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1. 发明授权

US08431202B2 Aluminum/alkaline or alkali/titanium containing polyesters having improved reheat, color and clarity 有权
标题翻译：具有改善的再热，颜色和透明度的铝/碱性或碱/含钛聚酯
公开(公告)号：US08431202B2
公开(公告)日：2013-04-30
申请号：US11229238
申请日：2005-09-16
申请人： Donna Rice Quillen , Rodney Scott Armentrout , Mary Therese Jernigan , Steven Lee Stafford , Zhiyong Xia
发明人： Donna Rice Quillen , Rodney Scott Armentrout , Mary Therese Jernigan , Steven Lee Stafford , Zhiyong Xia
IPC分类号： B29D22/00 , B29D23/00 , B32B1/08
CPC分类号： C08G63/83 , B29C47/0004 , B29C47/0016 , B29C47/0021 , C08G63/183 , C08G63/84 , Y10T428/1352 , Y10T428/1355 , Y10T428/139 , Y10T428/1397
摘要： A polyester composition containing: a) aluminum atoms; and b) alkaline earth atoms or alkali metal atoms or alkali compound residues such as lithium atoms; and c) particles comprising titanium, zirconium, vanadium, niobium, hafnium, tantalum, chromium, tungsten, molybdenum, iron, or nickel atoms or combinations thereof, where the particles improve the reheat rate of the polyester composition. The polyester polymer compositions may also contain phosphorus catalyst deactivators/stabilizers. The polyester compositions and the articles made from the compositions such as bottle preforms and stretch blow molded bottles have improved reheat rate while maintaining low haze, high L*, a b* below 3, and have low levels of acetaldehyde. In the process for making the polyester polymer, the polymer melt is polycondensed in the presence of a) and b), with the particles c) added in a melt phase process or added to the polymer in an injection molding machine or extruder. The polyester polymer composition can be made to high IV from the melt phase while avoiding solid state polymerization.
摘要翻译：一种聚酯组合物，其含有：a）铝原子; 和b）碱土金属原子或碱金属原子或碱金属化合物残基如锂原子; 和c）包含钛，锆，钒，铌，铪，钽，铬，钨，钼，铁或镍原子或其组合的颗粒，其中颗粒改善了聚酯组合物的再热速率。聚酯聚合物组合物还可以含有磷催化剂失活剂/稳定剂。聚酯组合物和由诸如瓶子预成型件和拉伸吹塑成型瓶的组合物制成的制品具有改善的再加热速率，同时保持低雾度，高L *，低于3的b *，并且具有低水平的乙醛。在制备聚酯聚合物的方法中，聚合物熔体在a）和b）存在下缩聚，颗粒c）在熔融相中加入或在注塑机或挤出机中加入到聚合物中。聚酯聚合物组合物可以从熔融相制成高IV，同时避免固态聚合。

2. 发明授权

US08791187B2 Aluminum/alkyline or alkali/titanium containing polyesters having improved reheat, color and clarity 有权
标题翻译：铝/烷基或含碱/钛的聚酯具有改善的再热，颜色和透明度
公开(公告)号：US08791187B2
公开(公告)日：2014-07-29
申请号：US13149248
申请日：2011-05-31
申请人： Donna Rice Quillen , Rodney Scott Armentrout , Mary Therese Jernigan , Steven Lee Stafford , Zhiyong Xia
发明人： Donna Rice Quillen , Rodney Scott Armentrout , Mary Therese Jernigan , Steven Lee Stafford , Zhiyong Xia
IPC分类号： B32B27/18
CPC分类号： C08G63/83 , B29C47/0004 , B29C47/0016 , B29C47/0021 , C08G63/183 , C08G63/84 , Y10T428/1352 , Y10T428/1355 , Y10T428/139 , Y10T428/1397
摘要： A polyester composition containing: a) aluminum atoms; and b) alkaline earth atoms or alkali metal atoms or alkali compound residues such as lithium atoms; and c) particles comprising titanium, zirconium, vanadium, niobium, hafnium, tantalum, chromium, tungsten, molybdenum, iron, or nickel atoms or combinations thereof, where the particles improve the reheat rate of the polyester composition. The polyester polymer compositions may also contain phosphorus catalyst deactivators/stabilizers. The polyester compositions and the articles made from the compositions such as bottle preforms and stretch blow molded bottles have improved reheat rate while maintaining low haze, high L*, a b* below 3, and have low levels of acetaldehyde. In the process for making the polyester polymer, the polymer melt is polycondensed in the presence of a) and b), with the particles c) added in a melt phase process or added to the polymer in an injection molding machine or extruder. The polyester polymer composition can be made to high IV from the melt phase while avoiding solid state polymerization.
摘要翻译：一种聚酯组合物，其含有：a）铝原子; 和b）碱土金属原子或碱金属原子或碱金属化合物残基如锂原子; 和c）包含钛，锆，钒，铌，铪，钽，铬，钨，钼，铁或镍原子或其组合的颗粒，其中颗粒改善了聚酯组合物的再热速率。聚酯聚合物组合物还可以含有磷催化剂失活剂/稳定剂。聚酯组合物和由诸如瓶子预成型件和拉伸吹塑成型瓶的组合物制成的制品具有改善的再加热速率，同时保持低雾度，高L *，低于3的b *，并且具有低水平的乙醛。在制备聚酯聚合物的过程中，聚合物熔体在a）和b）存在下缩聚，颗粒c）以熔融相方式加入，或者在注射成型机或挤出机中加入到聚合物中。聚酯聚合物组合物可以从熔融相制成高IV，同时避免固态聚合。

3. 发明申请

US20110281049A1 ALUMINUM/ALKYLINE OR ALKALI/TITANIUM CONTAINING POLYESTERS HAVING IMPROVED REHEAT, COLOR AND CLARITY 有权
标题翻译：含有改进的REHEAT，COLOR和CLARITY的聚酯的ALUMINUM / ALKYLINE或ALKALI / TITANIUM
公开(公告)号：US20110281049A1
公开(公告)日：2011-11-17
申请号：US13149248
申请日：2011-05-31
申请人： Donna Rice Quillen , Rodney Scott Armentrout , Mary Therese Jernigan , Steven Lee Stafford , Zhiyong Xia
发明人： Donna Rice Quillen , Rodney Scott Armentrout , Mary Therese Jernigan , Steven Lee Stafford , Zhiyong Xia
IPC分类号： B32B27/18 , B32B27/36 , B32B1/02 , C08K3/28 , C08K5/521
CPC分类号： C08G63/83 , B29C47/0004 , B29C47/0016 , B29C47/0021 , C08G63/183 , C08G63/84 , Y10T428/1352 , Y10T428/1355 , Y10T428/139 , Y10T428/1397
摘要： A polyester composition containing: a) aluminum atoms; and b) alkaline earth atoms or alkali metal atoms or alkali compound residues such as lithium atoms; and c) particles comprising titanium, zirconium, vanadium, niobium, hafnium, tantalum, chromium, tungsten, molybdenum, iron, or nickel atoms or combinations thereof, where the particles improve the reheat rate of the polyester composition. The polyester polymer compositions may also contain phosphorus catalyst deactivators/stabilizers. The polyester compositions and the articles made from the compositions such as bottle preforms and stretch blow molded bottles have improved reheat rate while maintaining low haze, high L*, a b* below 3, and have low levels of acetaldehyde. In the process for making the polyester polymer, the polymer melt is polycondensed in the presence of a) and b), with the particles c) added in a melt phase process or added to the polymer in an injection molding machine or extruder. The polyester polymer composition can be made to high IV from the melt phase while avoiding solid state polymerization.
摘要翻译：一种聚酯组合物，其含有：a）铝原子; 和b）碱土金属原子或碱金属原子或碱金属化合物残基如锂原子; 和c）包含钛，锆，钒，铌，铪，钽，铬，钨，钼，铁或镍原子或其组合的颗粒，其中颗粒改善了聚酯组合物的再热速率。聚酯聚合物组合物还可以含有磷催化剂失活剂/稳定剂。聚酯组合物和由诸如瓶子预成型件和拉伸吹塑成型瓶的组合物制成的制品具有改善的再加热速率，同时保持低雾度，高L *，低于3的b *，并且具有低水平的乙醛。在制备聚酯聚合物的过程中，聚合物熔体在a）和b）存在下缩聚，颗粒c）以熔融相方式加入，或者在注射成型机或挤出机中加入到聚合物中。聚酯聚合物组合物可以从熔融相制成高IV，同时避免固态聚合。

4. 发明授权

US07662880B2 Polyester polymer and copolymer compositions containing metallic nickel particles 有权
标题翻译：含有金属镍颗粒的聚酯聚合物和共聚物组合物
公开(公告)号：US07662880B2
公开(公告)日：2010-02-16
申请号：US10996924
申请日：2004-11-24
申请人： Zhiyong Xia , Donna Rice Quillen
发明人： Zhiyong Xia , Donna Rice Quillen
IPC分类号： B65D81/24
CPC分类号： C08K3/08 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14106 , B29B2911/14133 , B29C49/0005 , B29C49/06 , B29C51/00 , B29K2105/005 , B29K2105/065 , B29K2705/00 , C08K2003/0862 , Y10S428/913 , Y10T428/1355 , Y10T428/1372 , Y10T428/256 , C08L67/02
摘要： Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein metallic nickel particles that improve the reheat properties of the compositions. Processes for making such compositions are also disclosed. The nickel particles may be incorporated in the polyester by melt compounding, or may be added at any stage of the polymerization, such as during the melt-phase of the polymerization. A range of particle sizes may be used, as well as a range of particle size distributions. The polyester compositions are suitable for use in packaging made from processes in which a reheat step is desirable.
摘要翻译：公开了聚酯组合物，其包括其中掺入金属镍颗粒的聚酯聚合物或共聚物，其改善组合物的再加热性能。还公开了制备这种组合物的方法。镍颗粒可以通过熔融混合而引入聚酯中，或者可以在聚合的任何阶段，例如在聚合的熔融相期间加入。可以使用一定范围的粒度，以及一定范围的粒度分布。聚酯组合物适用于由需要再热步骤的方法制成的包装。

5. 发明授权

US08039577B2 Polyester polymer and copolymer compositions containing titanium nitride particles 有权
标题翻译：含有氮化钛颗粒的聚酯聚合物和共聚物组合物
公开(公告)号：US08039577B2
公开(公告)日：2011-10-18
申请号：US12073244
申请日：2008-03-03
申请人： Zhiyong Xia , Steven Lee Stafford , Susan Sims , Frederick Leslie Colhoun
发明人： Zhiyong Xia , Steven Lee Stafford , Susan Sims , Frederick Leslie Colhoun
IPC分类号： C08K3/22
CPC分类号： C08K3/28 , C08L67/00
摘要： Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein titanium nitride particles that provide one or more of the following advantages: improving the reheat properties of the compositions, improving the color of the compositions through reduced yellowness, and improving the UV-blocking properties of the compositions. Processes for making such compositions are also disclosed. The titanium nitride particles may be incorporated in the polyester by melt compounding, or may be added at any stage of the polymerization, such as during the melt-phase of the polymerization. A range of particle sizes may be used, as well as a range of particle size distributions. The polyester compositions are suitable for use in packaging made from processes in which a reheat step is desirable, or decreased yellowness is desired, or increased resistance to the effects of ultraviolet light is desired, or any combination of the foregoing.
摘要翻译：公开了聚酯组合物，其包括具有纳入其中的氮化钛颗粒的聚酯聚合物或共聚物，其提供一个或多个以下优点：改善组合物的再热性能，通过减少黄度改善组合物的颜色，并改善UV-阻断组合物的性质。还公开了制备这种组合物的方法。可以通过熔融配混将氮化钛颗粒引入聚酯中，或者可以在聚合的任何阶段例如在聚合的熔融相期间加入。可以使用一定范围的粒度，以及一定范围的粒度分布。聚酯组合物适用于由期望再热步骤或期望减少黄色的方法制成的包装或期望提高对紫外光效果的耐受性，或上述任何组合。

6. 发明授权

US07368523B2 Polyester polymer and copolymer compositions containing titanium nitride particles 有权
公开(公告)号：US07368523B2
公开(公告)日：2008-05-06
申请号：US11228672
申请日：2005-09-16
申请人： Zhiyong Xia , Steven Lee Stafford , Susan Sims , Frederick Leslie Colhoun
发明人： Zhiyong Xia , Steven Lee Stafford , Susan Sims , Frederick Leslie Colhoun
IPC分类号： C08K3/22
CPC分类号： C08K3/28 , Y10T428/1321 , Y10T428/1359 , C08L67/00
摘要： Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein titanium nitride particles that provide one or more of the following advantages: improving the reheat properties of the compositions, improving the color of the compositions through reduced yellowness, and improving the UV-blocking properties of the compositions. Processes for making such compositions are also disclosed. The titanium nitride particles may be incorporated in the polyester by melt compounding, or may be added at any stage of the polymerization, such as during the melt-phase of the polymerization. A range of particle sizes may be used, as well as a range of particle size distributions. The polyester compositions are suitable for use in packaging made from processes in which a reheat step is desirable, or decreased yellowness is desired, or increased resistance to the effects of ultraviolet light is desired, or any combination of the foregoing.

7. 发明申请

US20080153962A1 Polyester polymer and copolymer compositions containing titanium nitride particles 有权
标题翻译：含有氮化钛颗粒的聚酯聚合物和共聚物组合物
公开(公告)号：US20080153962A1
公开(公告)日：2008-06-26
申请号：US12073244
申请日：2008-03-03
申请人： Zhiyong Xia , Steven Lee Stafford , Susan Sims , Frederick Leslie Colhoun
发明人： Zhiyong Xia , Steven Lee Stafford , Susan Sims , Frederick Leslie Colhoun
IPC分类号： C08K3/10
CPC分类号： C08K3/28 , C08L67/00
摘要： Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein titanium nitride particles that provide one or more of the following advantages: improving the reheat properties of the compositions, improving the color of the compositions through reduced yellowness, and improving the UV-blocking properties of the compositions. Processes for making such compositions are also disclosed. The titanium nitride particles may be incorporated in the polyester by melt compounding, or may be added at any stage of the polymerization, such as during the melt-phase of the polymerization. A range of particle sizes may be used, as well as a range of particle size distributions. The polyester compositions are suitable for use in packaging made from processes in which a reheat step is desirable, or decreased yellowness is desired, or increased resistance to the effects of ultraviolet light is desired, or any combination of the foregoing.
摘要翻译：公开了聚酯组合物，其包括具有纳入其中的氮化钛颗粒的聚酯聚合物或共聚物，其提供一个或多个以下优点：改善组合物的再热性能，通过减少黄度改善组合物的颜色，并改善UV-阻断组合物的性质。还公开了制备这种组合物的方法。可以通过熔融配混将氮化钛颗粒引入聚酯中，或者可以在聚合的任何阶段例如在聚合的熔融相期间加入。可以使用一定范围的粒度，以及一定范围的粒度分布。聚酯组合物适用于由期望再热步骤或期望减少黄色的方法制成的包装或期望提高对紫外光效果的耐受性，或上述任何组合。

8. 发明申请

US20080319113A1 POLYESTER POLYMER AND COPOLYMER COMPOSITIONS CONTAINING METALLIC TITANIUM PARTICLES 审中-公开
标题翻译：包含金属钛颗粒的聚酯聚合物和共聚物组合物
公开(公告)号：US20080319113A1
公开(公告)日：2008-12-25
申请号：US12200976
申请日：2008-08-29
申请人： Zhiyong Xia
发明人： Zhiyong Xia
IPC分类号： C08K3/08
CPC分类号： B29C49/0005 , B29C49/06 , C08K3/08 , C08K2003/0881 , C08L67/02
摘要： Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein metallic titanium particles that improve the reheat properties of the compositions. Processes for making such compositions are also disclosed. The titanium particles may be incorporated in the polyester by melt compounding, or may be added at any stage of the polymerization, such as during the melt-phase of the polymerization. A range of particle sizes may be used, as well as a range of particle size distributions. The polyester compositions are suitable for use in packaging made from processes in which a reheat step is desirable.
摘要翻译：公开了聚酯组合物，其包括其中掺入金属钛颗粒的聚酯聚合物或共聚物，其改善组合物的再加热性能。还公开了制备这种组合物的方法。钛颗粒可以通过熔融混合掺入聚酯中，或者可以在聚合的任何阶段例如在聚合的熔融相期间加入。可以使用一定范围的粒度，以及一定范围的粒度分布。聚酯组合物适用于由需要再热步骤的方法制成的包装。

9. 发明申请

US20060106146A1 Polyester polymer and copolymer compositions containing titanium nitride particles 有权
标题翻译：含有氮化钛颗粒的聚酯聚合物和共聚物组合物
公开(公告)号：US20060106146A1
公开(公告)日：2006-05-18
申请号：US11228672
申请日：2005-09-16
申请人： Zhiyong Xia , Steven Stafford , Susan Sims , Frederick Colhoun
发明人： Zhiyong Xia , Steven Stafford , Susan Sims , Frederick Colhoun
IPC分类号： C08K3/22
CPC分类号： C08K3/28 , Y10T428/1321 , Y10T428/1359 , C08L67/00
摘要： Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein titanium nitride particles that provide one or more of the following advantages: improving the reheat properties of the compositions, improving the color of the compositions through reduced yellowness, and improving the UV-blocking properties of the compositions. Processes for making such compositions are also disclosed. The titanium nitride particles may be incorporated in the polyester by melt compounding, or may be added at any stage of the polymerization, such as during the melt-phase of the polymerization. A range of particle sizes may be used, as well as a range of particle size distributions. The polyester compositions are suitable for use in packaging made from processes in which a reheat step is desirable, or decreased yellowness is desired, or increased resistance to the effects of ultraviolet light is desired, or any combination of the foregoing.
摘要翻译：公开了聚酯组合物，其包括具有纳入其中的氮化钛颗粒的聚酯聚合物或共聚物，其提供一个或多个以下优点：改善组合物的再热性能，通过减少黄度改善组合物的颜色，并改善UV-阻断组合物的性质。还公开了制备这种组合物的方法。可以通过熔融配混将氮化钛颗粒引入聚酯中，或者可以在聚合的任何阶段例如在聚合的熔融相期间加入。可以使用一定范围的粒度，以及一定范围的粒度分布。聚酯组合物适用于由期望再热步骤或期望减少黄色的方法制成的包装或期望提高对紫外光效果的耐受性，或上述任何组合。

10. 发明申请

US20130213459A1 PHOTOVOLTAIC DEVICE WITH A POLYMERIC MAT AND METHOD OF MAKING THE SAME 审中-公开
标题翻译：具有聚合物的光伏器件及其制造方法
公开(公告)号：US20130213459A1
公开(公告)日：2013-08-22
申请号：US13852655
申请日：2013-03-28
申请人： Zhiyong Xia , Daniel W. Cunningham , John H. Wohlgemuth
发明人： Zhiyong Xia , Daniel W. Cunningham , John H. Wohlgemuth
IPC分类号： H01L31/048
CPC分类号： B32B27/283 , B32B3/08 , B32B5/022 , B32B5/024 , B32B5/08 , B32B7/10 , B32B7/12 , B32B17/10 , B32B17/10018 , B32B17/10788 , B32B25/04 , B32B27/08 , B32B27/12 , B32B27/18 , B32B27/285 , B32B27/286 , B32B27/302 , B32B27/306 , B32B27/308 , B32B27/32 , B32B27/322 , B32B27/34 , B32B27/36 , B32B27/365 , B32B27/40 , B32B2262/02 , B32B2262/0223 , B32B2262/023 , B32B2262/0238 , B32B2262/0246 , B32B2262/0253 , B32B2262/0261 , B32B2262/0276 , B32B2262/0292 , B32B2262/14 , B32B2270/00 , B32B2307/20 , B32B2307/204 , B32B2307/206 , B32B2307/412 , B32B2307/50 , B32B2307/546 , B32B2307/712 , B32B2307/7246 , B32B2307/7265 , B32B2367/00 , B32B2457/12 , H01L31/049 , Y02E10/50 , Y10T156/108
摘要： This invention relates to a photovoltaic device with a polymeric mat and a method of making a photovoltaic device with a polymeric mat. The photovoltaic device includes a transparent layer for receiving solar energy, and at least one photovoltaic cell disposed below the transparent layer. The photovoltaic device also includes a polymeric mat disposed below the at least one photovoltaic cell, and a backsheet disposed below the polymeric mat. The photovoltaic device also includes an encapsulant bonding the transparent layer, the at least one photovoltaic cell, the polymeric mat, and the backsheet.
摘要翻译：本发明涉及具有聚合物垫的光伏器件以及制造具有聚合物垫的光伏器件的方法。光伏器件包括用于接收太阳能的透明层，以及设置在透明层下方的至少一个光伏电池。光伏器件还包括设置在至少一个光伏电池下方的聚合物垫，以及设置在聚合物垫下方的底片。光伏器件还包括粘合透明层，至少一个光伏电池，聚合物垫和底片的密封剂。

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