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    • 6. 发明授权
    • Stable electrochromic module
    • 稳定的电致变色模块
    • US09535304B2
    • 2017-01-03
    • US14849476
    • 2015-09-09
    • Thueringisches Institut Fuer Textil- Und Kunststoff-Forschung E.V.
    • Gulnara KonkinMario SchrödnerHannes SchacheBernd Dawczynski
    • G02F1/15
    • G02F1/1521G02F1/15G02F2001/1515G02F2001/1519
    • Electrochromic module including first and second substrates is provided in which the first and/or second substrate are/is electrically conductive or are/is equipped with an electrically conductive coating. A first electrochromic polymer coating is arranged on the first substrate or the conductive coating, an ion-storage or charge-compensating layer is arranged on the second substrate or the conductive coating, and a polymer gel electrolyte is disposed between the electrochromic coating and the ion-storage or charge-compensating layer. The electrochromic polymer, a polymer of tetraarylbenzidine and (hetero)aromatic diol, is colorless in one redox state and colored in at least two redox states. The ion-storage or charge-compensating layer is formed from material selected from the group comprising cerium oxide, titanium oxide, tungsten oxide, nickel oxide, molybdenum oxide, vanadium oxide and mixtures thereof or redox-active polymer. The inventive modules achieve a large number of switching cycles, a high electrochromic contrast and a high electrochromic efficiency.
    • 提供包括第一和第二基板的电致变色模块,其中第一和/或第二基板是导电的或者配备有导电涂层。 第一电致变色聚合物涂层布置在第一衬底或导电涂层上,在第二衬底或导电涂层上布置离子存储或电荷补偿层,并且在电致变色涂层和离子之间设置聚合物凝胶电解质 储存或电荷补偿层。 电致变色聚合物,四芳基联苯胺和(杂)芳族二醇的聚合物在一种氧化还原状态下是无色的,并且在至少两种氧化还原状态下着色。 离子存储或电荷补偿层由选自氧化铈,氧化钛,氧化钨,氧化镍,氧化钼,氧化钒及其混合物或氧化还原活性聚合物的材料形成。 本发明的模块实现了大量的开关周期,高的电致变色对比度和高的电致变色效率。
    • 7. 发明授权
    • Electronically switchable privacy device
    • 电子切换隐私设备
    • US09500888B2
    • 2016-11-22
    • US14772246
    • 2014-03-07
    • 3M INNOVATIVE PROPERTIES COMPANY
    • Evan L. SchwartzMark J. PelleriteEncai HaoMichael L. Steiner
    • G02B26/00G02F1/00G02B26/08G02F1/29G02F1/13G02B26/02G02F1/15G02F1/161G02F1/163G02F1/155
    • G02F1/1323G02B26/02G02F1/1521G02F1/161G02F1/163G02F2001/1557
    • An electronically switchable privacy device suitable for use in display devices is described. The electronically switchable privacy device comprises a first transparent electrode layer, an electronically switchable layer disposed adjacent to the first transparent electrode layer, and a second transparent electrode layer disposed adjacent to the electronically switchable layer and opposite the first transparent electrode layer. The second transparent electrode layer comprises a transparent substrate layer having a plurality of microstructured ribs extending across a major surface of the transparent substrate layer such that the microstructured ribs form an alternating series of ribs and channels, each channel having channel walls defined by adjacent ribs. A plurality of transparent electrode members comprising a transparent electrode material are disposed on at least one channel wall in a corresponding plurality of the channels; and a bus member provides electrical connectivity across the plurality of transparent electrode members. A spacer element disposed in the electronically switchable layer keeps the first transparent electrode layer spaced apart from the second transparent electrode layer. A portion of the electronically switchable layer at least partially fills the plurality of channels and makes electrical contact with the plurality of transparent electrode members. The electronically switchable layer comprises an electronically switchable material capable of modulation between high and low light absorption states upon application of a direct current voltage across the first and second transparent electrode layers.
    • 描述适用于显示装置的可电切换隐私装置。 电子可切换隐私装置包括第一透明电极层,与第一透明电极层相邻布置的电子可切换层以及与电子可切换层相邻并与第一透明电极层相对设置的第二透明电极层。 第二透明电极层包括透明衬底层,透明衬底层具有延伸穿过透明衬底层的主表面的多个微结构肋,使得微结构肋形成交替的一系列肋和通道,每个沟道具有由相邻肋限定的通道壁。 包括透明电极材料的多个透明电极构件设置在相应的多个通道中的至少一个通道壁上; 并且总线构件提供穿过多个透明电极构件的电连接。 设置在电子可切换层中的间隔元件使第一透明电极层与第二透明电极层间隔开。 电子可切换层的一部分至少部分地填充多个通道并与多个透明电极构件电接触。 电子可切换层包括能够在施加直流电压跨越第一和第二透明电极层时在高光和低光吸收状态之间进行调制的电子可切换材料。