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1. 发明授权

US08288718B2 Ion mobility spectrometer and detecting method using the same 有权
标题翻译：离子迁移光谱仪及其检测方法
公开(公告)号：US08288718B2
公开(公告)日：2012-10-16
申请号：US12997719
申请日：2010-06-28
申请人： Yuanjing Li , Zhiqiang Chen , Qingjun Zhang , Shiping Cao , Dexu Lin , Shaoji Mao , Qinghua Wang
发明人： Yuanjing Li , Zhiqiang Chen , Qingjun Zhang , Shiping Cao , Dexu Lin , Shaoji Mao , Qinghua Wang
IPC分类号： H01J49/26 , H01J49/00 , B01D59/44
CPC分类号： G01N27/622
摘要： An ion mobility spectrometer comprises an electrode and two storage electrodes disposed at the two opposite sides of the electrode respectively. Ions from an intermediate part between the two storage electrodes are stored and the stored ions are released from the storage electrodes by changing electric potentials of the two storage electrodes. The present invention further discloses a detecting method using an ion mobility spectrometer.
摘要翻译：离子迁移谱仪包括分别设置在电极的两个相对侧的电极和两个存储电极。存储来自两个存储电极之间的中间部分的离子，并且通过改变两个存储电极的电位而将存储的离子从存储电极释放。本发明还公开了使用离子迁移谱仪的检测方法。

2. 发明授权

US08278627B2 Sample feeding device for trace detector and trace detector with sample feeding device 有权
标题翻译：采样装置用于跟踪检测器和跟踪检测器
公开(公告)号：US08278627B2
公开(公告)日：2012-10-02
申请号：US13142523
申请日：2011-05-16
申请人： Yuanjing Li , Zhiqiang Chen , Qingjun Zhang , Shaoji Mao , Ziran Zhao , Yinong Liu , Shiping Cao , Yan Zheng , Jianping Chang , Xiang Zou
发明人： Yuanjing Li , Zhiqiang Chen , Qingjun Zhang , Shaoji Mao , Ziran Zhao , Yinong Liu , Shiping Cao , Yan Zheng , Jianping Chang , Xiang Zou
IPC分类号： H01J49/04 , B01D59/44 , G01N1/10
CPC分类号： G01N27/622
摘要： A sample feeding device for a trace detector is disclosed. The sample feeding device comprises: a sample feeding chamber disposed in the sample feeding device to desorb a sample from a sample feeding member; and a valve assembly configured to fluidly communicate the sample feeding chamber with a drift tube of the trace detector during feeding sample. With the above configuration of the present invention, for example, the sensitivity of the detector can be increased by improving the permeation ratio of the sample. In addition, interior environment of the drift tube is isolated from exterior environment to avoid a drift region of the drift tube from being polluted. The important parameters, such as sensitivity, a position of a peak of a substance, a resolution, of the detector can be kept constant. As a result, operation reliability and consistency of the detector can be achieved.
摘要翻译：公开了一种用于跟踪检测器的采样馈送装置。样品供给装置包括：样品供给室，设置在样品供给装置中，以从样品供给部件解吸样品; 以及阀组件，其构造成在进给样品期间将样品供给室与迹线检测器的漂移管流体连通。利用本发明的上述结构，例如可以通过提高样品的透过率来提高检测器的灵敏度。此外，漂移管的内部环境与外部环境隔离，以避免漂移管的漂移区域被污染。可以保持检测器的重要参数，如灵敏度，物质峰的位置，分辨率等。结果，可以实现检测器的操作可靠性和一致性。

3. 发明授权

US08013297B2 Ion gate for dual ion mobility spectrometer and method thereof 有权
标题翻译：双离子迁移谱仪的离子门及其方法
公开(公告)号：US08013297B2
公开(公告)日：2011-09-06
申请号：US12579719
申请日：2009-10-15
申请人： Hua Peng , Qingjun Zhang , Jin Lin , Yuanjing Li , Zhiqiang Chen , Shaoji Mao , Zhude Dai , Dai Hua, legal representative , Shiping Cao , Zhongxia Zhang , Yangtian Zhang , Dexu Lin , Qinghua Wang
发明人： Hua Peng , Qingjun Zhang , Jin Lin , Yuanjing Li , Zhiqiang Chen , Shaoji Mao , Zhude Dai , Shiping Cao , Zhongxia Zhang , Yangtian Zhang , Dexu Lin , Qinghua Wang
IPC分类号： G01N27/64 , H01J49/06
CPC分类号： H01J3/04 , H01J49/004 , H01J49/061
摘要： Disclosed is an ion gate for a dual IMS and method. The ion gate includes an ion source, a first gate electrode placed on one side of the ion source, a second gate electrode placed on the other side of the ion source, a third gate electrode placed on the side of the first gate electrode away from the ion source, a fourth gate electrode placed on the side of the second gate electrode away from the ion source, wherein during the ion storage, the potential at the position on the tube axis of the ion gate corresponding to the first gate electrode is different from the potentials at the positions on the tube axis corresponding to the ion source and the third gate electrode, and the potential at the position on the tube axis corresponding to the second gate electrode is different from the potentials at the positions on the tube axis corresponding to the ion source and the fourth gate electrode. According to the present invention, after sample gas enters the ion gates, charge exchange with reaction ions occurs between the first gate electrode and the second electrode, and positive and negative ions are continuously stored into the storage regions for the positive and negative ions. This leads to an improvement of utility rate of ions. Then, the ions are educed in a step-wise manner from the storage regions for the positive and negative ions by a simple control of a combination of the electrodes.
摘要翻译：公开了一种用于双重IMS和方法的离子门。离子浇口包括离子源，位于离子源一侧的第一栅电极，位于离子源另一侧的第二栅电极，位于第一栅电极侧的第三栅电极，离子源，第四栅极放置在远离离子源的第二栅电极侧，其中在离子存储期间，对应于第一栅电极的离子门的管轴上的位置的电位不同从对应于离子源和第三栅电极的管轴上的位置的电位和对应于第二栅电极的管轴上的位置的电位与管轴对应的位置的电位不同到离子源和第四栅电极。根据本发明，在样品气体进入离子浇口之后，在第一栅电极和第二电极之间产生与反应离子的电荷交换，正离子和负离子被连续地存储在正离子和负离子的存储区中。这导致了离子的利用率的提高。然后，通过简单地控制电极的组合，从正离子和负离子的存储区域逐步地排出离子。

4. 发明授权

US08362422B2 Sample feeding device for ion mobility spectrometer, method of using the same and ion mobility spectrometer 有权
标题翻译：离子迁移谱仪的采样装置，使用方法和离子迁移谱仪
公开(公告)号：US08362422B2
公开(公告)日：2013-01-29
申请号：US13142500
申请日：2011-04-27
申请人： Qingjun Zhang , Zhiqiang Chen , Shiping Cao , Yuanjing Li , Ziran Zhao , Yinong Liu , Yan Zheng , Shaoji Mao , Xiang Zou , Jianping Chang
发明人： Qingjun Zhang , Zhiqiang Chen , Shiping Cao , Yuanjing Li , Ziran Zhao , Yinong Liu , Yan Zheng , Shaoji Mao , Xiang Zou , Jianping Chang
IPC分类号： H01J49/40 , H01J49/14 , G01N27/64
CPC分类号： G01N27/622
摘要： The present invention discloses a sample feeding device for an ion mobility spectrometer, which is adapted to guide a sample to be detected into an inlet of a drift tube of the ion mobility spectrometer. The sample feeding device comprises a solid sample feeding component; a sample inlet component; a attachment component, wherein the solid sample feeding component has an internal cavity defined therein, one end of the solid sample feeding component is communicated with the sample inlet component through the internal cavity, while the other end is communicated with the inlet of the ion drift tube through the attachment component; and a gaseous sample feeding component, comprising a body and an external attachment component, the body has a gas channel therein, and the external attachment component includes an inlet hole which is communicated with the gas channel, wherein when the external attachment component is fitted with the sample inlet component, the body is inserted into the internal cavity, so that a channel of the solid sample feeding component is closed, and only the gas channel of the gaseous sample feeding component is communicated with the inlet of the drift tube of the ion mobility spectrometer.
摘要翻译：本发明公开了一种用于离子迁移谱仪的样品供给装置，其适于将待检测样品引导到离子迁移谱仪的漂移管的入口中。样品供给装置包括固体样品供给部件; 样品入口组件; 附着部件，其中固体样品进料部件具有限定在其中的内部空腔，固体样品供给部件的一端通过内部空腔与样品入口部件连通，而另一端与离子漂移入口连通管穿过附件; 以及气体样品供给部件，其包括主体和外部附接部件，所述主体在其中具有气体通道，并且所述外部附接部件包括与所述气体通道连通的入口孔，其中当所述外部附接部件装配有样品入口部件，主体插入到内腔中，使得固体样品供给部件的通道关闭，并且仅气态样品供给部件的气体通道与离子的漂移管的入口连通移动光谱仪。

5. 发明申请

US20090283694A1 DOUBLE-FACED ION SOURCE 有权
标题翻译：双重离子源
公开(公告)号：US20090283694A1
公开(公告)日：2009-11-19
申请号：US12437044
申请日：2009-05-07
申请人： Zhiqiang CHEN , Yuanjing LI , Hua PENG , Qingjun ZHANG , Jin LIN , Shaoji MAO , Zhude DAI , Shiping CAO , Zhongxia ZHANG , Yangtian ZHANG , Dexu LIN , Qinghua WANG , Shaofeng WANG , Hui LI
发明人： Zhiqiang CHEN , Yuanjing LI , Hua PENG , Qingjun ZHANG , Jin LIN , Shaoji MAO , Zhude DAI , Shiping CAO , Zhongxia ZHANG , Yangtian ZHANG , Dexu LIN , Qinghua WANG , Shaofeng WANG , Hui LI
IPC分类号： H01J27/00 , H01J49/00 , G21G4/00
CPC分类号： H01J49/14 , H01J27/20
摘要： Disclosed is an ion source comprising a plate-shaped source body which has radioactivity on its both sides and allows positive and negative ions to penetrate through the source body. The present invention gives beneficial effects. First, the ion source structure can improve the ionization efficiency of sample molecules, and the generated sample ions have a centralized distribution within a flat space on both sides of the source body. Such distribution of ion cloud facilitates to improve the IMS sensitivity. Meanwhile, the source body of the present invention has a transmittance in itself. Thus, positive and negative ions generated on both sides of the source body can penetrate through the source body and be separated to the both sides of the source body. In this way, it is possible to improve the utilization efficiency of ions.
摘要翻译：公开了一种离子源，其包括在其两侧具有放射性并允许正离子和负离子穿过源体的板状源体。本发明具有有益效果。首先，离子源结构可以提高样品分子的电离效率，并且所产生的样品离子在源体的两侧的平坦空间内具有集中分布。这种离子云的分布有助于提高IMS灵敏度。同时，本发明的源体本身具有透光性。因此，源体两侧产生的正离子和负离子可以穿透源体并分离到源体的两侧。以这种方式，可以提高离子的利用效率。

6. 发明申请

US20140061490A1 BORON-COATED NEUTRON DETECTOR AND METHOD FOR MANUFACTURING THE SAME 有权
标题翻译： BORON涂层中性探测器及其制造方法
公开(公告)号：US20140061490A1
公开(公告)日：2014-03-06
申请号：US14112692
申请日：2012-04-13
申请人： Ziran Zhao , Yongqiang Wang , Zhiqiang Chen , Qingjun Zhang , Yuanjing Li , Yinong Liu , Shaoji Mao , Nan Yao , Shuqiang Dong
发明人： Ziran Zhao , Yongqiang Wang , Zhiqiang Chen , Qingjun Zhang , Yuanjing Li , Yinong Liu , Shaoji Mao , Nan Yao , Shuqiang Dong
IPC分类号： G01T3/00
CPC分类号： G01T3/00 , G01T3/008 , Y10T29/49117
摘要： A boron-coated neutron detector, comprising a cathode tube with a plurality of passages formed therein along its longitudinal direction, the inner wall of each passage being coated with boron material; an electrode wire serving as an anode and arranged longitudinally in each of the passages, the electrode wire adapted to be applied with high voltage; and an insulating end plate to which each end of the cathode tube is fixed, the electrode wire being fixed to the cathode tube via the insulating end plate. Preferably, the cathode tube is formed by jointing a plurality of boron-coated substrates. The boron-coated neutron detector increases the detection efficiency of the neutron detector, which may reach or even exceed the detection efficiency of the 3He neutron detector of the same size, and the cost thereof is much cheaper than the 3He neutron detector.
摘要翻译：一种硼涂覆的中子探测器，包括阴极管，其阴极管沿着其纵向方向形成在其中，多个通道在其中形成，每个通道的内壁涂覆有硼材料; 用作阳极的电极线，并且纵向地布置在每个通道中，电极线适于施加高电压; 以及绝缘端板，阴极管的每一端固定在该绝缘端板上，电极线通过绝缘端板固定在阴极管上。优选地，阴极管通过连接多个硼涂覆的基底而形成。硼覆盖的中子检测器提高了中子检测器的检测效率，这可能达到或甚至超过相同尺寸的3He中子检测器的检测效率，并且其成本比3He中子检测器便宜得多。

7. 发明授权

US08217365B2 Double-faced ion source 有权
标题翻译：双面离子源
公开(公告)号：US08217365B2
公开(公告)日：2012-07-10
申请号：US12437044
申请日：2009-05-07
申请人： Zhiqiang Chen , Yuanjing Li , Hua Peng , Qingjun Zhang , Jin Lin , Shaoji Mao , Zhude Dai , Shiping Cao , Zhongxia Zhang , Yangtian Zhang , Dexu Lin , Qinghua Wang , Shaofeng Wang , Hui Li
发明人： Zhiqiang Chen , Yuanjing Li , Hua Peng , Qingjun Zhang , Jin Lin , Shaoji Mao , Zhude Dai , Shiping Cao , Zhongxia Zhang , Yangtian Zhang , Dexu Lin , Qinghua Wang , Shaofeng Wang , Hui Li
IPC分类号： H01J27/20 , H01J49/14
CPC分类号： H01J49/14 , H01J27/20
摘要： Disclosed is an ion source comprising a plate-shaped source body which has radioactivity on its both sides and allows positive and negative ions to penetrate through the source body. The present invention gives beneficial effects. First, the ion source structure can improve the ionization efficiency of sample molecules, and the generated sample ions have a centralized distribution within a flat space on both sides of the source body. Such distribution of ion cloud facilitates to improve the IMS sensitivity. Meanwhile, the source body of the present invention has a transmittance in itself. Thus, positive and negative ions generated on both sides of the source body can penetrate through the source body and be separated to the both sides of the source body. In this way, it is possible to improve the utilization efficiency of ions.
摘要翻译：公开了一种离子源，其包括在其两侧具有放射性并允许正离子和负离子穿过源体的板状源体。本发明具有有益效果。首先，离子源结构可以提高样品分子的电离效率，并且所产生的样品离子在源体的两侧的平坦空间内具有集中分布。这种离子云的分布有助于提高IMS灵敏度。同时，本发明的源体本身具有透光性。因此，源体两侧产生的正离子和负离子可以穿透源体并分离到源体的两侧。以这种方式，可以提高离子的利用效率。

8. 发明申请

US20120168616A1 SAMPLE FEEDING DEVICE FOR ION MOBILITY SPECTROMETER, METHOD OF USING THE SAME AND ION MOBILITY SPECTROMETER 有权
标题翻译：离子移动光谱仪的采样装置，使用该方法和离子移动光谱仪
公开(公告)号：US20120168616A1
公开(公告)日：2012-07-05
申请号：US13142500
申请日：2011-04-27
申请人： Qingjun Zhang , Zhiqiang Chen , Shiping Cao , Yuanjing Li , Ziran Zhao , Yinong Liu , Yan Zheng , Shaoji Mao , Xiang Zou , Jianping Chang
发明人： Qingjun Zhang , Zhiqiang Chen , Shiping Cao , Yuanjing Li , Ziran Zhao , Yinong Liu , Yan Zheng , Shaoji Mao , Xiang Zou , Jianping Chang
IPC分类号： H01J49/34
CPC分类号： G01N27/622
摘要： The present invention discloses a sample feeding device for an ion mobility spectrometer, which is adapted to guide a sample to be detected into an inlet of a drift tube of the ion mobility spectrometer. The sample feeding device comprises a solid sample feeding component; a sample inlet component; a attachment component, wherein the solid sample feeding component has an internal cavity defined therein, one end of the solid sample feeding component is communicated with the sample inlet component through the internal cavity, while the other end is communicated with the inlet of the ion drift tube through the attachment component; and a gaseous sample feeding component, comprising a body and an external attachment component, the body has a gas channel therein, and the external attachment component includes an inlet hole which is communicated with the gas channel, wherein when the external attachment component is fitted with the sample inlet component, the body is inserted into the internal cavity, so that a channel of the solid sample feeding component is closed, and only the gas channel of the gaseous sample feeding component is communicated with the inlet of the drift tube of the ion mobility spectrometer.
摘要翻译：本发明公开了一种用于离子迁移谱仪的样品供给装置，其适于将待检测样品引导到离子迁移谱仪的漂移管的入口中。样品供给装置包括固体样品供给部件; 样品入口组件; 附着部件，其中固体样品进料部件具有限定在其中的内部空腔，固体样品供给部件的一端通过内部空腔与样品入口部件连通，而另一端与离子漂移入口连通管穿过附件; 以及气体样品供给部件，其包括主体和外部附接部件，所述主体在其中具有气体通道，并且所述外部附接部件包括与所述气体通道连通的入口孔，其中当所述外部附接部件装配有样品入口部件，主体插入到内腔中，使得固体样品供给部件的通道关闭，并且仅气态样品供给部件的气体通道与离子的漂移管的入口连通移动光谱仪。

9. 发明授权

US09470804B2 Boron coated neutron detector and method for manufacturing the same 有权
标题翻译：硼涂层中子探测器及其制造方法
公开(公告)号：US09470804B2
公开(公告)日：2016-10-18
申请号：US14112692
申请日：2012-04-13
申请人： Ziran Zhao , Yongqiang Wang , Zhiqiang Chen , Qingjun Zhang , Yuanjing Li , Yinong Liu , Shaoji Mao , Nan Yao , Shuqiang Dong
发明人： Ziran Zhao , Yongqiang Wang , Zhiqiang Chen , Qingjun Zhang , Yuanjing Li , Yinong Liu , Shaoji Mao , Nan Yao , Shuqiang Dong
IPC分类号： G01T3/00
CPC分类号： G01T3/00 , G01T3/008 , Y10T29/49117
摘要： A boron-coated neutron detector, comprising a cathode tube with a plurality of passages formed therein along its longitudinal direction, the inner wall of each passage being coated with boron material; an electrode wire serving as an anode and arranged longitudinally in each of the passages, the electrode wire adapted to be applied with high voltage; and an insulating end plate to which each end of the cathode tube is fixed, the electrode wire being fixed to the cathode tube via the insulating end plate. Preferably, the cathode tube is formed by jointing a plurality of boron-coated substrates. The boron-coated neutron detector increases the detection efficiency of the neutron detector, which may reach or even exceed the detection efficiency of the 3He neutron detector of the same size, and the cost thereof is much cheaper than the 3He neutron detector.
摘要翻译：一种硼涂覆的中子探测器，包括阴极管，其阴极管沿着其纵向方向形成在其中，多个通道在其中形成，每个通道的内壁涂有硼材料; 用作阳极的电极线，并且纵向地布置在每个通道中，电极线适于施加高电压; 以及绝缘端板，阴极管的每一端固定在该绝缘端板上，电极线通过绝缘端板固定在阴极管上。优选地，阴极管通过连接多个硼涂覆的基底而形成。硼覆盖的中子检测器提高了中子检测器的检测效率，这可能达到或甚至超过相同尺寸的3He中子检测器的检测效率，并且其成本比3He中子检测器便宜得多。

10. 发明申请

US20120168620A1 SAMPLE FEEDING DEVICE FOR TRACE DETECTOR AND TRACE DETECTOR WITH SAMPLE FEEDING DEVICE 有权
标题翻译：跟踪检测器和跟踪检测器的样品送料装置与样品送料装置
公开(公告)号：US20120168620A1
公开(公告)日：2012-07-05
申请号：US13142523
申请日：2011-05-16
申请人： Yuanjing Li , Zhiqiang Chen , Qingjun Zhang , Shaoji Mao , Ziran Zhao , Yinong Liu , Shiping Cao , Yan Zheng , Jianping Chang , Xiang Zou
发明人： Yuanjing Li , Zhiqiang Chen , Qingjun Zhang , Shaoji Mao , Ziran Zhao , Yinong Liu , Shiping Cao , Yan Zheng , Jianping Chang , Xiang Zou
IPC分类号： H01J49/40 , H01J49/00
CPC分类号： G01N27/622
摘要： A sample feeding device for a trace detector is disclosed. The sample feeding device comprises: a sample feeding chamber disposed in the sample feeding device to desorb a sample from a sample feeding member; and a valve assembly configured to fluidly communicate the sample feeding chamber with a drift tube of the trace detector during feeding sample. With the above configuration of the present invention, for example, the sensitivity of the detector can be increased by improving the permeation ratio of the sample. In addition, interior environment of the drift tube is isolated from exterior environment to avoid a drift region of the drift tube from being polluted. The important parameters, such as sensitivity, a position of a peak of a substance, a resolution, of the detector can be kept constant. As a result, operation reliability and consistency of the detector can be achieved.
摘要翻译：公开了一种用于跟踪检测器的采样馈送装置。样品供给装置包括：样品供给室，设置在样品供给装置中，以从样品供给部件解吸样品; 以及阀组件，其构造成在进给样品期间将样品供给室与迹线检测器的漂移管流体连通。利用本发明的上述结构，例如可以通过提高样品的透过率来提高检测器的灵敏度。此外，漂移管的内部环境与外部环境隔离，以避免漂移管的漂移区域被污染。可以保持检测器的重要参数，如灵敏度，物质峰的位置，分辨率等。结果，可以实现检测器的操作可靠性和一致性。

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