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    • 2. 发明申请
    • METHOD OF PREPARATION OF BIODIESEL AND APPARATUS THEREFOR
    • 生物柴油的制备方法及其装置
    • WO2018083576A1
    • 2018-05-11
    • PCT/IB2017/056707
    • 2017-10-28
    • NAYAK, Swarup KumarMISHRA, Purna Chandra
    • NAYAK, Swarup KumarMISHRA, Purna Chandra
    • C11C3/00
    • C11C3/003C11C3/00Y02E50/13
    • A method and an apparatus to produce biodiesel with high yield and purity is disclosed. The apparatus employing the method includes a methanol reactor tank to mix an acidic catalyst with methanol for carrying out processes subsequent. The mixture is transferred to an acid reactor tank in which vegetable oil is introduced and esterification carried out. The esterified oil is next transferred to a base reactor tank that receives methanol and a basic catalyst from the methanol reactor tank. Transesterification /neutralization of the esterified oil is carried out therein to produce biodiesel that is further purified using dry washing. Glycerine produced in acid reactor tank and base reactor tank is allowed to settle and decanted, while methanol in both the tanks is recovered using heat exchangers and recycled. Fluid transfer from one tank to another is achieved using gravity. The apparatus is mounted on a portable trolley and so is capable of quickly being relocated as needed.
    • 公开了一种生产高产量和高纯度生物柴油的方法和设备。 采用该方法的设备包括甲醇反应罐,以将酸性催化剂与甲醇混合以进行随后的过程。 将混合物转移到酸反应器罐中,在其中引入植物油并进行酯化。 接着将酯化的油转移到从甲醇反应器罐接收甲醇和碱性催化剂的碱性反应器罐中。 酯化油的酯交换/中和在其中进行以生产生物柴油,其使用干洗进一步纯化。 允许在酸反应器罐和碱反应器罐中产生的甘油沉降并倾析,而两个罐中的甲醇使用热交换器回收并再循环。 使用重力实现从一个罐到另一个罐的流体转移。 该设备安装在便携式手推车上,因此可根据需要快速重新定位。
    • 6. 发明申请
    • SYSTEMS AND METHODS FOR THE NON-CATALYTIC PRODUCTION OF BIODIESEL FROM OILS
    • 用于生物柴油从油中非催化生产的系统和方法
    • WO2016100944A2
    • 2016-06-23
    • PCT/US2015066932
    • 2015-12-18
    • INVENTURE RENEWABLES INC
    • SUTTERLIN WILLIAM RUSTYLONG RYANGRAY III LESTER TRUMMERSAWYER HAYDEN
    • C07C27/02
    • C07C67/03C07C67/08C10L1/026C11C3/003Y02E50/13C07C69/52
    • In alternative embodiments, provided are systems and processes for the preparation of high-quality biodiesel and high-quality glycerol from oils: e.g., natural oils: corn oil, distillers corn, linseed, flaxseed, cottonseed, rapeseed (canola), peanut, sunflower, safflower, coconut, palm, soybean, comprising a high percentage (e.g. >10%) of organic acids, e.g. free fatty acids. In alternative embodiments, provided are systems and processes for the production of biodiesel meeting or exceeding the specifications for B100 biodiesel set forth in ASTM Specification D6751-14, as well as a glycerol co-product meeting or exceeding the standards for U.S. Pharmacopeial Convention (USP)-grade glycerol from natural oil feedstocks comprising high percentages of organic acids. In alternative embodiments, natural oil feedstocks with high organic acid content are subjected to a transesterification reaction with an alcohol under conditions at or above the critical temperature and pressure of the alcohol in the absence of any catalyst.
    • 在替代实施方案中,提供了用于从油制备高品质生物柴油和高品质甘油的系统和方法:例如天然油:玉米油,蒸馏酒玉米,亚麻籽,亚麻籽,棉籽,油菜籽(油菜),花生,向日葵 ,红花,椰子,棕榈,大豆,包括高百分比(例如> 10%)的有机酸,例如 游离脂肪酸。 在替代实施例中,提供了用于生产生物柴油的系统和方法满足或超过ASTM规范D6751-14中所述的B100生物柴油的规格,以及满足或超过美国药典公约(USP)标准的甘油副产物 )从包含高百分比有机酸的天然油原料中分离甘油。 在替代实施方案中,具有高有机酸含量的天然油原料在醇或不高于醇的临界温度和压力的条件下在不存在任何催化剂的条件下进行与醇的酯交换反应。
    • 9. 发明申请
    • PROCESS FOR THE PRODUCTION OF HYDROCARBON FRACTIONS FROM MIXTURES OF A BIOLOGICAL ORIGIN
    • 生物原料混合物生产烃类的方法
    • WO2015107487A1
    • 2015-07-23
    • PCT/IB2015/050336
    • 2015-01-16
    • ENI S.P.A.
    • BELLUSSI, GiuseppeMOLINARI, DanieleASSANELLI, GiulioDE ANGELIS, Alberto Renato
    • C10G45/58C10G3/00C07C1/20C11B3/00C11C3/12
    • C10G3/50C10G45/58C11C1/04C11C1/08C11C1/10C11C3/003C11C3/12C11C3/14Y02E50/13Y02P30/20
    • A process is described for the production of hydrocarbon fractions which can be used as diesel fuel or as components of diesel fuel, starting from a mixture of a biological origin containing fatty acid esters with glycerine, and possibly containing aliquots of free fatty acids and/or phosphoglycerides, wherein said process comprises the following steps: - subjecting the mixture of a biological origin to hydrolysis, obtaining a mixture containing glycerine and a mixture of fatty acids, - neutralizing the mixture of fatty acids with ammonia, - subjecting the neutralized mixture to hydrodeoxygenation, - subjecting the mixture resulting from the hydrodeoxygenation to hydroisomerization. The process of the present invention allows the triglycerides. This aspect, in addition to allowing the recovery of glycerine, which can be used as precursor of fuel components, allows the hydrogen consumption to be avoided in the hydrodeoxygenation step, which occurs when glycerine is present and therefore undergoes reduction to propane. Furthermore, if the mixture of a biological origin also contains aliquots of free fatty acids, the process of the invention also avoids problems of corrosion due to said acids, during the hydrodeoxygenation treatment.
    • 描述了用于生产可用作柴油燃料或作为柴油燃料成分的烃馏分的方法,其起始于含有脂肪酸酯与甘油的生物来源的混合物,并且可能含有等分的游离脂肪酸和/或 磷酸甘油酯,其中所述方法包括以下步骤: - 使生物来源的混合物进行水解,得到含有甘油和脂肪酸混合物的混合物, - 中和脂肪酸混合物与氨, - 将中和的混合物进行加氢脱氧 将由加氢脱氧产生的混合物进行加氢异构化。 本发明的方法允许甘油三酸酯。 除了允许可用作燃料成分前体的甘油的回收之外,这一方面允许在加氢脱氧步骤中避免氢消耗,当甘油存在并因此经历还原成丙烷时,可以避免氢消耗。 此外,如果生物来源的混合物还含有游离脂肪酸的等分试样,则本发明的方法还避免了在加氢脱氧处理期间由于所述酸引起的腐蚀问题。