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    • 1. 发明授权
    • Hybrid epoxy resin adducts
    • 混合环氧树脂加合物
    • US09255177B2
    • 2016-02-09
    • US14117907
    • 2012-06-14
    • Robert E. Hefner, Jr.
    • Robert E. Hefner, Jr.
    • C08G59/14C08G59/04C08G59/18C08G59/02C08L63/00
    • C08G59/1477C08G59/022C08G59/04C08G59/184C08L63/00
    • A hybrid epoxy resin adduct comprising, consisting of, or consisting essentially of the reaction product of: (A) a material selected from the group consisting of a hybrid polyfunctional aliphatic epoxy resin, a hybrid cycloaliphatic epoxy resin, and combinations thereof; wherein (A) is formed by contacting: (a) a hydroxyl-containing material selected from the group consisting of an aliphatic hydroxyl-containing material, a cycloaliphatic hydroxyl-containing material, and combinations thereof; (b) a material selected from the group consisting of a monoglycidyl ether-containing material, a diglycidyl ether-containing material, and combinations thereof wherein (b) is prepared from a different precursor than (a); (c) an epihalohydrin; (d) a basic acting substance; (e) a non-Lewis acid catalyst; and (f) optionally, a solvent and (B) at least one epoxide reactive compound comprising one or more compounds having two or more epoxide-reactive hydrogen atoms per molecule, is disclosed.
    • 一种混合环氧树脂加合物,其包含由以下物质组成或由其组成:(A)选自杂化多官能脂族环氧树脂,杂化脂环族环氧树脂及其组合的材料; 其中(A)通过使(a)选自含脂肪族羟基的材料,含脂环族羟基的材料及其组合的含羟基材料接触而形成; (b)选自含有单缩水甘油醚的材料,含二缩水甘油醚的材料及其组合的材料,其中(b)由不同于(a)的前体制备; (c)表卤代醇; (d)基本作用物质; (e)非路易斯酸催化剂; 和(f)任选地,溶剂和(B)至少一种包含一种或多种每分子具有两个或更多个环氧化物反应性氢原子的化合物的环氧化物反应性化合物。
    • 2. 发明授权
    • Coating compositions
    • 涂料组合物
    • US09080059B2
    • 2015-07-14
    • US13817015
    • 2011-09-13
    • Xin JinRay E. DrumrightBernhard KainzJerry E. WhiteRobert E. Hefner, Jr.
    • Xin JinRay E. DrumrightBernhard KainzJerry E. WhiteRobert E. Hefner, Jr.
    • B32B15/092B32B27/38C09D163/00C08G59/24B05D3/02C09D5/00C08G59/06
    • C09D5/00C08G59/066C08L2205/05C09D163/00C08L33/02C08L67/00
    • A coating composition comprising an advanced epoxy resin polymeric composition having the following chemical structure:(formula) I where n is a number from 1 to about 3000; each m independently has a value of 0 or 1; each R0 is independently —H or —CH3; each R1 is independently —H or a C1 to C6 alkylene radical (saturated divalent aliphatic hydrocarbon radical); R′1-R′4 are independently hydrogen, an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent, for example, a nitro, an isocyanate, or an alkyloxy group; additionally, any two of R′1-R′4 may form fused ring independently; and X is cycloalkylene group, including substituted cycloalkylene group, where the substituent groups include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent group, for example, a halide, a cyano, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.
    • 一种涂料组合物,其包含具有以下化学结构的高级环氧树脂聚合物组合物:(式)I,其中n为1至约3000的数; 每个m独立地具有0或1的值; 每个R 0独立地是-H或-CH 3; 每个R 1独立地为-H或C 1至C 6亚烷基(饱和二价脂族烃基); R'1-R'4独立地为氢,烷基,环烷基,芳基或芳烷基或其它取代基,例如硝基,异氰酸酯基或烷氧基; 此外,R'1-R'4中的任何两个可以独立地形成稠环; 并且X是亚环烷基,包括取代的亚环烷基,其中取代基包括烷基,环烷基,芳基或芳烷基或其它取代基,例如卤素,氰基,硝基,封端异氰酸酯或 烷氧基 亚环烷基和亚烷基的组合以及亚烷基和亚环烷基之间的桥连部分的组合。
    • 3. 发明申请
    • EPOXY RESIN COMPOSITIONS
    • 环氧树脂组合物
    • US20140194554A1
    • 2014-07-10
    • US13816777
    • 2011-09-07
    • Robert E. Hefner, JR.
    • Robert E. Hefner, JR.
    • C08K5/01
    • C07K16/468C08G59/066C08G59/145C08K5/01C08L63/00C09D163/00C09J163/00
    • A re-epoxidized polyfunctional epoxy resin composition comprising the reaction product of: (I) an epoxidized polyfunctional epoxy resin oligomeric composition comprising a polyfunctional aliphatic or cycloaliphatic epoxy resin which has been isolated from an epoxy resin product formed as a result of an epoxidation process comprising the reaction of: (i) an aliphatic or cycloaliphatic hydroxyl-containing material; (ii) an epihalohydrin, (iii) a basic-acting substance, in the presence of (iv) a non-Lewis acid catalyst; and (v) optionally, one or more solvents; (II) an epihalohydrin; (III) a basic acting substance; in the presence of (IV) a non-Lewis acid catalyst; and (V) optionally, one or more solvents. A curable epoxy resin composition of the re-epoxidized polyfunctional epoxy resin composition and a thermoset of the curable composition is also disclosed.
    • 一种重新环氧化的多官能环氧树脂组合物,其包含以下反应产物:(I)环氧化的多官能环氧树脂低聚组合物,其包含多官能脂族或脂环族环氧树脂,其已经由作为环氧化方法的结果形成的环氧树脂产物分离, (i)脂族或脂环族含羟基材料的反应; (ii)表卤代醇,(iii)碱性作用物质,在(iv)非路易斯酸催化剂的存在下; 和(v)任选的一种或多种溶剂; (II)表卤代醇; (三)基本作用物质; 在(IV)非路易斯酸催化剂的存在下, 和(V)任选的一种或多种溶剂。 还公开了再环氧化多官能环氧树脂组合物的可固化环氧树脂组合物和可固化组合物的热固性。