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1. 发明授权

US08343632B2 Paper release compositions having improved adhesion to paper and polymeric films 有权
公开(公告)号：US08343632B2
公开(公告)日：2013-01-01
申请号：US12907281
申请日：2010-10-19
申请人： Roy Melvin Griswold , Richard Paul Eckberg , Slawomir Rubinsztajn , Stanislaw Slomkowski , Anna Kowalewska , Stanislaw Sosnowski
发明人： Roy Melvin Griswold , Richard Paul Eckberg , Slawomir Rubinsztajn , Stanislaw Slomkowski , Anna Kowalewska , Stanislaw Sosnowski
IPC分类号： B32B27/18 , B32B27/36 , B32B33/00 , C09D183/05 , C09D183/06 , C09D183/07
CPC分类号： C08L83/04 , C08G77/12 , C08G77/14 , C08G77/20 , C08G77/70 , C08G77/80 , C08J3/03 , C08J2383/04 , C09D183/04 , C09D183/06 , D21H19/32 , D21H27/001 , Y10T428/31663 , Y10T428/31786 , Y10T428/31938 , C08L83/00
摘要： The present invention relates to curable alkenyl based silicone release coating compositions having improved adhesion to paper and polymeric substrates. Furthermore the present invention relates to the process for making a silicone release coating with improved adhesion to paper and polymeric substrates.

2. 发明申请

US20120289110A1 SILICONE COATING COMPOSITION FOR AIR BAGS 审中-公开
标题翻译：空气袋用硅胶涂料组合物
公开(公告)号：US20120289110A1
公开(公告)日：2012-11-15
申请号：US13519880
申请日：2010-12-27
申请人： William Blackwood , David Danielson , Robert W. Pippenger , Randall Paul Sweet
发明人： William Blackwood , David Danielson , Robert W. Pippenger , Randall Paul Sweet
IPC分类号： C09D183/07 , C08K3/36 , B05D1/02 , B05D3/12 , B05D1/28 , B05D1/18 , B32B25/10 , B05D1/26
CPC分类号： B60R21/235 , B60R2021/23514 , C08G77/12 , C08G77/16 , C08G77/20 , C09D183/04 , Y10T442/20 , C08L83/00
摘要： Silicone rubber compositions for coating air bags, used for safety purposes to protect occupants of vehicles such as automobiles are described together with air bag fabrics coated with the composition and to air bags made from the coated fabric. The compositions are silicone rubber coating compositions which cure by hydrosilylation comprising an organopolysiloxane (A) having aliphatically unsaturated hydrocarbon or hydrocarbonoxy substituents, an organosilicon crosslinker having at least 3 silicon-bonded hydrogen atoms, a catalyst able to promote the reaction of the aliphatically unsaturated hydrocarbon or hydrocarbonoxy substituents with Si—H groups and a silica reinforcing filler, wherein the silica filler is pre-treated with 2% to 60% by weight based on the weight of the silica filler of an oligomeric organopolysiloxane containing Si-bonded methyl and vinyl groups and silanol end groups.
摘要翻译：与用于安全用途的用于保护诸如汽车的车辆的乘客的用于涂覆气囊的硅橡胶组合物与涂覆有该组合物的气囊织物和由涂覆织物制成的气囊一起被描述。组合物是通过氢化硅烷化固化的硅橡胶涂料组合物，其包含具有脂族不饱和烃或烃氧基取代基的有机聚硅氧烷（A），具有至少3个与硅键合的氢原子的有机硅交联剂，能够促进脂族不饱和烃或具有Si-H基团的烃氧基取代基和二氧化硅增强填料，其中基于含有Si键合的甲基和乙烯基的低聚有机聚硅氧烷的二氧化硅填料的重量，将二氧化硅填料预处理2％至60重量％和硅烷醇端基。

3. 发明申请

US20120184663A1 SILICONE RESIN COMPOSITION AND AN OPTICAL SEMICONDUCTOR DEVICE MAKING USE OF THE COMPOSITION 有权
标题翻译：硅酮树脂组合物和使用组合物的光学半导体器件
公开(公告)号：US20120184663A1
公开(公告)日：2012-07-19
申请号：US13349817
申请日：2012-01-13
申请人： Yoshihira HAMAMOTO , Tsutomu Kashiwagi
发明人： Yoshihira HAMAMOTO , Tsutomu Kashiwagi
IPC分类号： C09D183/07
CPC分类号： H01L23/296 , C08G77/12 , C08G77/20 , C08L83/04 , H01L33/56 , H01L2924/0002 , H01L2924/00
摘要： [Object]To provide a silicone resin composition for optical semiconductor devices, which has a low gas permeability and high dependability.[Means for solution]The silicone resin composition of the present invention contains the following components (A) through (D): (A) an organopolysiloxane as shown in the following general formula (1) in which the number of alkenyl groups contained per one molecule is two or more (R1SiO3/2)x(R23SiO1/2)y(R22SiO2/2)z (1) (wherein R1 is a cycloalkyl group, R2 is either one kind of or more than one kind of substituted or non-substituted monovalent hydrocarbon group having 1-10 carbon atoms, x is 0.5-0.9, y is 0.1-0.5, z is 0-0.2, and x+y+z=1.0), (B) a hydrogen organopolysiloxane containing at least two SiH groups per one molecule, (C) a catalyst for addition reaction, (D) an adhesion promoter agent.
摘要翻译：本发明提供一种透光性低，可靠性高的光半导体装置用有机硅树脂组合物。 [解决方案]本发明的有机硅树脂组合物含有下列组分（A）至（D）：（A）如下通式（1）所示的有机聚硅氧烷，其中每一个所含的烯基数分子是两个或多个（R 1 SiO 3/2）x（R 23 SiO 1/2）y（R 22 SiO 2/2）z（1）（其中R 1是环烷基，R 2是取代或未取代的一种或多种）具有1-10个碳原子的取代的单价烃基，x为0.5-0.9，y为0.1-0.5，z为0-0.2，x + y + z = 1.0），（B）含有至少两个SiH的氢有机聚硅氧烷（C）加成反应用催化剂，（D）粘合促进剂。

4. 发明授权

US07709549B2 Photocurable resin composition and article having a coating formed by curing such composition 有权
标题翻译：光固化树脂组合物和具有通过固化该组合物形成的涂层的制品
公开(公告)号：US07709549B2
公开(公告)日：2010-05-04
申请号：US11826174
申请日：2007-07-12
申请人： Yuji Yoshikawa , Masaaki Yamaya
发明人： Yuji Yoshikawa , Masaaki Yamaya
IPC分类号： C09D183/06 , C09D183/07
CPC分类号： C09D4/00 , C08L83/08 , C09D183/08 , Y10T428/31507 , Y10T428/31663 , C08L83/00
摘要： A thermosetting resin composition which forms a cured coating is provided. This resin composition is capable of providing the supporting substrate with scratch resistance, crack resistance, smudge proof property, removability of oil-base felted markers by wiping, and antistatic property. Also provided is an article having a coating formed from such composition. More specifically, the photocurable resin composition comprises (1) a siloxane compound containing a photoreactive group produced by hydrolyzing and condensing a system comprising (a) photoreactive group-containing hydrolyzable silane represented by formula (i) or (ii), with the proviso that, when one hydrolyzable silane is used, the silane comprises a trifunctional silane, and when two or more silanes are used, at least 70% by mole comprise a trifunctional silane, (b) a dimethylsiloxane containing a hydrolyzable group at opposite ends represented by formula (iii), and (c) a fluorine-containing hydrolyzable silane represented by formula (iv) in the presence of a basic catalyst by using water at an amount in excess of the amount required for hydrolyzing and condensing all hydrolyzable groups; (3) (CF3(CF2)mSO2)2NLi (wherein m is 0 to 7); and (4) a radical photopolymerization initiator. The article has a coating formed from this composition.
摘要翻译：提供了形成固化涂层的热固性树脂组合物。该树脂组合物能够通过擦拭赋予支撑基材的耐刮擦性，抗裂纹性，防污染性，油基毡标记物的可除去性和抗静电性。还提供了具有由这种组合物形成的涂层的制品。更具体地说，可光固化树脂组合物包含（1）含有通过水解和缩合系统制备的光反应性基团的硅氧烷化合物，该体系包含（a）由式（i）或（ii）表示的含光反应性基团的可水解硅烷，条件是当使用一种可水解硅烷时，硅烷包括三官能硅烷，当使用两种或更多种硅烷时，至少70％摩尔含有三官能硅烷，（b）在相对端含有可水解基团的二甲基硅氧烷，由式（iii）所示的含氟可水解硅烷，（c）在碱性催化剂的存在下，通过使用超过水解和缩合所有可水解基团所需量的水的水，由式（ⅳ）表示的含氟可水解硅烷; （3）（CF 3（CF 2）m SO 2）2 Ni（其中m为0〜7）; 和（4）自由基光聚合引发剂。该制品具有由该组合物形成的涂层。

5. 发明申请

US20050234181A1 Air bag coating composition 有权
标题翻译：气囊涂料组合物
公开(公告)号：US20050234181A1
公开(公告)日：2005-10-20
申请号：US11166246
申请日：2005-06-27
申请人： Masayuki Ikeno , Atsushi Yaginuma , Syuichi Azechi , Takeshi Miyao
发明人： Masayuki Ikeno , Atsushi Yaginuma , Syuichi Azechi , Takeshi Miyao
IPC分类号： B60R21/16 , B60R21/235 , C08K3/36 , C08K5/54 , C09D183/04 , C09D183/05 , C09D183/07 , D06N3/12 , C08L83/00
CPC分类号： D06N3/128 , B60R2021/23514 , B60R2021/23547 , C08K3/36 , C08K5/54 , C09D183/04 , Y10T428/31663 , C08L83/00
摘要： A silicone rubber coating composition which cures into a silicone rubber having a tear strength of 25-50 kN/m and a peeling bond strength of 30-60 N/cm is suited for coating of hollow weave type air bags. A hollow weave type air bag coated with the coating composition can be instantaneously inflated while the bag prevents the silicone rubber film from being peeled from the base fabric, eliminates inflating gas leakage, and retains an acceptable inflation time.
摘要翻译：固化成撕裂强度为25-50kN / m，剥离粘合强度为30-60N / cm的硅橡胶的硅橡胶涂料组合物适用于中空编织型气囊的涂布。涂覆有涂料组合物的空心编织型气囊可以瞬间充气，同时袋防止硅橡胶膜从基布上剥离，消除气体泄漏，并保持可接受的充气时间。

6. 发明申请

US20050208311A1 Use of siloxane copolymers comprising alkenyl groups as antimisting additives in cross-linkable silicone coating compositions 失效
标题翻译：在可交联硅氧烷涂料组合物中使用包含烯基作为防粘剂的硅氧烷共聚物
公开(公告)号：US20050208311A1
公开(公告)日：2005-09-22
申请号：US10506657
申请日：2003-02-20
申请人： Hans Lautenschlager , Christian Herzig
发明人： Hans Lautenschlager , Christian Herzig
IPC分类号： C08K5/00 , C08G77/20 , C08G77/50 , C08L83/04 , C08L83/05 , C08L83/07 , C08L83/14 , C09D183/04 , C09D183/05 , C09D183/07 , B32B9/04
CPC分类号： C08L83/14 , C08G77/12 , C08G77/18 , C08G77/20 , C08G77/50 , C08L83/04 , Y10T428/31663 , C08L83/00
摘要： Branched, alkenyl-functional organopolysiloxanes prepared by reacting an organic compound having at least two aliphatic double bonds with an organopolysiloxane having more than one Si-bonded hydrogen atom, in the presence of a hydrosilylation catalyst, and in a stoichiometric ratio of aliphatic double bonds to Si-bonded hydrogen such that an alkenyl-functional product is obtained, function as highly effective antimisting additives in the high speed coating of substrates with crosslinkable silicone compositions.
摘要翻译：通过使具有至少两个脂族双键的有机化合物与具有多于一个Si键合的氢原子的有机聚硅氧烷在氢化硅烷化催化剂的存在下反应制备的支链烯基官能的有机聚硅氧烷，并且以化学计量比的脂族双键与 Si键合的氢，使得得到烯基官能产物，在具有可交联的有机硅组合物的基材的高速涂布中起到高效的防雾添加剂的作用。

7. 发明申请

US20050159504A1 Substrates having a biofilm-inhibiting coating 有权
标题翻译：底物具有生物膜抑制涂层
公开(公告)号：US20050159504A1
公开(公告)日：2005-07-21
申请号：US10969008
申请日：2004-10-21
申请人： Carsten Becker-Willinger , Helmut Schmidt
发明人： Carsten Becker-Willinger , Helmut Schmidt
IPC分类号： B32B27/18 , C08K3/00 , C08L1/00 , C09D1/00 , C09D4/00 , C09D5/14 , C09D5/16 , C09D7/12 , C09D183/00 , C09D183/04 , C09D183/07 , C09D183/08
CPC分类号： C09D5/14 , C08K3/015 , C09D4/00 , C09D5/1618 , C09D5/1675 , F28F19/02 , Y10T428/31663 , C08G77/04 , C08L83/04
摘要： Substrates with a biofilm-inhibiting coating comprising an inorganic condensate modified with organic groups, at least some of the organic groups of the condensate containing fluorine atoms and the coating comprising copper colloids or silver colloids.
摘要翻译：具有生物膜抑制涂层的底物包含用有机基团改性的无机缩合物，至少一些含氟原子的缩合物的有机基团和包含铜胶体或银胶体的涂层。

8. 发明授权

US6068929A Radiation-curing or heat-curing organosiloxane compositions containing (methyl) styrene groups 失效
标题翻译：含有（甲基）苯乙烯基团的辐射固化或热固化有机硅氧烷组合物
公开(公告)号：US6068929A
公开(公告)日：2000-05-30
申请号：US72211
申请日：1998-05-04
申请人： Jochen Dauth , Josef Wolferseder , Bernward Deubzer
发明人： Jochen Dauth , Josef Wolferseder , Bernward Deubzer
IPC分类号： C08F299/08 , C08F290/14 , C08G77/38 , C08G77/46 , C08G77/50 , C08L83/07 , C09D155/00 , C09D183/07 , C09D183/12 , C09D183/14 , C08F283/12 , B32B27/00
CPC分类号： C09D183/12 , C08G77/46 , C08G77/50 , C09D183/14
摘要： Novel organosiloxane compositions which contain (methyl)styrene groups and can be prepared on the basis ofA) oligomeric or polymeric organosilicon compounds comprising at least one unit of the formulaGR.sub.c SiO.sub.(4-c-1)/2 (I)or at least one unit of the formula (I) and at least one unit of the formulaO.sub.(4-c-1)/2) R.sub.c Si--G.sup.1 --R.sub.c SiO.sub.(4-c-1)/2(II)B) monomeric alkenyloxy compounds, maleates, fumarates, maleimides, (meth)acrylates, (methyl)styrenes, acrylamides, itaconic esters and/or oligomeric or polymeric organosilicon compounds containing on average more than one alkenyloxy, maleate, fumarate, maleimide or (meth)acrylate group, where R are identical or different hydrocarbon radicals which may be halogenated or unhalogenated or a radical of the formula--R.sup.1 --[OCH.sub.2 CH.sub.2 ].sub.o --[OCH(CH.sub.3)CH.sub.2 ].sub.p --[O(CH.sub.2).sub.4 ].sub.q --OR.sup.2,whereR.sup.1 is a linear or branched alkylene radical,R.sup.2 is a hydrogen atom, an alkyl radical or a radical of the formula --CO--R.sup.3, where R.sup.3 is an alkyl radical,G is a radical of the formula (IV) --R.sup.4 -(phenyl) which is substituted by [--Y.sub.(5-d) ] and (--R.sup.5.sub.d), with the proviso that at least one radical R.sup.5 is present andG.sup.1 is a radical of the formula (V) --(phenyl)-(R.sup.4).sub.d -- which is substituted by [--Y.sub.4-d ], whereR.sup.4 is a linear or branched, substituted or unsubstituted alkylene radical,R.sup.5 is a vinyl radical or isopropenyl radical,Y can be identical or different and each Y is a hydrogen atom or is as defined for R, or is a radical of the formula --OR.sup.6, whereR.sup.6 is a C.sub.1-8 alkyl radical optionally interrupted by an ether oxygen atom, andc is 0, 1 or 2, on average from 0.0 to 2.0,d is 1, 2 or 3,o is 0 or an integer from 1 to 100,p is 0 or an integer from 1 to 100, andq is 0 or an integer from 1 to 100, with the proviso that the sum o+p+q is >0.
摘要翻译：含有（甲基）苯乙烯基团的新型有机硅氧烷组合物并且可以基于A）包含至少一种式GRcO（4-c-1）/ 2（I）单元的低聚或聚合有机硅化合物或至少一个单元（4-c-1）/ 2）RcSi-G1-RcSiO（4-c-1）/ 2（II）B）单体链烯氧基化合物，马来酸酯，富马酸酯的至少一个单元，马来酰亚胺，（甲基）丙烯酸酯，（甲基）苯乙烯，丙烯酰胺，衣康酸酯和/或低聚或聚合的有机硅化合物，其平均含有多于一个烯氧基，马来酸酯，富马酸酯，马来酰亚胺或（甲基）丙烯酸酯基团，其中R相同或可以被卤化或未卤化的不同烃基或式-R1- [OCH2CH2] o- [OCH（CH3）CH2]对 - [O（CH2）4] q-OR2的基团，其中R1是直链或支链亚烷基，R2是氢原子，烷基或式-CO-R3的基团，其中R3是烷基，G是式（IV）-R4-（苯基） h被[-Y（5-d）]和（-R5d）取代，条件是存在至少一个基团R 5，并且G 1是式（Ⅴ） - （苯基） - （R 4）d - 被[-Y4-d]取代，其中R4是直链或支链的取代或未取代的亚烷基，R5是乙烯基或异丙烯基，Y可以相同或不同，并且每个Y是氢原子或是如R所定义，或者是式-OR 6的基团，其中R 6是任选被醚氧原子中断的C 1-8烷基，c是0,1或2，平均为0.0至2.0，d为 1,2或3，o为0或1〜100的整数，p为0或1〜100的整数，q为0或1〜100的整数，条件是+ o + p + q是> 0。

9. 发明授权

US6063888A Liquid curable resin composition 失效
标题翻译：液体固化树脂组合物
公开(公告)号：US6063888A
公开(公告)日：2000-05-16
申请号：US168938
申请日：1998-10-09
申请人： Yoshikazu Yamaguchi , Junji Yoshizawa , Zen Komiya , Takashi Ukachi
发明人： Yoshikazu Yamaguchi , Junji Yoshizawa , Zen Komiya , Takashi Ukachi
IPC分类号： G02B6/44 , C03C25/24 , C08F2/46 , C08F290/00 , C08F299/06 , C08F299/08 , C08G18/28 , C08G18/67 , C08G77/388 , C09D175/14 , C09D175/16 , C09D183/07 , C09D183/10 , G02B1/04 , G03F7/027 , G03F7/038 , G03F7/075 , C08G77/20
CPC分类号： C08G18/672 , C08G18/289 , C08G77/388 , G02B1/048 , Y10T428/2942 , Y10T428/2962 , Y10T428/2991 , Y10T428/2995 , Y10T428/2998
摘要： A liquid radiation curable resin composition comprising a polydimethylsiloxane compound which has (i) at least two urethane bonds in one molecule, (ii) an unreactive organic group at at least one of the ends of the molecule, and (iii) a radical curable ethylenically unsaturated group at the other end of the molecule. The resin composition exhibits superior shelf life in a liquid state and produces cured products having slippery surface. It is suitable as a coating material for optical fibers.
摘要翻译：一种液体辐射固化树脂组合物，其包含聚二甲基硅氧烷化合物，所述聚二甲基硅氧烷化合物在一分子中具有（i）至少两个氨基甲酸酯键，（ii）所述分子的至少一个末端的非反应性有机基团，和（iii）可自由基固化的烯属在分子另一端的不饱和基团。树脂组合物在液态下表现出优异的保存期，并产生具有光滑表面的固化产物。它适用于光纤的涂层材料。

10. 发明授权

US6037394A Primer composition and article obtained using the same 有权
标题翻译：引物组合物和使用其得到的制品
公开(公告)号：US6037394A
公开(公告)日：2000-03-14
申请号：US243118
申请日：1999-02-03
申请人： Kazuharu Sato , Masaaki Yamaya
发明人： Kazuharu Sato , Masaaki Yamaya
IPC分类号： B05D7/24 , B32B27/30 , C08J7/04 , C09D5/00 , C09D133/00 , C09D133/06 , C09D143/04 , C09D183/07 , F21V3/04 , C08K5/34
CPC分类号： C08J7/04 , C08J7/047 , C09D133/06 , F21V3/04 , C08J2369/00 , C08J2433/00
摘要： A primer composition comprising (A) an acrylic resin, (B) a benzotriazole compound having not more than 1% by weight of heat loss when held at 150.degree. C. for 1 hour, and (C) an organic solvent. Also disclosed are an article obtained by forming a primer coat of the primer composition on the surface of a substrate, and an article obtained by forming the primer coat on the surface of a transparent plastic substrate and coating on the primer coat a protective coat comprising a condensation type curable silicone resin. The primer coat, which contains the above benzotriazole compound as an ultraviolet light absorber, has a superior weatherability while maintaining a good adhesion to the substrate.
摘要翻译：一种底漆组合物，其包含（A）丙烯酸树脂，（B）在150℃下保持1小时不超过1重量％的热损失的苯并三唑化合物和（C）有机溶剂。还公开了通过在基材的表面上形成底漆组合物的底漆层而获得的制品，以及通过在透明塑料基材的表面上形成底漆涂层而得到的制品，并在底漆涂层上涂布保护涂层，该保护涂层包含缩合型可固化硅树脂。含有上述苯并三唑化合物作为紫外光吸收剂的底漆具有优异的耐候性，同时保持与基材的良好粘合性。

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