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1. 发明申请

US20190315728A1 PROCESS FOR THE PREPARATION OF THIETANE DERIVATIVES 审中-公开
公开(公告)号：US20190315728A1
公开(公告)日：2019-10-17
申请号：US16389116
申请日：2019-04-19
申请人： Syngenta Participations AG
发明人： Jerome Yves CASSAYRE , Peter RENOLD , Thomas PITTERNA , Myriem EL QACEMI
IPC分类号： C07D413/12 , C07D409/12 , A01N43/36 , A01N43/80 , C07D331/04
摘要： The present invention relates to processes for the preparation of thietane derivatives of the formula IA and thietane derivatives of the formula IB wherein R1, R2, A1, A2, A3, A4, B, and n are as defined in the claims. The invention also relates to intermediates useful in the processes, as well as the compounds of formula IA and IB and their use as pesticides.

2. 发明授权

US10051861B2 N-arylamidine-substituted trifluoroethyl sulfide derivatives as acaricides and insecticides 有权
公开(公告)号：US10051861B2
公开(公告)日：2018-08-21
申请号：US15349297
申请日：2016-11-11
申请人： BAYER CROPSCIENCE AG , BAYER INTELLECTUAL PROPERTY GMBH
发明人： Adeline Koehler , Bernd Alig , Angela Becker , Arnd Voerste , Ulrich Goergens , Reiner Fischer , Wahed Ahmed Moradi , Silvia Cerezo-Galvez , Julia Johanna Hahn , Kerstin Ilg , Hans-Georg Schwarz , Takuya Gomibuchi , Masahito Ito , Daiei Yamazaki , Katsuhiko Shibuya , Eiichi Shimojo
IPC分类号： C07D207/22 , C07D207/34 , C07D211/38 , C07D211/72 , C07D211/98 , C07D239/28 , C07D241/24 , C07D263/28 , C07D277/16 , C07D277/18 , C07D277/38 , C07D277/54 , C07D279/06 , C07D285/08 , C07D295/125 , C07D295/13 , C07D305/08 , C07D307/24 , C07D307/68 , C07D331/04 , C07D333/38 , C07D333/48 , C07D401/06 , A01N41/10 , A01N41/12 , A01N43/40 , C07C323/36 , C07C323/44 , C07D213/78 , C07C317/40 , C07C323/41 , C07C335/16 , C07D213/61 , A01N43/08 , A01N43/10 , A01N43/36 , A01N43/60 , A01N43/84 , A01N43/86 , C07C315/02 , C07C317/34 , C07C319/20 , C07C323/45 , C07C319/14
摘要： The present invention relates to novel N-arylamide-substituted trifluoroethyl sulfide derivatives of the formula (I) in which X1, X2, X3, X4, R1, R2, R3, n have the meanings given in the description—to their use as acaricides and insecticides for controlling animal pests and to processes and intermediates for their preparation.

3. 发明授权

US09795139B2 Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto 有权
公开(公告)号：US09795139B2
公开(公告)日：2017-10-24
申请号：US15092641
申请日：2016-04-07
申请人： Dow AgroSciences LLC
发明人： Joseph D. Eckelbarger , Daniel I. Knueppel , Ronald J. Heemstra , Ronald Ross, Jr. , Kyle A. Dekorver , Kaitlyn Gray , Peter Vednor , Timothy P. Martin , Ricky Hunter , David A. Demeter , Tony K. Trullinger , Erich Baum , Zoltan L. Benko , Nakyen Choy , Gary Crouse , John F. Daeuble, Sr. , Fangzheng Li , Jeff Nissen , Michelle Riener , Tom Sparks , Frank Wessels , Maurice Yap
IPC分类号： A01N53/00 , A01N43/90 , C07D207/273 , A01N43/82 , C07D307/33 , C07D277/36 , C07D263/26 , C07D261/12 , C07D333/48 , C07D307/52 , C07D277/30 , C07D213/56 , C07C237/22 , C07D333/60 , C07D233/80 , C07D487/04 , A01N43/707 , A01N43/653 , A01N43/60 , A01N43/40 , A01N41/10 , A01N37/34 , A01N37/22 , C07D253/07 , C07D241/20 , C07C317/14 , C07C233/65 , C07C233/63 , C07D209/49 , C07C381/10 , C07D205/04 , C07C237/42 , C07D207/10 , C07D207/452 , C07C255/29 , C07C255/57 , C07D285/06 , C07D295/32 , C07D305/08 , C07C255/46 , C07D213/75 , C07C255/60 , C07C259/10 , C07D213/81 , C07D213/84 , C07D309/14 , C07D213/89 , C07D215/227 , C07C271/28 , C07C271/66 , C07D215/38 , C07D231/12 , C07D331/04 , C07D231/56 , C07D333/36 , C07D233/36 , C07C311/08 , C07C311/46 , C07D235/30 , C07C317/28 , C07C317/40 , C07C317/50 , C07C323/41 , C07C323/42 , C07C323/59 , C07D249/08 , C07C331/12
CPC分类号： A01N53/00 , A01N37/22 , A01N37/34 , A01N41/10 , A01N43/40 , A01N43/60 , A01N43/653 , A01N43/707 , A01N43/82 , A01N43/90 , C07C233/63 , C07C233/65 , C07C237/22 , C07C237/42 , C07C255/29 , C07C255/46 , C07C255/57 , C07C255/60 , C07C259/10 , C07C271/28 , C07C271/66 , C07C311/08 , C07C311/46 , C07C317/14 , C07C317/28 , C07C317/40 , C07C317/50 , C07C323/41 , C07C323/42 , C07C323/59 , C07C331/12 , C07C381/10 , C07C2601/02 , C07C2601/04 , C07C2601/08 , C07C2601/14 , C07D205/04 , C07D207/10 , C07D207/273 , C07D207/452 , C07D209/49 , C07D213/56 , C07D213/75 , C07D213/81 , C07D213/84 , C07D213/89 , C07D215/227 , C07D215/38 , C07D231/12 , C07D231/56 , C07D233/36 , C07D233/80 , C07D235/30 , C07D241/20 , C07D249/08 , C07D253/07 , C07D261/12 , C07D263/26 , C07D277/30 , C07D277/36 , C07D285/06 , C07D295/32 , C07D305/08 , C07D307/33 , C07D307/52 , C07D309/14 , C07D331/04 , C07D333/36 , C07D333/48 , C07D333/60 , C07D487/04
摘要： This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

4. 发明申请

US20170247361A1 PROCESS FOR THE PREPARATION OF THIETANE DERIVATIVES 审中-公开
公开(公告)号：US20170247361A1
公开(公告)日：2017-08-31
申请号：US15596766
申请日：2017-05-16
申请人： Jerome Yves CASSAYRE , Peter RENOLD , Thomas PITTERNA , Myriem EL QACEMI
发明人： Jerome Yves CASSAYRE , Peter RENOLD , Thomas PITTERNA , Myriem EL QACEMI
IPC分类号： C07D413/12 , A01N43/80 , C07D331/04
CPC分类号： C07D413/12 , A01N43/36 , A01N43/80 , C07D331/04 , C07D409/12
摘要： The present invention relates to processes for the preparation of thietane derivatives of the formula IA and thietane derivatives of the formula IB wherein R1, R2, A1, A2, A3, A4, B, and n are as defined in the claims. The invention also relates to intermediates useful in the processes, as well as the compounds of formula IA and IB and their use as pesticides.

5. 发明申请

US20170208805A1 MOLECULES HAVING PESTICIDAL UTILITY, AND INTERMEDIATES, COMPOSITIONS, AND PROCESSES, RELATED THERETO 有权
公开(公告)号：US20170208805A1
公开(公告)日：2017-07-27
申请号：US15408634
申请日：2017-01-18
申请人： Dow AgroSciences LLC
发明人： Thomas Barton , Xin Gao , Jim Hunter , Paul R. LePlae, JR. , Lori K. Lawler , William C. Lo , Jeff Petkus , Joshodeep Boruwa , Raghuram Tangirala , Gerald B. Watson , John Herbert
IPC分类号： A01N37/20 , A01N37/18 , C07D207/06 , C07D331/04 , C07D213/61 , A01N43/40 , C07D213/75 , A01N43/20 , C07C233/65 , A01N43/36
CPC分类号： A01N37/20 , A01N29/12 , A01N31/04 , A01N33/04 , A01N35/04 , A01N37/10 , A01N37/18 , A01N37/26 , A01N43/20 , A01N43/36 , A01N43/40 , A01N53/00 , C07C233/65 , C07C233/66 , C07C233/73 , C07C233/78 , C07C251/28 , C07C251/38 , C07C255/46 , C07C257/20 , C07C259/14 , C07C327/48 , C07C2601/02 , C07C2601/04 , C07C2601/14 , C07D207/06 , C07D213/61 , C07D213/75 , C07D331/04
摘要： This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, compositions containing such molecules, and processes of using such molecules and compositions against such pests. These molecules and compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

6. 发明授权

US09642363B2 N-arylamidine-substituted trifluoroethyl sulfide derivatives as acaricides and insecticides 有权
公开(公告)号：US09642363B2
公开(公告)日：2017-05-09
申请号：US14366715
申请日：2012-12-12
申请人： BAYER CROPSCIENCE AG , BAYER INTELLECTUAL PROPERTY GMBH
发明人： Adeline Koehler , Bernd Alig , Angela Becker , Arnd Voerste , Ulrich Goergens , Reiner Fischer , Wahed Ahmed Moradi , Silvia Cerezo-Galvez , Julia Johanna Hahn , Kerstin Ilg , Hans-Georg Schwarz , Takuya Gomibuchi , Masahito Ito , Daiei Yamazaki , Katsuhiko Shibuya , Eiichi Shimojo
IPC分类号： C07D207/22 , C07D207/34 , C07D211/38 , C07D211/72 , C07D213/61 , C07D213/78 , C07D239/28 , C07D241/24 , C07D263/28 , C07D277/18 , C07D279/06 , C07D285/08 , C07D295/125 , A01N41/10 , A01N41/12 , A01N43/40 , C07C323/36 , C07C323/44 , C07D331/04 , C07D333/38 , C07D333/48 , C07C317/40 , C07C323/41 , C07C335/16 , C07D305/08 , C07D307/24 , C07D307/68 , A01N43/08 , A01N43/10 , A01N43/36 , A01N43/60 , A01N43/84 , A01N43/86 , C07C315/02 , C07C317/34 , C07C319/20 , C07C323/45
CPC分类号： A01N41/10 , A01N41/12 , A01N43/08 , A01N43/10 , A01N43/36 , A01N43/40 , A01N43/60 , A01N43/84 , A01N43/86 , C07C315/02 , C07C317/34 , C07C317/40 , C07C319/14 , C07C319/20 , C07C323/36 , C07C323/41 , C07C323/44 , C07C323/45 , C07C335/16 , C07C2601/02 , C07C2601/04 , C07C2601/08 , C07C2601/14 , C07D207/22 , C07D207/34 , C07D211/38 , C07D211/72 , C07D211/98 , C07D213/61 , C07D213/78 , C07D239/28 , C07D241/24 , C07D263/28 , C07D277/16 , C07D277/18 , C07D277/38 , C07D277/54 , C07D279/06 , C07D285/08 , C07D295/125 , C07D295/13 , C07D305/08 , C07D307/24 , C07D307/68 , C07D331/04 , C07D333/38 , C07D333/48 , C07D401/06
摘要： The present invention relates to novel N-arylamide-substituted trifluoroethyl sulfide derivatives of the formula (I) in which X1, X2, X3, X4, R1, R2, R3, n have the meanings given in the description—to their use as acaricides and insecticides for controlling animal pests and to processes and intermediates for their preparation.

7. 发明申请

US20160302417A1 Molecules Having Pesticidal Utility, and Intermediates, Compositions, and Processes, Related Thereto 有权
标题翻译：具有杀虫效用的分子，以及与之相关的中间体，组合物和方法
公开(公告)号：US20160302417A1
公开(公告)日：2016-10-20
申请号：US15092641
申请日：2016-04-07
申请人： Dow AgroSciences LLC
发明人： Joseph D. Eckelbarger , Daniel I. Knueppel , Ronald J. Heemstra , Ronald Ross, JR. , Kyle A. DeKorver , Kaitlyn Gray , Peter Vednor , Timothy P. Martin , Ricky Hunter , David A. Demeter , Tony K. Trullinger , Erich Baum , Zoltan L. Benko , Nakyen Choy , Gary Crouse , John F. Daeuble, SR. , Fangzheng Li , Jeff Nissen , Michelle Riener , Tom Sparks , Frank Wessels , Maurice Yap
IPC分类号： A01N53/00 , C07C255/46 , C07D333/36 , C07D331/04 , C07D295/32 , C07D305/08 , C07D205/04 , C07D309/14 , C07D333/48 , C07D261/12 , C07D207/273 , C07D263/26 , C07D277/36 , C07D307/33 , C07D233/80 , C07C237/42
CPC分类号： A01N53/00 , A01N37/22 , A01N37/34 , A01N41/10 , A01N43/40 , A01N43/60 , A01N43/653 , A01N43/707 , A01N43/82 , A01N43/90 , C07C233/63 , C07C233/65 , C07C237/22 , C07C237/42 , C07C255/29 , C07C255/46 , C07C255/57 , C07C255/60 , C07C259/10 , C07C271/28 , C07C271/66 , C07C311/08 , C07C311/46 , C07C317/14 , C07C317/28 , C07C317/40 , C07C317/50 , C07C323/41 , C07C323/42 , C07C323/59 , C07C331/12 , C07C381/10 , C07C2601/02 , C07C2601/04 , C07C2601/08 , C07C2601/14 , C07D205/04 , C07D207/10 , C07D207/273 , C07D207/452 , C07D209/49 , C07D213/56 , C07D213/75 , C07D213/81 , C07D213/84 , C07D213/89 , C07D215/227 , C07D215/38 , C07D231/12 , C07D231/56 , C07D233/36 , C07D233/80 , C07D235/30 , C07D241/20 , C07D249/08 , C07D253/07 , C07D261/12 , C07D263/26 , C07D277/30 , C07D277/36 , C07D285/06 , C07D295/32 , C07D305/08 , C07D307/33 , C07D307/52 , C07D309/14 , C07D331/04 , C07D333/36 , C07D333/48 , C07D333/60 , C07D487/04
摘要： This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).
摘要翻译：本公开涉及具有杀虫效果的分子领域，其中包括节肢动物，软体动物和线虫中的害虫，产生这种分子的方法，用于此类方法的中间体，含有这种分子的杀虫组合物，以及使用这种杀虫剂组合物抗这种害虫的方法。这些杀虫剂组合物可以用作例如杀螨剂，杀虫剂，杀螨剂，杀软体动物剂和杀线虫剂。该文献公开了具有下式（“一级方程式”）的分子。

8. 发明申请

US20160073631A1 PROCESS FOR THE PREPARATION OF DIHYDROPYRROLE DERIVATIVES 审中-公开
标题翻译：制备二氢衍生物衍生物的方法
公开(公告)号：US20160073631A1
公开(公告)日：2016-03-17
申请号：US14945924
申请日：2015-11-19
申请人： Syngenta Participations AG , Syngenta Limited
发明人： Myriem EL QACEMI , Helmars SMITS , Jerome Yves CASSAYRE , Nicholas Phillip MULHOLLAND , Peter RENOLD , Edouard GODINEAU , Thomas PITTERNA
IPC分类号： A01N43/36 , C07D207/20 , C07D207/46 , C07C255/41 , C07D207/22 , C07D209/48 , C07D331/04 , C07C255/44 , C07C251/24 , C07C205/54 , C07D249/08
CPC分类号： A01N43/36 , A01N33/20 , A01N37/34 , A01N37/44 , A01N37/46 , A01N43/20 , A01N43/40 , A01N43/653 , C07C205/54 , C07C251/24 , C07C255/41 , C07D207/20 , C07D207/22 , C07D207/46 , C07D209/48 , C07D249/08 , C07D331/04
摘要： The present invention provides stereoselective processes for the preparation of compounds of formula (I) wherein P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; R1 is chlorodifluoromethyl or trifluoromethyl; R2 is optionally substituted aryl or optionally substituted heteroaryl; n is 0 or 1; including the process comprising (a-i) reacting a compound of formula II wherein P, R1 and R2 are as defined for the compound of formula I; with nitromethane in the presence a chiral catalyst to give a compound of formula III wherein P, R1 and R2 are as defined for the compound of formula I; and (a-ii) reductively cyclising the compound of formula III to give the compound of formula I. The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).
摘要翻译：本发明提供了制备式（I）化合物的立体选择性方法，其中P是苯基，萘基，含有一个或两个氮原子作为环成员的6元杂芳基或含有一个或多个氮原子的10元双环杂芳基两个氮原子作为环成员，并且其中苯基，萘基和杂芳基任选被取代; R1是氯二氟甲基或三氟甲基; R2是任选取代的芳基或任选取代的杂芳基; n为0或1; 包括（a-i）使式II化合物与式Ⅰ化合物反应的方法，其中P，R 1和R 2如对式I化合物所定义; 在硝基甲烷中存在手性催化剂，得到式III化合物，其中P，R 1和R 2如式I化合物所定义; 和（a-ii）还原性环化式III化合物以得到式I化合物。本发明还提供了可用于合成式（I）化合物的方法的中间体。

9. 发明授权

US09247740B2 Isoxazoline derivatives as insecticidal compounds 有权
标题翻译：异恶唑啉衍生物作为杀虫剂
公开(公告)号：US09247740B2
公开(公告)日：2016-02-02
申请号：US14240428
申请日：2012-08-24
申请人： Jerome Yves Cassayre , Peter Renold , Thomas Pitterna , Myriem El Qacemi
发明人： Jerome Yves Cassayre , Peter Renold , Thomas Pitterna , Myriem El Qacemi
IPC分类号： C07D413/12 , C07D331/04 , A01N43/20 , A01N43/80 , A01N43/40 , A01N43/54
CPC分类号： A01N43/20 , A01N43/40 , A01N43/54 , A01N43/80 , C07D331/04 , C07D413/12
摘要： The present invention provides compounds of formula (I), wherein G1 is oxygen; R1 is hydrogen; R2 is group P (P) L is a bond, methylene or ethylene; one of A1 and A2 is S, SO or SO2 and the other is —C(R4)R4—R3 is hydrogen or methyl; each R4 is independently hydrogen or methyl; Y1 is C—R6, CH or nitrogen; Y2 and Y3 are independently CH or nitrogen; wherein no more than two of Y1, Y2 and Y3 are nitrogen and wherein Y2 and Y3 are not both nitrogen; R5 is hydrogen, halogen, cyano, nitro, NH2, C1-C2alkyl, C1-C2haloalkyl, C3-C5cycloalkyl, C3-C5halocycloalkyl, C1-C2alkoxy, C1-C2haloalkoxy; R6 together with R5 forms a —CH═CH—CH═CH— bridge; X2 is C—X6 or nitrogen; X1, X3 and X6 are independently hydrogen, halogen or trihalomethyl, wherein at least two of X1, X3 and X6 are not hydrogen; X4 is trifluoromethyl, difluoromethyl or chlorodifluoromethyl. The invention also provides intermediates useful for the preparation of compounds of formula (I), as well as methods of controlling insects, acarines, nematodes or molluscs using the compounds of formula (I).
摘要翻译：本发明提供式（I）化合物，其中G1是氧; R1是氢; R2是基团P（P）L是键，亚甲基或亚乙基; A1和A2之一是S，SO或SO2，另一个是-C（R4）R4-R3是氢或甲基; 每个R 4独立地是氢或甲基; Y1是C-R6，CH或氮; Y2和Y3独立地是CH或氮; 其中Y1，Y2和Y3中不超过两个是氮，并且其中Y 2和Y 3不都是氮; R5是氢，卤素，氰基，硝基，NH2，C1-C2烷基，C1-C2卤代烷基，C3-C5环烷基，C3-C5卤代环烷基，C1-C2烷氧基，C1-C2卤代烷氧基; R6与R5一起形成-CH = CH-CH = CH-桥; X2是C-X6或氮; X1，X3和X6独立地为氢，卤素或三卤代甲基，其中X 1，X 3和X 6中的至少两个不是氢; X4是三氟甲基，二氟甲基或氯二氟甲基。本发明还提供了可用于制备式（I）化合物的中间体，以及使用式（I）化合物控制昆虫，螨虫，线虫或软体动物的方法。

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