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1. 发明授权

US09396884B2 Ionic liquids that can be used as part of the electrolyte composition for energy storage devices 有权
标题翻译：可用作储能装置的电解质组合物的一部分的离子液体
公开(公告)号：US09396884B2
公开(公告)日：2016-07-19
申请号：US14237091
申请日：2012-08-03
申请人： Herve Galiano , Mérièm Anouti , Daniel Lemordant , Laure Timperman
发明人： Herve Galiano , Mérièm Anouti , Daniel Lemordant , Laure Timperman
IPC分类号： H01G9/035 , H01G11/58 , C07F9/54 , B01J31/02 , H01G9/022 , H01G9/00
CPC分类号： H01G11/58 , B01J31/0288 , C07F9/5407 , H01G9/035 , H01G9/038 , H01G2009/0007 , H01G2009/0025 , H01M2300/0045 , Y02E60/13
摘要： The present invention relates to ionic liquids comprising, as cation, a specific phosphonium cation, as anion, a formate anion, which can be used, alone or as a mixture, to constitute electrolytes for energy storage devices.
摘要翻译：本发明涉及离子液体，其包含作为阳离子的特定鏻阳离子作为阴离子，甲酸根阴离子，其可以单独使用或作为混合物用于构成储能装置的电解质。

2. 发明申请

US20140168855A1 NOVEL IONIC LIQUIDS THAT CAN BE USED AS PART OF THE ELECTROLYTE COMPOSITION FOR ENERGY STORAGE DEVICES 有权
标题翻译：可用作能源储存装置的电解质组合物的一部分的新型离子液体
公开(公告)号：US20140168855A1
公开(公告)日：2014-06-19
申请号：US14237091
申请日：2012-08-03
申请人： Herve Galiano , Meriem Anouti , Daniel Lemordant , Laure Timperman
发明人： Herve Galiano , Meriem Anouti , Daniel Lemordant , Laure Timperman
IPC分类号： H01G11/58
CPC分类号： H01G11/58 , B01J31/0288 , C07F9/5407 , H01G9/035 , H01G9/038 , H01G2009/0007 , H01G2009/0025 , H01M2300/0045 , Y02E60/13
摘要： The present invention relates to ionic liquids comprising, as cation, a specific phosphonium cation, as anion, a formiate anion, which can be used, alone or as a mixture, to constitute electrolytes for energy storage devices.
摘要翻译：本发明涉及离子液体，其包含作为阳离子的特定鏻阳离子作为阴离子，甲酸根阴离子，其可以单独使用或作为混合物用于构成用于储能装置的电解质。

3. 发明申请

US20140113982A1 METHOD FOR PREPARING PROTON-CONDUCTING INORGANIC PARTICLES 有权
标题翻译：制备无机导电无机颗粒的方法
公开(公告)号：US20140113982A1
公开(公告)日：2014-04-24
申请号：US13990226
申请日：2011-11-28
申请人： Jannick Bigarre , Renaud Perrin , Pierrick Buvat , Herve Galiano
发明人： Jannick Bigarre , Renaud Perrin , Pierrick Buvat , Herve Galiano
IPC分类号： B01J39/20
CPC分类号： B01J39/20 , C08J5/2275 , H01B1/122
摘要： The invention relates to a method for functionalization of inorganic particles by polymers comprising at least one recurrent unit bearing at least one proton exchange group comprising the following steps: a) a step for functionalization of inorganic particles by an anionic polymerization termination agent comprising at least one group capable of being bound to the surface of said particles; b) a step for anionic polymerization of at least one monomer bearing at least one precursor group of a proton exchange group; c) a step for putting the particles obtained in step a) in contact with the polymers obtained in step b), in return for which the obtained particles are particles functionalized by said polymers by reaction between a reactive end of said polymeric polymers and at least one group of the aforementioned termination agent; and d) a step for transformation of the precursor group(s) of said proton exchange group(s).
摘要翻译：本发明涉及一种通过聚合物官能化无机颗粒的方法，所述聚合物包含至少一个具有至少一个质子交换基团的反应单元，该反应单元包括以下步骤：a）通过阴离子聚合终止剂官能化无机颗粒的步骤，所述阴离子聚合终止剂包含至少一个能够与所述颗粒的表面结合的基团; b）至少一种带有至少一个质子交换基团前体基团的单体进行阴离子聚合的步骤; c）将步骤a）中获得的颗粒与步骤b）中获得的聚合物接触的步骤，作为回报，所得颗粒是由所述聚合物官能化的颗粒，通过所述聚合物聚合物的反应性末端与至少一组上述终止剂; 和d）用于转化所述质子交换基团的前体基团的步骤。

4. 发明申请

US20080102339A1 Process for Preparing Proton-Conducting Clay Particles and Composite Material Comprising Such Particles 有权
标题翻译：制备质子传导粘土颗粒和包含这种颗粒的复合材料的方法
公开(公告)号：US20080102339A1
公开(公告)日：2008-05-01
申请号：US11547443
申请日：2005-04-15
申请人： Herve Galiano , Magaly Caravanier-Caillon , Philippe Bebin , Patrick Hourquebie , Faiza Bergaya , Fabienne Poncin Epaillard , Fabrice Lafleche
发明人： Herve Galiano , Magaly Caravanier-Caillon , Philippe Bebin , Patrick Hourquebie , Faiza Bergaya , Fabienne Poncin Epaillard , Fabrice Lafleche
IPC分类号： H01M8/10 , C07F7/02
CPC分类号： B01D69/141 , B01D67/0079 , C01P2006/12 , C01P2006/14 , C01P2006/40 , C09C1/42 , C09C3/048 , H01M8/1023 , H01M8/1039 , H01M8/1044 , H01M8/1081 , H01M2300/0082 , H01M2300/0088 , Y02P70/56
摘要： The invention relates to a process for preparing proton-conducting clay particles, successively comprising the following steps:a) a step of activating a clay powder, comprising a step in which the said powder is subjected to a gas plasma;b) a grafting step comprising a step of placing the activated powder obtained from step a) in contact with a solution comprising at least one compound comprising at least one group chosen from —PO3H2, —CO2H and —SO3H and salts thereof and comprising at least one group capable of grafting onto the surface of the said powder.Use of these particles for the manufacture of fuel cell membranes.
摘要翻译：本发明涉及一种制备质子传导粘土颗粒的方法，该方法依次包括以下步骤：a）活化粘土粉末的步骤，包括使所述粉末经受气体等离子体的步骤; b）接枝步骤，包括将从步骤a）获得的活化粉末与包含至少一种选自-PO 3 H 2的至少一种化合物的溶液接触的步骤 -CO 2 H和-SO 3 H及其盐，并且包含至少一个能够接枝到所述粉末的表面上的基团。使用这些颗粒来制造燃料电池膜。

5. 发明授权

US09227187B2 Method for preparing proton-conducting inorganic particles 有权
标题翻译：制备质子传导无机颗粒的方法
公开(公告)号：US09227187B2
公开(公告)日：2016-01-05
申请号：US13990226
申请日：2011-11-28
申请人： Jannick Bigarre , Renaud Perrin , Pierrick Buvat , Herve Galiano
发明人： Jannick Bigarre , Renaud Perrin , Pierrick Buvat , Herve Galiano
IPC分类号： B01J39/20 , H01B1/12 , C08J5/22
CPC分类号： B01J39/20 , C08J5/2275 , H01B1/122
摘要： The invention relates to a method for functionalization of inorganic particles by polymers comprising at least one recurrent unit bearing at least one proton exchange group comprising the following steps: a) a step for functionalization of inorganic particles by an anionic polymerization termination agent comprising at least one group capable of being bound to the surface of said particles; b) a step for anionic polymerization of at least one monomer bearing at least one precursor group of a proton exchange group; c) a step for putting the particles obtained in step a) in contact with the polymers obtained in step b), in return for which the obtained particles are particles functionalized by said polymers by reaction between a reactive end of said polymeric polymers and at least one group of the aforementioned termination agent; and d) a step for transformation of the precursor group(s) of said proton exchange group(s).
摘要翻译：本发明涉及一种通过聚合物官能化无机颗粒的方法，所述聚合物包含至少一个具有至少一个质子交换基团的反应单元，该反应单元包括以下步骤：a）通过阴离子聚合终止剂官能化无机颗粒的步骤，所述阴离子聚合终止剂包含至少一个能够与所述颗粒的表面结合的基团; b）至少一种带有至少一个质子交换基团前体基团的单体进行阴离子聚合的步骤; c）将步骤a）中获得的颗粒与步骤b）中获得的聚合物接触的步骤，作为回报，所得颗粒是由所述聚合物官能化的颗粒，通过所述聚合物聚合物的反应性末端与至少一组上述终止剂; 和d）用于转化所述质子交换基团的前体基团的步骤。

6. 发明申请

US20130092873A1 METHOD FOR PREPARING A COMPOSITE MATERIAL COMPRISING A POLYMERIC MATRIX AND A FILLER CONSISTING IN ION EXCHANGE INORGANIC PARTICLES 有权
标题翻译：制备包含聚合物基质的复合材料的方法和包含在离子交换无机颗粒中的填料
公开(公告)号：US20130092873A1
公开(公告)日：2013-04-18
申请号：US13704524
申请日：2011-06-15
申请人： Pierrick Buvat , Philippe Mazabraud , Herve Galiano , Jannick Bigarre , Veronique Bounor-Legare , Frederick Niepceron , Jean-Francois Gerard
发明人： Pierrick Buvat , Philippe Mazabraud , Herve Galiano , Jannick Bigarre , Veronique Bounor-Legare , Frederick Niepceron , Jean-Francois Gerard
IPC分类号： H01M8/10
CPC分类号： H01M8/1072 , B01D67/0048 , B01D67/0079 , B01D69/148 , B01D71/027 , B01D71/32 , B01D71/82 , B01D2323/40 , B01D2325/42 , C08J5/2275 , C08J5/2281 , C08J2327/16 , C08J2327/20 , H01M8/1039 , H01M8/1048 , H01M8/1074 , Y02E60/523
摘要： The invention relates to a method for preparing a composite material comprising a polymeric matrix and a filler consisting in ion exchange inorganic particles, comprising a step for synthesis in situ of said particles within the polymeric matrix.
摘要翻译：本发明涉及一种用于制备复合材料的方法，所述复合材料包含聚合物基质和由离子交换无机颗粒组成的填料，包括用于在聚合物基体内原位合成所述颗粒的步骤。

7. 发明授权

US07973089B2 Membrane preparation method comprising the extrusion of a thermoplastic polymer bearing alkaline groupings 有权
标题翻译：膜制备方法包括挤出含有碱性基团的热塑性聚合物
公开(公告)号：US07973089B2
公开(公告)日：2011-07-05
申请号：US11886467
申请日：2006-03-09
申请人： Jean-Yves Sanchez , Cristina Iojoiu , Regis Mercier , Manuel Marechal , Nadia El Kissi , Herve Galiano , France Chabert
发明人： Jean-Yves Sanchez , Cristina Iojoiu , Regis Mercier , Manuel Marechal , Nadia El Kissi , Herve Galiano , France Chabert
IPC分类号： C08J5/20
CPC分类号： B01D67/0025 , B01D67/002 , B01D67/003 , B01D71/52 , B01D71/68 , B01D71/82 , B01D2323/12 , B01D2325/32 , C08J5/2256 , C08J2371/12 , C08L71/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/1083 , H01M2300/0082 , Y02P70/56
摘要： The invention relates to a process for the extrusion of thermoplastic polymers having alkaline ionic groups.The process consists in preparing a mixture composed of a thermoplastic polymer having alkaline ionic groups and a plasticizer, in extruding the mixture obtained to form a film; then in washing the film obtained in aqueous medium to remove said plasticizer(s). The plasticizer is chosen from non-volatile compounds which are stable with respect to the ionic groups of the polymer, which are soluble in water or in solvents that are miscible with water, said plasticizers being chosen from the compounds that react with the ionic group of the polymer via formation of a weak bond of the hydrogen bond-type, and the compounds that react with the ionic group of the polymer via formation of a strong bond, of the ionic bond-type.
摘要翻译：本发明涉及挤出具有碱性离子基团的热塑性聚合物的方法。该方法包括制备由具有碱性离子基团的热塑性聚合物和增塑剂组成的混合物，挤出获得的混合物以形成膜; 然后洗涤在水介质中获得的膜以除去所述增塑剂。增塑剂选自相对于聚合物的离子基团稳定的非挥发性化合物，其可溶于水或与水混溶的溶剂中，所述增塑剂选自与离子基团的离子基团反应的化合物通过形成氢键型的弱键的聚合物，以及通过形成强键与聚合物的离子基团反应的离子键型的化合物。

8. 发明申请

US20090203805A1 Membrane Preparation Method Comprising the Extrusion of a Thermoplastic Polymer Bearing Alkaline Groupings 有权
标题翻译：包含热塑性聚合物挤压的膜制备方法
公开(公告)号：US20090203805A1
公开(公告)日：2009-08-13
申请号：US11886467
申请日：2006-03-09
申请人： Jean-Yves Sanchez , Cristina Iojoiu , Regis Mercier , Manuel Marechal , Nadia El Kissi , Herve Galiano , France Chabert
发明人： Jean-Yves Sanchez , Cristina Iojoiu , Regis Mercier , Manuel Marechal , Nadia El Kissi , Herve Galiano , France Chabert
IPC分类号： C08J5/22
CPC分类号： B01D67/0025 , B01D67/002 , B01D67/003 , B01D71/52 , B01D71/68 , B01D71/82 , B01D2323/12 , B01D2325/32 , C08J5/2256 , C08J2371/12 , C08L71/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/1083 , H01M2300/0082 , Y02P70/56
摘要： The invention relates to a process for the extrusion of thermoplastic polymers having alkaline ionic groups.The process consists in preparing a mixture composed of a thermoplastic polymer having alkaline ionic groups and a plasticizer, in extruding the mixture obtained to form a film; then in washing the film obtained in aqueous medium to remove said plasticizer(s). The plasticizer is chosen from non-volatile compounds which are stable with respect to the ionic groups of the polymer, which are soluble in water or in solvents that are miscible with water, said plasticizers being chosen from the compounds that react with the ionic group of the polymer via formation of a weak bond of the hydrogen bond-type, and the compounds that react with the ionic group of the polymer via formation of a strong bond, of the ionic bond-type.
摘要翻译：本发明涉及挤出具有碱性离子基团的热塑性聚合物的方法。该方法包括制备由具有碱性离子基团的热塑性聚合物和增塑剂组成的混合物，挤出获得的混合物以形成膜; 然后洗涤在水介质中获得的膜以除去所述增塑剂。增塑剂选自相对于聚合物的离子基团稳定的非挥发性化合物，其可溶于水或与水混溶的溶剂中，所述增塑剂选自与离子基团的离子基团反应的化合物通过形成氢键型的弱键的聚合物，以及通过形成强键与聚合物的离子基团反应的离子键型的化合物。

9. 发明授权

US09065109B2 Method for preparing a composite material comprising a polymeric matrix and a filler consisting in ion exchange inorganic particles 有权
标题翻译：制备复合材料的方法，所述复合材料包含聚合物基质和由离子交换无机颗粒组成的填料
公开(公告)号：US09065109B2
公开(公告)日：2015-06-23
申请号：US13704524
申请日：2011-06-15
申请人： Pierrick Buvat , Philippe Mazabraud , Herve Galiano , Jannick Bigarre , Veronique Bounor-Legare , Frederick Niepceron , Jean-Francois Gerard
发明人： Pierrick Buvat , Philippe Mazabraud , Herve Galiano , Jannick Bigarre , Veronique Bounor-Legare , Frederick Niepceron , Jean-Francois Gerard
IPC分类号： H01M8/10 , B01D69/14 , C08J5/22 , B01D67/00 , B01D71/02 , B01D71/32 , B01D71/82
CPC分类号： H01M8/1072 , B01D67/0048 , B01D67/0079 , B01D69/148 , B01D71/027 , B01D71/32 , B01D71/82 , B01D2323/40 , B01D2325/42 , C08J5/2275 , C08J5/2281 , C08J2327/16 , C08J2327/20 , H01M8/1039 , H01M8/1048 , H01M8/1074 , Y02E60/523
摘要： The invention relates to a method for preparing a composite material comprising a polymeric matrix and a filler consisting in ion exchange inorganic particles, comprising a step for synthesis in situ of said particles within the polymeric matrix.
摘要翻译：本发明涉及一种用于制备复合材料的方法，所述复合材料包含聚合物基质和由离子交换无机颗粒组成的填料，包括用于在聚合物基体内原位合成所述颗粒的步骤。

10. 发明授权

US09181363B2 Process for preparing novel copolymers with a fluoropolymer backbone comprising polyoxyalkylene pendant chains 有权
标题翻译：用含有聚氧化烯侧链的含氟聚合物主链制备新型共聚物的方法
公开(公告)号：US09181363B2
公开(公告)日：2015-11-10
申请号：US13811027
申请日：2011-07-19
申请人： Herve Galiano , Bruno Ameduri , Jérôme Vergnaud
发明人： Herve Galiano , Bruno Ameduri , Jérôme Vergnaud
IPC分类号： C08F214/18 , C08F14/22 , C08F214/22 , C08F220/22 , C08F20/22 , C08F220/30
CPC分类号： C08F14/22 , C08F20/22 , C08F214/18 , C08F214/22 , C08F220/22 , C08F2220/306
摘要： The invention relates to novel copolymers and to an associated preparation method, comprising recurrent units bearing a pendant chain of the polyoxyalkylene type.
摘要翻译：本发明涉及新的共聚物和相关的制备方法，其包括具有聚氧化烯型侧链的反复单元。

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