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1. 发明申请

US20180208947A1 PROCESS FOR PRODUCING ALKANES USING MICROORGANISMS COMBINED WITH KOLBE SYNTHESIS 审中-公开
公开(公告)号：US20180208947A1
公开(公告)日：2018-07-26
申请号：US15326552
申请日：2015-07-16
申请人： Evonik Degussa GmbH
发明人： Thomas HAAS , Uwe PAULMANN , Simon BECK
IPC分类号： C12P5/02 , C12P7/44 , C12P7/52 , C12P7/40 , C12P7/02 , C25B3/10
CPC分类号： C12P5/02 , C12P7/02 , C12P7/40 , C12P7/44 , C12P7/52 , C25B3/10 , Y02E50/343 , Y02T50/678
摘要： The present invention relates to a method of producing at least one alkane, the method comprising, —producing at least one carboxylic acid from a carbon source using a genetically modified microorganism, and —performing Kolbe electrolysis on the carboxylic acid to produce the alkane, wherein the alkane comprises at least 6 carbon atoms and the carboxylic acid comprises at least 4 carbon atoms and wherein the carbon source is selected from the group consisting of ethanol, acetate, propionate, butyrate, isobutyrate, valerate, hexanoate and combinations thereof and the microorganism is capable of producing the carboxylic acid using ethanol-carboxylate fermentation.

2. 发明申请

US20180179248A1 DECARBOXYLATIVE CONJUGATE ADDITIONS AND APPLICATIONS THEREOF 审中-公开
公开(公告)号：US20180179248A1
公开(公告)日：2018-06-28
申请号：US15579741
申请日：2016-06-03
申请人： The Trustees of Princeton University
发明人： David MACMILLAN , Daniel NOVOA , Stefan MCCARVER
IPC分类号： C07K1/113 , C25B3/10 , B01J31/18 , B01J35/00
CPC分类号： C07K1/113 , B01J31/181 , B01J31/1815 , B01J35/004 , B01J2231/324 , B01J2231/348 , B01J2531/827 , B01J2540/12 , B01J2540/22 , B01J2540/225 , C07K1/107 , C07K5/0205 , C25B3/10
摘要： Synthetic methods are described herein operable to efficiently produce a wide variety of molecular species through conjugate additions via decarboxylative mechanisms. For example, methods of functionalization of peptide residues are described, including selective functionalization of peptide C-terminal residues. In one aspect, a method of peptide functionalization comprises providing a reaction mixture including a Michael acceptor and a peptide and coupling the Michael acceptor with the peptide via a mechanism including decarboxylation of a peptide reside.

3. 发明授权

US09957622B2 Device and method of obtaining diols and other chemicals using decarboxylation 有权
公开(公告)号：US09957622B2
公开(公告)日：2018-05-01
申请号：US13790744
申请日：2013-03-08
申请人： FIELD UPGRADING LIMITED
发明人： James Mosby , Sai Bhavaraju , Mukund Karanjikar
IPC分类号： C25B9/08 , C25B15/00 , C25B9/06 , C25B3/10 , C10G3/00
CPC分类号： C25B3/10 , C10G3/00 , C10G2300/1011 , C10G2300/44 , C25B9/08 , Y02P30/20
摘要： A method for converting carboxylic acids (including carboxylic acids derived from biomass) into hydrocarbons. The produced hydrocarbons will generally have at least two oxygen containing substituents (or other substituents). In one example of application, the electrolysis converts alkali salts of carboxylic acids into diols which can then be used as solvents or be dehydrated to produce dienes, which can then be used to produce elastic polymeric materials. This process allows custom synthesis of high value chemicals from renewable feed stocks such as carboxylic acids derived from biomass.

4. 发明授权

US09956149B2 Emollients and cosmetic compositions based on specific branched hydrocarbons 有权
公开(公告)号：US09956149B2
公开(公告)日：2018-05-01
申请号：US14660344
申请日：2015-03-17
申请人： Cognis IP Management GmbH
发明人： Markus Dierker
IPC分类号： A61K8/31 , A61Q19/00 , C25B3/02 , C25B3/10 , A61K47/06
CPC分类号： A61K8/31 , A61K47/06 , A61K2800/10 , A61Q19/00 , C25B3/02 , C25B3/10
摘要： A cosmetic or pharmaceutical composition is provided. The composition contains a mixture of oils prepared by Kolbe electrolysis of branched chain fatty acids and mixtures of branched chain fatty acids with straight chain fatty acids. The fatty acids containing from 3 to 26 carbon atoms. The oils are a mixture of oils with different spreading rates (spreading cascade).

5. 发明授权

US09932679B2 Electrochemical conversion of hydrocarbons 有权
公开(公告)号：US09932679B2
公开(公告)日：2018-04-03
申请号：US14516934
申请日：2014-10-17
申请人： ExxonMobil Chemical Patents Inc.
发明人： Walter Weissman , Sumathy Raman , Mark A. Greaney
IPC分类号： C25B3/00 , C25B3/04 , C25B15/02 , C07C2/06 , C07C5/03 , C07C29/04 , C08F2/00 , B01D53/32 , C25B3/02 , C25B3/10
CPC分类号： C25B3/04 , B01D53/326 , B01D2257/7022 , C07C2/06 , C07C5/03 , C07C29/04 , C08F2/00 , C25B3/00 , C25B3/02 , C25B3/10 , C25B15/02
摘要： An electrochemical conversion method for converting at least a portion of a first mixture comprising hydrocarbon to C2+ unsaturates by repeatedly applying an electric potential difference, V(τ1), to a first electrode of an electrochemical cell during a first time interval τ1; and reducing the electric potential difference, V(τ1), to a second electric potential difference, V(τ2), for a second time interval τ2, wherein τ2≤τ1. The method is beneficial, among other things, for reducing coke formation in the electrochemical production of C2+ unsaturates in an electrochemical cell. Accordingly, a method of reducing coke formation in the electrochemical conversion of such mixtures and a method for electrochemically converting carbon to C2+ unsaturates as well as an apparatus for such methods are also provided.

6. 发明授权

US09797013B2 Compositions, devices, systems, and methods for using a nanopore 有权
公开(公告)号：US09797013B2
公开(公告)日：2017-10-24
申请号：US15162225
申请日：2016-05-23
申请人： The Regents of the University of California
发明人： Mark A. Akeson , David W. Deamer , Roger Jinteh Arrigo Chen
IPC分类号： C12Q1/68 , G01N33/487 , C25B3/10 , C12Q1/54 , G01N27/327 , G01N27/416
CPC分类号： C12Q1/6874 , C12Q1/54 , C12Q1/6869 , C25B3/10 , G01N27/3278 , G01N27/4166 , G01N33/48721 , C12Q2522/101 , C12Q2565/631
摘要： Devices and methods that can detect and control an individual polymer in a mixture is acted upon by another compound, for example, an enzyme, in a nanopore are provided. The devices and methods also determine (˜>50 Hz) the nucleotide base sequence of a polynucleotide under feedback control or using signals generated by the interactions between the polynucleotide and the nanopore. The invention is of particular use in the fields of molecular biology, structural biology, cell biology, molecular switches, molecular circuits, and molecular computational devices, and the manufacture thereof.

7. 发明授权

US09708722B2 Electrochemical co-production of products with carbon-based reactant feed to anode 有权
公开(公告)号：US09708722B2
公开(公告)日：2017-07-18
申请号：US14463430
申请日：2014-08-19
申请人： Liquid Light, Inc.
发明人： Kyle Teamey , Jerry J. Kaczur
IPC分类号： C25B3/00 , C25B3/02 , C25B3/04 , C25B3/06 , C25B15/08 , C07C51/15 , C07C29/149 , C07C51/02 , C25B1/00 , C25B9/10 , C25B9/08 , C25B1/24 , C07C51/367 , C07C67/08 , C07C1/26 , C07C29/58 , C25B15/00 , C25B13/08 , C25B3/10
CPC分类号： C25B3/00 , C07C1/26 , C07C29/149 , C07C29/58 , C07C51/02 , C07C51/15 , C07C51/367 , C07C67/08 , C25B1/00 , C25B1/24 , C25B3/02 , C25B3/04 , C25B3/06 , C25B3/10 , C25B9/08 , C25B9/10 , C25B13/08 , C25B15/00 , C25B15/08 , Y02P20/127 , Y02P20/132 , Y02P20/133 , Y02P20/582
摘要： The present disclosure is a system and method for producing a first product from a first region of an electrochemical cell having a cathode and a second product from a second region of the electrochemical cell having an anode. The method may include a step of contacting the first region with a catholyte comprising carbon dioxide. The method may include another step of contacting the second region with an anolyte comprising a recycled reactant and at least one of an alkane, haloalkane, alkene, haloalkene, aromatic compound, haloaromatic compound, heteroaromatic compound or halo-heteroaromatic compound. Further, the method may include a step of applying an electrical potential between the anode and the cathode sufficient to produce a first product recoverable from the first region and a second product recoverable from the second region.

8. 发明申请

US20170050910A1 PROCESS FOR PREPARING UNSYMMETRIC OCO PINCER LIGANDS FROM THE GROUP OF THE M-TERPHENYL COMPOUNDS 审中-公开
标题翻译：从M-TERPHENYL化合物组中制备不对称的OCO PINCER配体的方法
公开(公告)号：US20170050910A1
公开(公告)日：2017-02-23
申请号：US15239998
申请日：2016-08-18
申请人： EVONIK DEGUSSA GMBH
发明人： Katrin Marie DYBALLA , Robert FRANKE , Dirk FRIDAG , Siegfried R. WALDVOGEL , Bernd ELSLER , Anton WIEBE , Sebastian LIPS
IPC分类号： C07C43/23 , C07C41/30 , B01J31/02
CPC分类号： C07C43/23 , B01J31/0204 , C25B3/10 , Y02P20/55
摘要： The present invention relates to a process for preparing unsymmetric compounds from the group of the m-terphenyls which can be used as unsymmetric OCO pincer ligands, comprising the process steps of a) reacting a first substituted or unsubstituted phenol with a 1,3-disubstituted arene which may likewise be substituted in the 2 and 5 positions to obtain a phenol-arene coupling product and b) optionally protecting the OH group of the phenol-arene coupling product with a protecting group to obtain a protected phenol-arene coupling product, and c) reacting the phenol-arene coupling product from a) or b) with a second substituted or unsubstituted phenol to obtain an unsymmetric m-terphenyl, with the proviso that the first phenol and the second phenol have different substitution, characterized in that at least one of process steps a) and c) is conducted as an electrochemical process step.
摘要翻译：本发明涉及从可用作不对称OCO钳制配体的间三联苯组中制备不对称化合物的方法，包括以下工艺步骤：a）使第一取代或未取代的苯酚与1,3-二取代的芳烃可以在2和5位同样被取代以获得苯酚 - 芳烃偶联产物，和b）任选地用保护基保护苯酚 - 芳烃偶联产物的OH基团，得到被保护的苯酚 - 芳烃偶联产物，和 c）使来自a）或b）的苯酚 - 芳烃偶联产物与第二取代或未取代的苯酚反应，得到不对称的间三联苯，条件是第一酚和第二酚具有不同的取代，其特征在于至少作为步骤a）和c）之一作为电化学工艺步骤进行。

9. 发明申请

US20160355931A1 Electrochemical Co-Production of Chemicals from Carbon Dioxide Using Sulfur-Based Reactant Feeds to Anode 审中-公开
标题翻译：使用硫基反应物进料到阳极的二氧化碳化学品的电化学共同生产
公开(公告)号：US20160355931A1
公开(公告)日：2016-12-08
申请号：US15089126
申请日：2016-04-01
申请人： Liquid Light, Inc.
发明人： Jerry J. Kaczur , Kyle Teamey
IPC分类号： C25B1/00 , C25B9/10 , C25B15/08 , C25B3/04 , C25B13/08
CPC分类号： C25B3/00 , C07C1/26 , C07C29/149 , C07C29/58 , C07C51/02 , C07C51/15 , C07C51/367 , C07C67/08 , C25B1/00 , C25B1/24 , C25B3/02 , C25B3/04 , C25B3/06 , C25B3/10 , C25B9/08 , C25B9/10 , C25B13/08 , C25B15/00 , C25B15/08 , Y02P20/127 , Y02P20/132 , Y02P20/133 , Y02P20/582
摘要： The present disclosure includes a system and method for producing a first product from a first region of an electrochemical cell having a cathode and a second product from a second region of the electrochemical cell having an anode. The method may include a step of contacting the first region with a catholyte comprising carbon dioxide, producing a first product which may include carbon monoxide or an alkli metal formate. The method may include another step of contacting the second region with an anolyte comprising a sulfur-based reactant and producing a second product including oxygen and sulfur dioxide. Further, the method may include a step for introducing the separated oxygen from second region of the electrochemical cell with a hydrogen sulfide stream in a catalyst reactor bed, converting the hydrogen sulfide to sulfur dioxide. The sulfur dioxide may then be liquefied as a product, or a portion of the sulfur dioxide may be recycled to the second region of the electrochemical cell where it may be converted to sulfuric acid. The sulfuric acid may then be reacted with another reactant, such as ammonia, to produce an ammonium sulfate product.
摘要翻译：本公开包括用于从具有阴极的电化学电池的第一区域产生第一产物的系统和方法，以及来自具有阳极的电化学电池的第二区域的第二产物。该方法可以包括使第一区域与包含二氧化碳的阴极电解液接触的步骤，产生可包括一氧化碳或烷基金属甲酸盐的第一产物。该方法可以包括使第二区域与包含硫基反应物的阳极电解液接触并产生包括氧和二氧化硫的第二产物的另一步骤。此外，该方法可以包括将来自电化学电池的第二区域的分离的氧从催化剂反应器床中的硫化氢流引入到二氧化硫中的步骤。然后二氧化硫可以作为产品液化，或者二氧化硫的一部分可以再循环到电化学电池的第二区域，在那里它可以被转化成硫酸。然后可以将硫酸与另一种反应物如氨反应产生硫酸铵产物。

10. 发明申请

US20160354751A1 Neutralization and Containment of Redox Species Produced by Circumferential Electrodes 审中-公开
标题翻译：由环形电极产生的氧化还原物质的中和遏制
公开(公告)号：US20160354751A1
公开(公告)日：2016-12-08
申请号：US15208606
申请日：2016-07-13
申请人： CUSTOMARRAY, INC.
发明人： Karl Maurer , John J Cooper, Jr. , H Sho Fujii , Joseph Leonetti
IPC分类号： B01J19/00 , C25B9/06 , C25B3/10
CPC分类号： B01J19/0046 , B01J2219/00527 , B01J2219/00529 , B01J2219/00576 , B01J2219/00585 , B01J2219/00596 , B01J2219/00641 , B01J2219/00653 , B01J2219/00659 , B01J2219/00675 , B01J2219/00713 , B01J2219/00722 , B01J2219/00725 , B01J2219/00731 , B01J2219/00736 , B82Y30/00 , C25B3/10 , C25B9/06 , C25B11/02
摘要： There is disclosed an electrode array architecture employing continuous and discontinuous circumferential electrodes. There is further disclosed a process for the neutralization of acid generated at anode(s) by base generated at cathode(s) circumferentially located to each other so as to confine a region of pH change. The cathodes can be displayed as concentric rings (continuous) or as counter electrodes in a cross pattern (discontinuous). In this way reagents, such as acid, generated in a center electrode are countered (neutralized) by reagents, such as base, generated at the corners or at the outer ring.
摘要翻译：公开了采用连续和不连续周向电极的电极阵列结构。进一步公开了一种通过在阳极周围定位的基底产生的阳极中和阳离子的方法，以便限制pH变化的区域。阴极可以显示为同心环（连续）或以交叉图案（不连续）显示为对电极。以这种方式，在中心电极中产生的诸如酸的试剂如在拐角处或外环处产生的试剂（例如碱）被抵消（中和）。

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