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    • 4. 发明授权
    • Plasma etch chemistry and method of improving etch control
    • 等离子蚀刻化学和改进蚀刻控制的方法
    • US06372634B1
    • 2002-04-16
    • US09333459
    • 1999-06-15
    • Jianmin QiaoSanjay ThekdiManuj RathorJames E. Nulty
    • Jianmin QiaoSanjay ThekdiManuj RathorJames E. Nulty
    • H01L213065
    • H01L21/31116H01L21/76802H01L21/76816
    • A plasma etch chemistry and etch methodology is provided to improve critical dimension control for openings formed into and/or through a semiconductor thin film. According to an embodiment, the plasma etch chemistry includes an etchant mixture comprising a first etchant of the formula CxHyFz (where x≧2, y≧1 and z≧2) and a second etchant other than the first etchant to form the openings. The relationship of x, y and z may be such that y+z equals an even number ≦2x+2. According to an alternative embodiment, the plasma etch chemistry further includes strained cyclic (hydro)fluorocarbon. The plasma etch chemistry may be used to form openings in the layer in a single-etch step. In a further embodiment, the plasma etch chemistry described herein may etch less than the entire thickness of the layer, and a second plasma etch chemistry substantially free of the first etchant and strained cyclic (hydro)fluorocarbons etches the remainder of the layer to form the openings. Such an etch methodology advantageously reduces the risk of etching the materials underlying the layer.
    • 提供等离子体蚀刻化学和蚀刻方法以改进形成于和/或穿过半导体薄膜的开口的临界尺寸控制。 根据实施例,等离子体蚀刻化学品包括蚀刻剂混合物,其包含式C x H y F z(其中x> = 2,y> = 1和z> = 2)的第一蚀刻剂和除第一蚀刻剂之外的第二蚀刻剂, 开口 x,y和z的关系可以使得y + z等于偶数<= 2x + 2。 根据替代实施例,等离子体蚀刻化学品还包括应变的环状(氢)氟碳化合物。 等离子体蚀刻化学可以用于在单蚀刻步骤中在层中形成开口。 在另一个实施方案中,本文所述的等离子体蚀刻化学蚀刻可以蚀刻小于层的整个厚度,并且基本上不含第一蚀刻剂的第二等离子体蚀刻化学品和应变的环状(氢)氟碳化物蚀刻该层的其余部分,形成 开口 这种蚀刻方法有利地降低了蚀刻层之下的材料的风险。