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序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
181 RARE EARTH ALLOY SINTERED COMPACT AND METHOD OF MAKING THE SAME PCT/JP0203237 2002-03-29 WO02079530A2 2002-10-10 MORIMOTO HITOSHI; KANEKO YUJI
A rare earth sintered compact includes a main phase represented by (LR1xHRX)2T14A, where T is Fe with or without non-Fe transition metal element(s); A is boron with or without carbon; LR is a light rare earth element such as Nol; HR is a heavy rare earth element such as Dy; and O
182 Sm(Co, Fe, Cu, Zr, C) COMPOSITIONS AND METHODS OF PRODUCING SAME PCT/US9924989 1999-10-25 WO0026926A9 2000-11-09 GONG WEI; MA BAO-MIN
Carbon addition to the rapidly solidified, preferably melt spun, alloy system of Sm(Co, Fe, Cu, Zr) provides for good isotropic magnetic properties. Importantly, these alloys are nanocomposite in nature and comprise the SmCoC2 phase. Thermal processing of these materials can achieve good magnetic properties at lower temperatures and/or shorter processing times than conventional Sm(Co, Fe, Cu, Zr) powders for bonded magnet application.
183 THIN PLATE MAGNET HAVING MICROCRYSTALLINE STRUCTURE PCT/JP1998/000331 1998-01-28 WO98036428A1 1998-08-20
A method of manufacturing an Nd-Fe-B microcrystalline permanent magnet which contains a low concentration of rare-earth elements, in which a soft magnetic phase and a hard magnetic phase are intermixed, which has, after cast, an inherent coercive force iHc of not less than 2.5 kOe and a residual flux density Br of not less than 9 kG, which has a cost-performance comparable to that of a hard ferrite magnet, and which has a microcrystalline structure having a thickness of 70 mu m - 500 mu m and contributing to the size and thickness reduction of a magnetic circuit. The melt of an alloy with a specific composition is cast onto a rotating cooling roll in a depressurized inert gas atmosphere with a pressure not higher than 30 kPa and a microcrystalline permanent magnet alloy having a microcrystalline structure of 15 nm - 50 nm is directly manufactured from the alloy melt. By employing an alloy melt with a specific composition to which Co, Cr, Mn, Ni, Cu, Ga, Ag, Pt, Au and Pb are added in this manufacturing process, a microcrystalline permanent magnet alloy such that the inherent coercive force iHc can be improved to be not less than 2.5 kOe, an optimum roll circumferential velocity range with which the hard magnetic characteristics can be exhibited can be widened in comparison with the range of the manufacturing conditions of Nd-Fe-B ternary magnet, and the thickness of 70 mu m - 500 mu m can be obtained.
184 ANISOTROPIC NANOCOMPOSITE RARE EARTH PERMANENT MAGNETS AND METHOD OF MAKING PCT/US2005023489 2005-06-30 WO2006004998A3 2006-05-04 LIU SHIQIANG; LEE DON
A bulk, anisotropic, nanocomposite, rare earth permanent magnet. Methods of making the bulk, anisotropic, nanocomposite, rare earth permanent magnets are also described.
185 NANOCOMPOSITE MAGNET AND METHOD FOR PRODUCING SAME PCT/JP2001/009854 2001-11-09 WO02039465A1 2002-05-16
A method of making a material alloy for an iron-based rare earth magnet includes the step of forming a melt of an alloy with a composition of (Fe1-mTm)100-x-y-z-n(B1-pCp)xRyTizMn. T is Co and/or Ni; R is at least one element selected from Y (yttrium) and the rare earth elements; and M is at least one element selected from Al, Si, V, Cr, Mn, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Ag, Hf, Ta, W, Pt, Au and Pb, wherein the following inequalities are satisfied: 10
186 PROCESS FOR PRODUCING, THROUGH STRIP CASTING, RAW ALLOY FOR NANOCOMPOSITE TYPE PERMANENT MAGNET PCT/JP2001/008317 2001-09-25 WO02030595A1 2002-04-18
A process for efficiently producing at low cost a raw alloy for nanocomposite magnets which is mainly amorphous. The process comprises preparing a molten alloy represented by Fe100-x-y-zRxQyMz (wherein R is at least one of praseodymium, neodymium, dysprosium, and terbium; Q is at least one of boron and carbon; M is at least one of cobalt, aluminum, silicon, titanium, vanadium, chromium, manganese, nickel, copper, gallium, zirconium, niobium, molybdenum, silver, platinum, gold, and lead; 1 ≤ x < 6 at.%; 15 ≤ y ≤ 30 at.%; and 0 ≤ z ≤ 7 at.%) and feeding this molten alloy to a cooling roll rotating at a peripheral speed of 3 to 20 m/sec, excluding 20 m/sec, so that the feed rate per unit contact width is in the range of 0.2 to 5.2 kg/min/cm to thereby rapidly cool the alloy by strip casting. Thus, an alloy at least 60 vol.% of which is amorphous can be produced.
187 PERMANENT MAGNET INCLUDING MULTIPLE FERROMAGNETIC PHASES AND METHOD FOR PRODUCING THE MAGNET PCT/JP2001/004244 2001-05-21 WO01091139A1 2001-11-29
An iron-based rare earth alloy magnet has a composition represented by the general formula: (Fe1-mTm)100-x-y-zQxRyMz, where T is at least one element selected from the group consisting of Co and Ni; Q is at least one element selected from the group consisting of B and C; R is at least one rare earth element substantially excluding La and Ce; and M is at least one metal element selected from the group consisting of Ti, Zr and Hf and always includes Ti. In this formula, the mole fractions x, y, z and m meet the inequalities of: 10 at%<)x
188 Method for producing a magnetic article GB0817924 2008-10-01 GB2463931B 2011-01-12 KATTER MATTHIAS; GERSTER JOACHIM; ROTH OTTMAR
A magnetic article comprises, in total, elements in amounts capable of providing at least one (La1-aMa)(Fe1-b-cTbYc)13-dXe phase and less than 0.5 Vol % impurities, wherein 0@a@0.9, 0@b@0.2, 0.05@c@0.2, -1@d@+1, 0@e@3, M is one or more of the elements Ce, Pr and Nd, T is one or more of the elements Co, Ni, Mn and Cr, Y is one or more of the elements Si, Al, As, Ga, Ge, Sn and Sb and X is one or more of the elements H, B, C, N, Li and Be. The magnetic article comprises a permanent magnet.
189 RARE EARTH PERMANENT MAGNET MYPI20060340 2006-01-25 MY142024A 2010-08-16 NAKAMURA HAJIME; HIROTA KOICHI; SHIMAO MASANOBU; MINOWA TAKEHISA
A RARE EARTH PERMANENT MAGNET IS IN THE FORM OF A SINTERED MAGNET BODY HAVING A COMPOSITION R1aR2bTcAdFeOfMg WHEREIN F AND R2 ARE DISTRIBUTED SUCH THAT THEIR CONCENTRATION INCREASES ON THE AVERAGE FROM THE CENTER TOWARD THE SURFACE OF THE MAGNET BODY, AND GRAIN BOUNDARIES HAVING A CONCENTRATION OF R2/(R1+R 2 )WHICH IS ON THE AVERAGE HIGHER THAN THE CONCENTRATION OF R2/ (R1+R 2 ) CONTAINED IN PRIMARY PHASE GRAINS OF (R1,R2)2T14A TETRAGONAL SYSTEM FORM A THREE-DIMENSIONAL NETWORK STRUCTURE WHICH IS CONTINUOUS FROM THE MAGNET BODY SURFACE TO A DEPTH OF AT LEAST 10 UM. THE INVENTION PROVIDES R-FE-B SINTERED MAGNETS WHICH EXHIBIT A HIGH COERCIVE FORCE.
190 DE69940976 1999-10-25 DE69940976D1 2009-07-23 GONG WEI; MA BAO-MIN
191 DE60131561 2001-09-25 DE60131561T2 2008-03-06 MURAKAMI RYO; KANEKIYO HIROKAZU; HIROSAWA SATOSHI
To make a raw alloy, consisting mostly of amorphous structure, highly productively and at a reduced cost for a nanocomposite magnet, a molten alloy represented by Fe 100-x-y-z R x Q y M z (where R is at least one element selected from Pr, Nd, Dy and Tb; Q is B and/or C; M is at least one element selected from Co, Al, Si, Ti, V, Cr, Mn, Ni, Cu, Ga, Zr, Nb, Mo, Ag, Pt, Au and Pb; and 1 at%‰¦x<6 at%, 15 at%‰¦y‰¦30 at% and 0 at%‰¦z‰¦7 at%) is prepared. This molten alloy is rapidly cooled by a strip casting process in which the alloy is fed onto a chill roller, rotating at a peripheral velocity of 3 m/s to less than 20 m/s, at a feeding rate per unit contact width of 0.2 kg/min/cm to 5.2 kg/min/cm. In this manner, an alloy including at least 60 volume percent of amorphous phase can be obtained.
192 DE60131561 2001-09-25 DE60131561D1 2008-01-03 MURAKAMI RYO; KANEKIYO HIROKAZU; HIROSAWA SATOSHI
To make a raw alloy, consisting mostly of amorphous structure, highly productively and at a reduced cost for a nanocomposite magnet, a molten alloy represented by Fe 100-x-y-z R x Q y M z (where R is at least one element selected from Pr, Nd, Dy and Tb; Q is B and/or C; M is at least one element selected from Co, Al, Si, Ti, V, Cr, Mn, Ni, Cu, Ga, Zr, Nb, Mo, Ag, Pt, Au and Pb; and 1 at%‰¦x<6 at%, 15 at%‰¦y‰¦30 at% and 0 at%‰¦z‰¦7 at%) is prepared. This molten alloy is rapidly cooled by a strip casting process in which the alloy is fed onto a chill roller, rotating at a peripheral velocity of 3 m/s to less than 20 m/s, at a feeding rate per unit contact width of 0.2 kg/min/cm to 5.2 kg/min/cm. In this manner, an alloy including at least 60 volume percent of amorphous phase can be obtained.
193 РЕДКОЗЕМЕЛЬНЫЙ ПОСТОЯННЫЙ МАГНИТ RU2006103678 2006-02-08 RU2006103678A 2007-08-20
194 DE60215665 2002-07-19 DE60215665D1 2006-12-07 MIYOSHI TOSHIO; KANEKIYO HIROKAZU; HIROSAWA SATOSHI
Iron-based rare earth alloy nanocomposite magnetic powder is produced by an atomization method, and contains >=2 ferromagnetic crystal phases. The average size of the hard crystal phase is 10-200nm and the average size of the soft magnetic phase is 1-100nm. The powder has the composition (Fe 1-mT m) 100-x-y-z-nQ xR yTi zM n. T : Co and/or Ni; Q : B and/or C; R : rare earth metal and/or yttrium; M : Nb, Zr, Mo, Ta and/or Hf; x : 10-25 atom%; y : 6-10 atom%; z : 0.1-12 atom%; m : 0-0.5; n : 0-10 atom%. Independent claims are also included for (1) a bonded magnet containing the powder; (2) the manufacture of the powder; and (3) the manufacture of the bonded magnet.
195 NANOCOMPOSITE MAGNET AND METHOD FOR PRODUCING SAME MYPI20015220 2001-11-13 MY127175A 2006-11-30 HIROKAZU KANEKIYO; TOSHIO MIYOSHI; SATOSHI HIROSAWA
A METHOD OF MAKING A MATERIAL ALLOY FOR AN IRON-BASED RARE EARTH MAGNET INCLUDES THE STEP OF FORMING A MELT (3) OF AN ALLOY WITH A COMPOSITION OF (FEL-M TM) L00-X-Y-Z-N (BL-PCP) XRY TIZMN. T IS CO AND/OR NI; R IS AT LEAST ONE ELEMENT SELECTED FROM Y (YTTRIUM) AND THE RARE EARTH ELEMENTS; AND M IS AT LEAST ONE ELEMENT SELECTED FROM A1, SI, V, CR, MN, NI, CU, ZN, GA, ZR, NB, MO, AG, HF, TA, W,PT, AU AND PB, WHEREIN THE FOLLOWING INEQUALITIES ARE SATISFIED: 10 < X < 25 AT%, *6 < Y < 10 AT %, 0.5 < Z < 12 AT%, 0 < M < 0.5, 0 < N < 10 AT% AND 0 < P < 0.25. NEXT, THE MELT (3) IS FED ONTO A SHOOT (5) WITH A GUIDE SURFACE TILTED AT ABOUT 1 DEGREE TO ABOUT 80 DEGREES WITH RESPECT TO A HORIZONTAL PLANE, THEREBY MOVING THE MELT (3) ONTO A MELT/ROLLER CONTACT REGION.THE MELT (3) IS THEN RAPIDLY COOLED USING A CHILL ROLLER (7) TO MAKE A RAPIDLY SOLIDIFIED ALLOY INCLUDING AN R2FE14B PHASE.(FIG 1)
196 PERMANENT MAGNET INCLUDING MULTIPLE FERROMAGNETIC PHASES AND METHOD FOR PRODUCING THE MAGNET MYPI20012462 2001-05-24 MY125006A 2006-07-31 HIROKAZU KANEKIYO; TOSHIO MIYOSHI; SATOSHI HIROSAWA; YASUTAKA SHIGEMOTO; YUSUKE SHIOYA
AN IRON-BASED RARE EARTH ALLOY MAGNET HAS A COMPOSITION REPRESENTED BY THE GENERAL FORMULA: (FE?-M TM) 100-X-Y-Z QXRYMZ, WHERE T IS AT LEAST ONE ELEMENT SELECTED FROM THE GROUP CONSISTING OF B AND C; R IS AT LEAST ONE RARE EARTH ELEMENT SUBSTANTIALLY EXCLUDING LA AND CE; AND M IS AT LEAST ONE METAL ELEMENT SELECTED FROM THE GROUP CONSISTING OF Ti, Zr AND Hf AND ALWAYS INCLUDES Ti. IN THIS FORMULA, THE MOLE FRACTIONS X,Y,Z AND M MEET THE INEQUALITIES OF : 10 AT%< X? 20 AT%; 6 AT%? Y < 10 AT%; 0.1 AT? Z ? 12 AT%; AND 0 ? M ? 0.5, RESPECTIVELY.(FIGURE 4)
197 AT01123787 2001-10-04 AT327561T 2006-06-15 KANEKO YUJI; TANIGUCHI KATSUYA; SEKINO TAKAO
The present invention provides a rare-earth sintered magnet exhibiting desirable magnetic properties in which the amount of Nd and/or Pr forming a non-magnetic phase in a grain boundary phase is reduced. Specifically, the present invention provides a rare-earth sintered magnet having a composition of (R1x+R2y)T100-x-y-zQz where R1 is at least one element selected from the group consisting of all rare-earth elements excluding La (lanthanum), Y (yttrium) and Sc (scandium); R2 is at least one element selected from the group consisting of La, Y and Sc; T is at least one element selected from the group consisting of all transition elements; Q is at least one element selected from the group consisting of B and C, and including, as a main phase, a crystal grain of an Nd2Fe14B crystalline structure, wherein: molar fractions x, y and z satisfy 8≤ x≤ 18 at%, 0.1≤ y≤ 3.5 at% and 3≤ z≤ 20 at%, respectively; and a concentration of R2 is higher in at least a part of a grain boundary phase than in the main phase crystal grains.
198 Hard magnetic composition, permanent magnet powder, method for permanent magnet powder, and bonded magnet HK06104245 2006-04-07 HK1082318A1 2006-06-02 SAKAMOTO ATSUSHI; NAKANE MAKOTO; NAKAMURA HIDEKI; FUKUNO AKIRA
A single phase consisting of a ThMn12 phase can be obtained by having the composition thereof represented by a general formula R(Fe100-y-wCowTiy)xSizAv (in the general formula, R is at least one element selected from rare earth elements (here the rare earth elements signify a concept inclusive of Y), Nd accounts for 50 mol% or more of R, and A is N and/or C) in which the molar ratios in the general formula are such that x = 10 to 12.5, y = (8.3 - 1.7 x z) to 12.3, z = 0.1 to 2.3, v = 0.1 to 3 and w = 0 to 30, and the relation (Fe + Co + Ti + Si)/R > 12 is satisfied.
199 DE60117205 2001-09-18 DE60117205D1 2006-04-20 TOMIZAWA HIROYUKI; KANEKO YUJI
Magnetic alloy powder for a permanent magnet contains: R of about 20 mass percent to about 40 mass percent (R is Y, or at least one type of rare earth element); T of about 60 mass percent to about 79 mass percent (T is a transition metal including Fe as a primary component); and Q of about 0.5 mass percent to about 2.0 mass percent (Q is an element including B (boron) and C (carbon)). The magnetic alloy powder is formed by an atomize method, and the shape of particles of the powder is substantially spherical. The magnetic alloy powder includes a compound phase having Nd2Fe14B tetragonal structure as a primary composition phase. A ratio of a content of C to a total content of B and C is about 0.05 to about 0.90.
200 DE60205728 2002-02-06 DE60205728D1 2005-09-29 KANEKIYO HIROKAZU; KITAYAMA HIROKAZU; HIROSAWA SATOSHI; MIYOSHI TOSHIO
An iron-based rare-earth alloy powder includes: a first iron-based rare-earth alloy powder, which has a mean particle size of 10 mu m to 70 mu m and of which the powder particles have aspect ratios of 0.4 to 1.0; and a second iron-based rare-earth alloy powder, which has a mean particle size of 70 mu m to 300 mu m and of which the powder particles have aspect ratios of less than 0.3. The first and second iron-based rare-earth alloy powders are mixed at a volume ratio of 1:49 to 4:1. In this manner, an iron-based rare-earth alloy powder with increased flowability and a compound to make a magnet are provided.