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1. 发明申请

US20100298491A1 ADAMANTANE DERIVATIVE, RESIN COMPOSITION CONTAINING SAME, AND OPTOELECTRONIC MEMBER AND SEALING AGENT FOR ELECTRONIC CIRCUIT USING THOSE 有权
标题翻译：亚胺衍生物，含有它们的树脂组合物，以及使用这些物质的电子电路的光电子元件和密封剂
公开(公告)号：US20100298491A1
公开(公告)日：2010-11-25
申请号：US12160534
申请日：2007-01-19
申请人： Yasunari Okada , Hajime Ito , Hideki Yamane , Nobuaki Matsumoto
发明人： Yasunari Okada , Hajime Ito , Hideki Yamane , Nobuaki Matsumoto
IPC分类号： C08L63/00 , C07D303/12 , C07C39/10
CPC分类号： C07C39/17 , C07C37/16 , C07C37/20 , C07C2603/74 , C07D301/28 , C07D303/30 , C08G59/24 , C08G59/4215 , C08G59/4223 , C08G59/621 , G03F7/038 , Y10T428/1073 , Y10T428/31511
摘要： Disclosed is an adamantane derivative which provides a cured product excellent in optical characteristics such as transparency and light resistance, long-term heat resistance, electrical characteristics such as and dielectric constant, and low water absorption. Also disclosed are a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent. Specifically disclosed are an adamantane derivative represented by the formula (I-1) below, a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate, all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent.
摘要翻译：公开了一种金刚烷衍生物，其提供了透光性，耐光性，长期耐热性，电特性如介电常数，低吸水性等光学特性优异的固化物。还公开了含有金刚烷衍生物，电子电路用密封剂，光电子元件，半导体器件和覆铜层压板的树脂组合物，其全部使用该树脂组合物，以及含有上述金刚烷衍生物的辐射敏感性树脂组合物作为交联剂。具体公开了以下式（I-1）表示的金刚烷衍生物，含有金刚烷衍生物的树脂组合物，电子电路用密封剂，光电子部件，半导体装置和覆铜层压板，全部使用树脂组合物，以及含有上述金刚烷衍生物作为交联剂的辐射敏感性树脂组合物。

2. 发明申请

US20100048757A1 ADAMANTANE DERIVATIVE, PROCESS FOR PRODUCTION THEREOF, RESIN COMPOSITION, AND CURED PRODUCT OF THE RESIN COMPOSITION 审中-公开
标题翻译：衍生物衍生物，其生产方法，树脂组合物和树脂组合物的固化产物
公开(公告)号：US20100048757A1
公开(公告)日：2010-02-25
申请号：US12447308
申请日：2007-10-24
申请人： Yasunari Okada , Hideki Yamane , Katsuki Ito , Nobuaki Matsumoto
发明人： Yasunari Okada , Hideki Yamane , Katsuki Ito , Nobuaki Matsumoto
IPC分类号： C08F2/46 , C07C69/54 , C08L31/02
CPC分类号： G03F7/027 , C07C67/08 , C07C69/54 , C07C2603/74 , C08F20/20 , C08F20/28
摘要： Disclosed herein is an adamantane derivative represented by the following general formula (I): (wherein R represents a hydrogen atom, a fluorine atom, a methyl group or a trifluoromethyl group; Y represents a hydrogen atom, a hydroxyl group, ═O formed by two Ys together, a carboxyl group, or a hydrocarbon group having 1 to 20 carbon atoms or a cyclic hydrocarbon group having 3 to 20 carbon atoms; m is 13 and n is 3, or m is 12 and n is 4; and p is an integer of one or more), a production method thereof, a resin composition containing the adamantane derivative, and a cured product thereof. The present invention provides a cured product advantageous as various coating agents, a microlens, a film condenser, a colored composition for a liquid crystal color filter, a pattern organizer formed in nanoimprinting, and the like, having transparency, heat resistance, good mechanical properties, low volume shrinkage, and low coefficient of linear expansion, as well as liquid adamantyl group-containing (meth)acrylates to produce the cured product, the production method thereof, and the resin composition.
摘要翻译：本文公开了由以下通式（I）表示的金刚烷衍生物：其中R表示氢原子，氟原子，甲基或三氟甲基; Y表示氢原子，羟基，由式两个Y一起，一个羧基或一个碳原子数1〜20的烃基或碳原子数3〜20的环状烃基，m为13，n为3，m为12，n为4，p为 1个以上的整数），其制造方法，含有金刚烷衍生物的树脂组合物及其固化物。本发明提供了作为各种涂布剂，微透镜，薄膜冷凝器，液晶滤色器着色组合物，纳米压印等形成的图案组织器等有利的固化产物，具有透明性，耐热性，良好的机械性能，低体积收缩率和低的线性膨胀系数，以及含有金刚烷基的（甲基）丙烯酸酯以制备固化产物，其制备方法和树脂组合物。

3. 发明申请

US20090148706A1 OPTICAL WAVEGUIDE HAVING PERFLUOROADAMANTANE STRUCTURE 审中-公开
标题翻译：具有全氟化物结构的光波导
公开(公告)号：US20090148706A1
公开(公告)日：2009-06-11
申请号：US12296556
申请日：2007-04-27
申请人： Kyoji Kitamura , Masaki Nakamura , Yasunari Okada
发明人： Kyoji Kitamura , Masaki Nakamura , Yasunari Okada
IPC分类号： B32B27/28
CPC分类号： G02B6/1221 , C08F220/24 , C08F222/1006 , Y10T428/31544
摘要： The present invention provides an optical waveguide having a low temperature dependence of the difference in refractive index between a core resin and a clad resin and exhibiting excellent optical properties in all the operating temperatures.An optical waveguide of the present invention includes cured resin products each containing, as constituent components, first fluorine-containing monomers each having a perfluoroadamantane structure. With this arrangement, it is possible to obtain an optical waveguide that is excellent in both optical properties and temperature dependence of difference in refractive index between a core resin and a clad resin.
摘要翻译：本发明提供了一种光核心树脂和包覆树脂之间的折射率差的温度依赖性低的光波导，并且在所有工作温度下表现出优异的光学特性。本发明的光波导包括固化树脂产物，其各自含有具有全氟金刚烷结构的第一含氟单体作为构成成分。通过这种布置，可以获得在芯树脂和包层树脂之间的光学性质和折射率差的温度依赖性优异的光波导。

4. 发明申请

US20090099326A1 FLUORINE-CONTAINING ADAMANTANE DERIVATIVE, FLUORINE-CONTAINING ADAMANTANE DERIVATIVE HAVING POLYMERIZABLE GROUP, RESIN COMPOSITION CONTAINING THE SAME, AND ANTIREFLECTION FILM 审中-公开
标题翻译：含有含氟的衍生物，含有含氟聚氨酯衍生物，含有聚氨酯的组合物，含有它们的树脂组合物和抗反射膜
公开(公告)号：US20090099326A1
公开(公告)日：2009-04-16
申请号：US12298836
申请日：2007-04-20
申请人： Yasunari Okada , Hideki Yamane , Hajime Ito , Nobuaki Matsumoto
发明人： Yasunari Okada , Hideki Yamane , Hajime Ito , Nobuaki Matsumoto
IPC分类号： C08F214/18 , C07C35/44 , C07C69/753 , C08G65/22 , C07D303/18
CPC分类号： C07C31/44 , C07C69/653 , C07C2603/74 , C07D301/24 , C07D305/06 , C08F220/24 , C08F222/1006
摘要： To provide a polymerizable group-containing and fluorine-containing adamantane derivative capable of affording a cured product having good heat resistance, good mechanical properties such as mar resistance and a low refractive index, a resin composition containing such a polymerizable group-containing adamantane derivative, and a fluorine-containing adamantane derivative which is useful as a reaction intermediate used for the production of the polymerizable group-containing and fluorine-containing adamantane derivative.Specifically provided are a fluorine-containing adamantane derivative represented by the general formula (I) below, a polymerizable group-containing and fluorine-containing adamantane derivative represented by the general formula (II) below, and a resin composition containing such a polymerizable group-containing and fluorine-containing adamantane derivative. In the formula, R1 and R2 are each a hydrogen atom, for example, n is an integer of 0 or more, X1 is a polymerizable group represented by the formula (III-a), for example, Y is a hydrogen atom, for example, s and t are each an integer of 1 to 15, and u is an integer of 0 to 14, with the proviso that s+t+u=16.
摘要翻译：为了提供能够提供具有良好耐热性，良好机械性能如耐磨性和低折射率的固化产物的含可聚合基团的含氟金刚烷衍生物，含有这种含聚合基团的金刚烷衍生物的树脂组合物，以及可用作制备含聚合基团和含氟金刚烷衍生物的反应中间体的含氟金刚烷衍生物。具体地提供由以下通式（I）表示的含氟金刚烷衍生物，下述通式（II）表示的可聚合基团的含氟金刚烷衍生物和含有这样的聚合性基团的树脂组合物，含氟和金属金刚烷衍生物。在该式中，R 1和R 2各自为氢原子，例如n为0以上的整数，X 1为式（III-a）表示的聚合性基团，例如，Y为氢原子，作为例如，s和t分别为1〜15的整数，u为0〜14的整数，条件是s + t + u = 16。

5. 发明申请

US20070129532A1 Adamantane derivatives and process for producing the same 有权
标题翻译：金刚烷衍生物及其制备方法
公开(公告)号：US20070129532A1
公开(公告)日：2007-06-07
申请号：US10588080
申请日：2005-02-01
申请人： Naoyoshi Hatakeyama , Shinji Tanaka , Hidetoshi Ono , Yasunari Okada
发明人： Naoyoshi Hatakeyama , Shinji Tanaka , Hidetoshi Ono , Yasunari Okada
IPC分类号： C08G69/14
CPC分类号： C07C69/54 , C07C67/29 , C07C303/28 , C07C309/66 , C07C2603/74
摘要： The present invention provides an adamantane derivative (I) having a structure represented by the general formula (I); an adamantane derivative (II) having a structure represented by the general formula (II); and a process for producing those adamantane derivatives. An alcohol form of an adamantane compound is reacted with a sulfonyl compound to obtain the adamantane derivative (II), which is then reacted with an alcohol to obtain the adamantane derivative (I). The adamantane derivative (I) and adamantane derivative (II) each having the structure represented by the general formula (I) and general formula (II), respectively, is a novel adamantyl(meth)acrylate compound and useful as a monomer for functional resins such as a photosensitive resin in the field of photolithography.
摘要翻译：本发明提供具有由通式（I）表示的结构的金刚烷衍生物（I）; 具有由通式（II）表示的结构的金刚烷衍生物（II）; 以及生产这些金刚烷衍生物的方法。将金刚烷化合物的醇形式与磺酰基化合物反应，得到金刚烷衍生物（II），然后与醇反应得到金刚烷衍生物（I）。分别具有由通式（I）和通式（II）表示的结构的金刚烷衍生物（I）和金刚烷衍生物（II）分别是新型金属（甲基）丙烯酸酯金属化合物，并且可用作功能性树脂的单体例如光刻领域的感光性树脂。

6. 发明申请

US20100274043A1 ADAMANTYL GROUP-CONTAINING EPOXY-MODIFIED (METH)ACRYLATE AND RESIN COMPOSITION CONTAINING THE SAME 有权
标题翻译：含有铵基团的环氧改性（甲基）丙烯酸酯和含有它的树脂组合物
公开(公告)号：US20100274043A1
公开(公告)日：2010-10-28
申请号：US12831763
申请日：2010-07-07
申请人： Yasunari OKADA , Hajime ITO , Hideki YAMANE , Nobuaki MATSUMOTO
发明人： Yasunari OKADA , Hajime ITO , Hideki YAMANE , Nobuaki MATSUMOTO
IPC分类号： C07C69/732
CPC分类号： C08F290/06 , C08F222/1006 , C08F290/061 , C08F290/064 , C08G59/186
摘要： The present invention provides an adamantyl group containing epoxy-modified (meth)acrylate and a resin composition containing it which are imparted by transparency, optical characteristics such as (durable) light resistance and the like, heat-resistance, and good mechanical properties.For example, they are an adamantyl group containing epoxy-modified (meth)acrylate having the following general formula (I) and a composition containing it. In the formula, R1 represents a hydrogen atom or a methyl group, and R2 represents a halogen atom or an aliphatic hydrocarbon group which may contain a hetero atom. Plural R2 may be the same or different, and m represents an integer of 0 to 4 and n represents an integer of 0 or more. A:
摘要翻译：本发明提供含有环氧改性（甲基）丙烯酸金刚烷基和含有它的树脂组合物，它们由透明性，耐光性等光学特性赋予耐热性和良好的机械性能。例如，它们是含有具有以下通式（I）的环氧改性（甲基）丙烯酸酯和含有它的组合物的金刚烷基。在该式中，R 1表示氢原子或甲基，R 2表示卤素原子或可含有杂原子的脂肪族烃基。多个R2可以相同或不同，m表示0〜4的整数，n表示0以上的整数。 A：

7. 发明申请

US20100130712A1 ADAMANTANE DERIVATIVE, RESIN COMPOSITION USING THE SAME, AND RESIN CURED PRODUCT 审中-公开
标题翻译： ADAMANTANE衍生物，使用该树脂的树脂组合物和树脂固化产品
公开(公告)号：US20100130712A1
公开(公告)日：2010-05-27
申请号：US12594254
申请日：2008-03-31
申请人： Katsuki Ito , Yasunari Okada , Hideki Yamane , Shinobu Yamao
发明人： Katsuki Ito , Yasunari Okada , Hideki Yamane , Shinobu Yamao
IPC分类号： C08F124/00 , C07D205/04
CPC分类号： C07D303/12 , C07D305/06 , C08F220/28 , C08F220/32 , C08G65/105 , C08G65/18 , C08L63/00
摘要： Provided is a cured resin of an adamantane derivative having a specific structure, which has excellent optical properties such as transparency and (long-term) light stability, long-term heat resistance, dielectric constant, and mechanical properties, and which can be utilized suitably in the field of electronic and optical materials.
摘要翻译：提供具有特定结构的金刚烷衍生物的固化树脂，其具有优异的光学性能如透明度和（长期）光稳定性，长期耐热性，介电常数和机械性能，并且可以适当地使用在电子和光学材料领域。

8. 发明申请

US20090062481A1 ADAMANTANE DERIVATIVE, COMPOSITION COMPRISING THE DERIVATIVE, AND OPTICAL AND ELECTRONIC MEMBER USING THE COMPOSITION 失效
标题翻译：衍生物，包含衍生物的组合物，以及使用组合物的光学和电子成员
公开(公告)号：US20090062481A1
公开(公告)日：2009-03-05
申请号：US12279772
申请日：2007-02-01
申请人： Hajime Ito , Yasunari Okada , Hideki Yamane , Nobuaki Matsumoto
发明人： Hajime Ito , Yasunari Okada , Hideki Yamane , Nobuaki Matsumoto
IPC分类号： C08L63/00 , C07D305/06 , C07D303/12
CPC分类号： C07D303/30 , C07D305/06 , C08G59/24 , C08G59/42
摘要： To provide an adamantane derivative, a compound having an adamantane skeleton, compositions containing them that can provide a cured product having excellent optical properties such as transparency and light resistance, long-term heat resistance and electric characteristics such as dielectric permittivity, and optical electronic members using the compositions.An adamantane derivative represented by the general formula (I), a compound with an adamantane skeleton represented by the general formula (VII) or (VIII), compositions containing them, and optical electronic members using the resin compositions. In the formulas, W represents, for example, a hydrogen atom, X represents, for example, a group represented by the general formula (II), Y represents a group represented by the formula (V) or (VI), R1 represents a methyl group or an ethyl group, R2 represents a C1 to C10 hydrocarbon group which may contain O or S, m is an integer of 2 to 4, k is an integer of 0 to (16−m) and p and q are each an integer of 1 to 5.
摘要翻译：为了提供金刚烷衍生物，具有金刚烷骨架的化合物，含有它们的组合物可以提供具有优异的光学性质如透明性和耐光性，长期耐热性和电特性如介电常数的固化产物和光学电子部件使用组合物。由通式（I）表示的金刚烷衍生物，具有由通式（VII）或（VIII）表示的金刚烷骨架的化合物，含有它们的组合物和使用该树脂组合物的光学电子部件。在该式中，W表示例如氢原子，X表示例如由通式（II）表示的基团，Y表示由式（V）或（VI）表示的基团，R1表示甲基或乙基，R2表示可以含有O或S的C1〜C10烃基，m为2〜4的整数，k为0〜（16-m）的整数，p和q各自为 1〜5的整数。

9. 发明授权

US07790917B2 Adamantyl group-containing epoxy-modified (meth)acrylate and resin composition containing the same 有权
标题翻译：含有金刚烷基的环氧改性（甲基）丙烯酸酯和含有其的树脂组合物
公开(公告)号：US07790917B2
公开(公告)日：2010-09-07
申请号：US12298260
申请日：2007-04-24
申请人： Yasunari Okada , Hajime Ito , Hideki Yamane , Nobuaki Matsumoto
发明人： Yasunari Okada , Hajime Ito , Hideki Yamane , Nobuaki Matsumoto
IPC分类号： C07C69/34 , C08D303/12
CPC分类号： C08F290/06 , C08F222/1006 , C08F290/061 , C08F290/064 , C08G59/186
摘要： The present invention provides an adamantyl group containing epoxy-modified (meth)acrylate and a resin composition containing it which are imparted by transparency, optical characteristics such as (durable) light resistance and the like, heat-resistance, and good mechanical properties.For example, they are an adamantyl group containing epoxy-modified (meth)acrylate having the following general formula (I) and a composition containing it. In the formula, R1 represents a hydrogen atom or a methyl group, and R2 represents a halogen atom or an aliphatic hydrocarbon group which may contain a hetero atom. Plural R2 may be the same or different, and m represents an integer of 0 to 4 and n represents an integer of 0 or more.
摘要翻译：本发明提供含有环氧改性（甲基）丙烯酸金刚烷基和含有它的树脂组合物，它们由透明性，耐光性等光学特性赋予耐热性和良好的机械性能。例如，它们是含有具有以下通式（I）的环氧改性（甲基）丙烯酸酯和含有它的组合物的金刚烷基。在该式中，R 1表示氢原子或甲基，R 2表示卤素原子或可含有杂原子的脂肪族烃基。多个R2可以相同或不同，m表示0〜4的整数，n表示0以上的整数。

10. 发明申请

US20100093947A1 ADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME, RESIN COMPOSITION CONTAINING THE ADAMANTANE DERIVATIVE AND USE THEREOF 有权
标题翻译：亚胺衍生物，其制备方法，含有衍生物的树脂组合物及其用途
公开(公告)号：US20100093947A1
公开(公告)日：2010-04-15
申请号：US12598041
申请日：2008-04-28
申请人： Yasunari Okada , Hidetoshi Ono , Katsuki Ito
发明人： Yasunari Okada , Hidetoshi Ono , Katsuki Ito
IPC分类号： C08L63/00 , C08G63/06 , C08L67/00
CPC分类号： C07D303/16 , C08G59/24 , C08G59/3218 , C08G59/42 , C08L63/00 , G03F7/038
摘要： Provided are: an adamantane derivative represented by the following general formula (I) giving a cured product excellent in optical characteristics such as transparency and light resistance, durabilities such as heat resistance, and electrical characteristics such as dielectric constant; a method of producing the adamantane derivative; a resin composition containing the adamantane derivative and an epoxy resin curing agent; and a sealing agent for an optical semiconductor using the resin composition: where: Y represents a group selected from a hydrocarbon group, a hydroxyl group, a carboxyl group, and an ═O group formed by two Y's being combined together; Z represents a cyclic ether group; n represents an integer of 0 or more; and p represents an integer of 2 to 4 and q represents an integer of 0 to 14, while satisfying 2≦p+q≦16.
摘要翻译：提供：由以下通式（I）表示的金刚烷衍生物，其得到透明性和耐光性，耐热性等耐久性，介电常数等光学特性优异的固化物。生产金刚烷衍生物的方法; 含有金刚烷衍生物和环氧树脂固化剂的树脂组合物; 以及使用该树脂组合物的光学半导体用密封剂，其中：Y表示选自由两个Y组合在一起形成的烃基，羟基，羧基和≡O基的基团; Z表示环状醚基; n表示0以上的整数， p表示2〜4的整数，q表示0〜14的整数，满足2＆nlE; p + q＆nlE; 16。

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