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1. 发明授权

US10106686B2 Particles for electrophoretic displays 有权
公开(公告)号：US10106686B2
公开(公告)日：2018-10-23
申请号：US14896842
申请日：2014-05-15
申请人： Merck Patent GmbH , The Queen's University of Belfast
发明人： Louise D. Farrand , Claire Topping , Sarah Norman
IPC分类号： C09C3/10 , C09C1/56 , C08F220/68 , G02F1/167 , C08L33/12 , C09B31/043 , C09B47/24 , C09C1/36 , C09B29/08 , C09B29/42 , C09B47/06 , C09B47/067 , C09B67/08 , C09B69/10
摘要： This invention relates to particles comprising a pigment core particle encapsulated by a polymer, a process for their preparation, electrophoretic fluids comprising such particles, and electrophoretic display devices comprising such fluids.

2. 发明授权

US08778073B2 Phthalocyanine dye with extended conjugation, ink and detection system using same 有权
标题翻译：具有延伸共轭的酞菁染料，油墨和使用其的检测系统
公开(公告)号：US08778073B2
公开(公告)日：2014-07-15
申请号：US13126337
申请日：2008-10-30
申请人： Sivapackia Ganapathiappan , Zhang-Lin Zhou , Jayprakash C. Bhatt
发明人： Sivapackia Ganapathiappan , Zhang-Lin Zhou , Jayprakash C. Bhatt
IPC分类号： C09D11/02 , C09B47/04 , G01N21/00 , C09D11/00 , C09B69/10 , C09B47/06 , C09B47/00 , C09B47/24
CPC分类号： C09B69/108 , C09B47/00 , C09B47/045 , C09B47/062 , C09B47/24 , C09D11/328
摘要： A phthalocyanine dye with extended conjugation includes one or both of a phthalocyanine component and a naphthalocyanine component and at least one water soluble substituent on an aryl group of the phthalocyanine dye. The extended conjugation of the phthalocyanine dye includes at least one benzene moiety of the component being one of (a) joined to an aryl group either indirectly using an alkylene linkage or directly, (b) joined to a benzene moiety of another of the components to form an oligomer of the components, and (c) a combination of (a) and (b). The extended conjugation shifts absorption of the phthalocyanine dye to greater than 800 nm.
摘要翻译：具有延伸共轭的酞菁染料包括酞菁组分和萘酞菁组分中的一种或两种，以及酞菁染料的芳基上的至少一个水溶性取代基。酞菁染料的延长缀合包括至少一个该部分的苯部分，其中（a）间接地使用亚烷基键或直接连接到芳基上，（b）连接到另一组分的苯部分，形成组分的低聚物，和（c）（a）和（b）的组合。延长的共轭将酞菁染料的吸收转移到大于800nm。

3. 发明申请

US20050104944A1 Process for preparing phthalocyanine compounds 失效
标题翻译：酞菁化合物的制备方法
公开(公告)号：US20050104944A1
公开(公告)日：2005-05-19
申请号：US10507594
申请日：2003-02-13
申请人： Colin Robertson , Jill Johnson , Prakash Patel
发明人： Colin Robertson , Jill Johnson , Prakash Patel
IPC分类号： B41J2/01 , B41M5/00 , C09B47/24 , C09B47/26 , C09B67/22 , C09B67/44 , C09D11/00 , G01D11/00
CPC分类号： C09D11/328 , C09B47/24 , C09B47/26 , C09B67/0035
摘要： A process for preparing a mixture of copper phthalocyanine dyes of Formula (1): CuPc(SO3M)x(SO2NH2)y, CuPc is copper phthalocyanine; M is a cation; x and y each independently have a value of from 0.5 to 3.5; and (x+y)=2 to 5; which process comprises: (vii) chlorosulphonating a copper phthalocyanine compound using a chlorosulphonating agent; and (viii) condensing the product of step (i) with ammonia to give a mixture of copper phthalocyanine dyes of Formula (1); (ix) optionally exchanging the cation M in the mixture of copper phthalocyanine dyes of Formula (1) resulting from step (ii) for an alternative cation M; wherein the chlorosulphonating agent comprises a mixture of chlorosulphonic acid and a chlorinating agent selected from phosphorous oxychloride and phosphorous trichloride. Also the dyes obtainable from this process; compositions and inks comprising these dyes; materials printed with these dyes, compositions or inks; ink-jet printer cartridges containing inks made from the dyes; and ink-jet printers comprising these cartridges.
摘要翻译：制备式（1）的铜酞菁染料的混合物的方法：CuPc（SO 3 N）M（SO 3 N）NH CuPc是铜酞菁; M是阳离子; x和y各自独立地具有0.5至3.5的值; 和（x + y）= 2〜5; 该方法包括：（vii）使用氯磺化剂氯磺化铜酞菁化合物; 和（viii）将步骤（i）的产物与氨缩合，得到式（1）的酞菁铜染料的混合物; （ix）任选地将由步骤（ii）得到的式（1）的酞菁铜染料的混合物中的阳离子M交替替代阳离子M; 其中氯磺化剂包括氯磺酸和选自磷酰氯和三氯化磷的氯化剂的混合物。也可以从该方法得到的染料; 包含这些染料的组合物和油墨; 用这些染料，组合物或油墨印刷的材料; 含有由染料制成的油墨的喷墨打印机墨盒; 以及包括这些盒的喷墨打印机。

4. 发明申请

US20050073563A1 Water-soluble phthalocyanine compound-containing ink for ink jetting, ink jet recording method and method for improving ozone gas discoloration of colored image material 有权
标题翻译：用于喷墨的水溶性酞菁化合物油墨，喷墨记录方法和改善着色图像材料臭氧气体变色的方法
公开(公告)号：US20050073563A1
公开(公告)日：2005-04-07
申请号：US10502217
申请日：2003-01-17
申请人： Naoyuki Hanaki , Keiichi Tateishi , Shigeaki Tanaka
发明人： Naoyuki Hanaki , Keiichi Tateishi , Shigeaki Tanaka
IPC分类号： B41J2/01 , B41M5/00 , C07D487/22 , C09B47/06 , C09B47/067 , C09B47/24 , C09B47/26 , C09B67/22 , C09D11/00 , C09D11/30 , G03G9/09 , G11B7/248 , G01D11/00
CPC分类号： C07D487/22 , C09B47/065 , C09B47/0675 , C09B47/24 , C09B47/26 , C09B67/0035 , C09D11/32 , C09D11/328 , G03G9/0918 , G11B7/248
摘要： To provide an ink capable of giving an image having excellent (color) hue and high fastness to light and ozone gas, an ink for ink jetting containing the ink, an ink jet recording method, and a method for enhancing the ozone resistance of an image. An ink comprising a water-soluble phthalocyanine compound, wherein in the spectral absorption curve of an aqueous solution of the phthalocyanine compound, the absorbance ratio b/a of the maximum absorbance b in the absorption band of 660 to 680 nm and the maximum absorbance a in the absorption band of 600 to 640 nm is less than 0.8 and the counter ion for the ionic hydrophilic group of the phthalocyanine compound is lithium ion.
摘要翻译：为了提供能够给出具有优异的（彩色）色调和对光和臭氧气体的高牢度的图像的油墨，包含油墨的喷墨用油墨，喷墨记录方法和增强图像的耐臭氧性的方法。一种包含水溶性酞菁化合物的油墨，其中在酞菁化合物的水溶液的光谱吸收曲线中，吸收带中的最大吸收率b的吸光度比b / a为660〜680nm，最大吸光度a 600〜640nm的吸收带小于0.8，酞菁化合物的离子性亲水基的抗衡离子为锂离子。

5. 发明申请

US20050004260A1 Ink and ink set for inkjet, and inkjet recording method 有权
标题翻译：喷墨油墨和喷墨记录方法
公开(公告)号：US20050004260A1
公开(公告)日：2005-01-06
申请号：US10811395
申请日：2004-03-29
申请人： Toshiki Taguchi
发明人： Toshiki Taguchi
IPC分类号： B41J2/01 , B41M5/00 , C09B29/42 , C09B29/48 , C09B31/153 , C09B47/24 , C09D11/00 , C09D11/328 , C09D11/40 , C03C17/00
CPC分类号： C09D11/328 , C09D11/037 , C09D11/40
摘要： Provided are an inkjet ink prepared by dissolving or dispersing a specific dye in an aqueous medium and containing one of at least one alkylene diol where one alkylene group has at least 3 carbon atoms or homologue thereof and at least one polymer compound; and an ink set containing an ink including a specific dye and an ink including one compound capable of interacting with the dye; thereby being able to provide an ink and the like having a good jet-out stability, and forming images of good quality with neither beading nor bronzing, and the images formed of the inks have good fastness to heat, light and ozone.
摘要翻译：提供通过将特定染料溶解或分散在水性介质中并含有至少一种亚烷基二醇（其中一个亚烷基具有至少3个碳原子或其同系物）和至少一种聚合物化合物而制备的喷墨油墨; 以及含有包含特定染料和包含能够与染料相互作用的化合物的油墨的油墨的油墨组; 从而能够提供具有良好喷出稳定性的油墨等，并且既没有珠状也不形成青铜，形成质量好的图像，并且由油墨形成的图像具有良好的耐热性，耐光性和耐臭氧性。

6. 发明授权

US6060598A Fluorescence immunoassays using fluorescent dyes free of aggregation and serum binding 失效
标题翻译：使用无聚集和血清结合的荧光染料的荧光免疫测定
公开(公告)号：US6060598A
公开(公告)日：2000-05-09
申请号：US874820
申请日：1997-06-13
申请人： Robert Francis Devlin , Walter Beach Dandliker , Peter Olaf Gustaf Arrhenius
发明人： Robert Francis Devlin , Walter Beach Dandliker , Peter Olaf Gustaf Arrhenius
IPC分类号： A61K41/00 , A61K47/48 , A61K49/00 , C07D487/22 , C07J43/00 , C07J51/00 , C09B47/00 , C09B47/04 , C09B47/073 , C09B47/08 , C09B47/24 , C09B69/00 , G01N33/52 , G01N33/533 , G01N33/58
CPC分类号： A61K49/0032 , A61K41/0071 , A61K47/48192 , A61K47/48215 , A61K49/0015 , A61K49/0052 , A61K49/0054 , C07D487/22 , C07J43/003 , C07J51/00 , C09B47/00 , C09B47/045 , C09B47/073 , C09B47/08 , C09B47/24 , C09B69/00 , G01N33/52 , G01N33/533 , G01N33/582 , G01N2333/19 , Y10S436/817
摘要： Fluorescence immunoassays methods are provided which use fluorescent dyes which are free of aggregation and serum binding. Such immunoassay methods are thus, particularly useful for the assay of biological fluids, such as serum, plasma, whole blood and urine.
摘要翻译：提供荧光免疫测定方法，其使用不含聚集和血清结合的荧光染料。因此，这样的免疫测定方法对生物流体如血清，血浆，全血和尿液的测定特别有用。

7. 发明授权

US5889181A Process for the syntheses of monosulphonated phthalocyanines, naphthobenzoporphyrazines and porphyrins via a modified meerwein reaction 失效
标题翻译：通过改性的麦格林反应合成单磺化酞菁，萘并苯并吡啶和卟啉的方法
公开(公告)号：US5889181A
公开(公告)日：1999-03-30
申请号：US519453
申请日：1995-08-25
申请人： Sveltana V. Kudrevich , Hasrat Ali , Johan E. Van Lier
发明人： Sveltana V. Kudrevich , Hasrat Ali , Johan E. Van Lier
IPC分类号： C09B47/24 , C09B47/00 , C09B62/00 , C09D47/22
CPC分类号： C09B47/24
摘要： Disclosed herein is a selective method for the preparation of single positional isomers of monosulphonated metallo derivatives of compounds selected from the group consisting of monosulphophthalocyanines, monosulphonaphthobenzoporphyrazines and monosulphotetraphenylporphyrins.
摘要翻译：本文公开了一种选择性方法，用于制备选自单磺基酞菁，单磺酰萘并苯并菲啶和单硫代四苯基卟啉的化合物的单磺化金属衍生物的单一位置异构体。

8. 发明授权

US5728204A Preparation of phthalocyanine-containing waterborne coating systems 失效
标题翻译：含酞菁水性涂料体系的制备
公开(公告)号：US5728204A
公开(公告)日：1998-03-17
申请号：US594197
申请日：1996-01-31
申请人： Abdul Sattar , Michael J. Greene , Herman Gerson
发明人： Abdul Sattar , Michael J. Greene , Herman Gerson
IPC分类号： C09B67/20 , C09B47/24 , C09B67/22 , C09D5/00 , C09D7/00 , C09D7/12 , C09D17/00 , C09D167/00 , C09B67/50
CPC分类号： C09B67/0035 , C09B47/24 , C09D167/00 , C09D7/007
摘要： This invention relates to water-dispersible phthalocyanine pigment formulations that are mixtures of (a) about 60 to about 99.5% by weight, based on the total amount of components (a) and (b), of a conditioned metal phthalocyanine pigment, and(b) about 0.5 to about 40% by weight, based on the total amount of components (a) and (b), of a water-insoluble sulfonated phthalocyanine having the formula Pc(SO.sub.2 OR).sub.x (I) wherein Pc represents a phthalocyanine moiety; R is H or M, wherein M is a monovalent metal, divalent metal, trivalent metal, or ammonium cation, and x is a from about 0.2 to about 4.
摘要翻译：本发明涉及水分散性酞菁颜料制剂，它们是（a）基于组分（a）和（b）的总量约60-约99.5重量％的调节金属酞菁颜料和（ b）基于组分（a）和（b）的总量的约0.5至约40重量％的具有式Pc（SO 2 OR）x（I）的水不溶性磺化酞菁，其中Pc表示酞菁部分 ; R为H或M，其中M为一价金属，二价金属，三价金属或铵阳离子，x为约0.2至约4。

9. 发明授权

US5717077A Fiber reactive phthalocyanine monoazo compounds having improved dyeing properties 失效
标题翻译：具有改善染色性能的纤维反应性酞菁单偶氮化合物
公开(公告)号：US5717077A
公开(公告)日：1998-02-10
申请号：US570415
申请日：1995-12-11
申请人： Toshiyuki Araki , Takemi Tokieda , Shin-ichi Yabushita , Yasuyoshi Ueda , Bunzi Tsukise
发明人： Toshiyuki Araki , Takemi Tokieda , Shin-ichi Yabushita , Yasuyoshi Ueda , Bunzi Tsukise
IPC分类号： C09B62/44 , C09B62/503 , C09B47/24 , C09B62/085
CPC分类号： C09B62/503 , C09B62/4403
摘要： A phthalocyanine monoazo compound which is represented by the following formula (I): ##STR1## wherein Pc represents a phthalocyanine group; M represents nickel, cobalt or copper; R.sub.1 represents a hydrogen atom or a lower alkyl group; R.sub.2 and R.sub.3 represent a hydrogen atom, a lower alkyl group, a lower alkoxy group or a sulfo group; R.sub.4 represents a hydrogen or a lower alkyl group; A represents a group containing a triazine group or a pyrazole group and/or --SO.sub.2 X wherein X represents --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 Y and Y represents a group splittable by the action of an alkali; p is a number of 0-2; q is a number of 1-3; r is a number of 1-2; p+q+r is 4 or less or which is a salt of the compound of formula (I).
摘要翻译：由下式（I）表示的酞菁单偶氮化合物：其中Pc表示酞菁基团; M表示镍，钴或铜; R1表示氢原子或低级烷基; R2和R3表示氢原子，低级烷基，低级烷氧基或磺基; R4表示氢或低级烷基; A表示含有三嗪基或吡唑基和/或-SO 2 X的基团，其中X表示-CH = CH 2或-CH 2 CH 2 Y，Y表示可通过碱的作用而分裂的基团; p是0-2的数; q是1-3的数量; r是1-2的数量; p + q + r为4以下，或者为式（I）的化合物的盐。

10. 发明授权

US5641878A Porphyrin, azaporphyrin, and related fluorescent dyes free of aggregation and serum binding 失效
标题翻译：卟啉，azaporphyrin和相关的荧光染料无聚集和血清结合
公开(公告)号：US5641878A
公开(公告)日：1997-06-24
申请号：US333603
申请日：1994-11-02
申请人： Walter B. Dandliker , Mao-Lin Hsu
发明人： Walter B. Dandliker , Mao-Lin Hsu
IPC分类号： A61K49/00 , C07D487/22 , C09B47/00 , C09B47/08 , C09B47/24 , G01N33/58 , C09B47/30
CPC分类号： A61K49/0021 , A61K49/0052 , A61K49/0054 , C07D487/22 , C09B47/00 , C09B47/08 , C09B47/24 , G01N33/582 , G01N2333/19
摘要： Fluorescent dyes which are free of aggregation and serum binding are provided. These dyes are suitable for applications such as fluorescence immunoassays, in vivo imaging and in vivo tumor therapy. The dyes are particularly useful in fluorescence immunoassays of biological samples containing serum. Such dyes have two polyoxyhydrocarbyl moities, one located on either side of a planar molecular structure such as a porphyrin derivative, azaporphyrin derivative, corrin derivative, sapphyrin derivative or porphycene derivative.
摘要翻译：提供了没有聚集和血清结合的荧光染料。这些染料适用于荧光免疫测定，体内成像和体内肿瘤治疗。染料在含有血清的生物样品的荧光免疫测定中特别有用。这样的染料具有两个聚氧化烃基，一个位于平面分子结构的两侧，例如卟啉衍生物，氮杂卟啉衍生物，cor啉衍生物，卟啉衍生物或卟吩衍生物。

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