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1. 发明授权

US3876600A Deactivating removing aluminum and titanium contaminant from ziegler-natta polymerization mixtures 失效
标题翻译：从ZIEGLER-NATTA聚合混合物中去除铝和金属污染物
公开(公告)号：US3876600A
公开(公告)日：1975-04-08
申请号：US42708373
申请日：1973-12-21
申请人： GULF RESEARCH DEVELOPMENT CO
发明人： CUPPLES BARRETT L , LYNCH THOMAS J , MURPHY CLARENCE R
IPC分类号： C08F6/02 , C08F1/88 , C08F1/52
CPC分类号： C08F6/02 , C08L23/02
摘要： A polymerization reaction product comprising a solution of a poly(1-alkene) and a hydrocarbon polymerization solvent is purified of Ziegler-Natta aluminum and titanium containing catalyst residue by treating with flux-calcined diatomite to deactivate and insolubilize the aluminum and titanium and filtering out the insolubilized aluminum and titanium.

2. 发明授权

US3661802A Polymerization catalysts using supported rhenium oxides 失效
标题翻译：使用支持的氧化氙的聚合催化剂
公开(公告)号：US3661802A
公开(公告)日：1972-05-09
申请号：US3661802D
申请日：1970-08-31
申请人： STANDARD OIL CO
发明人： NICPON PHILIP E
IPC分类号： C08F4/60 , C08F10/00 , C08F36/04 , C08F1/52
CPC分类号： C08F10/00 , C08F4/695
摘要： A COMPOSITIONS OF MATTER USEFUL AS A CATALYST FOR THE POLYMERIZATION OF MONO- AND DIOLEFINS TO NORMALLY SOLID POLYMERS WHICH COMPRISES A MINOR AMOUNT OF A HIGHER OXIDE OF RHENIUM SUPPORTED ON A MAJOR AMOUNT OF A HIGHSURFACE-AREA SILICA, SAID OXIDE IN COMBINATION WITH SAID SILICA, WHEREIN SAID COMBINATION HAS VEEN HEATED IN THE TEMPERATURE RANGE FROM ABOUT 400*C. TO ABOUT 950*C., AND A PROMOTER CHOSEN FROM THE GROUP CONTAINING COMPOUNDS OF FORMULA R3AL WHEREIN R IS A LOWER ALKYL GROUP OF FROM 1 TO 6 CARBON ATOMS AND WHEREIN THE MOLE RATIO OF SAID PROMOTER TO SAID HIGHER OXIDE OF RHENIUM RUNS FROM ABOUT 0.5 TO ABOUT 50.

3. 发明授权

US4051308A Process for polymerizing butadiene with cobalt complex, AlR.sub.3 and CS.sub.2 失效
标题翻译：用钴复合物，ALR'3'和CS'2聚合丁二烯的方法
公开(公告)号：US4051308A
公开(公告)日：1977-09-27
申请号：US629437
申请日：1975-11-06
申请人： Adel Farhan Halasa
发明人： Adel Farhan Halasa
IPC分类号： C08F136/06 , C08F1/52 , C08F3/18
CPC分类号： C08F136/06
摘要： 1,3-Butadiene is polymerized in the liquid phase in the presence of a catalyst composition comprising:A. A complex of a cobalt salt;B. AlR.sub.3 wherein R is hydrocarbon, andC. CS.sub.2.The complex comprises one of a cobalt salt, preferably CoCl.sub.2, with an organic compound containing nitrogen and oxygen or sulfur, preferably with no more than 2 carbon atoms separating the nitrogen and oxygen or sulfur, and the organometal reducing agent AlR.sub.3, wherein R is a hydrocarbon radical, preferably of no more than 10 carbon atoms. The polybutadiene has a microstructure of at least 80% and generally more than 90% 1,2, is also syndiotactic in character, has a melting point of 190.degree.-227.degree. C, and may be obtained in approximately quantitative yields.

4. 发明授权

US3478008A Preparation of propylene having intermediate crystallinity with a catalyst comprising (1) ticl4-metal hydride-alkyl aluminum halide and (2) aluminum trialkyl 失效
标题翻译：具有包含（1）TICL4金属氢化烷基铝卤化物的催化剂的中间晶体结构的丙烯的制备和（2）铝原铝
公开(公告)号：US3478008A
公开(公告)日：1969-11-11
申请号：US3478008D
申请日：1965-07-12
申请人： DOW CHEMICAL CO
发明人： LEDBETTER HARVEY D
IPC分类号： C08F10/06 , C08F1/52 , B01J11/84 , C08F1/48
CPC分类号： C08F10/06 , Y10S526/907 , C08F4/646

5. 发明授权

US3899477A Polymerization of ethylene 失效
标题翻译：乙烯聚合
公开(公告)号：US3899477A
公开(公告)日：1975-08-12
申请号：US33325073
申请日：1973-02-16
申请人： MONSANTO CO
发明人： ALTEMORE JOSEPH M , ORT MORRIS R
IPC分类号： C08F110/02 , C08F1/52
CPC分类号： C08F110/02 , C08F4/685
摘要： Ethylene polymers are made by bringing ethylene under polymerization conditions at low pressures into contact with a catalyst comprising a titanium halide, a vanadium halide and an organoaluminum compound. Molecular weight distribution of the polymers is controlled by reacting the titanium halide, the vanadium halide and the organoaluminum compound in such proportions that the Al/(Ti+V) ratio is between about 0.1 and 0.5 and admixing the resulting catalyst complex with a mixture of an alkylaluminum sesquiethoxide and a trialkylaluminum prior to contacting of ethylene therewith.
摘要翻译：通过在低压下的聚合条件下将乙烯与包含卤化钛，卤化钒和有机铝化合物的催化剂接触来制备乙烯聚合物。聚合物的分子量分布通过使卤化钛，卤化钒和有机铝化合物以Al /（Ti + V）比为约0.1至0.5的比例反应来控制，并将得到的催化剂配合物与在乙烯与乙烯接触之前的烷基铝倍半乙氧基化物和三烷基铝。

6. 发明授权

US3852373A Process for the production of liquid butadiene polymers 失效
标题翻译：生产液体二聚体聚合物的方法
公开(公告)号：US3852373A
公开(公告)日：1974-12-03
申请号：US25164872
申请日：1972-05-09
申请人： HUELS CHEMISCHE WERKE AG
发明人： HESSE K , VON PORTATIUS H
IPC分类号： C08F36/04 , C08F1/52
CPC分类号： C08F36/04 , Y10S585/952 , C08F4/7098
摘要： A process for preparing liquid butadiene polymers which comprises polymerizing 1,3-butadiene at a temperature of 10*180*C with a catalytic amount of a mixed catalyst including a solvent-soluble organonickel compound and an organoaluminum compound in contact with a molecular weight regulating amount of at least one monoolefinically unsaturated compound of the formula

WHEREIN R1 and R2 are each hydrogen, chlorine, or alkyl of 1-5 carbon atoms, and R3 is hydrogen or chlorine. High yields are attainable at elevated polymerization temperatures without extreme increases in viscosity of the product.
摘要翻译：一种制备液体丁二烯聚合物的方法，其包括在10-180℃的温度下用催化量的混合催化剂聚合1,3-丁二烯，所述混合催化剂包括与分子量接触的溶剂可溶的有机镍化合物和有机铝化合物调节量至少一种式WHEREIN R1和R2的单烯属不饱和化合物各自为氢，氯或1-5个碳原子的烷基，R3为氢或氯。在高聚合温度下可获得高产率，而不会极大地提高产品的粘度。

7. 发明授权

US3462403A Polymerization catalyst comprising (1) transition metal amide,(2) znr2 or zncl2 and (3) ziegler catalyst or ziegler catalyst reducing component 失效
标题翻译：包含（1）过渡金属酰胺，（2）ZNR2或ZNCL2和（3）齐聚物催化剂或齐格勒催化剂还原组分的聚合催化剂
公开(公告)号：US3462403A
公开(公告)日：1969-08-19
申请号：US3462403D
申请日：1964-05-11
申请人： COLUMBIAN CARBON
发明人： PENDLETON JOHN F
IPC分类号： C08F4/06 , C08F4/12 , C08F4/50 , C08F10/00 , C08F36/04 , C08F1/56 , C08F1/42 , C08F1/52
CPC分类号： C08F36/04 , C08F4/06 , C08F4/12 , C08F10/00 , Y10S526/906 , C08F4/606 , C08F4/72 , C08F4/64 , C08F110/06 , C08F2500/01

8. 发明授权

US3454538A Polymerization of olefinically unsaturated compounds using pi-olefin complexes as polymerization initiators 失效
标题翻译：使用PI-OLEFIN复合物作为聚合引发剂的烯烃非饱和化合物的聚合
公开(公告)号：US3454538A
公开(公告)日：1969-07-08
申请号：US3454538D
申请日：1965-02-16
申请人： BASF AG
发明人： NAARMANN HERBERT , HOFMANN HERMANN PANKRAZ , KASTNING ERNST-GUENTHER
IPC分类号： C08F2/00 , C08F4/12 , C08F36/00 , C08F36/04 , C08F1/52 , C08F5/00
CPC分类号： C08F36/04 , C08F4/12 , C08F36/00 , C08F4/72 , C08F4/52 , C08F4/50

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