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1. 发明授权

US3796707A Dibenzofuryl-benzoxazolyl-styrenes 失效
标题翻译：二苯并呋喃并苯并咪唑 - 苯乙烯
公开(公告)号：US3796707A
公开(公告)日：1974-03-12
申请号：US3796707D
申请日：1972-09-14
申请人： CIBA GEIGY AG
发明人： SIEGRIST A , GARMATTER J
IPC分类号： C07D307/91 , C07D5/44
CPC分类号： C07D307/91 , Y10S8/922
摘要： THE INVENTION RELATES TO NEW DIBENZOFURAN COMPOUNDS, WHICH ARE SUBSTITUTED IN POSITION 2 OR 3 WITH A BENZOXAZOLYL-STYRYL RESIDUE AND WHEREIN THE BENZOXAZOLYL MOIETY MAY BE FURTHER SUBTITUTED WITH NON-CHROMOPHORIC SUBSTITUENTS. THE COMPOUNDS ARE USEFUL AS FLUORESCENT WHITENING AGENTS ESPECIALLY FOR SPINNING MASSES OF SYNTHETIC ORGANIC MATERIALS.

2. 发明授权

US3781278A Novel p-phenylstilbyl heterocyclic and naphthyl-vinylphenylene heterocyclic optical brighteners 失效
标题翻译：新型对苯二甲酸异戊酯和萘乙烯基苯乙烯杂环光亮剂
公开(公告)号：US3781278A
公开(公告)日：1973-12-25
申请号：US3781278D
申请日：1970-08-28
申请人： CIBA GEIGY AG
发明人： SIEGRIST A , LIECHTI P , MAEDER E , WEBER K , GUGLIELMETTI L , MEYER H
IPC分类号： C07D213/16 , C07D215/04 , C07D231/12 , C07D233/56 , C07D235/18 , C07D239/26 , C07D241/42 , C07D249/06 , C07D249/08 , C07D249/20 , C07D249/22 , C07D249/24 , C07D251/24 , C07D253/065 , C07D263/00 , C07D263/56 , C07D263/57 , C07D271/06 , C07D271/10 , C07D271/107 , C07D277/66 , C07D285/12 , C09B23/00
CPC分类号： C07D213/16 , C07D215/04 , C07D235/18 , C07D239/26 , C07D241/42 , C07D249/06 , C07D249/08 , C07D249/20 , C07D249/22 , C07D249/24 , C07D251/24 , C07D253/065 , C07D263/00 , C07D263/57 , C07D271/06 , C07D271/107 , C07D277/66 , C07D285/12
摘要： THE PRESENT INVENTION RELATES TO NEW COMPOUNDS OF THE FORMULA

(4-(DELTA-),B-PHENYL)-CH=CH-GAMMA

IN WHICH B REPRESENTS A HYDROGEN ATOM OR A METHYL GROUP, $ REPRESENTS A DIPHENYL OR 1-NAPHTHYL OR 2-NAPHTHYL RESIDUE AND $ DENOTES A RESIDUE OF THE SERIES
WHERE (I) D REPRESENTS HYDROGEN OR PHENYL, E AND F REPRESENT PHENYL, STILLBENYL, P-PHENYLSTILLBENYL OR BENZOSTILBENYL, AND FURTHERMORE Y2 REPRESENTS A BRIDGE MEMBER -O-, -NH- OR -N(ALKYL)-, WHERE (II) U5 DENOTES HYDROGEN, A STRYRL RESIDUE OR A P-PHENYLSTYRYL RESIDUE, AND WHERE (III) TERMINAL PHENYL OR NAPHTHYL RESIDUES MAY CONTAIN ALKYL, HALOGEN OR ALKOXY GROUPS. THESE NEW COMPOUNDS REPRESENT VALUABLE OPTICAL BRIGHTENING AGENTS.

-C
2-(4-U5-PHENYL),4,5-DI(C6H5-)IMIDAZOL-1-YL, AND

4-F,5-E-4H-1,2,4-TRIAZOL-3-YL

2H-BENZOTRIAZOL-2-YL, 2H-NAPHTHO(1,2-D)TRIAZOL-2-YL,

3. 发明授权

US3725395A Heterocyclic compounds containing ethylene double bonds and process for their manufacture 失效
公开(公告)号：US3725395A
公开(公告)日：1973-04-03
申请号：US3725395D
申请日：1970-08-28
申请人： CIBA GEIGY AG
发明人： SIEGRIST A , LIECHTI P , MEYER H , WEBER K , MAEDER E , GUGLIELMETTI L
IPC分类号： C07D213/16 , C07D215/04 , C07D231/12 , C07D233/56 , C07D235/18 , C07D239/26 , C07D241/42 , C07D249/06 , C07D249/08 , C07D249/20 , C07D249/22 , C07D249/24 , C07D251/24 , C07D253/065 , C07D263/00 , C07D263/56 , C07D263/57 , C07D271/06 , C07D271/10 , C07D271/107 , C07D277/66 , C07D285/12 , C09B23/00
CPC分类号： C07D213/16 , C07D215/04 , C07D235/18 , C07D239/26 , C07D241/42 , C07D249/06 , C07D249/08 , C07D249/20 , C07D249/22 , C07D249/24 , C07D251/24 , C07D253/065 , C07D263/00 , C07D263/57 , C07D271/06 , C07D271/107 , C07D277/66 , C07D285/12
摘要： The present invention comprises a process for the manufacture of heterocyclic compounds containing ethylene double bonds. This process is characterized by reacting a compound of formula

IN WHICH R1 represents a heterocyclic ring system of aromatic character which (a) contains at least one 5-membered or 6membered heterocyclic ring with at least one ring nitrogen atom, (b) is free of hydrogen atoms which (1) are bonded to ring nitrogen atoms and (2) which are replaceable by alkali metal, and (c) is bonded to a ring member of R2 by means of a ring member or has two adjacent ring members in common with two adjacent ring members of R2, in which R2 denotes a carbocyclic ring system of aromatic character which contains 6 ring members, and which optionally is condensed with a further aromatic or hydroaromatic ring system, and in which (b) the methyl group shown in the formula is in a p-position to the bond to R1, is reacted with a Schiff base in the presence of a strongly basic alkali compound, with the reaction medium to be used being dimethylformamide, which is practically anhydrous, except in the case of the use of an alkali hydroxide as the strongly basic alkali compound, in which case the alkali hydroxide may have a water content of up to 25 percent. The products obtained according to this process are valuable fluorescent compounds and useful as optical brighteners.

4. 发明授权

US3793315A Triazole derivatives 失效
公开(公告)号：US3793315A
公开(公告)日：1974-02-19
申请号：US3793315D
申请日：1971-09-30
申请人： CIBA GEIGY AG
发明人： SIEGRIST A
IPC分类号： C07D249/16 , C08K5/3475 , C07D55/02
CPC分类号： C07D249/16 , C08K5/3475
摘要： THE INVENTION DEALS WITH NEW TRIAZOLE DERIVATIVES OF THE FORMULA

2-(4-((4-D-PHENYL)-CH=CH-)PHENYL),7-(RX,RY,RZ-PHENYL)

DIHYDROBENZO(1,2-D:3,4-D'')BISTRIAZOLE

WHEREIN D DENOTES A RADICAL FROM THE GROUP OF BENZOXAZOL-2-YL, 1,3,4 - OXADIAZOL-2-YL. BENZTRIAZOL-2-YL, NAPHTH(1,2-D) - TRIAZOL - 2 - YL AND BENZO(1,2-D:3,4D'')-BIS-TRIAZOL-2-YL, AND THESE RADICALS CAN CONTAIN 1 TO 3 SUBSTITUENTS FROM THE GROUP OF HALOGEN, ALKYL WITH AT LEAST 2 CARBON ATOMS OR METHYL IN THE CASE OF BENZOXAZOL-2-YL RADICAL, ALKOXY, PHENOXY, PHENYL, PHENYLALKYL, CYCLOALKYL OR A METHYLENEDIOXY GROUP AND RX, RY AND RZ ARE IDENTICAL OR DIFFERENT AND DENOTE HYDROGEN, HALOGEN, ALKYL IWTH AT LEAST 2 CARBON ATOMS OR ALKOXY, AND FURTHERMORE RX CAN REPRESENT PHENYL OR PHENYLALKYL AND RX TOGETHER WITH RY CAN FORM A METHYLENEDIOXY GROUP. FURTHERMORE THE INVENTION CONCERNS A PROCESS FOR PREPARATION BY MEANS OF THE "ANILE-SYNTHESIS". THE COMPOUNDS ARE VALUABLE FLUORESCENT WHITENING AGENTS.

5. 发明授权

US3711472A Optical brightening agents 失效
标题翻译：光学加工代理
公开(公告)号：US3711472A
公开(公告)日：1973-01-16
申请号：US3711472D
申请日：1970-08-28
申请人： CIBA GEIGY AG
发明人： MAEDER E , MEYER H , SIEGRIST A , LIECHTI P , WEBER K
IPC分类号： C07D213/16 , C07D215/04 , C07D231/12 , C07D233/56 , C07D235/18 , C07D239/26 , C07D241/42 , C07D249/06 , C07D249/08 , C07D249/20 , C07D249/22 , C07D249/24 , C07D251/24 , C07D253/065 , C07D263/00 , C07D263/56 , C07D263/57 , C07D271/06 , C07D271/10 , C07D271/107 , C07D277/66 , C07D285/12 , C09B23/00 , C09B23/14
CPC分类号： C07D213/16 , C07D215/04 , C07D235/18 , C07D239/26 , C07D241/42 , C07D249/06 , C07D249/08 , C07D249/20 , C07D249/22 , C07D249/24 , C07D251/24 , C07D253/065 , C07D263/00 , C07D263/57 , C07D271/06 , C07D271/107 , C07D277/66 , C07D285/12
摘要： THE PRESENT INVENTION RELATES TO NEW COMPOUNDS OF THE FORMULA

2-B2,6-(B1-CH=CH-),B1-BENZOXAZOLE

IN WHICH A1 REPRESENTS A HYDROGEN ATOM, A METHYL GROUP OR A HALOGEN ATOM, B1 DENOTES A RESIDUE OF THE SERIES PHENYL, DIPHENYL, 1-NAPHTHYL OR 2-NAPHTHYL AND B2 REPRESENTS A RESIDUE OF THE SERIES PHENYL, DIPHENYL, STYRYL, STILBENYL, P-PHENYL-STILBENYL, 1-NAPHTHYL OR 2-NAPHTHYL, AND IN WHICH TERMINAL PHENYL AND NAPHTHYL RESIDUES MAY CONTAIN ALKYL, LHALOGEN OR ALKOXY GROUPS. THESE NEW COMPOUNDS REPRESENT VALUABLE OPTICAL BRIGHTENING AGENTS.
摘要翻译：本发明包括制备含有乙烯双键的杂环化合物的方法。（a）含有至少一个5元或6元杂环与至少一个环氮原子的芳族特征杂环体系，（b）式（1）与环氮原子键合的氢原子和（2）可被碱金属取代的氢原子，（c）通过环状部件与R2的环状部件结合，或具有两个相邻的环状部件与R2的两个相邻的环成员相同，其中R2表示含有6个环成员的芳族特征的碳环系，并且任选地与另外的芳族或芳族环系统缩合，并且其中（b）甲基在式中所示的位置为与R1键合的对位，在强碱性碱性化合物的存在下与希夫碱反应，待反应介质为二甲基甲酰胺，其实际上是无水的，除了在的情况使用碱性氢氧化物作为强碱性碱性化合物，在这种情况下碱金属氢氧化物的含水量可达25％。根据该方法获得的产物是有价值的荧光化合物并且可用作荧光增白剂。

6. 发明授权

US3830848A Diphenyl derivatives 失效
标题翻译：二苯基衍生物
公开(公告)号：US3830848A
公开(公告)日：1974-08-20
申请号：US18510871
申请日：1971-09-30
申请人： CIBA GEIGY AG
发明人： SIEGRIST A
IPC分类号： C07C311/00 , C07C317/14 , C07D213/16 , C07D249/06 , C07D249/16 , C07D249/18 , C07D249/20 , C07D249/22 , C07D249/24 , C07D263/62 , C07D263/64 , C07D271/10 , C07D271/107 , C07D307/79 , D06L3/12 , C07C147/06
CPC分类号： C07D213/16 , C07C317/00 , C07D249/06 , C07D249/16 , C07D249/18 , C07D249/24 , C07D263/64 , C07D271/107 , Y10S428/913
摘要： THE INVENTION DEALS WITH NEW DIPHENYL DERIVATIVES OF THE FORMULA

4,4''-BIS((4-A1''-PHENYL)-CH=CH-)-DIPHENYL

WHEREIN A, REPRESENTS A RADICAL

WHEREIN R4 DENOTES HYDROGEN, METHOXY, AN ALKYL GROUP CONTAINING 1 TO 12 CARBON ATOMS, A PHENYLALKYL GROUP WITH 1 TO 8 CARBON ATOMS IN THE ALKYL PART, A PHENYL GROUP OR CHLORINE, R5 DENOTES HYDROGEN OR AN ALKYL GROUP CONTAINING 1 TO 4 CARBON ATOMS, R6 DENOTES HYDROGEN, CHLORINE OR AN ALKOXY GROUP CONTAINING 1 TO 8 CARBON ATOMS, AN ALKYL GROUP CONAINING 2 TO 4 CARBON ATOMS OR A PHENYL GROUP, R7 DENOTES HYDROGEN, CHLORINE OR AN ALKYL GROUP CONTAINING 2 TO 4 CARBON ATOMS AND R8 DENOTES HYDROGEN OR PHENYL, AND N REPRESENTS AN INTERGER FROM 1 TO 2. THE SAID COMPOUNDS ARE VALUABLE FLUORESCENT WHITENING AGENTS. THEY ARE PREPARED BY MEANS OF THE ANILESYTHESIS.
R4,(R5)N-BENZOXAZOL-2-YL, R4,(R5)N-BENZOFURAN-2-YL,

2-(R6,R7-PHENYL)-1,3,4-OXADIAZOL-5-YL, 7-(R6,R7-PHENYL)-

2,7-DIHYDROBENZO(1,2-D:3,4-D'')BISTRIAZOL-2-YL,

2H-BENZOTRIAZOLYL, 2H-NAPHTHO(1,2-D)TRIAZOLYL

4-R8,5-PHENYL-2H-1,2,3-TRIAZOLYL

7. 发明授权

US3804773A Triazole derivatives 失效
标题翻译：三唑衍生物
公开(公告)号：US3804773A
公开(公告)日：1974-04-16
申请号：US18542171
申请日：1971-09-30
申请人： CIBA GEIGY AG
发明人： SIEGRIST A
IPC分类号： C07D249/16 , C08K5/3475 , D06L3/12
CPC分类号： C07D249/16 , C08K5/3475 , C08L67/02
摘要： THE INVENTION CONCERNS A PROCESS FOR THE MANUFACTURE OF TRIAZOLE DERIVATIVES OF THE FORMULA

2-(3-X'',4-(A2''-CH=CH-)PHENYL),7-A1''-2,7-DIHYDROBENZO-

(1,2-D:3,4-D'')BISTRIAZOLE

WHEREIN A1'' DENOTES DIPHENYLYL-(4), NAPHTHYL OR A RADICAL

R1'',R2'',R3''-PHENYL

A2'' DENOTES DIPHENYLYL-(4), NAPHTHYL, PYRIDYL-(3), THIENYL(2), M-TOLYL OR RADICAL

R1",R2'',R3''-PHENYL

X'' DENOTES HYDROGEN, CHLORINE, NITRILE~R METHOXY AND R1", R2'' AND R3'' ARE IDENTICAL OR DIFFERENT AND REPRESENT HYDROGEN, ALKYL WITH AT LEAST 2 CARBON ATOMS, ALKOXY OR CHLORINE AND R1" CAN ALSO DENOTE PHENOXY, PHENYLMERCAPTAN OR ALKYLMERCAPTO AND R1" TOGETHER WITH R2'' CAN DENOTE A METHYLENEDIOX GROUP, BY MEANS OF THE ANILESYNTHEIS. THESE NEW COMPOUNDS ARE USEFUL FLUORESCENT WHITENING AGENTS.

8. 发明授权

US3796705A Stilbene derivatives 失效
标题翻译： STILBENE DERIVATIVES
公开(公告)号：US3796705A
公开(公告)日：1974-03-12
申请号：US3796705D
申请日：1971-09-30
申请人： CIBA GEIGY AG
发明人： SIEGRIST A
IPC分类号： C07D249/22 , C08K5/35 , C07D55/04
CPC分类号： C07D249/22 , C08K5/35
摘要： THE INVENTION CONCERNS NEW FLUORESCENT WHITENING AGENT CORRESPONDING TO THE FORMULA

1-E,4-((4-G-PHENYL)-CH=CH-)BENZENE

WHEREIN E DENOTES A BENZTRIAZOL-2-YL OR NAPTH-(1,2-D)TRIAZOL-2-YL RADICAL AND G REPRESENTS A RADICAL OF THE FORMULA

(R1,(R2)N-BENZOXAZOL-2-YL), NAPHTH(1,2-D)OXAZOL-2-YL,

2H-BENZOTRIAZOL-2-YL, 2H-NAPHTHO(1,2-D)TRIAZOL-2-YL,

(2-(R3,R3''-PHENYL)-1,3,4-OXADIAZOL-5-YL)

WHREIN R1 REPRESENTS HYDROGEN, CHLORINE, ALKYL OR ALKOXY WITH 1 TO 4 CARBON ATOMS, PHENYL OR PHENYLALKYL WITH 1 TO 4 CARBON ATOMS IN THE ALKYL PART, R2 REPRESENTS HYDROGEN OR ALKYL WITH 1 TO 8 CARBON ATOMS, R3 AND R3'' ARE IDENTICAL OR DIFFERENT AND DENOTE HYDROGEN, ALKYL WITH 2 TO 4 CARBON ATOMS OR A METHYL GROUP IN THE M-POSITION, CHLORINE OR ALKOXY WITH 1 TO 2 CARBON ATOMS, AND N REPRESENTS THE NUMBERS 1,2,OR 3, AS WELL AS A PROCESS FOR THEIR PREPARATION BY MEANS OF THE ANILE-SYNTHESIS.

9. 发明授权

US3849163A Process for the optical brightening of organic materials 失效
标题翻译：有机材料的光学加工工艺
公开(公告)号：US3849163A
公开(公告)日：1974-11-19
申请号：US29540572
申请日：1972-10-05
申请人： CIBA GEIGY AG
发明人： MEYER H , WEBER K , MAEDER E , GUGLIELMETTI L , SIEGRIST A , LIECHTI P
IPC分类号： C07D213/16 , C07D215/04 , C07D231/12 , C07D233/56 , C07D235/18 , C07D239/26 , C07D241/42 , C07D249/06 , C07D249/08 , C07D249/20 , C07D249/22 , C07D249/24 , C07D251/24 , C07D253/065 , C07D263/00 , C07D263/56 , C07D263/57 , C07D271/06 , C07D271/10 , C07D271/107 , C07D277/66 , C07D285/12 , D06P5/00 , C09B23/00
CPC分类号： C07D213/16 , C07D215/04 , C07D235/18 , C07D239/26 , C07D241/42 , C07D249/06 , C07D249/08 , C07D249/20 , C07D249/22 , C07D249/24 , C07D251/24 , C07D253/065 , C07D263/00 , C07D263/57 , C07D271/06 , C07D271/107 , C07D277/66 , C07D285/12
摘要： The present invention relates to a process for the optical brightening of organic materials using compounds of the formula

IN WHICH A REPRESENTS HYDROGEN, HALOGEN, THE METHYL GROUP OR THE METHOXY GROUP, Z1 and/or Z2 denotes a ring member CH- or N- and Alpha represents a hydrogen atom, a phenyl residue or a residue of the series

IN WHICH (I) at least one residue Alpha differs from hydrogen or phenyl and has the significance of one of the other residues quoted for Alpha , and in which (II) terminal phenyl or naphthyl residues may contain alkyl, halogen or alkoxy groups. These new compounds represent valuable optical brightening agents.
摘要翻译：本发明涉及一种使用下式的化合物进行有机材料的光学增白的方法：其中氢，卤素，甲基或甲氧基，Z1和/或Z2表示环成员= CH-或= N - 和α表示氢原子，苯基残基或其中的（I）的残基，至少一个残基α与氢或苯基不同，并且具有引用为α的其它残基之一的含义，其中（ II）末端苯基或萘基残基可以含有烷基，卤素或烷氧基。这些新化合物代表有价值的荧光增白剂。

10. 发明授权

US3819615A Process for the manufacture of stilbene compounds 失效
标题翻译：苯乙烯化合物的制备方法
公开(公告)号：US3819615A
公开(公告)日：1974-06-25
申请号：US30428972
申请日：1972-11-06
申请人： CIBA GEIGY AG
发明人： SIEGRIST A
IPC分类号： C07D333/52 , C07C1/00 , C07C2/84 , C07C15/52 , C07C15/54 , C07C17/00 , C07C25/24 , C07C67/00 , C07D249/20 , C07D249/24 , C07D263/56 , C07D263/62 , C07D263/64 , C07D307/77 , C07D307/79 , C07D307/92 , C07D333/54 , C07D333/74 , C09B57/00 , C07D55/02
CPC分类号： C07D263/64 , C07C15/54 , C07D249/20 , C07D249/24 , C07D307/79 , C07D307/92 , C07D333/54 , C07D333/74
摘要： THE PRESENT INVENTION PROVIDES A PROCESS FOR THE MANUFACTURE OF STILBENE COMPOUNDS OF THE FORMULA

2,2''-DI(Y-),4,4''-DI(A-)STILBENE

WHEREIN A STANDS FOR A BENZO (B)FURNAL-2-YL, NAPHTHO(1,2-B)FURAN-2-YL, NAPHTHOL(2,1-B)FURAN-2-YL, BENZO (B) THIOPHEN-2-YL, NAPHTHOL(2,1-B)THIOPNEH-2-YL, BENZOXAZOL2-7L, NAPHTHOXAZOL-2-YL, BENZOTRIAZOL-2-YL, NAPHTHOL(1,2-D) TRIAZOL-2-YL, BENZO(1,2-D:3,4-D'')BIS-TRAZOL-2-YL OR PHENETHINYL RADICAL, WHICH ITSELF CAN AGAIN BE SUBSTITUTED BY CHLORINE OR ALKYL, CYCLOHEXYL PHENYL-(1-4C)-ALKYL, PHENYL, METHYLENEDIOXY, PHENOXY OR ALKOXY GROUPS OR WHICH CAN CONTAIN A 6-MEMBERED CARBOCYCLIC RING WHICH IS FUSED TO IT AND WHEREIN Y STANDS FOR A HYDROGEN ATOM, CHLORINE OR THE N,N-DIMETHYLCARBAMYL RADICAL, CHARACTERISED IN THAT A COMPOUND OF THE FORMULA

1-CH3,2-Y,4-A-BENZENE

WHEREIN A AND Y HAVE THE PREVIOUSLY INDICATED MEANING IS OXIDISED IN DIMETHYLFORMAMIDE, WHILST EXCLUDING AIR, IN THE PRESENCE OF A POTASSIUM COMPOUND OF THE FORMULA

KOC(X-1)H(2X-1)

WHEREIN X DENOTES AN INTEGER FROM 1 TO 6, WITH THE AZOBENZENE OF THE FORMULA

((Z1-PHENYL)-N=N-),Z2-BENZENE

WHEREIN Z1 AND Z2 STAND FOR HYDROGEN OR CHLORINE; THE PRESENT INVENTION FURTHER PROVIDES NEW STILBENE DERIVATIVE WHICH CAN BE MANUFACTURE ACCORDING TO THIS PROCESS AND WHICH CAN BE USED AS OPTICAL BRIGHTENERS.

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