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    • 73. 发明授权
    • Method and system for providing a thin film with a controlled crystal orientation using pulsed laser induced melting and nucleation-initiated crystallization
    • 使用脉冲激光诱导熔融和成核引发结晶来提供具有受控晶体取向的薄膜的方法和系统
    • US07399359B2
    • 2008-07-15
    • US10953312
    • 2004-09-29
    • James S. ImJae Beom Choi
    • James S. ImJae Beom Choi
    • H01L21/00H01L21/31
    • H01L21/76867B23K26/066C30B13/24C30B29/02H01L21/76838
    • Method and system for generating a metal thin film with a uniform crystalline orientation and a controlled crystalline microstructure are provided. For example, a metal layer is irradicated with a pulsed laser to completely melt the film throughout its entire thickness. The metal layer can then resolidify to form grains with a substantially uniform orientation. The resolidified metal layer can be irradiated with a sequential lateral solidification technique to modify the crystalline microstructure (e.g., create larger grains, single-crystal regions, grain boundary controlled microstructures, etc.) The metal layer can be irradiated by patterning a beam using a mask which includes a first region capable of attenuating the pulsed laser and a second region allowing complete irradiation of sections of the thin film being impinged by the masked laser beam. An inverse dot-patterned mask can be used, the microstructure that may have substantially the same as the geometric pattern as that of the dots of the mask.
    • 提供了用于产生具有均匀结晶取向和受控结晶微结构的金属薄膜的方法和系统。 例如,用脉冲激光对金属层进行辐射,以使其在整个厚度上完全熔化。 然后可以将金属层重新固化以形成具有基本均匀取向的晶粒。 可以用连续的侧向固化技术照射再固化的金属层,以改变结晶微结构(例如,产生更大的晶粒,单晶区域,晶界控制的微结构等)。金属层可以通过使用 掩模,其包括能够衰减所述脉冲激光的第一区域和允许被所述被掩模的激光束照射所述薄膜的部分的完全照射的第二区域。 可以使用反点阵图案掩模,该微结构可以具有与掩模点的几何图案基本相同的微结构。
    • 75. 发明授权
    • Nanostructures including a metal
    • 纳米结构包括金属
    • US07344753B2
    • 2008-03-18
    • US10664431
    • 2003-09-19
    • Hyungsoo Choi
    • Hyungsoo Choi
    • C23C16/00
    • C30B25/02B82Y30/00C30B29/02C30B29/605Y10T428/12993Y10T428/24917Y10T428/26
    • One embodiment includes noncatalytically forming a nanowire on a substrate from an organometallic vapor without application of any type of reduction agent. The nanowire is grown during this formation in a direction away from the substrate and is freestanding during growth. The nanowire has a first dimension of 500 nanometers or less and a second dimension extending from the substrate to a free end of the nanowire at least 10 times greater than the first dimension. In one form, the organometallic vapor includes copper and the nanowire essentially consists of elemental copper, a copper alloy, or oxide of copper. Alternatively or additionally, the nanowire is of a monocrystalline structure.
    • 一个实施方案包括在不使用任何类型的还原剂的情况下从有机金属蒸气在基材上非催化形成纳米线。 纳米线在这种形成过程中沿远离基底的方向生长,并且在生长期间是独立的。 纳米线具有500纳米或更小的第一尺寸和从基底延伸到纳米线的自由端的第二尺寸比第一尺寸大至少10倍。 在一种形式中,有机金属蒸汽包括铜,并且纳米线基本上由元素铜,铜合金或铜的氧化物组成。 或者或另外,纳米线是单晶结构的。
    • 77. 发明申请
    • Fullerene Hollow Structure Needle Crystal and C60-C70 Mixed Fine Wire, and Method for Preparation Thereof
    • 富勒烯中空结构针晶和C60-C70混合细线及其制备方法
    • US20080003165A1
    • 2008-01-03
    • US10593870
    • 2005-02-14
    • Kun'ichi MiyazawaMasahisa FujinoMasaru TachibanaKen-ichi KobayashiTadatomo Suga
    • Kun'ichi MiyazawaMasahisa FujinoMasaru TachibanaKen-ichi KobayashiTadatomo Suga
    • C01B31/02
    • B82Y40/00B82Y30/00C01B32/15C01B32/152C30B7/00C30B29/02C30B29/62
    • A needle crystal in the form of a capsule comprising fullerene molecules such as C60 and a C60 platinum derivative and having a hollow portion (a fullerene shell capsule) is provided. The fullerene shell capsule which has been prepared by the liquid-liquid interface precipitation method, which comprises (1) a step in which a solution containing a first solvent dissolving fullerene therein is combined with a second solvent in which the solubility of fullerene is lower than in the above first solvent; (2) a step in which a liquid-liquid interface is formed between the above solution and the above second solvent; and (3) a step in which a carbon fine wire is precipitated on the above liquid-liquid interface, has a novel characteristic in its form and can be used as a catalyst supporting material, a raw material for a plastic composite material, a storage material for gas such as hydrogen, a catalyst for fuel cell, or the like. Further, provided are novel C60-C70 mixed fine wire which is fullerene fine wire comprising two components of C60 and C70, and a method for preparing the mixed fine wire.
    • 提供了包含富勒烯分子例如C 60和C 60 Pt衍生物并具有中空部分(富勒烯壳胶囊)的胶囊形式的针状晶体。 通过液 - 液界面沉淀法制备的富勒烯壳胶囊,其包括(1)将含有其中溶解富勒烯的第一溶剂的溶液与富勒烯的溶解度低于第二溶剂的第二溶剂组合的步骤 在上述第一溶剂中; (2)在上述溶液和上述第二溶剂之间形成液 - 液界面的步骤; (3)在上述液 - 液界面上析出碳细线的步骤,具有新颖的形态特征,可用作催化剂载体材料,塑料复合材料用原料,储存 气体如氢气,燃料电池用催化剂等。 此外,提供了作为包含C 60和C 20的两个组分的富勒烯细线的新颖的C 60 -C 70混合细线, 70 <! - SIPO - >和细混合线的制备方法。
    • 78. 发明申请
    • Method of Manufacturing Carbon Nanostructure
    • 制造碳纳米结构的方法
    • US20070224107A1
    • 2007-09-27
    • US11587212
    • 2005-01-28
    • Takeshi Hikata
    • Takeshi Hikata
    • C01B31/02B82B3/00
    • C30B29/02B01J23/8906B01J23/8913B01J23/8993B01J35/06B82Y30/00B82Y40/00C01B32/162C30B25/02Y10S977/742
    • A method of manufacturing carbon nanostructures that allows carbon nanostructures having more uniform shape to be produced in high purity and in a stable manner is provided. The present invention relates to a method of manufacturing a carbon nanostructure for growing crystalline carbon by means of vapor deposition from a crystal growth surface of a catalytic base including a catalytic material, and in particular, to a method of manufacturing a carbon nanostructure where at least two gases including a feedstock gas are brought into contact with the catalytic base simultaneously. Preferably, the at least two gases are constituted by at least one feedstock gas and at least one carrier gas. Preferably, the carrier gas is brought into contact with the crystal growth surface, and the feedstock gas is brought into contact with at least a part of a region except for the crystal growth surface with which the carrier gas has been brought into contact. Preferably, the material gas contains an ion, and further preferably, it contains a carbon ion.
    • 提供一种制造碳纳米结构的方法,其允许以高纯度和稳定的方式制备具有更均匀形状的碳纳米结构。 本发明涉及一种通过从包括催化材料的催化底物的晶体生长表面进行气相沉积来生长结晶碳的碳纳米结构体的制造方法,特别涉及一种制造碳纳米结构的方法,其中至少 包括原料气体的两种气体同时与催化底物接触。 优选地,至少两种气体由至少一种原料气体和至少一种载气构成。 优选地,使载气与晶体生长表面接触,并且使原料气体与除载体气体已经接触的晶体生长表面以外的区域的至少一部分接触。 优选地,原料气体含有离子,进一步优选含有碳离子。