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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
141		FR898576D	1943-10-04	FR898576A	1945-04-26

142		FR862423D	1939-12-19	FR862423A	1941-03-06

143	Verfahren zur Herstellung von Borsten für Bürsten, Besen und andere Artikel.	CH212436D	1939-03-27	CH212436A	1940-11-30	FARBENINDUSTRIE AKTIENGESELLSC

144	A process for manufacturing films, ribbons, foils, threads, and fibres	GB3692838	1938-12-19	GB527075A	1940-10-02
527,075. Reaction products of rubbers. FIFE, J. G. (Naamlooze Vennootschap de Bataafsche Petroleum Maatschappij). Dec. 19, 1938, Nos. 36928/38, 15971/39 and 32189/39. [Class 70] [Also in Group IV] Multi-unsaturated organic compounds of high molecular weight (at least about 5000) are reacted with inorganic acids or anhydrides {except those of highest state of valency where the acid-forming element has more than one valency) in the presence of liquid organic compounds containing " ether like " oxygen atoms {i.e. oxygen atoms linked by single bonds to each of two carbon atoms). Suitable initial bodies are polymers of butadiene, acetylene and their substitution products and homologues and co-polymers of these substances with other unsaturated bodies such as olefines, styrene, vinyl esters, acrylic and methacrylic acids and unsaturated aldehydes, ketones and ethers, and also natural rubber. Suitable inorganic acids and anhydrides are phosphorous, sulphurous, and nitrous anhydrides and acids ; hydrogen sulphide and halogen hydrides, but mixtures which produce free sulphur (such as SO 2 +H 2 S) are excluded. Activating agents such as metal salts which form addition compounds with ether-like compounds may also be present. The reaction may be effected in the presence of a solvent or solvent mixture which may itself contain an ether-like compound. In examples (1) SO 2 is passed into butadiene polymer in benzene and dioxane is added (3) rubber in benzene is treated with SO 2 and dioxane ; (4) a divinyl acetylene polymer is treated similarly ; (5) hydrogen sulphide is passed into butadiene polymer in dioxane ; (6) butadiene polymer in dioxane is coagulated in a bath containing acetic acid, water, and sulphur dioxide ; (7) a bath containing methanol, water, and sulphur dioxide is used for coagulating butadiene polymer solutions in a dioxane alone and together with di-isopropyl ether, diethyl acetal, paraldehyde, diethyl ether, pentane, carbon disulphide and benzene respectively ; (8) NO+NO 2 is passed into butadiene polymer in dioxane, isopropyl ether and benzene, methyl propene methylene dioxide, ethene methylene dioxide, and dioxane and isopropyl ether respectively, butadiene polymer in dioxane is coagulated in (9) aqueous sodium nitrate and hydrochloric acid, (10) aqueous phosphorous acid (11) nitrous acid saturated with SO 2 (12) mixtures of menthanol, water and SO 2 containing FeSO 4 FeCl 3 and MnSO 4 respectively, but CuSO 4 and ZnCl 2 may also be used ; (13) a solution of butadiene polymer in dioxane is spun upwardly into a vertical tube filled with a coagulation liquid consisting of ethyl and benzyl alcohols and water saturated with SO 2 (14) the same dutadiene polymer solution into ethyl alcohol saturated with SO 2 ; (15) butadiene polymer in dioxane is injected into a coagulation bath containing boron fluoride, acetic acid and SO 2 ; (16) butadiene polymer in dioxane and paraldehyde is injected into liquid SO 2 at -15‹C. ; (17) butadiene polymer in dioxane is spun into a vertical tube filled with SO 2 at 60‹C.; (18) neoprene and butadiene polymer in dioxane is coagulated in a bath containing methanol, water and SO 2 to produce films ; (19) butadiene polymer and ethyl cellulose or cellulose acetate in dioxane is coagulated in the same mixture ; (20) butadiene polymer in dioxane is poured into a silk gauze and SO 2 + CO 2 is passed over the film, leaving a gastight layer ; (21) linen is boiled in dioxane and then immersed in butadiene polymer in dioxane containing Igepon T,"Igepon" being a Registered Trade Mark, the material being then pressed and passed into a bath containing methanol, water and SO 2 washed and dried, this treatment increases the crease stability. Specification 500,515 is referred to.
145	Improvements in shaped bodies, such as thin sheets, threads or the like, composed essentially of rubber hydrochloride and methods of producing such bodies	GB1192237	1937-04-26	GB497788A	1938-12-28
497,788. Halogenated rubber ; compound sheet materials ; yarns etc.; catgut substitutes. MINICH, H. D. April 26, 1937, No. 11922. Convention date, April 30, 1936. [Class 70] [Also in Groups VIII, IX, and XXV] Rubber hydrochloride bodies, particularly in the form of thin sheets or threads, are heated to a temperature at which they are plastic (150-230‹ F.), stretched in one or more directions, and cooled while stretched to solidification temperature ; this makes them stronger, more resilient, more tear-resistant, lustrous and crackly. A film may be stretched to 2-6 times its original length. The process may be repeatedly applied to a sheet or to a plurality of sheets. Transparent strips 21 and narrow red strips 22 are assembled in a funnel 30, passed over a heating cylinder 32, under an auxiliary heater 41, and through a cooler 34, and stretched by rollers 35 which rotate faster than rollers 31. The strips fuse into a homogeneous strip. The slots 28 in the assembly plate 27 and the exit end of the funnel 30 may be narrower than the widest sheet fed therethrough, so that the edges of the said sheet are rolled over and beads are formed on the finished article. The surface of the cylinder 32 may be grained or ribbed, and the surface of one or both of the idler rollers 42, 43 may be provided with ornamental or other designs. One or more of the intermediate layers may be imprinted or perforated. The relative speeds of the sheets may be varied, e.g. by rotating the upper of the rollers 35 or 31 at a higher or lower speed than the lower. The drive of the heating cylinder 32 may be correlated with the drive of the rollers 31 or 35 or both. In making laminated coalesced films coloured films may be placed above, below or between other films, e.g. between transparent films ; opaque films may be placed under or between one or more coloured or transparent layers. Several films which have been stretched laterally and longitudinally are superposed in crosswise grain directions and again stretched and fused together under pressure ; longitudinal ribs may be produced in such laminations by inserting between the films, before stretching, narrow unstretched strips. A sheet is obtained by coalescing superposed layers of stretched and unstretched material while they are being stretched and heated to a plastic state and releasing them while they are plastic ; a strip having a crinkled central surface and ruffled edges may be obtained by thus treating two narrow pre-stretched strips enclosed between two wider unstretched strips. Compound sheet or strip material may be used in making shower curtains, raincoats, table covers, umbrella coverings, wall covering, packing material and dress goods. Narrow untreated strips may be rolled back and forth as they are moved over a heated surface and stretched as they are drawn away from it ; the thread so produced may be used as a substitute for gut for surgical sutures, musical strings, stringing racquets, leaders in angling and fishing lines and nets. Several ribbons of the rolled stretched material may be twisted together while being heated and stretched. A strip of untreated material may be twisted with a strip of pre-stretched material while the two are heated and stretched. The rubber hydrochloride may be made by dissolving 5 to 7 parts of rubber in 100 parts (by weight) of a solvent, e.g. benzene, and maintaining the solution at 50‹ F. for 6 hours while dry HC1 gas is passed through it. The treated solution is left for 24 hours at room temperature and the solvent and excess HC1 are then driven off by steam distillation or by passing nitrogen or air through the solution. The mass is washed with ammonia solution and water and the residual mass of rubber hydrochloride and ammonium hydrochloride is dried under vacuum. A film is obtained by making a 5 per cent by weight solution in, e.g. chloroform, which may contain a dye (or opaque, insoluble colouring matter) and an age-resister, e.g. cyclohexylamine formaldehyde, running the solution on to a moving belt surfaced with cellulose acetate or celluloid, removing the solvent by passing a stream of air over the surface and continuously stripping the film from the belt. Alternatively the rubber hydrochloride may be made by subjecting thin sheets of washed, milled, pale crepe rubber to the action of dry HCl gas at pressures up to 8 atmospheres at 180‹ F. for 12 to 48 hours, releasing the residual free HC1 and removing all traces of HC1 by heating under vacuum. In a third method, washed, milled, crepe rubber is treated with dry, liquid HC1 at low temperature, the required high pressure effecting hydrochlorination almost instantaneously. The Specification as open to inspection under Sect. 91 comprises also the application of the invention to bodies made of halogenated and hydrohalogenated butadiene bodies in general, e.g. the products of the reaction of HBr, HI, chlorine, bromine and iodine with rubber, guttapercha, balata, isoprene, erythiene, " chloroprene '' and the substance known under the Registered Trade Mark " Duprene." This subject-matter does not appear in the Specification as accepted.
146	전자 차폐성 경량 고강도 탄소 복합재료의 제조방법	KR1019980045222	1998-10-28	KR1020000027315A	2000-05-15	정두환; 김상진; 임정수; 조영근
PURPOSE: A light strong carbon complex material is provided to have the excellent electronic shielding property by thermally processing and after-processing a reinforcing complex material of carbon fiber. CONSTITUTION: A light and strong carbon complex material is produced by hot pressing after making a prepreg of carbon fibrous complex fiber by drying after impregnating a single fiber or a fibrous mat formed by cutting a carbon fiber in a regular length in a high molecular resin. A material selected from a group formed by a filling agent, a hardening catalyst, a coloring agent, an inner release agent, and their compound into the resin after controlling the concentration of the resin using an acetone, an ethanol, or a methanol of 100-500% of the resin weight as a solvent to be the 45-90% content of the resin among the complex material of carbon fiber obtained finally.
147		DE69129787	1991-11-13	DE69129787T2	1998-11-19	TAKAI YOUSUKE
Ion exchange fibers comprising a polymer component having a main chain of a syndiotactic poly(1,2-butadiene) structure and containing ion exchange functional groups introduced at least part of side chain ethylene groups. These fibers may be suitably formed into a non-woven fabrics, and thus an ion exchange cloth can be obtained, which has excellent ion exchange capacity, flexiblity excellent processing capacity, high mechanical strength and elongation. The ion exchange fibers have excellent ion exchange capacity with respect to fluid such as water or gas and thus can be used as cartridge filters and fiber-filled filters.
148	ELASTOMERIC FIBRES, STRUCTURES FASHIONED THEREFROM AND ELASTOMERIC FILMS	AU2116688	1988-08-18	AU608045B2	1991-03-21	HIMES GLENN ROY

149	DIRECT METHOD FOR PREPARING SYNDIOTACTIC 1,2-POLYBUTADINE	ZA87158	1987-01-09	ZA87158B	1987-08-26	BELL ANTHONY JOSEPH
Short fibers of syndiotactic 1,2-polybutadiene are utilized in making tires that have improved resistance against heat build-up and improved wear characteristics. The preparation of syndiotactic 1,2-polybutadiene in fibrous form has traditionally involved an extrusion and stretching step. However, the technique of the present invention circumvents the necessity of hot mill flexing and/or extrusion in making fibrous syndiotactic 1,2-polybutadiene. The present invention more specifically involves a process for preparing syndiotactic 1,2-polybutadiene fibers directly comprising polymerizing 1,3-butadiene monomer in the presence of (1) a catalyst composition which is comprised of (a) a cobalt compound and (b) an organoaluminum compound; (2) carbon disulfide; and (3) at least one member selected from the group consisting of liquid polymers and naphthenic oils.
150	NON WOVEN FABRIC OF 1,2 SBD	CA347180	1980-03-06	CA1137267A	1982-12-14	KONTOS EMMANUEL G
A non-woven fabric comprising an assembly of fibers of discrete length which are interconnected and, at least a portion of which are in contact with each other, said fibers comprising crystalline syndiotactic 1,2-polybutadiene (1,2 SBD).
151		AT461066	1966-05-16	AT263996B	1968-08-12
A solution of a sulphochlorinated polyolefine is spun into a primary or secondary diamine or into a solution of a primary or a secondary diamine in a solvent which is miscible with the solvent of the spinning solution. The polyolefine may be polyethylene, polypropylene, or an ethylene/propylene copolymer. The polymer solvent may be an aromatic hydrocarbon, a light petroleum spirit, or a halogenated hydrocarbon such as chlorobenzene chloroform or carbon tetrachloride. The last-named solvent is especially advantageous since the polyolefine is dissolved therein for sulphochlorination. The diamines (which cross-link the sulphochlorinated polyolefines) may be primary or secondary aliphatic, aromatic or araliphatic diamines, aliphatic diamines being used with special advantage. The carbon chain of the diamines may also be interrupted by bridging elements or groups such as oxygen or the carbonyl group. The amines which may be used include phenylenediamines, 4,41-diaminobenzophenone, xylylene diamine, the diaminodecanes, 2,21-diamino-diethyl ether, and N,N1-dimethyl-ethylene-diamine. Diamines having a chain of 2 to 6 carbon atoms are used with special advantage. In the preferred wet spinning process, the diamine solvent used for the coagulating bath may be a monohydric short-chain alcohol and/or a low molecular weight ketone. The coagulating bath may contain a compound such as a tertiary amine or sodium bicarbonate to neutralize the hydrochloric acid formed by the reaction between the sulphochlorinated polyolefine and the diamine which takes place in the bath. The filaments formed in the bath may be washed by passing them through a bath of hot water and stretched.
152	Process for the manufacture of cross-linked sulphochlorinated polyolefin filaments	GB2114566	1966-05-12	GB1110845A	1968-04-24
A solution of a sulphochlorinated polyolefine is spun into a primary or secondary diamine or into a solution of a primary or a secondary diamine in a solvent which is miscible with the solvent of the spinning solution. The polyolefine may be polyethylene, polypropylene, or an ethylene/propylene copolymer. The polymer solvent may be an aromatic hydrocarbon, a light petroleum spirit, or a halogenated hydrocarbon such as chlorobenzene chloroform or carbon tetrachloride. The last-named solvent is especially advantageous since the polyolefine is dissolved therein for sulphochlorination. The diamines (which cross-link the sulphochlorinated polyolefines) may be primary or secondary aliphatic, aromatic or araliphatic diamines, aliphatic diamines being used with special advantage. The carbon chain of the diamines may also be interrupted by bridging elements or groups such as oxygen or the carbonyl group. The amines which may be used include phenylenediamines, 4,41-diaminobenzophenone, xylylene diamine, the diaminodecanes, 2,21-diamino-diethyl ether, and N,N1-dimethyl-ethylene-diamine. Diamines having a chain of 2 to 6 carbon atoms are used with special advantage. In the preferred wet spinning process, the diamine solvent used for the coagulating bath may be a monohydric short-chain alcohol and/or a low molecular weight ketone. The coagulating bath may contain a compound such as a tertiary amine or sodium bicarbonate to neutralize the hydrochloric acid formed by the reaction between the sulphochlorinated polyolefine and the diamine which takes place in the bath. The filaments formed in the bath may be washed by passing them through a bath of hot water and stretched.
153	Polymeric materials and methods of preparing them	GB676864	1964-02-18	GB1011316A	1965-11-24
A polybutadiene sulphone consists of a plurality of units of formula in which the sulphur content (as sulphone) is 27 to 32 grams per gram equivalent weight of polymerized butadiene and the polymerized butadiene consists of at least 85% butadiene units connected in the 1,4 position. The polymer is prepared by extruding into a reaction medium containing sulphur dioxide a solution of a butadiene polymer which contains at least 85% of the repeating units in the 1,4 position and containing also a hydroperoxide catalyst, e.g. tertiary butyl-hydroperoxide.
154		NL6401425	1964-02-17	NL6401425A	1964-08-19

155		FR60687D	1950-07-06	FR60687E	1954-11-22

156		DEN0001549	1944-03-28	DE899708C	1953-12-14	NIE WILLEM LEENDERT JOHANNES D; RUMSCHEIDT GOTTFRIED ERNST

157		DEN0001552	1942-11-25	DE896107C	1953-11-09	RUMSCHEIDT GOTTFRIED ERNST; NIE WILLEM LEENDERT JOHANNES D

158		FR1040665D	1951-04-03	FR1040665A	1953-10-16

159	Improvements in and relating to the manufacture of artificial threads, fibres, filaments and the like	GB3099550	1950-12-20	GB694809A	1953-07-29	WILLIAMS HAROLD MALCOLM GORDON
Artificial threads are obtained by extruding a solution of a synthetic rubber obtained by polymerizing 1,3-butadiene or chloroprene either alone or in combination with a minor proportion of other polymerizable compounds such as styrene or acrylonitrile, containing a hydroperoxide into a coagulant bath containing sulphur dioxide, and at least 5 per cent by weight of the solvent used to dissolve the rubber, the extrusion being carried out in the presence of water. The water is preferably added in a proportion of 2-8 per cent by volume to the coagulant bath but may be added to the spinning bath in which case a water-miscible blending solution such as ethanol is also added. The hydroperoxide may be tertiary butyl hydroperoxide and the solvent toluene and the coagulant bath a mixture of ethanol or isopropanol and toluene. Specification 679,040 is referred to.ALSO:Artificial threads are obtained by extruding a solution of a natural rubber or a synthetic rubber obtained by polymerizing 1.3 butadiene or chloroprene either alone or in combination with a minor proportion of other polymerizable compounds such as styrene or acronitrile containing a hydroperoxide into a coagulant bath containing sulphur dioxide, and at least 5 per cent. by weight of the solvent used to dissolve the rubber the extrusion being carried out in the presence of water. The water is preferably added in a proportion of 2 to 8 per cent. by volume to the coagulant bath but may be added to the spinning bath in which case a water miscible blending solution such as ethanol is also added. The hydroperoxide may be tertiary butyl hydroperoxide and the solvent toluene and the coagulant bath a mixture of ethanol or isopropanol and toluene. Specification 679,040 is referred to.
160		FR1034066D	1951-03-16	FR1034066A	1953-07-17

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