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11. 发明授权

US4364738A Crystalline bromide or iodide salts of triazole dyes for polyacrylonitrile 失效
标题翻译：用于聚丙烯腈的三唑染料的结晶溴化物或碘化物盐
公开(公告)号：US4364738A
公开(公告)日：1982-12-21
申请号：US285903
申请日：1981-07-23
申请人： Rudolf Zink , Peter Loew
发明人： Rudolf Zink , Peter Loew
IPC分类号： C09B44/18 , C09B67/00 , C09B69/06
CPC分类号： C09B67/0029 , C09B44/18 , C09B69/06 , Y10S8/927
摘要： There are described novel crystalline bromine and iodine salts of triazole dyes of the formula ##STR1## wherein R is the CH.sub.3 or C.sub.2 H.sub.5 group,R.sub.1 is a C.sub.1 -C.sub.4 -alkyl group,R.sub.2 is an unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl group, andX is the bromine or iodine ion,and also processes for producing them, and their use for dyeing and printing in particular polyacrylonitrile materials.
摘要翻译：描述了式（I）的三唑染料的新型结晶溴和碘盐，其中R是CH 3或C 2 H 5基团，R 1是C 1 -C 4烷基，R 2是未取代或取代的C 1 -C 4 - 烷基，X是溴或碘离子，也用于制造它们，以及它们用于特别是聚丙烯腈材料的染色和印刷。

12. 发明授权

US4360679A Benzofuranyl-benzimidazoles 失效
标题翻译：苯并呋喃基 - 苯并咪唑
公开(公告)号：US4360679A
公开(公告)日：1982-11-23
申请号：US192576
申请日：1980-09-30
申请人： Hans R. Meyer , Kurt Weber
发明人： Hans R. Meyer , Kurt Weber
IPC分类号： D06L3/12 , C07D405/04 , C07D493/04 , C09B57/00 , C07D405/14
CPC分类号： C07D493/04 , Y10S8/927
摘要： Novel benzofuranyl benzimidazoles of the formula ##STR1## wherein R.sub.1 represents a hydrogen atom, an alkenyloxy or cycloalkyloxy radical, an unsubstituted or substituted alkoxy, phenylalkoxy or phenoxy radical,each ofR.sub.2 and R.sub.3 independently represents a hydrogen atom, an alkyl or alkoxy radical, a halogen atom, or, if R.sub.1 represents hydrogen, together in the ortho-position to each other they represent a radical of the formula --CH.dbd.CH--CH.dbd.CH--, --O--CH.sub.2 --O-- or --O--CH.sub.2 --CH.sub.2 --O--,R.sub.4 represents a hydrogen atom, an alkyl, alkoxy or phenyl radical,R.sub.5 represents a sulpho or carboxyl group or the functional derivatives thereof including the cyano group or the trifluoromethyl group,R.sub.6 represents a hydrogen or halogen atom, an alkyl or alkoxy radical,R.sub.7 represents a cycloalkyl, alkenyl, or unsubstituted or substituted alkyl, phenyl or phenylalkyl radical, or, if n is 0, also represents a hydrogen atom,R.sub.8 represents a hydrogen atom, a cycloalkyl, alkenyl, or unsubstituted or substituted alkyl or phenylalkyl radical,A.sup.w.crclbar. represents a colorless anion of an inorganic or organic acid andw represents the valency of the anion A, andn is 0 or 1,their preparation as well as their use as optical brighteners are disclosed.
摘要翻译：新的式（ⅠA）苯并呋喃基苯并咪唑其中R 1表示氢原子，烯氧基或环烷氧基，未取代或取代的烷氧基，苯基烷氧基或苯氧基，R2和R3各自独立地表示氢原子，烷基或烷氧基，卤素原子，或者如果R1表示氢，则彼此邻位，它们代表式-CH = CH-CH = CH-，-O-CH2-O-或-O-CH2- CH2-O-，R4代表氢原子，烷基，烷氧基或苯基，R5代表磺基或羧基或其官能衍生物，包括氰基或三氟甲基，R6代表氢或卤素原子，烷基或烷氧基，R7表示环烷基，烯基或未取代或取代的烷基，苯基或苯基烷基，或者，如果n为0，也表示氢原子，R8表示氢原子，环烷基，烯基或未取代或取代的烷基或苯基烷基，Aw（ - ）表示无机或有机酸的无色阴离子，w表示阴离子A的化合价，n为0或1，公开了它们的制备方法及其作为荧光增白剂的用途。

13. 发明授权

US4266940A Method for dyeing acrylonitrile polymer and copolymer fibres 失效
标题翻译：丙烯腈聚合物和共聚物纤维染色方法
公开(公告)号：US4266940A
公开(公告)日：1981-05-12
申请号：US16690
申请日：1979-03-02
申请人： David Blackburn , Malcolm S. Wild
发明人： David Blackburn , Malcolm S. Wild
IPC分类号： D06P1/92 , D06P3/70
CPC分类号： D06P1/90 , D06P3/702 , Y10S8/927
摘要： There is disclosed a process for the coloration of wet spun acrylic and modacrylic fibres in the gel form which comprises using a cationic dye, or its dye bases, which are substantially insoluble in water but soluble or partly soluble in organic solvents. There are also disclosed acrylic fibres so colored.
摘要翻译：公开了以凝胶形式着色湿纺丙烯酸和改性聚丙烯酸纤维的方法，该方法包括使用基本上不溶于水但可溶于或部分可溶于有机溶剂的阳离子染料或其染料碱。还公开了如此着色的丙烯酸纤维。

14. 发明授权

US4264325A Phenyl-benzimidazolyl-furanes for optical brightening of organic materials 失效
标题翻译：苯基 - 苯并咪唑基 - 呋喃用于有机材料的光学增白
公开(公告)号：US4264325A
公开(公告)日：1981-04-28
申请号：US54043
申请日：1979-07-02
申请人： Hans R. Meyer , Kurt Weber
发明人： Hans R. Meyer , Kurt Weber
IPC分类号： C08K5/00 , D06L3/12 , D21H21/30 , C07D405/04
CPC分类号： D21H21/30 , C08K5/0041 , D06L3/1221 , Y10S8/921 , Y10S8/922 , Y10S8/924 , Y10S8/927
摘要： 2-Phenyl-5-benzimidazol-2'-yl-furanes of the formula ##STR1## in which R.sub.1 to R.sub.6 are as defined in the specification, n is the number 0 or 1 and A.crclbar. is a colorless anion equivalent to the cation of the fluorescent brightener, their preparation as well as their use for optically brightening organic materials are disclosed.
摘要翻译：式（1）的2-苯基-5-苯并咪唑-2'-基 - 呋喃，其中R1至R6如说明书中所定义，n为数字0或1，A（ - ）为无色公开了与荧光增白剂的阳离子相当的阴离子，它们的制备及其对光学增白有机材料的用途。

15. 发明授权

US4252535A Process for dyeing uniformly polyacrylonitrile fiber materials 失效
标题翻译：均匀地染色聚丙烯腈纤维材料的方法
公开(公告)号：US4252535A
公开(公告)日：1981-02-24
申请号：US16300
申请日：1979-02-28
申请人： Norbert Kollodzeiski , Rudolf Lowenfeld , Eberhard Mundlos , Reinhard Mohr , Kurt Hohmann
发明人： Norbert Kollodzeiski , Rudolf Lowenfeld , Eberhard Mundlos , Reinhard Mohr , Kurt Hohmann
IPC分类号： D06P3/76 , D06P3/70 , C09B27/00
CPC分类号： D06P3/76 , Y10S534/01 , Y10S8/927
摘要： A dyeing process has been found which enables to dye uniformly polyacrylonitrile fiber materials, by using as dyestuffs basic azo dyestuffs being non-quarternized and containing neither cationic quaternary ammonium groups nor cationic N-substituted or N-unsubstituted iminium groups, said azo dyestuffs containing on the other hand at least one unsubstituted or substituted amino group, hydrazino group, amidino group or guanidino group capable of forming salts. The very dyeing process as such is carried out according to usual processing data for dyeing polyacrylonitriles in a slightly acid medium. Especially with the use of several of these dyestuffs for polychromic dyeing, such as trichromic dyeing, special advantages are obtained, insofar that even at cut-rate dyeing periods and for preparing light color shades, there are obtained even dyes with constant color shades, when using these dyestuffs having good migrating properties.
摘要翻译：已经发现染色工艺能够均匀地染色聚丙烯腈纤维材料，通过使用染色剂，碱性偶氮染料不被季铵化并且既不含阳离子季铵基团也不含阳离子N-取代或N-未取代的亚胺基团，所述偶氮染料含有另一方面至少一个能够形成盐的未取代或取代的氨基，肼基，脒基或胍基。根据通常的加工数据，在微酸性介质中染色聚丙烯腈进行染色。特别是使用这些染料中的几种用于多色染色，如三色染色，得到了特殊的优点，即使在切割染色期间和用于制备浅色色调的情况下，甚至获得具有恒定色调的均匀染料，当使用具有良好迁移性能的这些染料。

16. 发明授权

US4159192A Transfer dyes and transfer printing process 失效
标题翻译：转印染料和转印工艺
公开(公告)号：US4159192A
公开(公告)日：1979-06-26
申请号：US832918
申请日：1977-09-13
申请人： Peter Mockli
发明人： Peter Mockli
IPC分类号： C09B23/00 , C09B23/01 , D06P5/00 , D06P5/28 , D06P1/645
CPC分类号： D06P5/006 , C09B23/0058 , Y10S8/921 , Y10S8/922 , Y10S8/927
摘要： The invention relates to a process for printing flat-surface structures made from synthetic man-made or regenerated man-made polymer materials, for example polyester, polyacetate and preferably polyacrylonitrile fibres, by transfer printing, by means of auxiliary carriers which are printed with printing inks or printing pastes using dyes of the formula I ##STR1## wherein N IS 0 OR 1,R.sub.1 represents hydrogen, methyl, ethyl, propyl or butyl, branched or unbranched, while R.sub.1 together with the phenyl nucleus can form a 6-membered heterocyclic ring,R.sub.2 represents hydrogen, methyl, ethyl, propyl, branched or unbranched, cyanomethyl, cyanoethyl, hydroxyethyl, chloroethyl, phenyl or benzyl, substituted or unsubstituted, andR.sub.3 represents hydrogen, methyl, ethyl and nitro, orR.sub.1 and R.sub.2 together with the nitrogen atom to which they are attached form a 5- or 6-membered heterocyclic ring, in particular morpholine.Furthermore the invention relates to novel dyes of the formulae ##STR2##
摘要翻译：本发明涉及用合成人造或再生的人造聚合物材料制成的平面结构的方法，例如聚酯，聚乙酸酯，优选聚丙烯腈纤维，通过转移印刷，通过印刷印刷的辅助载体油墨或印刷浆料，其中N IS 0 OR 1，R 1表示氢，甲基，乙基，丙基或丁基，支链或非支链的式I（I）的染料，而R1与苯基核可以形成6 氰基甲基，氰基乙基，羟基乙基，氯乙基，苯基或苄基，取代或未取代的，R 3表示氢，甲基，乙基和硝基，或R 1和R 2 与它们所连接的氮原子一起形成5-或6-元杂环，特别是吗啉。

17. 发明授权

US4138570A Indoline linked to 2-pyrazoline 失效
标题翻译：吲哚啉与2-吡唑啉连接
公开(公告)号：US4138570A
公开(公告)日：1979-02-06
申请号：US683622
申请日：1976-05-05
申请人： Hubertus Psaar
发明人： Hubertus Psaar
IPC分类号： C07D209/10 , C07D209/12 , C07D491/107 , C07F9/572 , C07F9/6561 , C09B23/10 , C09B26/02 , C09B26/04 , C09B57/00 , C07D403/04
CPC分类号： C09B23/102 , C09B26/04 , Y10S8/922 , Y10S8/924 , Y10S8/927
摘要： Dyestuffs of the formula ##STR1## WHEREIN R.sub.1 denotes halogen, alkyl, cycloalkyl, aralkyl, nitro, cyano, acyl, acylamino, amino, aminocarbonyl, aminosulphonyl, alkylsulphonyl, arylsulphonyl, alkoxy, aryloxy, aralkoxy, carboxyl, alkoxycarbonyl, aryloxycarbonyl or aralkoxycarbonyl or arylazo,R.sub.2 denotes alkyl, alkenyl, cycloalkyl, aryl or aralkyl,R.sub.3 and R.sub.4 denote alkyl, cycloalkyl or aralkyl,R.sub.5, r.sub.6, r.sub.7 and R.sub.8 denote hydrogen, alkyl, cycloalkyl, aralkyl or aryl,And whereinR.sub.6 and R.sub.7 can together form a fused cycloaliphatic ring,A denotes aryl or heteryl,N denotes 0, 1 or 2 andAn.sup.(-) denotes an anion,Process for their preparation and their use for dyeing and printing especially polyacrylonitrile and acid modified polyamides and polyesters.
摘要翻译：式中，R1表示卤素，烷基，环烷基，芳烷基，硝基，氰基，酰基，酰基氨基，氨基，氨基羰基，氨基磺酰基，烷基磺酰基，芳基磺酰基，烷氧基，芳氧基，芳烷氧基，羧基，烷氧基羰基，芳氧基羰基或芳烷氧基羰基或芳基偶氮，R2表示烷基，烯基，环烷基，芳基或芳烷基，R3和R4表示烷基，环烷基或芳烷基，R5，R6，R7和R8表示氢，烷基，环烷基，芳烷基或芳基，其中R6和R7可以一起形成稠合脂环族环，A表示芳基或杂芳基，N，DENOTES 0,1 OR 2，An（ - ）表示阴离子，其制备方法及其用于染色和印刷特殊聚丙烯酰胺和酸改性聚酰胺和聚酯的用途。

18. 发明授权

US4097230A Method for transferring heat-transferable dyes 失效
标题翻译：转移可转移染料的方法
公开(公告)号：US4097230A
公开(公告)日：1978-06-27
申请号：US730884
申请日：1976-10-08
申请人： M. Akram Sandhu
发明人： M. Akram Sandhu
IPC分类号： B41M5/52 , D06P5/28 , D06P5/00 , C08G63/12
CPC分类号： D06P5/004 , B41M5/5272 , Y10S428/914 , Y10S8/92 , Y10S8/921 , Y10S8/926 , Y10S8/927 , Y10S8/928 , Y10T428/31507 , Y10T428/31616 , Y10T428/31649 , Y10T428/31681 , Y10T428/31786 , Y10T428/3179
摘要： An improved method for transferring heat transferable dyes comprises diffusing the dyes into a dye receiving element comprising a transparent layer containing an amorphous, solvent-soluble, aromatic polyester having at least 30 mole percent of its recurring units comprised of the condensation residue of a diol and a dicarboxylic acid, the residue containing a saturated gem-bivalent radical having a saturated polycyclic three-dimensional structure that includes a saturated bicyclic atomic bridged hydrocarbon ring member, the gem-bivalent radical linking two aromatic groups.
摘要翻译：用于转移可转移染料的改进方法包括将染料扩散到染料接收元件中，染料接收元件包括含有无定形溶剂可溶性芳族聚酯的透明层，所述无定形溶剂可溶的芳族聚酯具有至少30摩尔％的由二醇的缩合残基构成的重复单元，二羧酸，其中含有具有饱和多环三维结构的饱和二价基团的残基包括饱和双环原子桥连烃环成员，连接两个芳族基团的偕二价基团。

19. 发明授权

US4087241A Printing inks for transfer printing 失效
标题翻译：印刷油墨用于转印
公开(公告)号：US4087241A
公开(公告)日：1978-05-02
申请号：US695848
申请日：1976-06-14
申请人： Hubertus Psaar
发明人： Hubertus Psaar
IPC分类号： B41M5/385 , B41M5/39 , C09B11/02 , C09B11/04 , C09B23/04 , C09B23/10 , C09B23/14 , C09B23/16 , C09D11/02 , D06P5/28 , D06P5/00 , C09D11/00
CPC分类号： B41M5/385 , C09B11/02 , C09B11/04 , C09B23/04 , C09B23/105 , C09B23/145 , C09B23/164 , C09D11/037 , D06P5/006 , B41M5/3854 , B41M5/3856 , B41M5/39 , Y10S8/922 , Y10S8/927
摘要： Printing inks for the production of auxiliary carriers for transfer printing on acid-modified textile fiber materials, characterized in that they contain at least(a) as a dyestuff intermediate, a carbinol base of cationic dyestuffs, which can be sublimed at 160.degree.-240.degree. C, of the formula ##STR1## (b) a practically anhydrous neutral organic solvent and (C) A NEUTRAL RESIN WHICH IS SOLUBLE IN THIS SOLVENT.
摘要翻译：用于在酸改性纺织纤维材料上生产用于转印的辅助载体的印刷油墨，其特征在于它们至少含有（A）AS A DYESTUFF中间体，可以在160°-240°附近沉积的碳酸氢钠基（B）实际上无水的中性有机溶剂和（C）本溶剂中可溶的中性树脂。

20. 发明授权

US4052159A Dyeing process using quaternary ammonium salt as retarder 失效
标题翻译：使用季铵盐作为延迟剂的染色工艺
公开(公告)号：US4052159A
公开(公告)日：1977-10-04
申请号：US702956
申请日：1976-07-06
申请人： Ernst Fuerst , Jozsef Gerendas , Rudolf Rokohl , Rolf Fikentscher , Herbert Helfert
发明人： Ernst Fuerst , Jozsef Gerendas , Rudolf Rokohl , Rolf Fikentscher , Herbert Helfert
IPC分类号： D06P1/66 , D06P3/76 , D06P5/06
CPC分类号： D06P3/76 , D06P1/66 , Y10S8/927
摘要： Special quaternary ammonium salts derived from triaminoalkyl derivatives of hexahydrotriazine for use as retarders in the dyeing of anionic polyacrylonitrile fibers with basic dyes.

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