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61. 发明授权

US08222462B2 Process for generation of polyols from saccharides 有权
标题翻译：由糖生成多元醇的方法
公开(公告)号：US08222462B2
公开(公告)日：2012-07-17
申请号：US13192970
申请日：2011-07-28
申请人： Tom N. Kalnes , Joseph A. Kocal , John Q. Chen
发明人： Tom N. Kalnes , Joseph A. Kocal , John Q. Chen
IPC分类号： C07C29/00 , C07C31/18
CPC分类号： C07C29/00 , C07C31/202 , C07C31/205
摘要： A process for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. The process involves, contacting, hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one unsupported component and at least one supported component.
摘要翻译：以包含糖的原料生成至少一种多元醇的方法以连续或间歇的方式进行。该方法包括使氢，水和包含糖的原料与催化剂体系接触以产生包含至少一种多元醇的流出物流并从流出物流中回收多元醇。催化剂体系包含至少一种未负载的组分和至少一种负载的组分。

62. 发明申请

US20120165494A1 METHODS FOR PRODUCING POLYOLS AND POLYURETHANES 审中-公开
标题翻译：生产聚氨酯和聚氨酯的方法
公开(公告)号：US20120165494A1
公开(公告)日：2012-06-28
申请号：US13040256
申请日：2011-03-03
申请人： Yebo Li , Yuguang Zhou
发明人： Yebo Li , Yuguang Zhou
IPC分类号： C08G18/00 , C07C29/00
CPC分类号： C08G18/6492 , C08G18/36 , C08G2101/00 , C11C3/003
摘要： Methods for producing a polyols and polyurethanes are described. The polyols described herein can be produced directly from crude glycerin or through liquefaction of lignocellulosic biomass using a solvent comprising crude glycerin. The polyols produced in accordance with certain aspects may be derived from a significant proportion of renewable resources.
摘要翻译：描述了制备多元醇和聚氨酯的方法。本文所述的多元醇可以直接由粗甘油或通过使用包含粗甘油的溶剂液化木质纤维素生物质来生产。根据某些方面生产的多元醇可能来自相当大比例的可再生资源。

63. 发明申请

US20120149926A1 PROCESS FOR IMPROVING THE SELECTIVITY OF AN EO CATALYST 有权
标题翻译：改进EO催化剂选择性的方法
公开(公告)号：US20120149926A1
公开(公告)日：2012-06-14
申请号：US13310273
申请日：2011-12-02
申请人： Wayne Errol EVANS , Marek MATUSZ , Paul Michael MCALLISTER
发明人： Wayne Errol EVANS , Marek MATUSZ , Paul Michael MCALLISTER
IPC分类号： C07D301/04 , C07C213/00 , C07C68/00 , C07C29/00 , C07C41/02
CPC分类号： C07D303/04 , Y02P20/142
摘要： The present invention relates to a process for improving the overall selectivity of an EO process for converting ethylene to ethylene oxide utilizing a highly selective EO silver catalyst containing a rhenium promoter wherein following normal operation a chloride strip of the chloride on the surface of the catalyst is conducted in order to remove a portion of the chlorides on the surface of the catalyst. The chloride strip involves the addition of certain saturated hydrocarbons to the feed. Following the chloride strip, the catalyst is optionally re-optimized.
摘要翻译：本发明涉及使用含有铼助催化剂的高度选择性的EO银催化剂来改善EO转化为环氧乙烷的EO方法的总体选择性的方法，其中在正常操作之后，催化剂表面上氯化物的氯化物条是进行以除去催化剂表面上的一部分氯化物。氯化物条包括向进料中加入某些饱和烃。在氯化带之后，任选地重新优化催化剂。

64. 发明申请

US20120122662A1 CATALYST FOR CONVERSION OF HYDROCARBONS, PROCESS OF MAKING AND PROCESS OF USING THEREOF - BIMETALLIC DEPOSITION 审中-公开
标题翻译：碳氢化合物转化催化剂，其制备方法及其使用方法 - 双金属沉积
公开(公告)号：US20120122662A1
公开(公告)日：2012-05-17
申请号：US13110157
申请日：2011-05-18
申请人： Alla K. Khanmamedova , Scott F. Mitchell , Scott A. Stevenson , Gopalakrishnan G. Juttu
发明人： Alla K. Khanmamedova , Scott F. Mitchell , Scott A. Stevenson , Gopalakrishnan G. Juttu
IPC分类号： B01J29/04 , C07C7/148 , B01J37/08 , C07C29/00 , C07C51/00 , C07C67/00 , C07C4/06 , C10G47/02
CPC分类号： C07C1/20 , B01J29/047 , B01J29/405 , B01J29/44 , B01J2229/186 , C07C2/12 , C07C2/24 , C07C2/66 , C07C2/76 , C07C4/06 , C07C5/2708 , C07C5/2754 , C07C6/123 , C07C6/126 , C07C2529/44 , C07C2529/62 , C07C2529/74 , C10G35/095 , C10G47/18 , C10G2300/1081 , C10G2300/1088 , Y02P20/52 , C07C15/02
摘要： This invention is for a catalyst for conversion of hydrocarbons. The catalyst is a non-acidic germanium zeolite, such as Ge-ZSM-5, on which at least two metals, platinum and at least one other metal selected from Group 7, Group 8, Group 9, Group 10 and tin, are deposited on the germanium zeolite. Examples of the other metal are iridium, rhenium, palladium, ruthenium, rhodium, iron, cobalt and tin. The catalyst is prepared by synthesizing a germanium zeolite; depositing platinum and at least one other metal on the germanium zeolite; and calcining after preparation of the zeolite, before depositing the metals or after depositing the metals. The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with a hydrocarbon stream containing alkanes, olefins and mixtures thereof having 2 to 12 carbon atoms per molecule and recovering the product.
摘要翻译：本发明是用于烃转化的催化剂。催化剂是诸如Ge-ZSM-5的非酸性锗沸石，其上沉积了至少两种金属，铂和选自第7组，第8组，第9组，第10组和锡中的至少一种其他金属在锗沸石上。其他金属的实例是铱，铼，钯，钌，铑，铁，钴和锡。催化剂是通过合成锗沸石制备的; 在锗沸石上沉积铂和至少一种其他金属; 并在制备沸石之后，在沉积金属之前或在沉积金属之后进行煅烧。催化剂可用于通过使催化剂与含有每分子具有2至12个碳原子的烷烃，烯烃和其混合物的烃流接触并回收产物来将烃如丙烷转化为芳族化合物的方法。

65. 发明申请

US20110301386A1 Process for Increasing the Carbon Monoxide Content of a Syngas Mixture 有权
标题翻译：增加合成气混合物中一氧化碳含量的方法
公开(公告)号：US20110301386A1
公开(公告)日：2011-12-08
申请号：US13140405
申请日：2009-12-15
申请人： Aggadin Kh. Mamedov , Mubarak Bashir
发明人： Aggadin Kh. Mamedov , Mubarak Bashir
IPC分类号： C07C41/01 , C07C29/00 , C01B3/38
CPC分类号： C07C41/01 , B01J23/26 , C01B3/34 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/025 , C01B2203/0435 , C01B2203/047 , C01B2203/0495 , C01B2203/06 , C07C29/136 , C07C29/1518 , C10G2/32 , C10K3/02 , Y02P20/146 , Y02P20/52 , C07C31/04 , C07C43/043
摘要： The invention relates to a process for increasing the carbon monoxide content of a feed gas mixture comprising carbon dioxide, hydrogen and carbon monoxide via a catalytic reversed water gas shift reaction, comprising the steps of (1) heating the feed gas mixture having an initial feed temperature of at most 350° C. in a first zone to a temperature within a reaction temperature range in the presence of a first catalyst; and (2) contacting the heated feed gas in a second zone within the reaction temperature range with a second catalyst. This process shows relatively high conversion of carbon dioxide, and virtually no methane or coke is being formed, allowing stable operation.
摘要翻译：本发明涉及通过催化反向水煤气变换反应来增加包含二氧化碳，氢气和一氧化碳的原料气体混合物的一氧化碳含量的方法，其包括以下步骤：（1）加热具有初始进料的进料气体混合物温度在第一区域中至多350℃，在第一催化剂存在下在反应温度范围内的温度; 和（2）在反应温度范围内的第二区域中与第二催化剂接触加热的进料气体。该方法显示二氧化碳转化率相对较高，实际上没有形成甲烷或焦炭，从而能够稳定运行。

66. 发明申请

US20110245554A1 Production of Hydrogen, Liquid Fuels, and Chemicals from Catalytic Processing of Bio-Oils 失效
标题翻译：生物油的催化加工生产氢，液体燃料和化学品
公开(公告)号：US20110245554A1
公开(公告)日：2011-10-06
申请号：US13119750
申请日：2009-09-18
申请人： George W. Huber , Tushar P. Vispute , Kamalakanta Routray
发明人： George W. Huber , Tushar P. Vispute , Kamalakanta Routray
IPC分类号： C07C4/00 , C01B3/26 , C07C29/00 , C07D307/00
CPC分类号： C01B3/323 , B01J23/002 , B01J27/1856 , B01J37/0205 , B01J2523/00 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1264 , C01B2203/148 , C10G1/083 , C10G1/086 , C10G3/47 , C10G3/52 , C10G49/007 , C10G2300/1014 , C10G2400/02 , C10G2400/04 , Y02P20/52 , Y02P30/20 , B01J2523/48 , B01J2523/51 , B01J2523/828
摘要： Disclosed herein is a method of generating hydrogen from a bio-oil, comprising hydrogenating a water-soluble fraction of the bio-oil with hydrogen in the presence of a hydrogenation catalyst, and reforming the water-soluble fraction by aqueous-phase reforming in the presence of a reforming catalyst, wherein hydrogen is generated by the reforming, and the amount of hydrogen generated is greater than that consumed by the hydrogenating. The method can further comprise hydrocracking or hydrotreating a lignin fraction of the bio-oil with hydrogen in the presence of a hydrocracking catalyst wherein the lignin fraction of bio-oil is obtained as a water-insoluble fraction from aqueous extraction of bio-oil. The hydrogen used in the hydrogenating and in the hydrocracking or hydrotreating can be generated by reforming the water-soluble fraction of bio-oil.
摘要翻译：本文公开了一种从生物油产生氢的方法，包括在氢化催化剂存在下用氢气氢化生物油的水溶性馏分，并通过水相重整在水溶性馏分中重整重整催化剂的存在，其中通过重整生成氢，并且产生的氢的量大于通过氢化消耗的氢的量。该方法可以进一步包括在加氢裂化催化剂存在下用氢气加氢裂解或加氢处理生物油的木质素部分，其中生物油的木质素部分作为水不溶性部分从生物油的水提取物中获得。用于氢化和加氢裂化或加氢处理的氢气可以通过重整生物油的水溶性部分来产生。

67. 发明申请

US20110223643A1 SYSTEM FOR BIONIC CATALYTIC HYDROLYZING CELLULOSE AND ITS USE IN PRODUCING LIQUID FUEL FROM CELLULOSE BIOMASS 审中-公开
标题翻译：用于生物降解纤维素的生物液体系统及其在纤维素生物质生产液体燃料中的应用
公开(公告)号：US20110223643A1
公开(公告)日：2011-09-15
申请号：US12744267
申请日：2007-11-23
申请人： Meg M. Sun , Zuolin Zhu , Hongping Yie
发明人： Meg M. Sun , Zuolin Zhu , Hongping Yie
IPC分类号： C12P7/06 , C07F19/00 , C07F15/02 , C12P5/00 , C12P1/00 , C07C29/00 , C07C1/00
CPC分类号： B01J31/2239 , B01J31/1805 , B01J2531/842 , C08B15/02 , C10G2300/1011 , C10L1/02 , C13K1/02 , Y02E50/17 , Y02P20/584 , Y02P30/20
摘要： A bionic catalyst for hydrolyzing cellulose and hemicellulose and its preparation method. The catalyst comprises double acid radical catalytic portions and cellulose-linking portions, and can be used under room temperature and high temperature. The catalyst can hydrolyze cellulose and hemicellulose simultaneously, while not decompose glucose and xylose, and may be recycled efficiently. The catalyst can be combined with the process in the prior art to produce liquid fuel.
摘要翻译：一种用于水解纤维素和半纤维素的仿生催化剂及其制备方法。该催化剂包括双酸自由基催化部分和纤维素连接部分，并且可以在室温和高温下使用。催化剂可以同时水解纤维素和半纤维素，而不会分解葡萄糖和木糖，并且可以有效回收。催化剂可以与现有技术中的方法组合以产生液体燃料。

68. 发明申请

US20110133132A1 Chemically functionalized submicron graphitic fibrils, methods for producing same and compositions containing same 有权
标题翻译：化学官能化的亚微米石墨原纤维，其制备方法和含有它们的组合物
公开(公告)号：US20110133132A1
公开(公告)日：2011-06-09
申请号：US12804190
申请日：2010-07-16
申请人： Aruna Zhamu , Bor Z. Jang
发明人： Aruna Zhamu , Bor Z. Jang
IPC分类号： H01B1/24 , C01B31/02 , B32B5/16 , C12N11/14 , D01F9/12 , C07C51/00 , C01B31/26 , C07C209/00 , C07C67/00 , C07C29/00 , C07C231/00
CPC分类号： D01F9/12 , B82Y30/00 , B82Y40/00 , C01B32/16 , C01B32/174 , D01D5/423 , H01G11/38 , Y02E60/13 , Y10T428/25 , Y10T428/2918
摘要： The present invention provides a chemically functionalized submicron graphitic fibril having a diameter or thickness less than 1 μm, wherein the fibril is free of continuous thermal carbon overcoat, free of continuous hollow core, and free of catalyst. The fibril is obtained by splitting a micron-scaled carbon fiber or graphite fiber along the fiber axis direction. These functionalized graphitic fibrils exhibit exceptionally high electrical conductivity, high thermal conductivity, high elastic modulus, high strength and good interfacial bonding with a matrix resin in a composite. The present invention also provides several products that contain submicron graphitic fibrils: (a) paper, thin-film, mat, and web products; (b) rubber or tire products; (c) energy conversion or storage devices, such as fuel cells, lithium-ion batteries, and supercapacitors; (d) adhesives, inks, coatings, paints, lubricants, and grease products; (e) heavy metal ion scavenger; (f) absorbent (e.g., to recover spill oil); (g) sensors; (h) friction and brake components; (i) radiation-shield components; (j) catalyst carrier; and (k) composite materials.
摘要翻译：本发明提供直径或厚度小于1μm的化学官能化亚微米石墨原纤，其中原纤维不含连续的热碳外涂层，不含连续的中空芯，并且不含催化剂。原纤维通过沿纤维轴线方向分裂微米级碳纤维或石墨纤维而获得。这些官能化石墨纤维表现出特别高的导电性，高导热性，高弹性模量，高强度和与复合材料中的基体树脂的良好的界面粘合。本发明还提供了几种含有亚微米石墨原纤的产品：（a）纸，薄膜，垫和网产品; （b）橡胶或轮胎产品; （c）燃料电池，锂离子电池和超级电容器等能量转换或存储装置; （d）粘合剂，油墨，涂料，涂料，润滑剂和油脂产品; （e）重金属离子清除剂; （f）吸收剂（例如，以回收溢油）; （g）传感器; （h）摩擦和制动部件; （i）辐射屏蔽部件; （j）催化剂载体; 和（k）复合材料。

69. 发明申请

US20110071229A1 Synthetic Gas Recycle Apparatus and Methods 审中-公开
标题翻译：合成气回收设备及方法
公开(公告)号：US20110071229A1
公开(公告)日：2011-03-24
申请号：US12563800
申请日：2009-09-21
申请人： Mark K. Robertson , Gwo-Jang Abraham Liou
发明人： Mark K. Robertson , Gwo-Jang Abraham Liou
IPC分类号： C07C1/04 , C07C27/06 , C07C29/00
CPC分类号： C01B3/52 , B01J2219/00006 , C01B3/00 , C01B3/16 , C01B3/34 , C01B3/501 , C01B2203/0233 , C01B2203/0283 , C01B2203/04 , C01B2203/0405 , C01B2203/0415 , C01B2203/0475 , C01B2203/0485 , C01B2203/062 , C01B2203/1047 , C07C29/1518 , C10G2/30 , C10G2/32 , C10J3/463 , C10J2300/0906 , C10J2300/093 , C10J2300/0959 , C10J2300/0969 , C10J2300/1659 , C10J2300/1665 , C10J2300/1678 , C10K1/004 , C10K1/005 , C10K3/04 , C10K3/06 , C07C31/04
摘要： Processes and apparatuses for synthesizing a hydrocarbon by reacting a carbon-containing feedstock with an oxygen-containing gas stream having a greater molar ratio of oxygen than the feedstock to produce a first synthetic gas comprising carbon monoxide and hydrogen, reacting the first synthetic gas in a shift reaction zone to produce a shifted synthetic gas, optionally but preferably blending a recycled synthetic gas with the shifted synthetic gas to produce a second synthetic gas, reacting the second synthetic gas with a catalyst in a synthesis reaction zone to produce hydrocarbon(s) and a purge gas, passing the purge gas through a separation zone to produce a hydrogen-containing permeate stream having an increased hydrogen molar ratio compared to the purge gas and a methane-containing non-permeate stream having an increased methane molar ratio compared to the purge gas, and reacting the methane-containing non-permeate stream in a reformation zone to produce the recycled synthetic gas.
摘要翻译：通过使含碳原料与具有比原料更大的氧摩尔比的含氧气体流反应以产生包含一氧化碳和氢的第一合成气体来合成烃的方法和装置，使第一合成气体在转化反应区以产生位移的合成气体，任选地但优选地将再循环的合成气与所转换的合成气体混合以产生第二合成气体，使第二合成气体与合成反应区中的催化剂反应以产生烃和净化气体，使净化气体通过分离区，以产生与吹扫气体相比具有增加的氢摩尔比的含氢渗透物流和与吹扫相比具有增加的甲烷摩尔比的含甲烷非渗透物流气体，并使重新形成区域中的含甲烷的非渗透物流反应，生成再生合成物 s。

70. 发明申请

US20110070135A1 Processes and Apparatuses for Purifying Greenhouse Gases 审中-公开
标题翻译：净化温室气体的工艺和设备
公开(公告)号：US20110070135A1
公开(公告)日：2011-03-24
申请号：US12562263
申请日：2009-09-18
申请人： Maria Balmas , Henry Chan , Chris Gibson , Craig Skinner , Kam Vakil
发明人： Maria Balmas , Henry Chan , Chris Gibson , Craig Skinner , Kam Vakil
IPC分类号： B01D53/62 , B01D47/00 , B01D53/46 , C01B31/20 , C07C29/00 , C01C1/04 , C07C5/02 , B01J19/00
CPC分类号： B01D53/1475 , B01D53/263 , B01D2256/22 , B01D2257/80 , C01B3/22 , C01B3/32 , C01B3/52 , C01B32/50 , C01B2203/0205 , C01B2203/025 , C01B2203/0266 , C01B2203/0288 , C01B2203/0415 , C01B2203/045 , C01B2203/0475 , C01B2203/0485 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/84 , C01B2203/86 , Y02C10/06 , Y02P20/152 , Y02P30/30
摘要： This invention relates to processes and apparatuses for purifying greenhouse gases. This invention relates to processes and apparatuses for drying carbon dioxide and/or producing syngas. The process includes the step of contacting a greenhouse gas stream having a contaminant with a solvent stream to at least partially reduce an amount of the contaminant and form a used solvent stream. The process includes the step of using the greenhouse gas stream for carbon sequestration, enhanced oil recovery, industrial gas supply, or chemical synthesis and production.
摘要翻译：本发明涉及用于净化温室气体的方法和装置。本发明涉及用于干燥二氧化碳和/或生产合成气的方法和装置。该方法包括使具有污染物的温室气体流与溶剂流接触以至少部分地减少污染物的量并形成用过的溶剂流的步骤。该过程包括使用温室气体流进行碳固存，提高采油，工业气体供应或化学合成和生产的步骤。

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