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    • 1. 发明授权
    • Silica supported transition metal catalyst
    • 二氧化硅负载过渡金属催化剂
    • US5231151A
    • 1993-07-27
    • US854175
    • 1992-03-20
    • Lee SpencerBrian W. S. KolthammerMiriam P. RipplingerJeffrey J. WoosterPak-Wing S. ChumJacquelyn A. deGroot
    • Lee SpencerBrian W. S. KolthammerMiriam P. RipplingerJeffrey J. WoosterPak-Wing S. ChumJacquelyn A. deGroot
    • C08J5/18B29C55/02B29K23/00B29L7/00C08F4/646C08F4/658C08F4/685C08F10/00C08F210/00C08F210/02C08F210/16
    • C08F10/00Y10S428/91Y10T428/26Y10T428/31855
    • A transition metal containing catalyst useful for the polymerization of .alpha.-olefins is prepared by (A) forming in an inert atmosphere which excludes oxygen and moisture a slurry of (1) a porous inorganic oxide support material selected from the group consisting of silica, alumina, or a combination of silica and alumina, said support material containing not greater than about 5 millimoles of hydroxyl groups per gram of support material and a particle size not greater than about 10 microns and a surface area of from about 50 to about 800 m.sup.2 /g in an inert organic liquid medium; (B) mixing said slurry with (2) an alkoxide and stirring the resultant mixture at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to saturate the surface of the support material; (C) mixing the product form (B) with (3) a titanium compound or a combination of a titanium compound and (4) a vanadium compound and stirring the resultant mixture at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to allow complete reaction of the titanium compound and the vanadium compound with the organomagnesium moieties remaining on the solid support; (D) mixing the product from (C) with an inert organic solution of (5) a Group IIIA metal alkyl halide at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to complete the reduction of the titanium and vanadium, if present, compounds to their final oxidation state.
    • 用于α-烯烃聚合的含过渡金属的催化剂通过以下步骤制备:(A)在惰性气氛中形成不含氧和水分的淤浆(1)多孔无机氧化物载体材料,其选自二氧化硅,氧化铝 ,或二氧化硅和氧化铝的组合,所述载体材料每克载体材料含有不大于约5毫摩尔羟基,粒度不大于约10微米,表面积为约50至约800平方米/ g在惰性有机液体介质中; (B)将所述浆料与(2)醇盐混合并在约-20℃至约120℃的温度下搅拌所得混合物足以使载体材料表面饱和的时间; (C)将产品形式(B)与(3)钛化合物或钛化合物和(4)钒化合物的组合混合并在约-20℃至约120℃的温度下搅拌所得混合物 在足以允许钛化合物和钒化合物与残留在固体载体上的有机镁部分完全反应的时间; (D)将来自(C)的产物与(5)IIIA族金属烷基卤的惰性有机溶液在约-20℃至约120℃的温度下混合足以完成还原的时间 的钛和钒(如果存在)化合物达到其最终氧化态。
    • 8. 发明授权
    • Silica supported transition metal catalyst
    • 二氧化硅负载过渡金属催化剂
    • US06747113B1
    • 2004-06-08
    • US09715566
    • 2000-11-17
    • Lee SpencerMiriam P. RipplingerBrian W. S. KolthammerJeffrey J. Wooster
    • Lee SpencerMiriam P. RipplingerBrian W. S. KolthammerJeffrey J. Wooster
    • C08F21000
    • C08F10/00C08F110/02C08L23/04C08L23/0815C08L2205/02C08L2205/025C08L2308/00C08L2314/02C08F4/6555C08F4/6357C08L2666/04C08F2500/08C08F2500/12C08F2500/24
    • A polymer produced by a transition metal containing catalyst useful for the polymerization of &agr;-olefins is prepared by (A) forming in an inert atmosphere which excludes oxygen and moisture a slurry of (1) a porous inorganic oxide support material selected from the group consisting of silica, alumina, or a combination of silica and alumina, said support material containing not greater than about 5 millimoles of hydroxyl groups per gram of support material and a particle size not greater than about 10 microns and a surface area of from about 50 to about 800 m2/g in an inert organic liquid medium; (B) mixing said slurry with (2) an alkoxide and stirring the resultant mixture at a temperature of from about −20° C. to about 120° C. for a time sufficient to saturate the surface of the support material; (C) mixing the product form (B) with (3) a titanium compound or a combination of a titanium compound and (4) a vanadium compound and stirring the resultant mixture at a temperature of from about −20° C. to about 120° C. for a time sufficient to allow complete reaction of the titanium compound and the vanadium compound with the organomagnesium moieties remaining on the solid support; (D) mixing the product from (C) with an inert organic solution of (5) a Group IIIA metal alkyl halide at a temperature of from about −20° C. to about 120° C. for a time sufficient to complete the reduction of the titanium and vanadium, if present, compounds to their final oxidation state. Ethylene/alpha-olefin copolymers which have greater than 17 percent high density fraction and a Mw/Mn ratio of less than about 3.6 are shown to be useful in making cast films which have good stretchability and good puncture resistance. Copolymers of the present invention having the specified properties are especially useful in making the films.
    • 由用于α-烯烃聚合的含过渡金属的催化剂制备的聚合物是通过(A)在惰性气氛中形成的,其中不包括氧气和水分,(1)多孔无机氧化物载体材料的浆料选自 的二氧化硅,氧化铝或二氧化硅和氧化铝的组合,所述载体材料每克载体材料含有不大于约5毫摩尔羟基,粒径不大于约10微米,表面积为约50至 在惰性有机液体介质中约800m 2 / g; (B)将所述浆料与(2)醇盐混合并在约-20℃至约120℃的温度下搅拌所得混合物足以使载体材料表面饱和的时间; (C)将产品形式(B)与(3)钛化合物或钛化合物和(4)钒化合物的组合混合并在约-20℃至约120℃的温度下搅拌所得混合物 在足以允许钛化合物和钒化合物与残留在固体载体上的有机镁部分完全反应的时间; (D)将来自(C)的产物与(5)IIIA族金属烷基卤的惰性有机溶液在约-20℃至约120℃的温度下混合足以完成还原的时间 的钛和钒(如果存在)化合物达到其最终氧化态。 显示出具有大于17%的高密度分数和小于约3.6的Mw / Mn比的乙烯/α-烯烃共聚物可用于制备具有良好的拉伸性和良好的耐穿刺性的流延薄膜。 具有特定性质的本发明的共聚物在制备膜中特别有用。
    • 9. 发明授权
    • Silica supported transition metal catalyst
    • 二氧化硅负载过渡金属催化剂
    • US06172173B2
    • 2001-01-09
    • US08946785
    • 1997-10-08
    • Lee SpencerBrian W. S. KolthammerMiriam P. RipplingerJeffrey J. WoosterPak-Wing S. ChumJacquelyn A. deGroot
    • Lee SpencerBrian W. S. KolthammerMiriam P. RipplingerJeffrey J. WoosterPak-Wing S. ChumJacquelyn A. deGroot
    • C08F1014
    • C08L23/04C08F110/02C08L23/0815C08L2205/02C08L2205/025C08L2308/00C08L2314/02C08L2666/04C08F2500/08C08F2500/12C08F2500/24
    • A polymer produced by a transition metal containing catalyst useful for the polymerization of &agr;-olefins is prepared by (A) forming in an inert atmosphere which excludes oxygen and moisture a slurry of (1) a porous inorganic oxide support material selected from the group consisting of silica, alumina, or a combination of silica and alumina, said support material containing not greater than about 5 millimoles of hydroxyl groups per gram of support material and a particle size not greater than about 10 microns and a surface area of from about 50 to about 800 m2/g in an inert organic liquid medium; (B) mixing said slurry with (2) an alkoxide and stirring the resultant mixture at a temperature of from about −20° C. to about 120° C. for a time sufficient to saturate the surface of the support material; (C) mixing the product form (B) with (3) a titanium compound or a combination of a titanium compound and (4) a vanadium compound and stirring the resultant mixture at a temperature of from about −20° C. to about 120° C. for a time sufficient to allow complete reaction of the titanium compound and the vanadium compound with the organomagnesium moieties remaining on the solid support; (D) mixing the product from (C) with an inert organic solution of (5) a Group IIIA metal alkyl halide at a temperature of from about −20° C. to about 120° C. for a time sufficient to complete the reduction of the titanium and vanadium, if present, compounds to their final oxidation state. Ethylene/alpha-olefin copolymers which have greater than 17 percent high density fraction and a Mw/Mn ratio of less than about 3.6 are shown to be useful in making cast films which have good stretchability and good puncture resistance. Copolymers of the present invention having the specified properties are especially useful in making the films.
    • 由用于α-烯烃聚合的含过渡金属的催化剂制备的聚合物是通过(A)在惰性气氛中形成的,其中不包括氧气和水分,(1)多孔无机氧化物载体材料的浆料选自 的二氧化硅,氧化铝或二氧化硅和氧化铝的组合,所述载体材料每克载体材料含有不大于约5毫摩尔羟基,粒径不大于约10微米,表面积为约50至 在惰性有机液体介质中约800m 2 / g; (B)将所述浆料与(2)醇盐混合并在约-20℃至约120℃的温度下搅拌所得混合物足以使载体材料表面饱和的时间; (C)将产品形式(B)与(3)钛化合物或钛化合物和(4)钒化合物的组合混合并在约-20℃至约120℃的温度下搅拌所得混合物 在足以允许钛化合物和钒化合物与残留在固体载体上的有机镁部分完全反应的时间; (D)将来自(C)的产物与(5)IIIA族金属烷基卤的惰性有机溶液在约-20℃至约120℃的温度下混合足以完成还原的时间 的钛和钒(如果存在)化合物达到其最终氧化态。 显示出具有大于17%的高密度分数和小于约3.6的Mw / Mn比的乙烯/α-烯烃共聚物可用于制备具有良好的拉伸性和良好的耐穿刺性的流延薄膜。 具有特定性质的本发明的共聚物在制备膜中特别有用。