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1. 发明申请

US20130059993A1 CATALYST FOR POLYMERIZATION OF NORBORNENE MONOMERS, METHOD FOR PRODUCING NORBORNENE POLYMER, METHOD FOR PRODUCING NORBORNENE COPOLYMER, NORBORNENE POLYMER AND TRANSITION METAL COMPLEX 有权
标题翻译：用于NORBENNENE单体聚合的催化剂，生产NORBNNENE聚合物的方法，生产NORBNENNENE共聚物的方法，NORBENNENE聚合物和过渡金属络合物
公开(公告)号：US20130059993A1
公开(公告)日：2013-03-07
申请号：US13663475
申请日：2012-10-30
申请人： SHOWA DENKO K.K.
发明人： Satoshi FUJIBE , Nobuyuki KIBINO , Tsuneo TAJIMA
IPC分类号： C08F4/82 , C07F15/00 , C08F132/04
CPC分类号： C07F15/006 , C08F4/64048 , C08F232/08
摘要： A catalyst for a polymerization of norbornene monomers includes a transition metal complex represented by a formula (1). A method for producing a norbornene copolymer includes copolymerizing first norbornene monomers corresponding to a first monomer unit represented by a formula (2) and second norbornene monomers corresponding to a second monomer unit represented by a formula (3) in a presence of the catalyst. The transition metal complex is preferably (π-allyl){2-[N-(2,6-diisopropylphenyl)iminomethyl]phenolate}palladium, (π-allyl){2-[N-(2,6-diisopropylphenyl)iminomethyl]-4-fluorophenolate}palladium, (π-allyl)[2-(N-phenyliminomethyl)phenolate]palladium or (π-allyl){2-[N-(2,6-diisopropylphenyl)iminomethyl]-6-methylphenolate}palladium.
摘要翻译：用于降冰片烯单体的聚合的催化剂包括由式（1）表示的过渡金属络合物。降冰片烯共聚物的制造方法包括：在催化剂存在下，使对应于由式（2）表示的第一单体单元的第一降冰片烯单体和对应于式（3）所示的第二单体单元的第二降冰片烯单体共聚。过渡金属配合物优选为（2- {N-（2,6-二异丙基苯基）亚氨基甲基]苯酚盐}钯（{（R） - 烯丙基）{2- [N-（2,6-二异丙基苯基）亚氨基甲基] -4-氟苯甲酸酯}钯（（+） - [2-（N-苯基亚氨基甲基）苯甲酸酯]钯或（β-烯丙基）{2- [N-（2,6-二异丙基苯基）亚氨基甲基] - 甲基苯酚盐}钯。

2. 发明授权

US5714427A Catalyst system comprising two zirconocenes and aluminoxane 失效
标题翻译：包含两种锆氧化物和铝氧烷的催化剂体系
公开(公告)号：US5714427A
公开(公告)日：1998-02-03
申请号：US311068
申请日：1994-09-23
申请人： Andreas Winter , Volker Dolle , Walter Spaleck
发明人： Andreas Winter , Volker Dolle , Walter Spaleck
IPC分类号： C08F4/642 , C07F17/00 , C08F4/60 , C08F4/64 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/82 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/16
CPC分类号： C08F10/06 , C07F17/00 , C08F10/00 , C08F110/06 , C08F210/16 , C08F4/65904 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A catalyst system comprising an aluminoxane and a transition-metal component (metallocene) is used, the transition-metal component comprising at least one zirconocene of the formula I ##STR1## and at least one zirconocene of the formula Ia or alternatively at least 2 zirconocenes of the formula I.
摘要翻译：使用包含铝氧烷和过渡金属组分（茂金属）的催化剂体系，所述过渡金属组分包含至少一种式I（I）式Ia的氧化锆或者至少2种式一世。

3. 发明授权

US4338219A Catalyst compositions used for copolymerization of isomonoolefins with conjugated dienes 失效
标题翻译：用于共聚异烯烃与共轭二烯的催化剂组合物
公开(公告)号：US4338219A
公开(公告)日：1982-07-06
申请号：US910040
申请日：1978-05-26
申请人： Floyd E. Naylor
发明人： Floyd E. Naylor
IPC分类号： C08F210/00 , C08F210/12 , C08F236/04 , C08F4/26 , C08F4/80 , C08F4/82 , C08F36/06
CPC分类号： C08F210/12 , C08F210/00 , C08F236/04
摘要： The copolymerization of isoolefins with dienes is initiated by nickel source complexes with compounds of titanium or vanadium. For example, isobutylene and butadiene are copolymerized in the presence of a catalyst of bis(1,5-cyclooctadiene)nickel and titanium tetrachloride.
摘要翻译：异烯烃与二烯的共聚是由与钛或钒化合物的镍源配合物引发的。例如，在双（1,5-环辛二烯）镍和四氯化钛的催化剂存在下，异丁烯和丁二烯共聚。

4. 发明授权

US11471867B2 Ligand for forming ruthenium complex, ruthenium complex catalyst, production method therefor and use thereof 有权
公开(公告)号：US11471867B2
公开(公告)日：2022-10-18
申请号：US16609197
申请日：2018-06-22
申请人： GWANGJU INSTITUTE OF SCIENCE AND TECHNOLOGY
发明人： Sukwon Hong , Seunghwan Byun
IPC分类号： B01J31/22 , C07F15/00 , C08G61/00 , C07B35/08 , C08F4/82
摘要： The present invention relates to a novel ligand for forming a ruthenium complex, a ruthenium complex catalyst, a production method therefor and a use thereof. The ligand for forming a ruthenium complex and the ruthenium complex catalyst, according to the present invention, exhibit high catalytic activity, high selectivity, and stability.

5. 发明授权

US5525688A Highly active .pi.-allynickel-based polymerization initiators 失效
标题翻译：高活性的基于pialallynickel的聚合引发剂
公开(公告)号：US5525688A
公开(公告)日：1996-06-11
申请号：US342805
申请日：1994-11-21
申请人： Bruce Novak , Timothy J. Deming
发明人： Bruce Novak , Timothy J. Deming
IPC分类号： B01J31/04 , B01J31/22 , C08F4/82
CPC分类号： C08F4/82 , B01J31/2239 , B01J31/2291 , B01J2531/0205 , B01J2531/847
摘要： A .pi.-allylnickel/counterion complex is reacted with a hologenated ketone to produce a highly active polymerization initiator.
摘要翻译：将pilyallynickel /抗衡离子络合物与氢化酮反应以产生高活性聚合引发剂。

6. 发明授权

US5171832A Polymerization of carbon monoxide/olefin with P bidentate ligand having (1) alkoxy phenyl P group and (2) monosubstituted divalent bridging group 失效
标题翻译：具有（1）烷基苯基P基团和（2）单取代的多价桥联组合的具有P二价配位体的二氧化碳/烯烃的聚合
公开(公告)号：US5171832A
公开(公告)日：1992-12-15
申请号：US684109
申请日：1991-04-12
申请人： Johannes J. Keijsper , Alexander W. van der Made
发明人： Johannes J. Keijsper , Alexander W. van der Made
IPC分类号： C08F4/82 , B01J31/24 , B01J31/28 , C07F9/50 , C08F210/00 , C08G67/00 , C08G67/02
CPC分类号： B01J31/2409 , C07F9/5027 , C07F9/5077 , C08G67/02 , B01J2231/10 , B01J2531/80 , B01J2531/824
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a novel catalyst composition formed from a compound of palladium, the anion of a strong non-hydrohalogenic acid and a bidentate ligand of phosphorus wherein each monovalent phosphorus substituent is phenyl substituted by at least one alkoxy group on a ring carbon atom ortho to the atom through which the group is connected to phosphorus and the divalent alkylene bridging group has a single substituent (other than hydrogen) having atoms of carbon, hydrogen and optionally oxygen.

7. 发明授权

US4501866A Continuous method for preparing high cis-1,4 polybutadiene 失效
标题翻译：制备高顺式-1,4聚丁二烯的连续方法
公开(公告)号：US4501866A
公开(公告)日：1985-02-26
申请号：US633814
申请日：1984-07-23
申请人： David M. Roggeman , Shrikant R. Malani , Jung W. Kang
发明人： David M. Roggeman , Shrikant R. Malani , Jung W. Kang
IPC分类号： C08F4/00 , C08F2/04 , C08F2/06 , C08F4/54 , C08F4/60 , C08F4/70 , C08F36/06 , C08F136/06 , C08F4/82
CPC分类号： C08F136/06
摘要： A method for preparing high cis-1,4 polybutadiene by a continuous process which involves the continuous polymerization of 1,3-butadiene in solution under adiabatic conditions is provided. The method comprises the steps of: (I) feeding continuously to a single agitated polymerization reactor: (a) a monomer stream comprising 1,3-butadiene in a hydrocarbon solvent; (b) a preformed .pi. allyl catalyst stream formed by admixing a carboxylated metal oxy borate compound represented by the formulae (RCOOMO).sub.3 B or (ROCOOMO).sub.2 B-OR' wherein R and R' are alkyl radicals containing from 7 to 17 carbon atoms and M is nickel or cobalt, an organo aluminum compound, an alcohol, a small amount of 1,3-butadiene and a hydrocarbon solvent; and (c) a cocatalyst stream comprising a boron trifluoride complex with an alcohol; and (II) withdrawing continuously from said reactor high cis-1,4 polybutadiene at the same rate as said monomer, preformed catalyst and cocatalyst streams are fed to the reactor.In an additional embodiment of the invention, a method of preparing a preformed .pi. allyl catalyst having improved stability and solubility in hydrocarbon solvent is provided.High cis-1,4 polybutadiene polymers produced by the method of the invention have good green strength and tack and may be used as tire rubbers and impact modifiers for plastics.
摘要翻译：提供了一种通过连续方法制备高顺式-1,4聚丁二烯的方法，该方法涉及在绝热条件下在溶液中连续聚合1,3-丁二烯。该方法包括以下步骤：（I）连续进料到单一搅拌聚合反应器中：（a）在烃溶剂中包含1,3-丁二烯的单体料流; （b）通过将由式（RCOOMO）3B或（ROCOOMO）2B-OR'表示的羧化金属硼酸硼酸盐化合物（RCOOMO）2B-OR'（其中R和R'是含有7至17个碳原子的烷基）和 M是镍或钴，有机铝化合物，醇，少量的1,3-丁二烯和烃溶剂; 和（c）包含三氟化硼配合物与醇的助催化剂流; 和（II）以与所述单体相同的速率从所述反应器高顺式-1,4-聚丁二烯中连续排出，将预制的催化剂和助催化剂物流进料到反应器中。在本发明的另外的实施方案中，提供了一种制备具有改进的在烃溶剂中的稳定性和溶解度的预制的丙烯酸烯丙酯的方法。通过本发明方法制备的高顺-1,4聚丁二烯聚合物具有良好的生坯强度和粘性，并可用作塑料的轮胎橡胶和抗冲击改性剂。

8. 发明授权

US4105845A Copolymerization of isomonoolefins with conjugated dienes 失效
标题翻译：异壬烯与共轭二烯的共聚
公开(公告)号：US4105845A
公开(公告)日：1978-08-08
申请号：US446427
申请日：1974-02-27
申请人： Floyd E. Naylor
发明人： Floyd E. Naylor
IPC分类号： C08F210/00 , C08F210/12 , C08F236/04 , C08F4/80 , C08F4/82
CPC分类号： C08F210/12 , C08F210/00 , C08F236/04
摘要： The copolymerization of isoolefins with dienes is initiated by nickel source complexes with compounds of titanium or vanadium. For example, isobutylene and butadiene are copolymerized in the presence of a catalyst of bis(1,5-cyclooctadiene)nickel and titanium tetrachloride.
摘要翻译：异烯烃与二烯的共聚是由与钛或钒化合物的镍源配合物引发的。例如，在双（1,5-环辛二烯）镍和四氯化钛的催化剂存在下，异丁烯和丁二烯共聚。

9. 发明申请

US20110282014A1 NORBORNENE COPOLYMER AND PRODUCTION METHOD THEREOF 有权
标题翻译：诺贝恩共聚物及其生产方法
公开(公告)号：US20110282014A1
公开(公告)日：2011-11-17
申请号：US13146600
申请日：2010-01-29
申请人： Shojiro Kaita , Nobuyuki Kibino , Kazufumi Kai
发明人： Shojiro Kaita , Nobuyuki Kibino , Kazufumi Kai
IPC分类号： C08F4/82 , C08F232/08
CPC分类号： C08F232/08
摘要： The invention relates to a norbornene copolymer having excellent properties such as transparency, heat resistance, low water absorption and electric insulating property, which copolymer comprises a monomer unit represented by formula (1) and formula (2) and having a number average molecular weight (Mn) of 300,000 to 2,000,000. (In the formulae, R1 represents an alkyl group having 1 to 10 carbon atoms; and R2, R3 and R4 independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms.)
摘要翻译：本发明涉及具有透明性，耐热性，低吸水性和电绝缘性等优异性能的降冰片烯共聚物，该共聚物包括由式（1）和式（2）表示的单体单元，其数均分子量（ Mn）为30万至2,000,000。（式中，R1表示碳原子数1〜10的烷基，R2，R3，R4分别表示氢原子或碳原子数1〜10的烷基。

10. 发明授权

US5395811A Highly active .pi.-allylnickel-based polymerization initiators 失效
标题翻译：高活性的基于胶体的聚合引发剂
公开(公告)号：US5395811A
公开(公告)日：1995-03-07
申请号：US150479
申请日：1993-11-15
申请人： Bruce Novak , Timothy J. Deming
发明人： Bruce Novak , Timothy J. Deming
IPC分类号： B01J31/04 , B01J31/22 , C08F4/82 , B01J31/12
CPC分类号： C08F4/82 , B01J31/2239 , B01J31/2291 , B01J2531/0205 , B01J2531/847
摘要： A .pi.-allylnickel/counterion complex is reacted with a halogenated ketone to product a highly active polymerization initiator.
摘要翻译：将一个吡咯烷酮/抗衡离子络合物与卤代酮反应以产生高活性聚合引发剂。

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