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序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
121 DE69010974 1990-05-07 DE69010974D1 1994-09-01 BUSCHOW KURT HEINZ JUERGEN; DE MOOIJ DIRK BASTIAAN; JACOBS THEODORA HENDRICA
A description is given of a hard magnetic material whose composition corresponds to the formula RE2Fe17Cx, RE consisting for at least 70 at.% of Sm. This material has a favourable uniaxial anisotropy and a relatively high Tc and is very suitable for use in permanent magnets.
122 AT90201155 1990-05-07 AT109299T 1994-08-15 BUSCHOW KURT HEINZ JUERGEN C O; DE MOOIJ DIRK BASTIAAN C O INT; JACOBS THEODORA HENDRICA C O I
A description is given of a hard magnetic material whose composition corresponds to the formula RE2Fe17Cx, RE consisting for at least 70 at.% of Sm. This material has a favourable uniaxial anisotropy and a relatively high Tc and is very suitable for use in permanent magnets.
123 DE68904811 1989-05-26 DE68904811T2 1993-05-27 OHASHI KEN; TAWARA YOSHIO; OSUGI RYO
A rare earth permanent magnet of the formula R(Fe1-x-yCoxMy)z , in which R is rare earth element(s) and/or Y, M is Si, Ti, Mo, B, W, V, Cr, Mn, Al, Nb, Ni, Sn, Ta, Zr, and/or Hf, and x, y, z are numbers such that 0
124 PT9741191 1991-04-18 PT97411A 1992-01-31 COEY JOHN MICHAEL DAVID; SUN HONG
125 HOT WORKED RARE EARTH-IRON-CARBON MAGNETS CA2034632 1991-01-21 CA2034632A1 1991-08-21 FUERST CARLTON D; BREWER EARL G
126 DE60139158 2001-11-12 DE60139158D1 2009-08-13 KANEKIYO HIROKAZU; MIYOSHI TOSHIO; HIROSAWA SATOSHI
The material alloy manufacture involves feeding the melt of iron-based rare earth material alloy onto a guide having a guide surface which defines an angle of 1-80[deg] with respect to horizontal plane so as to move the melt onto a region where the melt is contacted with the chill roller, and rapidly cooling the melt in the chill roller to make a rapidly solidified alloy comprising iron boride phase. The material alloy manufacture involves feeding the melt of iron-based rare earth material alloy onto the guide having a guide surface which defines an angle of 1-80[deg] with respect to horizontal plane so as to move the melt onto a region where the melt is contacted with the chill roller, and rapidly cooling the melt in the chill roller to make a rapidly solidified alloy comprising iron boride (R 2Fe 14B) phase. Iron-based material alloy has the composition: (Fe 1-mT m) 100-x-y-z-n(B 1-pCp) xR yTi zM n T is cobalt and/or nickel; R is yttrium and/or rare earth elements; M is aluminum, silicon, vanadium, chromium, manganese, copper, zinc, gallium, zirconium, niobium, molybdenum, silver, hafnium, tantalum, tungsten, platinum, gold, and/or lead; and the mole fraction x, y, z, m, n and p satisfy the relations: 10 atom% less than x=25 atom%, 6 atom% =y less than 10 atom%, 0.5 atom% =z=12 atom%, 0=m=0.5, 0 atom%=n=10 atom% and 0=p=0.25. Independent claims are included for the following: (1) production of iron-based permanent magnet; (2) production of bonded magnet; (3) rapidly solidifying alloy; and (4) magnetic powder having the alloy composition.
127 DE69938467 1999-07-28 DE69938467T2 2009-04-09 KAMADA MASAMI; OBATA MICHIO; SATO YUICHI
128 AT02710497 2002-02-04 AT404982T 2008-08-15 KANEKIYO HIROKAZU; HIROSAWA SATOSHI
A melt of an iron-based rare earth material alloy, represented by (Fe1-mTm)100-x-y-zQxRyMz, is prepared. T is Co and/or Ni; Q is B and/or C; R is selected from Y (yttrium) and the rare earth elements; M is selected from Al, Si, Ti, V, Cr, Mn, Cu, Zn, Ga, Zr, Nb, Mo, Ag, Hf, Ta, W, Pt, Au and Pb; 10<=x<=30 at %; 2%<=y<10 at %; 0<=z<=10 at % and 0<=m<=0.5. The melt is fed onto a guide to form a flow of the melt thereon and move the melt onto a melt/chill roller contact region, where the melt is rapidly cooled by the chill roller to make a rapidly solidified alloy. An oxygen concentration of the melt yet to be fed onto the guide is controlled at about 3,000 ppm or less in mass percentage.
129 AT02749324 2002-07-19 AT343842T 2006-11-15 MIYOSHI TOSHIO; KANEKIYO HIROKAZU; HIROSAWA SATOSHI
Iron-based rare earth alloy nanocomposite magnetic powder is produced by an atomization method, and contains >=2 ferromagnetic crystal phases. The average size of the hard crystal phase is 10-200nm and the average size of the soft magnetic phase is 1-100nm. The powder has the composition (Fe 1-mT m) 100-x-y-z-nQ xR yTi zM n. T : Co and/or Ni; Q : B and/or C; R : rare earth metal and/or yttrium; M : Nb, Zr, Mo, Ta and/or Hf; x : 10-25 atom%; y : 6-10 atom%; z : 0.1-12 atom%; m : 0-0.5; n : 0-10 atom%. Independent claims are also included for (1) a bonded magnet containing the powder; (2) the manufacture of the powder; and (3) the manufacture of the bonded magnet.
130 DE60213642 2002-11-19 DE60213642D1 2006-09-14 KANEKIYO HIROKAZU; MIYOSHI TOSHIO; HIROSAWA SATOSHI
A nanocomposite magnet has a composition represented by (Fe1-mTm)100-x-y-z-nQxRyTizMn, where T is at least one of Co and Ni, Q is at least one of B and C, R is at least one rare earth element that always includes at least one of Nd and Pr and optionally includes Dy and/or Tb, and M is at least one element selected from the group consisting of Al, Si, V, Cr, Mn, Cu, Zn, Ga, Zr, Nb, Mo, Ag, Hf, Ta, W, Pt, Au and Pb. The mole fractions x, y, z, m and n satisfy 10 at %
131 DE60117205 2001-09-18 DE60117205T2 2006-07-27 TOMIZAWA HIROYUKI; KANEKO YUJI
Magnetic alloy powder for a permanent magnet contains: R of about 20 mass percent to about 40 mass percent (R is Y, or at least one type of rare earth element); T of about 60 mass percent to about 79 mass percent (T is a transition metal including Fe as a primary component); and Q of about 0.5 mass percent to about 2.0 mass percent (Q is an element including B (boron) and C (carbon)). The magnetic alloy powder is formed by an atomize method, and the shape of particles of the powder is substantially spherical. The magnetic alloy powder includes a compound phase having Nd2Fe14B tetragonal structure as a primary composition phase. A ratio of a content of C to a total content of B and C is about 0.05 to about 0.90.
132 DE60206031 2002-03-29 DE60206031T2 2006-01-19 MORIMOTO HITOSHI; KANEKO YUJI
A rare earth alloy sintered compact includes a main phase represented by (LR 1-x HR x ) 2 T 14 A, where T is Fe with or without non-Fe transition metal element(s); A is boron with or without carbon; LR is a light rare earth element; HR is a heavy rare earth element; and 0
133 DE69831256 1998-01-28 DE69831256D1 2005-09-22 KANEKIYO HIROKAZU; HIROSAWA SATOSHI
The purpose of the present invention is to present a thin-plate magnet with a fine crystalline structure that is 70 mu m to 500 mu m thick, making miniature, thin magnetic circuits possible, and has, as cast, an inherent coercive force iHc of 2.5 kOe or higher and residual magnetic flux density of 9 kG or higher and a performance-to-cost ratio rivaling that of hard ferrite magnets when Nd-Fe-B fine crystalline permanent magnets with a low rare earth content that are a mixture of a soft magnetic phase and a hard magnetic phase are produced. iHc can be increased to 2.5 kOe or higher and the optimum roll circumferential speed range within which hard magnetic properties are realized can be expanded when compared to the conditions under which Nd-Fe-B ternary magnets are produce, while at the same time, a fine crystalline permanent magnet alloy with a thickness of 70 mu m to 500 mu m is obtained, by using an alloy melt with a specific composition to which Co, Cr, Mn, Ni, Cu, Ga, Ag, Pt, Au, or Pb has been added during the process whereby a fine crystalline permanent magnet alloy having a fine crystalline structure of 15 nm to 50 nm is produced directly from an alloy melt by continuously casting the alloy melt on a cooling roller that is rotating in an inert gas atmosphere under reduced pressure of 30 kPa or less.
134 DE69822798 1998-01-28 DE69822798T2 2004-08-05 KANEKIYO HIROKAZU; HIROSAWA SATOSHI
The present invention is presented with the object of providing a manufacturing method for thin-plate magnets that, as cast, exhibit an intrinsic coercive force iHc of 2.5 kOe or greater and a residual magnetic flux density Br of 9 kG or greater, exhibit a performance-to-cost ratio comparable to hard ferrite magnets, and exhibit a fine crystalline structure with a thickness of 70 to 500 mu m wherewith magnetic circuits can be made smaller and thinner. By employing alloy melts to which specific elements have been added, in a process wherein alloy melts of specific composition are continuously cast on a rotating cooling roller or rollers in a reduced-pressure inert or inactive gas atmosphere at 30 kPa or less, and fine crystalline permanent magnets having a fine crystalline structure of 10 to 50 nm are fabricated, fine crystalline permanent magnets having a thickness of 70 to 500 mu m can be obtained wherein iHc is improved to 2.5 kOe or greater, and the ideal roller circumferencied speed range wherein hard magnetic properties are manifested can be broadened as compared to the conditions under which Nd-Fe-B ternary magnets are fabricated
135 DE60102278 2001-11-12 DE60102278D1 2004-04-15 KANEKIYO HIROKAZU; MIYOSHI TOSHIO; HIROSAWA SATOSHI
The material alloy manufacture involves feeding the melt of iron-based rare earth material alloy onto a guide having a guide surface which defines an angle of 1-80[deg] with respect to horizontal plane so as to move the melt onto a region where the melt is contacted with the chill roller, and rapidly cooling the melt in the chill roller to make a rapidly solidified alloy comprising iron boride phase. The material alloy manufacture involves feeding the melt of iron-based rare earth material alloy onto the guide having a guide surface which defines an angle of 1-80[deg] with respect to horizontal plane so as to move the melt onto a region where the melt is contacted with the chill roller, and rapidly cooling the melt in the chill roller to make a rapidly solidified alloy comprising iron boride (R 2Fe 14B) phase. Iron-based material alloy has the composition: (Fe 1-mT m) 100-x-y-z-n(B 1-pCp) xR yTi zM n T is cobalt and/or nickel; R is yttrium and/or rare earth elements; M is aluminum, silicon, vanadium, chromium, manganese, copper, zinc, gallium, zirconium, niobium, molybdenum, silver, hafnium, tantalum, tungsten, platinum, gold, and/or lead; and the mole fraction x, y, z, m, n and p satisfy the relations: 10 atom% less than x=25 atom%, 6 atom% =y less than 10 atom%, 0.5 atom% =z=12 atom%, 0=m=0.5, 0 atom%=n=10 atom% and 0=p=0.25. Independent claims are included for the following: (1) production of iron-based permanent magnet; (2) production of bonded magnet; (3) rapidly solidifying alloy; and (4) magnetic powder having the alloy composition.
136 AT01126888 2001-11-12 AT261609T 2004-03-15 KANEKIYO HIROKAZU; MIYOSHI TOSHIO; HIROSAWA SATOSHI
The material alloy manufacture involves feeding the melt of iron-based rare earth material alloy onto a guide having a guide surface which defines an angle of 1-80[deg] with respect to horizontal plane so as to move the melt onto a region where the melt is contacted with the chill roller, and rapidly cooling the melt in the chill roller to make a rapidly solidified alloy comprising iron boride phase. The material alloy manufacture involves feeding the melt of iron-based rare earth material alloy onto the guide having a guide surface which defines an angle of 1-80[deg] with respect to horizontal plane so as to move the melt onto a region where the melt is contacted with the chill roller, and rapidly cooling the melt in the chill roller to make a rapidly solidified alloy comprising iron boride (R 2Fe 14B) phase. Iron-based material alloy has the composition: (Fe 1-mT m) 100-x-y-z-n(B 1-pCp) xR yTi zM n T is cobalt and/or nickel; R is yttrium and/or rare earth elements; M is aluminum, silicon, vanadium, chromium, manganese, copper, zinc, gallium, zirconium, niobium, molybdenum, silver, hafnium, tantalum, tungsten, platinum, gold, and/or lead; and the mole fraction x, y, z, m, n and p satisfy the relations: 10 atom% less than x=25 atom%, 6 atom% =y less than 10 atom%, 0.5 atom% =z=12 atom%, 0=m=0.5, 0 atom%=n=10 atom% and 0=p=0.25. Independent claims are included for the following: (1) production of iron-based permanent magnet; (2) production of bonded magnet; (3) rapidly solidifying alloy; and (4) magnetic powder having the alloy composition.
137 Production of a magnetic alloy material used as a magnetic coolant or magnetostrictive material comprises forming a melt made from an alloy, rapidly cooling, allowing to solidify and producing a connecting phase having a crystal structure DE10338467 2003-08-21 DE10338467A1 2004-03-04 KOGURE RYOSUKE; KANEKIYO HIROKAZU; NISHIUCHI TAKESHI; HIROSAWA SATOSHI
Production of a magnetic alloy material comprises: forming a melt made from an alloy material having a predetermined composition; rapidly cooling; allowing to solidify to form an alloy of specified composition; and producing a connecting phase having a crystal structure of the sodium zinc type in an amount of approximately 70 vol.%. Production of a magnetic alloy material comprises: forming a melt made from an alloy material having a predetermined composition; rapidly cooling; allowing to solidify to form an alloy of the composition: Fe100-a-b-cREaAbTMc (where RE = La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er or Tm with at least 90 at.% La; A = Al, Si, Ga, Ge or Sn; TM = Sc, Ti, V, Cr, Mn, Co, Ni, Cu or Zn, a = 5-10 at.%; b = 4.7-18 at.%; and c = 0-9 at.%), and producing a connecting phase having a crystal structure of the NaZn13 type in an amount of approximately 70 vol.%. An Independent claim is also included for a magnetic alloy material produced by the above method.
138 Nanocrystalline and nanocomposite rare earth permanent magnet materials and method of making the same AU2003279698 2003-05-22 AU2003279698A8 2004-02-25 LIU SHIQIANG; CUI BAOZHI; LEE DON; HILTON JOHN STANLEY
Nanocrystalline and nanocomposite rare earth permanent magnet materials and methods for making the magnets are provided. The magnet materials can be isotropic or anisotropic and do not have a rare-earth rich phase. The magnet materials comprise nanometer scale grains and possesses a potential high maximum energy product, a high remancence, and a high intrinsic coercivity. The magnet materials having these properties are produced by using methods including magnetic annealing and rapid heat processing.
139 DE69906513 1999-05-26 DE69906513T2 2004-02-19 FRUCHART DANIEL; PERRIER DE LA BATHIE RENE; RIVOIRARD SOPHIE; DE RANGO PATRICIA
The invention concerns a method for preparing a magnetic material by forging, characterised in that, in a first embodiment, it comprises the following steps; placing in a sheath an alloy based on at least one rare earth, at least one transition metal and at least one other element selected among boron and carbon; bringing the whole alloy to a temperature not less than 500° C.; forging the whole at a deformation speed of the material not less than 8 s-1. After forging, it is possible to subject the resulting product to at least one annealing and hydridation then dehydridation, in another embodiment, it consists in starting with an alloy based on at least one rare earth and one transition metal and proceeding as in the first embodiment. After forging and, optionally, annealing, hydridation and dehydridation treatments, the resulting material is subjected to nitriding. The invention also concerns a magnetic material in power form, characterised in that has a coercivity not less than 9 kOe and retentivity not less than 9 kG.
140 BONDED PERMANENT MAGNETS AU2003223276 2003-03-13 AU2003223276A1 2003-10-27 BLUME WALTER SCOTT
A flexible permanent magnet containing atomized, generally spherical rare earth magnet particles bonded in a binder resin including a nitrile rubber and precipitated amorphous silica. The bonded permanent magnet exhibits high mechanical flexibility and elasticity, good magnetic properties, and good heat aging, and the magnet powder may be mixed with the binder resin with little to no risk of combustion. In an exemplary embodiment, a permanent magnet composition includes a nitrile rubber with about 23-37% acrylonitrile content, an ethylene vinyl acetate copolymer, a precipitated amorphous silica, and atomized, generally spherical rare earth magnet particles having a size distribution including a median particle size in the range of about 35-55 mum with a standard deviation in the range of about 10-30 mum and less than about 0.1% of the particles having a diameter above about 115 mum. Bonded permanent magnets of the present invention exhibit a percent ultimate elongation greater than about 100%, and even greater than about 200%, thereby providing at least a 10-fold improvement in elasticity concurrently with good magnetic properties.