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    • 3. 发明申请
    • COMPOSITE SEAL FOR FUEL CELLS, PROCESS OF MANUFACTURE, AND FUEL CELL STACK USING SAME
    • 燃料电池的复合密封,制造工艺和使用其的燃料电池堆叠
    • US20130101915A1
    • 2013-04-25
    • US13806152
    • 2010-06-25
    • Jean YamanisSunil G. WarrierSarah Arsenault-PreeceJustin R. Hawkes
    • Jean YamanisSunil G. WarrierSarah Arsenault-PreeceJustin R. Hawkes
    • H01M8/02
    • H01M8/028H01M8/0282H01M8/0286H01M8/2425H01M8/2432H01M8/2457H01M8/249Y02P70/56
    • A seal is provided for use in a solid oxide fuel cell, wherein the seal is formed of alternating adjacent layers of a fiber tow material and a foil material. A solid oxide fuel cell stack is also disclosed and is formed of repeating cell units, each cell unit having a plurality of fuel cell stack components defining opposed component surfaces, and the seal as described above positioned between the opposed component surfaces. A process is also provided for manufacturing a composite seal for a solid oxide fuel cell, and the process including the steps of: (a) feeding a quantity of spooled fiber tow material through an inert bonding agent to form a coated fiber tow material; (b) winding the coated fiber tow material about a mandrel to form a wound layer of fiber tow material; (c) feeding a quantity of spooled foil material about the wound layer of fiber tow material to form a wound layer of foil material; and (d) repeating steps (a) through (c) until forming a composite seal having desired thickness and width.
    • 提供用于固体氧化物燃料电池的密封件,其中密封件由交替的纤维丝束材料和箔材料的相邻层形成。 还公开了固体氧化物燃料电池堆,并且由重复的电池单元形成,每个电池单元具有限定相对的元件表面的多个燃料电池堆组件,以及定位在相对的组件表面之间的如上所述的密封件。 还提供了一种用于制造用于固体氧化物燃料电池的复合密封件的方法,该方法包括以下步骤:(a)通过惰性粘合剂将一定数量的缠绕纤维丝束材料供给以形成涂覆的纤维束材料; (b)围绕心轴卷绕涂覆的纤维丝束材料以形成纤维束材料的卷绕层; (c)在纤维丝束材料的缠绕层周围供给一定数量的缠绕箔材料以形成箔材料的卷绕层; 和(d)重复步骤(a)至(c),直到形成具有所需厚度和宽度的复合密封件。
    • 6. 发明授权
    • High toughness, high strength sintered silicon nitride
    • 高韧性,高强度烧结氮化硅
    • US5312788A
    • 1994-05-17
    • US76940
    • 1993-06-16
    • Chien-Wei LiJean Yamanis
    • Chien-Wei LiJean Yamanis
    • C04B35/584C04B35/593C04B35/80C04B41/80C04B35/58
    • C04B41/80C04B35/5935C04B35/806
    • A silicon nitride sintered body has a composition consisting essentially of 85 to 94% by weight .beta. silicon nitride, 6 to 15% by weight grain boundary phase consisting essentially of (i) at least two rare earth elements, wherein yttrium is considered a rare earth, and, optionally, strontium which, calculated as SrO, is 0-2 percent by weight of the total body, and (ii) at least two of Si, N, O and C, and an additive consisting essentially of a metal-carbon compound present in the amount of about 0.2 to 3.5% by volume. The additive is substantially homogeneously dispersed within the sintered body. The sintered body has a density at least 95% of theoretical and the ceramic has high strength and high toughness and is especially suited for industrial applications such as components for gas turbine and automotive engines. The sintered body has a microstructure wherein (i) the .beta. silicon nitride grains are acicular and have an average grain width ranging from 0.5 to 1.5 .mu.m, (ii) at least 25% of the grains have width greater than 0.7 .mu.m, and at least 10% of the grains have width greater than 1 .mu.m, and (iii) no more than 5% of grains have width greater than 3.5 .mu.m and apparent aspect ratio greater than 5, with the proviso that the average aspect ratio is at least 1.8.
    • 氮化硅烧结体具有基本上由85至94重量%的β氮化硅,6至15重量%的晶界相组成的组成,其基本上由(i)至少两个稀土元素组成,其中钇被认为是稀土 ,和任选的以SrO计为0-2重量%的锶,和(ii)Si,N,O和C中的至少两个,以及基本上由金属 - 碳组成的添加剂 化合物的存在量为约0.2-3.5%(体积)。 添加剂基本均匀地分散在烧结体内。 烧结体的密度至少为理论值的95%,陶瓷具有高强度和高韧性,特别适用于燃气轮机和汽车发动机的部件等工业应用。 所述烧结体具有以下微结构:(i)所述β型氮化硅晶粒为针状,平均晶粒宽度为0.5〜1.5μm,(ii)所述晶粒的至少25%的宽度大于0.7μm, 至少10%的晶粒具有大于1μm的宽度,和(iii)不超过5%的晶粒宽度大于3.5μm,并且视在长宽比大于5,条件是平均纵横比为 至少1.8。
    • 8. 发明授权
    • Preparation of lanthanum chromite powders by sol-gel
    • 通过溶胶 - 凝胶制备亚铬酸镧粉
    • US5128284A
    • 1992-07-07
    • US715206
    • 1991-06-14
    • William L. OlsonBeili LiJean Yamanis
    • William L. OlsonBeili LiJean Yamanis
    • C01G37/00C04B35/42H01M8/02H01M8/12
    • H01M8/0215C01G37/006C04B35/42C01P2002/02C01P2002/34C01P2002/54C01P2004/61C01P2004/62C01P2006/10H01M2008/1293H01M2300/0074
    • This invention relates to a process for the preparation of a crystalline compound having an empirical formula LaCr.sub.x A.sub.1-x O.sub.4 .multidot.yH.sub.2 O where A is a metal selected from the group consisting of Mg, Sr, Ca and Ba, x ranges from 0.99 to about 0.7 and y ranges from 0 to 0.15. The process comprises adding a solution of the appropriate metal salts to a solution of ammonium hydroxide thereby precipitating a hydroxide gel intermediate, which is dried and calcined in air to yield the resultant crystalline compound which has a huttonite structure. Additionally, this invention relates to a process for the preparation of a ceramic powder having the empirical formula LaCr.sub.x A.sub.1-x O.sub.3, where A is a metal selected from the group consisting of Mg, Sr, Ca and Ba and x ranges from 0.99 to about 0.7. Finally, a ceramic composition having the empirical formula LaCr.sub.x S.sub.1-x O.sub.4 .multidot.yH.sub.2 O having a huttonite structure is also disclosed.
    • 本发明涉及一种制备具有经验式LaCrxAl-xO4xyH2O的结晶化合物的方法,其中A是选自Mg,Sr,Ca和Ba的金属,x为0.99至约0.7,y为 0〜0.15。 该方法包括将合适的金属盐溶液加入到氢氧化铵溶液中,由此使氢氧化凝胶中间体沉淀,将其在空气中干燥和煅烧,得到所得到的具有钙钛矿结构的结晶化合物。 另外本发明涉及制备具有经验式LaCrxAl-xO3的陶瓷粉末的方法,其中A是选自Mg,Sr,Ca和Ba的金属,x在0.99至约0.7的范围内。 最后,还公开了具有钙钛矿结构的经验式LaCrxS1-xO4xyH2O的陶瓷组合物。
    • 10. 发明授权
    • Production of anhydrous 1,4-dioxane
    • 生产无水1,4-二恶烷
    • US4365071A
    • 1982-12-21
    • US151593
    • 1980-05-20
    • Jean Yamanis
    • Jean Yamanis
    • C07D319/12C07D319/04
    • C07D319/12
    • This invention relates to the production of anhydrous 1,4-dioxane by the dimerization of ethylene oxide in the presence of an acidic type of cation exchanger, preferably an acidic cation exchanger resin having sulfonic acid groups associated therewith. The 1,4-dioxane is formed by contacting ethylene oxide in the liquid phase with an acidic-type cation exchanger at a first temperature and for a time sufficient to yield a reaction product of the ethylene oxide and the cation exchanger, and thereafter heating the reaction product at a second temperature higher than the first temperature and for a time period sufficient to dissociate the reaction product and thereby yield 1,4-dioxane.
    • 本发明涉及在酸性类型的阳离子交换剂,优选与其相关的具有磺酸基团的酸性阳离子交换树脂的存在下,通过环氧乙烷的二聚制备无水1,4-二恶烷。 通过使液相中的环氧乙烷与酸性型阳离子交换剂在第一温度下接触足够的时间以产生环氧乙烷和阳离子交换剂的反应产物,然后加热所述1,4-二恶烷 反应产物在高于第一温度的第二温度下反应足够的时间以解离反应产物,从而得到1,4-二恶烷。