, and Pb from the desired Ra; wherein said extraction chromatography has an extractant system on the basis of a crown ether. The invention is further related to a method for recycling of 226Ra, for target preparation for 225Ac production from radium sources irradiated with accelerated protons (p,2n), after separation of the produced 225AC. In this method a combination of the above extraction chromatography and a cation exchange chromatography is used. The obtained 226Ra is essentially free of the following chemical contaminants consisting of Ag, Al, As, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, K, Li, Mg, Mn, Na, Ni, Pb, Sr, V, Zn, and Ba.
摘要翻译：本申请涉及用于纯化镭（特别是226Ra）的方法，用于使用提取色谱法将化学上类似的元素如Ba，Sr和 Pb从所需的Ra; 其中所述提取色谱法具有基于冠醚的萃取剂体系。本发明进一步涉及一种用于回收226Ra的方法，用于在分离生成的225AC之后，用加速质子（p，2n）照射的镭源的225Ac生产的目标制备。在该方法中，使用上述提取色谱和阳离子交换层析的组合。得到的226Ra基本上不含由Ag，Al，As，Be，Bi，Ca，Cd，Co，Cr，Cu，Fe，Ga，K，Li，Mg，Mn，Na，Ni，Pb组成的以下化学污染物，Sr，V，Zn和Ba。

7. 发明授权

US07524469B2 Extractant composition including crown ether and calixarene extractants 失效
标题翻译：萃取剂组合物，包括冠醚和杯芳烃萃取剂
公开(公告)号：US07524469B2
公开(公告)日：2009-04-28
申请号：US11859453
申请日：2007-09-21
申请人： David H. Meikrantz , Terry A. Todd , Catherine L. Riddle , Jack D. Law , Dean R. Peterman , Bruce J. Mincher , Christopher A. McGrath , John D. Baker
发明人： David H. Meikrantz , Terry A. Todd , Catherine L. Riddle , Jack D. Law , Dean R. Peterman , Bruce J. Mincher , Christopher A. McGrath , John D. Baker
IPC分类号： B01D11/00
CPC分类号： C22B3/002 , C22B26/00 , Y02P10/234
摘要： An extractant composition comprising a mixed extractant solvent consisting of calix[4] arene-bis-(tert-octylbenzo)-crown-6 (“BOBCalixC6”), 4′,4′,(5′)-di-(t-butyldicyclo-hexano)-18-crown-6 (“DtBu18C6”), and at least one modifier dissolved in a diluent. The DtBu18C6 may be present at from approximately 0.01M to approximately 0.4M, such as at from approximately 0.086 M to approximately 0.108 M. The modifier may be 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol (“Cs-7SB”) and may be present at from approximately 0.01M to approximately 0.8M. In one embodiment, the mixed extractant solvent includes approximately 0.15M DtBu18C6, approximately 0.007M BOBCalixC6, and approximately 0.75M Cs-7SB modifier dissolved in an isoparaffinic hydrocarbon diluent. The extractant composition further comprises an aqueous phase. The mixed extractant solvent may be used to remove cesium and strontium from the aqueous phase.
摘要翻译：一种萃取剂组合物，其包含由杯[4]芳烃 - 双 - （叔辛基苯并） - 起始-6（“BOBCalixC6”），4'，4'，（5'） - 二 - （叔丁基二环己烷）-18-冠-6（“DtBu18C6”）和溶解在稀释剂中的至少一种改性剂。 DtBu18C6可以以约0.01M至约0.4M，例如约0.086M至约0.108M存在。改性剂可以是1-（2,2,3,3-四氟丙氧基）-3-（4- 仲丁基苯氧基）-2-丙醇（“Cs-7SB”），并且可以以约0.01M至约0.8M存在。在一个实施方案中，混合萃取剂溶剂包括溶解在异链烷烃稀释剂中的约0.15M DtBu18C6，约0.007M BOBCalixC6和约0.75M Cs-7SB改性剂。萃取剂组合物还包含水相。混合的萃取剂溶剂可用于从水相中除去铯和锶。

8. 发明授权

US06297395B1 Calixarenes and their use for sequestration of metals 失效
标题翻译：杯芳烃及其用于金属螯合的用途
公开(公告)号：US06297395B1
公开(公告)日：2001-10-02
申请号：US09460237
申请日：1999-12-13
申请人： Graeme P. Nicholson , Mark J. Kan , Gareth Williams , Michael G. Drew , Paul D. Beer
发明人： Graeme P. Nicholson , Mark J. Kan , Gareth Williams , Michael G. Drew , Paul D. Beer
IPC分类号： C07C22900
CPC分类号： C07C235/20 , C07C235/24 , C07C327/42 , C07C2603/92 , C07D273/00 , C22B3/002 , G01N27/3335 , Y02P10/234
摘要： Disclosed are “acid-amide” calixarenes of formula (I) wherein: L is [—CH2—] or [—O—CH2—O—] and may be the same or different between each aryl group; R5 is H, halogen, or C1-C10 aliphatic hydrocarbyl group, C6-C20 aryl group, C6-C10 hydrocarbyaryl group, any of which may optionally be substituted by one or more halo or oxo groups or interrupted by one or more oxo groups, and R5 may be the same or different on each aryl group; R1 comprises an optionally protected carboxy group; two groups out of R2, R3, and R4 are H; the one group out of R2, R3, and R4 not being H comprises an amide group. The amide group may be linked to a second calixarene to form a dimer. Also disclosed are methods of use of such calixarenes for the purposes of metal sequestration, especially of lanthanides and actinides. Also disclosed are calixarene dimer derivatives of the calixarenes of the invention. Also disclosed are processes for preparing the calixarenes and dimers.
摘要翻译：公开了式（I）的“酸酰胺”杯芳烃，其中：L是[-CH 2 - ]或[-O-CH 2 -O-]，并且在每个芳基之间可以相同或不同; R5是H，卤素或C1-C10脂族烃基，C6-C20芳基，C6-C10烃氧基，其中任何一个可以任选地被一个或多个卤代或氧代基取代或被一个或多个氧代基中断，并且R 5可以在每个芳基上相同或不同; R1包含任选保护的羧基; R2，R3和R4中的两个基团是H; R2，R3和R4不为H的一个基团包含酰胺基。酰胺基团可以与第二杯咖啡连接以形成二聚体。还公开了使用这种杯芳烃用于金属螯合的方法，特别是镧系元素和锕系元素的方法。还公开了本发明的杯芳烃的杯芳烃二聚体衍生物。还公开了制备杯芳烃和二聚体的方法。

9. 发明授权

US06174503B1 Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions 失效
标题翻译：杯芳烃冠醚溶剂组合物及其用于从碱性废溶液中萃取铯的用途
公开(公告)号：US06174503B1
公开(公告)日：2001-01-16
申请号：US09146800
申请日：1998-09-03
申请人： Bruce A. Moyer , Richard A. Sachleben , Peter V. Bonnesen , Derek J. Presley
发明人： Bruce A. Moyer , Richard A. Sachleben , Peter V. Bonnesen , Derek J. Presley
IPC分类号： C22B2610
CPC分类号： C22B3/002 , C22B26/10 , Y02P10/234
摘要： A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.
摘要翻译：描述了从含有Cs和可能的其它竞争性金属离子的中性和碱性溶液中提取铯（Cs）的溶剂组成和相应方法。该方法需要使含水的含Cs溶液与溶解在含有特定类别的烷基 - 芳族醚醇作为改性剂的烃基稀释剂中的特定类别的亲油性杯[4]芳烃 - 冠醚萃取剂组成的溶剂接触。随后从萃取剂中回收铯值，然后通过使含Cs的有机溶液与水性剥离溶液接触，随后再循环溶剂。这种组合萃取和汽提方法特别适用于从高碱性废液中去除铯-137的方法，该方法也非常浓缩在钠和钾中。不需要对废溶液进行预处理，并且可以使用水，稀（毫摩尔）酸溶液或稀（毫摩尔）盐溶液，使用安全且廉价的汽提方法回收铯。本发明的重要应用是碱性核罐废物的处理。或者，本发明可以应用于含有铯-137的酸性再处理废物的去污。

10. 发明授权

US5888398A Composition and process for separating cesium ions from an acidic aqueous solution also containing other ions 失效
标题翻译：从含有其他离子的酸性水溶液中分离铯离子的组成和方法
公开(公告)号：US5888398A
公开(公告)日：1999-03-30
申请号：US789653
申请日：1997-01-27
申请人： Mark L. Dietz , E. Philip Horwitz , Richard A. Bartsch , Richard E. Barrans, Jr. , David Rausch
发明人： Mark L. Dietz , E. Philip Horwitz , Richard A. Bartsch , Richard E. Barrans, Jr. , David Rausch
IPC分类号： C07D323/00 , C22B3/26 , C22B26/10 , B01D11/00 , B01D11/02 , C01D17/00
CPC分类号： C07D323/00 , C22B26/10 , C22B3/002 , Y02P10/234
摘要： A crown ether cesium ion extractant is disclosed as is its synthesis. The crown ether cesium ion extractant is useful for the selective purification of cesium ions from aqueous acidic media, and more particularly useful for the isolation of radioactive cesium-137 from nuclear waste streams. Processes for isolating cesium ions from aqueous acidic media using the crown ether cesium extractant are disclosed as are processes for recycling the crown ether cesium extractant and processes for recovering cesium from a crown ether cesium extractant solution.
摘要翻译：公开了冠醚铯离子提取剂的合成。冠醚铯离子萃取剂可用于从酸性水溶液中选择性纯化铯离子，更特别适用于从核废料流中分离放射性铯-137。公开了使用冠醚铯提取剂从含水酸性介质中分离铯离子的方法，用于回收冠醚铯提取剂的方法和从冠醚铯提取剂溶液回收铯的方法。

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