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    • 1. 发明授权
    • Method for binding compounds to textiles
    • 将化合物与纺织品结合的方法
    • US07785376B1
    • 2010-08-31
    • US12273882
    • 2008-11-19
    • David T. ChunGary R. Gamble
    • David T. ChunGary R. Gamble
    • D06P1/38
    • D06M16/00A01N43/54A01N43/80Y10S8/916Y10S8/92A01N25/10A01N2300/00
    • A method to bind compounds (e.g., antibiotics) to natural or synthetic yarn or fabric, involving reacting the compounds with cyanuric chloride, a hydroxide base (e.g., NaOH), and deionized water to form reactive compounds; forming a dyebath composed of the reactive compounds, at least one nonioinic, cationic or anionic surfactant, salt (e.g., sodium sulfate), deionized water, and natural or synthetic yarn or fabric; heating the dyebath (generally for about 1 to about 100 minutes at a temperature of about 25° to about 100° C.); adding a hydroxide base (e.g., NaOH) to the dyebath and heating (generally for about 1 to about 100 at a temperature of about 80° to about 100° C.); rinsing the natural or synthetic yarn or fabric; placing the natural or synthetic yarn or fabric in deionized water and heating (generally for about 1 to about 100 minutes at a temperature of about 25° to about 100° C.); rinsing the natural or synthetic yarn or fabric; and drying the natural or synthetic yarn or fabric. Also natural or synthetic yarn or fabric bound to antibiotics prepared by the method are disclosed herein.
    • 将化合物(例如抗生素)与天然或合成纱或织物结合的方法,包括使化合物与氰尿酰氯,氢氧化物碱(例如NaOH)和去离子水反应以形成反应性化合物; 形成由反应性化合物,至少一种非碘,阳离子或阴离子表面活性剂,盐(例如硫酸钠),去离子水和天然或合成纱线或织物组成的染浴; 加热染浴(在约25℃至约100℃的温度下通常约1至约100分钟); 向染浴中加入氢氧化物碱(例如NaOH)并加热(通常在约80℃至约100℃的温度下约1至约100℃); 冲洗天然或合成纱线或织物; 将天然或合成纱线或织物放置在去离子水中并加热(通常在约25℃至约100℃的温度下约1至约100分钟); 冲洗天然或合成纱线或织物; 并干燥天然或合成纱线或织物。 本文公开了通过该方法制备的与抗生素结合的天然或合成纱线或织物。
    • 5. 发明授权
    • Azo dyes, a process for their preparation and their use in the dyeing or printing of hydrophobic fiber materials
    • 偶氮染料,其制备方法及其在染色或印刷疏水性纤维材料中的应用
    • US07005507B2
    • 2006-02-28
    • US10470039
    • 2002-01-18
    • Yvonne PichlerUrs Lauk
    • Yvonne PichlerUrs Lauk
    • C09B29/42D06P1/18
    • C09B67/0051C09B29/0059C09B29/3639Y10S8/92
    • The present invention relates to an azo dye of formula (1), wherein R1 is the radical of a diazo component of the benzene, naphthalene, diphenyl, azobenzene, thiophene, benzothiazole, thiadiazole, indazole, benzatriazole, pyrazole, anthraquinone, naphtholic acid imide, chromone, phthalimide or diphenylene oxide series, R2 is an unsubstitued or substitued aryl radical or an unsubstituted or substituted aralkyl radical and R3 is an unsubstituted or substituted aryl radical or an unsubstituted or substituted aralkyl radical, with the proviso that one of the substituents R2 and R3 is an unsubstituted or substituted aryl radical and the other is an unsubstituted or substituted aralkyl radical, 2-hydroxy-2-phenylethyl being expected as a substituted aralkyl radical, to mixtures comprising at least two structually different azo dyes of formula (1) and to the use of those azo dyes and dye mixtures in the dyeing or printing of semi-synthetic or synthetic hydrophobic fibre materials.
    • 本发明涉及式(1)的偶氮染料,其中R 1是苯,萘,二苯基,偶氮苯,噻吩,苯并噻唑,噻二唑,吲唑,苯并三唑的重氮组分的基团 吡唑,蒽醌,萘甲酰亚胺,色酮,邻苯二甲酰亚胺或二苯醚系列,R 2是未取代的或取代的芳基或未取代或取代的芳烷基,R 3' 是未取代或取代的芳基或未取代或取代的芳烷基,条件是取代基R 2和R 3中的一个是未取代或取代的芳基, 另一个是未取代或取代的芳烷基,预期为取代的芳烷基的2-羟基-2-苯乙基与包含至少两种结构不同的式(1)的偶氮染料的混合物和使用那些偶氮染料和染料 半合成染色或印刷中的混合物 c或合成疏水纤维材料。
    • 6. 发明申请
    • Azo dyes, a process for their preparation and their use in the dyeing or printing of hydrophobic fibre materials
    • 偶氮染料,其制备方法及其在染色或印刷疏水性纤维材料中的应用
    • US20040055097A1
    • 2004-03-25
    • US10470039
    • 2003-07-23
    • Yvonne PichlerUrs Lauk
    • D06P005/12
    • C09B67/0051C09B29/0059C09B29/3639Y10S8/92
    • The present invention relates to an azo dye of formula (1), wherein R1 is the radical of a diazo component of the benzene, naphthalene, diphenyl, azobenzene, thiophene, benzothiazole, thiadiazole, indazole, benzatriazole, pyrazole, anthraquinone, naphtholic acid imide, chromone, phthalimide or diphenylene oxide series, R2 is an unsubstitued or substitued aryl radical or an unsubstituted or substituted aralkyl radical and R3 is an unsubstituted or substituted aryl radical or an unsubstituted or substituted aralkyl radical, with the proviso that one of the substituents R2 and R3 is an unsubstituted or substituted aryl radical and the other is an unsubstituted or substituted aralkyl radical, 2-hydroxy-2-phenylethyl being expected as a substituted aralkyl radical, to mixtures comprising at least two structually different azo dyes of formula (1) and to the use of those azo dyes and dye mixtures in the dyeing or printing of semi-synthetic or synthetic hydrophobic fibre materials.
    • 本发明涉及式(1)的偶氮染料,其中R1是苯,萘,二苯基,偶氮苯,噻吩,苯并噻唑,噻二唑,吲唑,苯并三唑,吡唑,蒽醌,萘甲酰亚胺的重氮组分的基团 ,色酮,邻苯二甲酰亚胺或二苯醚系列,R2是未取代或取代的芳基或未取代或取代的芳烷基,R3是未取代或取代的芳基或未取代或取代的芳烷基,条件是取代基R2 并且R3是未取代或取代的芳基,另一个是未取代或取代的芳烷基,作为取代的芳烷基的2-羟基-2-苯基乙基与包含至少两种结构上不同的式(1)的偶氮染料的混合物, 以及在半合成或合成疏水纤维材料的染色或印刷中使用那些偶氮染料和染料混合物。
    • 7. 发明授权
    • Aminated acetate fiber
    • 氨基醋酸纤维
    • US5981741A
    • 1999-11-09
    • US63162
    • 1998-04-20
    • Andreas SchrellJimmy G. Welborn
    • Andreas SchrellJimmy G. Welborn
    • C08B15/00C08B31/16D01F1/10D01F2/28C08B3/06D06M11/00D06M13/00
    • D01F1/10C08B31/16D01F2/28Y10S8/92Y10S8/921
    • Disclosed are aminated acetate fiber comprising acetylcellulose and one or more water-insoluble quaternary starch ether esters, said starch ether esters containing ester groups of formulae --O--CO--CH.sub.3 and/or --O--CO--C.sub.2 H.sub.5 and ether groups of the general formula I--O--CH.sub.2 --X--CH.sub.2 --N.sup.+ R.sub.3 A.sup.- (I)whereX is a direct bond or --CH(OH)-- andA.sup.- is an anion or one equivalent of an anion, andR is hydrogen, methyl and/or ethyl,and the degree of substitution of said ether group being within the range from 0.002 to 0.8, the degree of substitution of said ester group being within the range from 0.7 to 2.998 and the overall degree of substitution being within the range from 1.5 to 3, its preparation and its use and also quaternary starch ether esters present therein.
    • 公开了包含乙酰纤维素和一种或多种水不溶性季淀粉醚酯的胺化醋酸纤维素,所述淀粉醚酯含有式-O-CO-CH 3和/或-O-CO-C 2 H 5的酯基和通式 I-O-CH2-X-CH2-N + R3A-(I)其中X是直接键或-CH(OH) - ,A-是阴离子或一当量阴离子,R是氢,甲基和 /或乙基,所述醚基的取代度在0.002〜0.8的范围内,所述酯基的取代度在0.7〜2.998的范围内,总的取代度在1.5以下的范围内 至3,其制备及其用途以及其中存在的季铵淀粉醚酯。
    • 10. 发明授权
    • Multicoloring polyester textile materials with acid dyes
    • 多色聚酯纺织材料与酸性染料
    • US3989453A
    • 1976-11-02
    • US432645
    • 1974-01-11
    • Dara Ardeshir Jilla
    • Dara Ardeshir Jilla
    • D06P5/00D06P1/38D06P1/62D06P3/52D06P5/12D06B21/00C09B27/00
    • D06P5/12D06P1/38D06P1/625D06P3/521Y10S8/92Y10S8/929
    • A process is disclosed for making a multicolored polyester material dyed with acid dyes for use as the face yarn of carpets, upholstery and apparel fabrics, which comprises treating a polyester material having an affinity for acid dyes with an aqueous solution or a printing paste of (A) a condensation product of (a) formaldehyde and (b) naphthalenesulfonic acid, phenol, sulfonated phenol, diaryl sulfone, urea, melamine, or dicyandiamide; and (B) a reactive or fiber-reactive compound which contains a chromophore, preferably but not necessarily colorless, and has attached to it a reactive group, which reacts readily with a nitrogen atom of the above-mentioned modified polyester material having an affinity for acid dyes, and then exposing same to steam or dry heat at a temperature between 100.degree. C. and 200.degree. C. for a period of 20 seconds to 20 minutes, thereby imparting to the treated polyester material ability to "resist" acid type dyes, so that the localized regions of the polyester material pre-treated with the above-mentioned impregnation-treatment will now "resist" acid dyestuffs applied later in the dyeing process whereby no coloration or coloration to a much lower depth is produced in the treated regions whereas very strong, bright and uniform coloration is produced due to acid dyes in the localized regions which were not pre-treated; thus resulting in a selective, multicoloration of the polyester material in a predetermined manner.The resulting acid-dyed multicolored polyester material is also described and claimed.
    • 公开了一种制造用酸性染料染色的多色聚酯材料用作地毯,室内装潢和服装织物的面纱的方法,该方法包括用水溶液或印刷糊剂处理对酸性染料具有亲和性的聚酯材料( A)(a)甲醛和(b)萘磺酸,苯酚,磺化苯酚,二芳基砜,脲,三聚氰胺或双氰胺的缩合产物; 和(B)反应性或纤维反应性化合物,其包含发色团,优选但不一定是无色的,并且与其连接的反应性基团,其容易与上述具有亲和力的改性聚酯材料的氮原子反应 酸性染料,然后在100〜200℃的温度下将其暴露于蒸汽或干热20秒〜20分钟的时间,由此赋予经处理的聚酯材料“抵抗”酸性染料的能力 ,使得通过上述浸渍处理预处理的聚酯材料的局部区域现在将“抗拒”在染色过程中稍后施加的酸性染料,由此在处理区域中不产生明显更低深度的着色或着色 而由于未经预处理的局部区域中的酸性染料,产生非常强烈,明亮和均匀的着色; 从而以预定的方式导致聚酯材料的选择性多色化。