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    • 35. 发明授权
    • Halogenation treatment
    • 卤化处理
    • US4484954A
    • 1984-11-27
    • US404814
    • 1982-08-03
    • Gregorio Tarancon
    • Gregorio Tarancon
    • C08F8/00B01J15/00C08F8/18C08J7/12C23C8/08C23C22/00C23C11/00
    • B01J15/00C08J7/126
    • A batch process for the halogenation of solid polymeric or metallic material comprising the following steps:(a) providing a closed system comprising a chamber containing air at about atmospheric pressure and having inlet and outlet means, a heat exchanger, and a circulation pump, all connected in series;(b) introducing the material into the chamber;(c) heating the chamber and the material to a selected temperature in the range of about 100.degree. F. to about 200.degree. F. by recirculating the air through the heat exchanger;(d) evacuating the system;(e) introducing a halogen into the system in an amount (i) of up to about 10 percent in excess of the theoretical amount of halogen required to halogenate the polymeric material to a desired depth and (ii) sufficient to provide a partial pressure in the system in the range of about 0.1 psia to about 3 psia;(f) introducing an inert gas into the system in an amount sufficient to provide a total pressure in the system of about one atmosphere;(g) maintaining the selected temperature by recirculating the halogen/inert gas mixture through the heat exchanger;(h) recirculating the halogen/inert gas mixture a sufficient number of times to reduce the amount of halogen to less than about 5 percent of the amount of halogen initially introduced into the system;(i) evacuating the system;(j) introducing air into the system to provide about atmospheric pressure; and(k) removing the material.
    • 用于卤化固体聚合物或金属材料的分批方法,包括以下步骤:(a)提供封闭系统,其包括在约大气压下容纳空气的室,并具有入口和出口装置,热交换器和循环泵,全部 串联连接 (b)将材料引入室内; (c)通过将空气再循环通过热交换器,将室和材料加热至约100°F至约200°F范围内的选定温度; (d)疏散系统; (e)将卤素引入系统中,其量(i)超过将聚合物材料卤化至所需深度所需的理论卤素量的至多约10%,和(ii)足以提供分压 系统在约0.1psia至约3psia范围内; (f)将惰性气体引入系统中,其量足以提供系统中约一个大气压的总压力; (g)通过将卤素/惰性气体混合物再循环通过热交换器来维持所选择的温度; (h)将卤素/惰性气体混合物再循环足够的次数以将卤素的量减少到小于初始引入系统的卤素的量的约5%; (i)疏散系统; (j)将空气引入系统以提供大气压力; 和(k)除去材料。