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1. 发明授权

US07226710B2 Photocurable/therosetting resin composition, photosensitive dry film formed therefrom and method of forming pattern with the same 有权
标题翻译：可光固化/固化树脂组合物，由其形成的感光干燥膜和与其形成图案的方法
公开(公告)号：US07226710B2
公开(公告)日：2007-06-05
申请号：US10980190
申请日：2004-11-04
申请人： Tadatomi Nishikubo , Atsushi Kameyama , Masaki Sasaki , Masatoshi Kusama , Seiya Onodera
发明人： Tadatomi Nishikubo , Atsushi Kameyama , Masaki Sasaki , Masatoshi Kusama , Seiya Onodera
IPC分类号： G03F7/038
CPC分类号： G03F7/038 , C08G65/18 , G03F7/0045 , H05K3/285 , H05K3/287 , H05K3/4644 , H05K2203/124
摘要： A photocurable and thermosetting resin composition comprising (A) a photosensitive prepolymer having a carboxyl group in combination with at least two ethylenically unsaturated double bonds in its molecule, (B) a polymerization initiator, (C) a diluent, (D) an oxetane compound having at least two oxetanyl groups in its molecule, and (E) a curing promotor is developable with an alkaline solution and can be formulated as a one package preparation. Such a photocurable and thermosetting resin composition and a photosensitive dry film prepared by the use thereof are useful as various resist materials and electrical insulating materials, particularly as solder resists for printed circuit boards, interlaminar insulating materials for build-up multi-layer printed circuit boards, and the like.
摘要翻译：一种光固化性和热固性树脂组合物，其包含（A）在其分子中具有羧基与至少两个烯属不饱和双键组合的光敏预聚物，（B）聚合引发剂，（C）稀释剂，（D）氧杂环丁烷化合物在其分子中具有至少两个氧杂环丁烷基，和（E）固化促进剂可用碱性溶液显影，并且可以配制成一包装制剂。这种光固化性和热固性树脂组合物和通过其使用制备的光敏干燥膜可用作各种抗蚀剂材料和电绝缘材料，特别是用于印刷电路板的阻焊剂，用于积聚多层印刷电路板的层间绝缘材料，等等。

2. 发明申请

US20070123736A1 Calixarene compound, process for producing the same, intermediate therefor, and composition thereof 有权
标题翻译：杯芳烃化合物，其制备方法，其中间体及其组合物
公开(公告)号：US20070123736A1
公开(公告)日：2007-05-31
申请号：US10588313
申请日：2005-02-04
申请人： Tadatomi Nishikubo , Hiroto Kudou , Kouji Mitani
发明人： Tadatomi Nishikubo , Hiroto Kudou , Kouji Mitani
IPC分类号： C07C43/20 , C07C39/12
CPC分类号： G03F7/004 , C07C13/70 , C07C39/16 , C07C39/17 , C07C43/215 , C07C43/23 , C07C69/54 , C07C2603/92
摘要： A novel calixarene compound, a method for manufacturing the same, an intermediate of the calixarene compound, and a composition comprising the same are provided. The calixarene compound is expected to be useful as an inclusion compound and, if functional groups are introduced, can be used for a curable composition and a photoresist and as an inclusion compound. The calixarene compound is shown by following formula (1): wherein R1 to R6 individually represent a substituted or unsubstituted alkylene group having 1 to 8 carbon atoms; X1 to X12 individually represent a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 10 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 10 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 10 carbon atoms, a substituted or unsubstituted alkoxyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted phenoxy group; Z1 to Z24 individually represent a hydrogen atom, a group having a polymerizable functional group, a group having an alkali-soluble group, or a substituted alkyl group having an alkyl chain with a 1-8 carbon atom content, or two adjacent Zs in combination represent a substituted or unsubstituted alkylene group having 1 to 8 carbon atoms; q1 to q12 individually represent an integer of 0 or 1.
摘要翻译：提供了一种新的杯芳烃化合物，其制备方法，杯芳烃化合物的中间体和包含其的组合物。预期杯芳烃化合物可用作包合物，并且如果引入官能团，则可以将其用作可固化组合物和光致抗蚀剂以及作为包合物。杯芳烃化合物由下式（1）表示：其中R 1至R 6独立地表示取代或未取代的具有1至8个碳原子的亚烷基; X 12与X 12独立地表示取代或未取代的碳原子数1〜10的烷基，取代或未取代的碳原子数2〜10的烯基，取代或未取代的取代或未取代的碳原子数为7〜10的芳烷基，取代或未取代的碳原子数1〜10的烷氧基，取代或未取代的苯氧基等。 Z 1至Z 24各自独立地表示氢原子，具有可聚合官能团的基团，具有碱可溶性基团的基团或具有烷基的取代烷基具有1-8个碳原子的链，或两个相邻的Z组合表示具有1至8个碳原子的取代或未取代的亚烷基; q + 1至q 12独立地表示0或1的整数。

3. 发明申请

US20050112500A1 Photocurable/therosetting resin composition, photosensitive dry film formed therefrom and method of forming pattern with the same 有权
标题翻译：可光固化/固化树脂组合物，由其形成的感光干燥膜和与其形成图案的方法
公开(公告)号：US20050112500A1
公开(公告)日：2005-05-26
申请号：US10980190
申请日：2004-11-04
申请人： Tadatomi Nishikubo , Atsushi Kameyama , Masaki Sasaki , Masatoshi Kusama , Seiya Onodera
发明人： Tadatomi Nishikubo , Atsushi Kameyama , Masaki Sasaki , Masatoshi Kusama , Seiya Onodera
IPC分类号： C08F2/48 , C08G65/18 , G03F7/004 , G03F7/038 , H05K3/28 , H05K3/46 , G03C1/73
CPC分类号： G03F7/038 , C08G65/18 , G03F7/0045 , H05K3/285 , H05K3/287 , H05K3/4644 , H05K2203/124
摘要： A photocurable and thermosetting resin composition comprising (A) a photosensitive prepolymer having a carboxyl group in combination with at least two ethylenically unsaturated double bonds in its molecule, (B) a polymerization initiator, (C) a diluent, (D) an oxetane compound having at least two oxetanyl groups in its molecule, and (E) a curing promotor is developable with an alkaline solution and can be formulated as a one package preparation. Such a photocurable and thermosetting resin composition and a photosensitive dry film prepared by the use thereof are useful as various resist materials and electrical insulating materials, particularly as solder resists for printed circuit boards, interlaminar insulating materials for build-up multi-layer printed circuit boards, and the like.
摘要翻译：一种光固化性和热固性树脂组合物，其包含（A）在其分子中具有羧基与至少两个烯属不饱和双键组合的光敏预聚物，（B）聚合引发剂，（C）稀释剂，（D）氧杂环丁烷化合物在其分子中具有至少两个氧杂环丁烷基，和（E）固化促进剂可用碱性溶液显影，并且可以配制成一包装制剂。这种光固化性和热固性树脂组合物和通过其使用制备的光敏干燥膜可用作各种抗蚀剂材料和电绝缘材料，特别是用于印刷电路板的阻焊剂，用于积聚多层印刷电路板的层间绝缘材料，等等。

4. 发明授权

US06867282B2 Photocurable and thermosetting resin composition 有权
标题翻译：光固化和热固性树脂组合物
公开(公告)号：US06867282B2
公开(公告)日：2005-03-15
申请号：US10452516
申请日：2003-06-03
申请人： Tadatomi Nishikubo , Atsushi Kameyama , Masatoshi Kusama
发明人： Tadatomi Nishikubo , Atsushi Kameyama , Masatoshi Kusama
IPC分类号： C08F2/44 , C08F2/50 , C08F20/28 , C08F283/10 , C08F290/02 , C08F290/06 , C08G65/18 , C08G65/332 , C08L63/00 , C08L71/00 , C08L101/00 , G03F7/027 , G03F7/032 , G03F7/038 , C08G2/06
CPC分类号： G03F7/038 , C08F20/28 , C08F283/10 , C08F290/06 , C08F290/061 , C08G65/18 , C08G65/332 , C08L63/00 , C08L71/00 , G03F7/027 , C08L2666/22
摘要： The photocurable and thermosetting resin composition of the present invention includes (A) an actinic energy ray-curable resin having at least one structure represented by the following general formula (1), (B) a photopolymerization initiator, (C) a diluent, and (D) a thermosetting component. In the general formula (1), R1 represents a hydrogen atom or an alkyl group of 1 to 6 carbon atoms, R2, R3 and R4 independently represent a hydrogen atom, an alkyl group of 1 to 6 carbon atoms, an aryl group, an aralkyl group, a cyano group, a fluorine atom, or a furyl group, and X represents a polybasic acid anhydride residue.
摘要翻译：本发明的光固化性和热固性树脂组合物包含（A）具有以下通式（1）表示的至少一种结构的光化学能量射线固化性树脂，（B）光聚合引发剂，（C）稀释剂，和（D）热固性组分。在通式（1）中，R 1表示氢原子或1至6个碳原子的烷基，R 2，R 3和R 4独立地表示氢原子，碳原子数1〜6的烷基，芳基，芳烷基，氰基，氟原子或呋喃基，X表示多元酸酐残基。

5. 发明授权

US06861500B2 Resins curable with actinic energy ray, process for the production thereof, and photocurable and thermosetting resin composition 有权
标题翻译：用光化能射线固化的树脂，其制备方法和光固化性和热固性树脂组合物
公开(公告)号：US06861500B2
公开(公告)日：2005-03-01
申请号：US10256021
申请日：2002-09-27
申请人： Tadatomi Nishikubo , Atsushi Kameyama , Masaki Sasaki , Masatoshi Kusama
发明人： Tadatomi Nishikubo , Atsushi Kameyama , Masaki Sasaki , Masatoshi Kusama
IPC分类号： C07C69/54 , C07C69/593 , C07C69/75 , C08F283/10 , C08F290/06 , C08F299/02 , C08G65/18 , G03F7/027 , G03F7/032 , G03F7/033 , G03F7/038 , H05K3/28 , C08G65/02
CPC分类号： C08F299/026 , G03F7/027 , G03F7/032 , G03F7/033 , G03F7/038 , G03F7/0388 , H05K3/287 , Y10T428/31515 , Y10T428/31522 , Y10T428/31855
摘要： A photocurable and thermosetting resin composition comprises (A) an actinic energy ray-curable resin having at least one structure represented by the following general formula (1), (B) a polymerization initiator, (C) a diluent, and (D) a polyfunctional oxetane compound. The actinic energy ray-curable resin mentioned above can be produced by causing the reaction of (a) a polyfunctional oxetane compound with (b) an unsaturated monocarboxylic acid and the subsequent reaction of (c) a polybasic acid anhydride with a primary hydroxyl group of the resultant modified oxetane resin (a′). wherein R1 represents a hydrogen atom or an alkyl group of 1 to 6 carbon atoms, R2, R3 and R4 independently represent a hydrogen atom, an alkyl group of 1 to 6 carbon atoms, an aryl group, an aralkyl group, a cyano group, a fluorine atom, or a furyl group, and X represents a polybasic acid anhydride residue.
摘要翻译：光固化性和热固性树脂组合物包含（A）具有由以下通式（1）表示的至少一种结构的光化能量射线固化性树脂，（B）聚合引发剂，（C）稀释剂和（D）多官能氧杂环丁烷化合物。可以通过使（a）多官能氧杂环丁烷化合物与（b）不饱和一元羧酸的反应和随后的（c）多元酸酐与伯羟基的反应来制备上述光化学能量射线固化树脂得到的改性氧杂环丁烷树脂（a'），其中R 1表示氢原子或1〜6个碳原子的烷基，R 2，R 3和R 4独立地表示氢原子， 1〜6个碳原子的烷基，芳基，芳烷基，氰基，氟原子或呋喃基，X表示多元酸酐残基。

6. 发明授权

US5623023A Curable compositions which release imidazole upon irradiation 失效
标题翻译：照射时释放咪唑的可固化组合物
公开(公告)号：US5623023A
公开(公告)日：1997-04-22
申请号：US650981
申请日：1996-05-21
申请人： Tadatomi Nishikubo
发明人： Tadatomi Nishikubo
IPC分类号： C08G59/50 , C08G59/68 , C08G59/44 , C08G59/54
CPC分类号： C08G59/5073 , C08G59/686
摘要： Disclosed is a curable composition comprising (A) an imidazole derivative represented by the following general formula (1), which is capable of generating free imidazole by exposure to light, and (B) a polyfunctional epoxy compound: ##STR1## wherein R represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an aralkyl group, a nitro group, a cyano group, an alkoxyl group, a phenoxy group, or an aromatic ring residue capable of forming a condensed ring in combination with a benzene ring. The composition may further incorporate therein at least one compound selected from the group consisting of polyfunctional phenol compounds, polyfunctional carboxylic acids, acid anhydrides, and amine compounds.
摘要翻译：公开了一种可固化组合物，其包含（A）能够通过曝光产生游离咪唑的下列通式（1）表示的咪唑衍生物，和（B）多官能环氧化合物：其中 R表示氢原子，卤素原子，烷基，芳基，芳烷基，硝基，氰基，烷氧基，苯氧基或能够形成稠环的芳香环残基与苯环组合。该组合物还可以含有至少一种选自多官能酚化合物，多官能羧酸，酸酐和胺化合物的化合物。

7. 发明授权

US3980483A Photocurable composition 失效
标题翻译：可光固化组合物
公开(公告)号：US3980483A
公开(公告)日：1976-09-14
申请号：US575426
申请日：1975-05-07
申请人： Tadatomi Nishikubo , Shinzi Ugai , Taro Ichijo , Masahiko Kishida
发明人： Tadatomi Nishikubo , Shinzi Ugai , Taro Ichijo , Masahiko Kishida
IPC分类号： G03F7/031 , G03F7/032 , G03C1/58 , C08F8/00
CPC分类号： G03F7/031 , G03F7/032 , Y10S430/124 , Y10S430/126 , Y10S525/922
摘要： A photocurable composition comprising the reaction product of the addition compound obtained from an epoxy resin and a photopolymerizable .alpha..beta.-unsaturated carboxylic acid, and a dibasic acid anhydride; a photopolymerizable monomer; and a photopolymerization initiator. The composition is used for making a relief image.
摘要翻译：一种可光固化组合物，其包含由环氧树脂获得的加成化合物与可光聚合的αβ-不饱和羧酸和二元酸酐的反应产物; 光聚合单体; 和光聚合引发剂。该组合物用于制作浮雕图像。

8. 发明授权

US07705189B2 Calixarene compound, process for producing the same, intermediate therefor, and composition thereof 有权
标题翻译：杯芳烃化合物，其制备方法，其中间体及其组合物
公开(公告)号：US07705189B2
公开(公告)日：2010-04-27
申请号：US10588313
申请日：2005-02-04
申请人： Tadatomi Nishikubo , Hiroto Kudou , Kouji Mitani
发明人： Tadatomi Nishikubo , Hiroto Kudou , Kouji Mitani
IPC分类号： C07C43/20 , C07C39/12
CPC分类号： G03F7/004 , C07C13/70 , C07C39/16 , C07C39/17 , C07C43/215 , C07C43/23 , C07C69/54 , C07C2603/92
摘要： A novel calixarene compound, a method for manufacturing the same, an intermediate of the calixarene compound, and a composition comprising the same are provided. The calixarene compound is expected to be useful as an inclusion compound and, if functional groups are introduced, can be used for a curable composition and a photoresist and as an inclusion compound. The calixarene compound is shown by following formula (1): wherein R1 to R6 individually represent a substituted or unsubstituted alkylene group having 1 to 8 carbon atoms; X1 to X12 individually represent a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 10 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 10 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 10 carbon atoms, a substituted or unsubstituted alkoxyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted phenoxy group; Z1 to Z24 individually represent a hydrogen atom, a group having a polymerizable functional group, a group having an alkali-soluble group, or a substituted alkyl group having an alkyl chain with a 1-8 carbon atom content, or two adjacent Zs in combination represent a substituted or unsubstituted alkylene group having 1 to 8 carbon atoms; q1 to q12 individually represent an integer of 0 or 1.
摘要翻译：提供了一种新的杯芳烃化合物，其制备方法，杯芳烃化合物的中间体和包含其的组合物。预期杯芳烃化合物可用作包合物，并且如果引入官能团，则可以将其用作可固化组合物和光致抗蚀剂以及作为包合物。杯芳烃化合物由下式（1）表示：其中R 1至R 6各自表示取代或未取代的具有1至8个碳原子的亚烷基; X1至X12各自表示取代或未取代的碳原子数1〜10的烷基，取代或未取代的碳原子数2〜10的烯基，取代或未取代的碳原子数2〜10的炔基，取代或未取代的芳烷基具有7〜10个碳原子，取代或未取代的碳原子数1〜10的烷氧基或取代或未取代的苯氧基; Z1至Z24各自表示氢原子，具有可聚合官能团的基团，具有碱溶性基团的基团或具有1-8个碳原子含量的烷基链的取代的烷基，或两个相邻的Z组合表示取代或未取代的碳原子数1〜8的亚烷基。 q1〜q12分别表示0或1的整数。

9. 发明授权

US07238763B2 Unsaturated monocarboxylic ester compounds 有权
标题翻译：不饱和单羧酸酯化合物
公开(公告)号：US07238763B2
公开(公告)日：2007-07-03
申请号：US11236546
申请日：2005-09-28
申请人： Tadatomi Nishikubo , Atsushi Kameyama , Masaki Sasaki , Masatoshi Kusama
发明人： Tadatomi Nishikubo , Atsushi Kameyama , Masaki Sasaki , Masatoshi Kusama
IPC分类号： C08F20/10 , C07C69/52
CPC分类号： C08F20/26 , C07C69/533 , C07C69/54 , C08F20/28
摘要： An unsaturated monocarboxylic ester compound has at least two structures represented by the following general formula (1): wherein R1 represents a hydrogen atom or an alkyl group of 1 to 6 carbon atoms, and R2, R3 and R4 independently represent a hydrogen atom, an alkyl group of 1 to 6 carbon atoms, an aryl group, an aralkyl group, a cyano group, a fluorine atom, or a furyl group. A curable composition comprises (A) the unsaturated monocarboxylic ester compound having two or more structures represented by the general formula (1) mentioned above, (B) a polymerization initiator, and optionally (C) a diluent.
摘要翻译：不饱和单羧酸酯化合物具有由以下通式（1）表示的至少两种结构：其中R 1表示氢原子或1至6个碳原子的烷基，R“ 2，R 3和R 4独立地表示氢原子，1至6个碳原子的烷基，芳基，芳烷基，氰基，氟原子或呋喃基。可固化组合物包含（A）具有两个或更多个由上述通式（1）表示的结构的不饱和单羧酸酯化合物，（B）聚合引发剂和任选的（C）稀释剂。

10. 发明申请

US20050158661A1 Resins curable with actinic energy ray, process for the production thereof, and photocurable and thermosetting resin composition 失效
标题翻译：用光化能射线固化的树脂，其制备方法和光固化性和热固性树脂组合物
公开(公告)号：US20050158661A1
公开(公告)日：2005-07-21
申请号：US11010317
申请日：2004-12-14
申请人： Tadatomi Nishikubo , Atsushi Kameyama
发明人： Tadatomi Nishikubo , Atsushi Kameyama
IPC分类号： C07C69/54 , C07C69/593 , C07C69/75 , C08F283/10 , C08F290/06 , C08F299/02 , C08G65/18 , G03F7/027 , G03F7/032 , G03F7/033 , G03F7/038 , H05K3/28 , G03C1/73
CPC分类号： C08F299/026 , G03F7/027 , G03F7/032 , G03F7/033 , G03F7/038 , G03F7/0388 , H05K3/287 , Y10T428/31515 , Y10T428/31522 , Y10T428/31855
摘要： A photocurable and thermosetting resin composition comprises (A) an actinic energy ray-curable resin having at least one structure represented by the following general formula (1), (B) a-polymerization initiator, (C) a diluent, and (D) a polyfunctional oxetane compound. The actinic energy ray-curable resin mentioned above can be produced by causing the reaction of (a) a polyfunctional oxetane compound with (b) an unsaturated monocarboxylic acid and the subsequent reaction of (c) a polybasic acid anhydride with a primary hydroxyl group of the resultant modified oxetane resin (a′). wherein R1 represents a hydrogen atom or an alkyl group of 1 to 6 carbon atoms, R2, R3 and R4 independently represent a hydrogen atom, an alkyl group of 1 to 6 carbon atoms, an aryl group, an aralkyl group, a cyano group, a fluorine atom, or a furyl group, and X represents a polybasic acid anhydride residue.
摘要翻译：光固化性和热固性树脂组合物包含（A）具有由以下通式（1）表示的至少一种结构的光化能量射线固化性树脂，（B）α-聚合引发剂，（C）稀释剂和（D）多官能氧杂环丁烷化合物。可以通过使（a）多官能氧杂环丁烷化合物与（b）不饱和一元羧酸的反应和随后的（c）多元酸酐与伯羟基的反应来制备上述光化学能量射线固化树脂得到的改性氧杂环丁烷树脂（a'）。其中R 1表示氢原子或1至6个碳原子的烷基，R 2，R 3和R 4 独立地表示氢原子，1〜6个碳原子的烷基，芳基，芳烷基，氰基，氟原子或呋喃基，X表示多元酸酐残基。

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