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    • 7. 发明授权
    • Optical glass, optical element, and method for manufacturing optical glass
    • 光学玻璃,光学元件和制造光学玻璃的方法
    • US09040439B2
    • 2015-05-26
    • US14190387
    • 2014-02-26
    • THE UNIVERSITY OF TOKYOCANON KABUSHIKI KAISHA
    • Michio EndoShingo EguchiHiroyuki InoueAtsunobu Masuno
    • C03C3/15C03C3/155C03C3/068C03B19/00C03C3/253C03B40/04C03B19/10
    • C03C3/253C03B19/00C03B19/1035C03B19/1055C03B40/04C03B2215/48C03C3/068C03C3/15C03C3/155
    • An optical glass including B3+, La3+ and Nb5+ as cationic components constituting the glass, wherein the optical glass satisfies the following expressions represented in cation percentages: 10 cat. %≦B3+≦50 cat. %; 40 cat. %≦La3+≦65 cat. %; 0 cat. %≦Nb5+≦40 cat. %; 80 cat. %≦(total amount of B3++La3++Nb5+)≦100 cat. %; and 0 cat. %≦Si4+≦10 cat. %; 0 cat. %≦Ge4+≦5 cat. %; 0 cat. %≦Mg2+≦5 cat. %; 0 cat. %≦Ba2+≦10 cat. %; 0 cat. %≦Ca2+≦10 cat. %; 0 cat. %≦Sr2+≦10 cat. %; 0 cat. %≦Zn2+≦20 cat. %; 0 cat. %≦W6+≦5 cat. %; 0 cat. %≦Zr4+≦5 cat. %; 0 cat. %≦Ti4+≦5 cat. %; 0 cat. %≦Bi3+≦5 cat. %; 0 cat. %≦Ta5+≦10 cat. %; 0 cat. %≦(total amount of Y3++Gd3+)≦20 cat. %; and 0 cat. %≦(total amount of Yb3++Lu3+)≦10 cat. %.
    • 包含构成玻璃的阳离子成分的B3 +,La3 +,Nb5 +的光学玻璃,其中,所述光学玻璃的阳离子比例为10mA。 %≦̸ B3 +≦̸ 50猫 %; 40猫 %≦̸ La3 +≦̸ 65猫。 %; 0猫 %≦̸ Nb5 +≦̸ 40只猫。 %; 80猫 %≦̸(B3 ++ La3 ++ Nb5 +的总量)≦̸ 100只猫。 %; 和0猫。 %≦̸ Si4 +≦̸ 10只猫。 %; 0猫 %≦̸ Ge4 +≦̸ 5只猫。 %; 0猫 %≦̸ Mg2 +≦̸ 5只猫。 %; 0猫 %≦̸ Ba2 +≦̸ 10只猫 %; 0猫 %≦̸ Ca2 +≦̸ 10只猫。 %; 0猫 %≦̸ Sr2 +≦̸ 10只猫 %; 0猫 %≦̸ Zn2 +≦̸ 20只猫。 %; 0猫 %≦̸ W6 +≦̸ 5只猫。 %; 0猫 %≦̸ Zr4 +≦̸ 5只猫。 %; 0猫 %≦̸ Ti4 +≦̸ 5只猫 %; 0猫 %≦̸ Bi3 +≦̸ 5只猫。 %; 0猫 %≦̸ Ta5 +≦̸ 10只猫 %; 0猫 %≦̸(Y3 + + Gd3 +总量)≦̸ 20只猫。 %; 和0猫。 %≦̸(Yb3 ++ Lu3 +的总量)≦̸ 10只猫。 %。
    • 9. 发明授权
    • Optical glass for mold press forming
    • 用于模压成型的光学玻璃
    • US08951926B2
    • 2015-02-10
    • US14055929
    • 2013-10-17
    • Nippon Electric Glass Co., Ltd.
    • Takahiro MatanoFumio SatoYoko Usui
    • C03C3/14C03C3/064C03C4/02C03C3/15C03C3/155C03C3/253
    • C03C4/02C03C3/14C03C3/15C03C3/155C03C3/253
    • The invention provides an optical glass for press molding which can satisfy all of the following requirements: (1) it contains no environmentally undesirable components; (2) it can easily achieve a low glass transition point; (3) it has a high refractive index and high dispersion; (4) it can easily provide a glass having an excellent visible light transmittance; and (5) it has excellent resistance to devitrification during preparation of a preform. The optical glass for press molding has a refractive index nd of 1.925 or more, an Abbe's number νd of 10 to 30, and a glass composition, in % by mass, of 20 to 80% Bi2O3, 10 to 30% B2O3, and 0 to 5.5% GeO2 and is substantially free of lead component, arsenic component, and F component.
    • 本发明提供了一种用于压制成型的光学玻璃,其可以满足以下所有要求:(1)其不含环境不理想的组分; (2)可以轻松实现低玻璃化转变点; (3)折射率高,色散高; (4)可以容易地提供具有优异的可见光透射率的玻璃; 和(5)在制备预成型件时具有优异的耐失透性。 用于压制成形的光学玻璃的折射率nd为1.925以上,阿贝数n为10〜30,玻璃组合物的质量%为20〜80%Bi 2 O 3,10〜30%B 2 O 3, 和0〜5.5%的GeO 2,并且基本上不含铅成分,砷成分和F成分。
    • 10. 发明授权
    • Optical glass, preform for precision press molding, optical element and method of manufacturing thereof
    • 光学玻璃,精密加压成型用预成型体,光学元件及其制造方法
    • US08748328B2
    • 2014-06-10
    • US13652693
    • 2012-10-16
    • Yasuhiro Fujiwara
    • Yasuhiro Fujiwara
    • C03C3/15C03C3/155C03C3/068C03C3/066
    • C03C3/068C03B2215/50
    • An optical glass having a refractive index nd of 1.70 or greater and an Abbé number of 50 or greater. Given as mole percentages, it comprises: B2O3 (20 to 80 percent), SiO2 (0 to 30 percent), Li2O (1 to 25 percent), ZnO (0 to 20 percent), La2O3 (4 to 30 percent), Gd2O3 (1 to 25 percent), Y2O3 (0 to 20 percent), ZrO2 (0 to 5 percent), MgO (0 to 25 percent), CaO (0 to 15 percent), and SrO (0 to 10 percent), with the combined quantity of the above components being 97 percent or greater. The molar ratio of {ZnO/(La2O3+Gd2O3+Y2O3)} is 0.8 or less and the molar ratio of {(CaO+SrO+BaO)/(La2O3+Gd2O3+Y2O3)} is 0.8 or less. Ta2O5 may be incorporated as an optional component, with the molar ratio {(ZrO2+Ta2O5)/(La2O3+Gd2O3+Y2O3)} being 0.4 or less.
    • 折射率nd为1.70以上,Abbé数为50以上的光学玻璃。 以百分比计,B2O3(20-80%),SiO2(0-30%),Li2O(1%至25%),ZnO(0-20%),La2O3(4-30%),Gd2O3 1〜25%),Y2O3(0〜20%),ZrO2(0〜5%),MgO(0〜25%),CaO(0〜15%)和SrO(0〜10% 上述成分的量为97%以上。 {ZnO /(La 2 O 3 + Gd 2 O 3 + Y 2 O 3)}的摩尔比为0.8以下,{(CaO + SrO + BaO)/(La2O3 + Gd2O3 + Y2O3)}的摩尔比为0.8以下。 Ta2O5可以以((ZrO 2 + Ta 2 O 5)/(La 2 O 3 + Gd 2 O 3 + Y 2 O 3)}的摩尔比为0.4以下的任意成分结合。