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1. 发明授权

US07880040B2 Method for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US07880040B2
公开(公告)日：2011-02-01
申请号：US11592442
申请日：2006-11-03
申请人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Rajiv R. Singh , Haiyou Wang , Robert C. Johnson , Rajesh K. Dubey
发明人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Rajiv R. Singh , Haiyou Wang , Robert C. Johnson , Rajesh K. Dubey
IPC分类号： C07C19/08
CPC分类号： C07C17/25 , C07C21/18
摘要： Disclosed is a method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CFnCHmXa-m (I) to at least one compound of formula (II) CF3CZCHZ (II). where each X is independently Cl, I or Br; each Z is independently H or F; n is 1 or 2; m is 1, 2 or 3, provided that when n is 1, m is 1 or 2; a is 2 or 3, and a-m≧0. Certain embodiments include the step of reacting fluorinated C2 olefin, such as tetrafluoroethylene, with a C1 addition agent under conditions effective to produce a compound of formula (I).
摘要翻译：公开了一种制备氟化有机化合物的方法，包括氢氟丙烯，其优选包括将至少一种式（I）化合物：CF 3 CF n CH m X a-m（I）转化为至少一种式（II）CF 3 CZCHZ（II）化合物。其中每个X独立地为Cl，I或Br; 每个Z独立地为H或F; n为1或2; m为1,2或3，条件是当n为1时，m为1或2; a为2或3，a-m≥0。某些实施方案包括在有效产生式（I）化合物的条件下使氟化C 2烯烃如四氟乙烯与C1加成剂反应的步骤。

2. 发明授权

US07951982B2 Method for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US07951982B2
公开(公告)日：2011-05-31
申请号：US11592842
申请日：2006-11-03
申请人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Robert C. Johnson , Daniel C. Merkel
发明人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Robert C. Johnson , Daniel C. Merkel
IPC分类号： C07C21/18
CPC分类号： C07C17/25 , B01J23/02 , B01J23/44 , B01J23/755 , B01J23/78 , B01J23/83 , B01J35/06 , C07C17/00 , C07C17/269 , C07C21/18 , C07C19/08
摘要： Disclosed is a process for the preparation of fluorinated olefins. In preferred embodiments C3 olefins are produced by methods comprising contacting a compound of the Formula (I) C(R1aR2bR3c) (I) with a compound of Formula (II) C(R1aR2bR3c)Cn(R1aR2bR3c) II wherein R1a, R2b, and R3c are independently a hydrogen atom or a halogen selected from the group consisting of fluorine; chlorine, bromine and iodine, provided that the compound of formula I has at least three halogen substituents and that said at three halogen substituents comprise at least one fluorine; a, b and c are independently=0, 1, 2 or 3 and (a+b+c)=2 or 3; and n is 0 or 1, under conditions effective to produce at least one C3 fluoroolefin.
摘要翻译：公开了一种制备氟化烯烃的方法。在优选实施方案中，C3烯烃通过以下方法制备：包括使式（I）C（R 1a R 2b b C 3）（I）的化合物与式（II）的化合物C（R1aR2bR3c）Cn（R1aR2bR3c）II的化合物接触，其中R1a，R2b和R3c 独立地为氢原子或选自氟的卤素; 氯，溴和碘，条件是式I化合物具有至少三个卤素取代基，并且在三个卤素取代基上含有至少一个氟; a，b和c独立地为= 0,1,2或3，（a + b + c）= 2或3; 在有效产生至少一种C3氟代烯烃的条件下，n为0或1。

3. 发明授权

US08927791B2 Method for producing tetrafluoropropenes 有权
标题翻译：生产四氟丙烯的方法
公开(公告)号：US08927791B2
公开(公告)日：2015-01-06
申请号：US13073023
申请日：2011-03-28
申请人： Selma Bektesevic , Hsueh S. Tung , Haiyou Wang , Daniel C. Merkel , Robert C. Johnson
发明人： Selma Bektesevic , Hsueh S. Tung , Haiyou Wang , Daniel C. Merkel , Robert C. Johnson
IPC分类号： C07C17/00 , C07C17/25 , C07C19/08 , C07C21/18 , C07C17/21 , C07C17/087
CPC分类号： C07C17/21 , C07C17/087 , C07C17/25 , C07C19/10 , C07C19/08 , C07C21/18
摘要： The current invention relates to a process for making a tetrafluoropropene using a tetrafluorochloropropane and/or a pentafluoropropane as starting or intermediate reagents. More specifically, though not exclusively, the present invention relates to a novel method for preparing a tetrafluoropropene by dehydrohalogenating a starting or intermediate tetrafluorochloropropane and/or pentafluoropropane material in the presence of a caustic solution at a temperature range greater than 40° C. and less than or equal to 80° C.
摘要翻译：本发明涉及使用四氟氯丙烷和/或五氟丙烷作为起始剂或中间体试剂制备四氟丙烯的方法。更具体地说，本发明涉及一种通过在苛性碱溶液存在下，在大于40℃和更低的温度范围内将起始或中间四氟氯丙烷和/或五氟丙烷物质脱卤化氢来制备四氟丙烯的新方法超过或等于80℃

4. 发明申请

US20110270000A1 METHOD FOR PRODUCING TETRAFLUOROPROPENES 有权
标题翻译：生产四氢呋喃的方法
公开(公告)号：US20110270000A1
公开(公告)日：2011-11-03
申请号：US13073023
申请日：2011-03-28
申请人： Selma Bektesevic , Hsueh S. Tung , Haiyou Wang , Daniel C. Merkel , Robert C. Johnson
发明人： Selma Bektesevic , Hsueh S. Tung , Haiyou Wang , Daniel C. Merkel , Robert C. Johnson
IPC分类号： C07C17/23
CPC分类号： C07C17/21 , C07C17/087 , C07C17/25 , C07C19/10 , C07C19/08 , C07C21/18
摘要： The current invention relates to a process for making a tetrafluoropropene using a tetrafluorochloropropane and/or a pentafluoropropane as starting or intermediate reagents. More specifically, though not exclusively, the present invention relates to a novel method for preparing a tetrafluoropropene by dehydrohalogenating a starting or intermediate tetrafluorochloropropane and/or pentafluoropropane material in the presence of a caustic solution at a temperature range greater than 40° C. and less than or equal to 80° C.
摘要翻译：本发明涉及使用四氟氯丙烷和/或五氟丙烷作为起始剂或中间体试剂制备四氟丙烯的方法。更具体地说，本发明涉及一种通过在苛性碱溶液存在下，在大于40℃和更低的温度范围内将起始或中间四氟氯丙烷和/或五氟丙烷物质脱卤化氢来制备四氟丙烯的新方法超过或等于80℃

5. 发明授权

US07026521B1 Methane and methyl chloride as selective reducing agent in the transformation of hydrochlorofluorocarbons or chlorofluorocarbons to hydrofluorocarbons 失效
标题翻译：甲烷和氯甲烷作为选择性还原剂，在氢氯氟烃或氯氟烃转化为氢氟碳化合物
公开(公告)号：US07026521B1
公开(公告)日：2006-04-11
申请号：US11091311
申请日：2005-03-28
申请人： Sudip Mukhopadhyay , HsuehSung Tung , Daniel C. Merkel , Robert C. Johnson
发明人： Sudip Mukhopadhyay , HsuehSung Tung , Daniel C. Merkel , Robert C. Johnson
IPC分类号： C07C17/00
CPC分类号： B01J23/04 , B01J23/02 , B01J37/0201 , C07C17/23 , C07C19/08
摘要： A gas phase reaction process for producing a hydrofluorocarbon from a hydrochlorofluorocarbon or chlorofluorocarbon reactant by contacting, in the presence of a catalyst, the hydrochlorofluorocarbon or chlorofluorocarbon reactant with a reducing agent selected from methane, methyl chloride and mixtures thereof, to produce the hydrofluorocarbon.
摘要翻译：一种用于由氢氯氟烃或氯氟烃反应物生产氢氟烃的气相反应方法，其中在催化剂存在下，将氢氯氟烃或氯氟烃反应物与选自甲烷，氯甲烷及其混合物的还原剂接触，制备氢氟烃。

6. 发明申请

US20090099396A1 PROCESS FOR SYNTHESIS OF FLUORINATED OLEFINS 有权
标题翻译：合成氟化烯烃的方法
公开(公告)号：US20090099396A1
公开(公告)日：2009-04-16
申请号：US12249958
申请日：2008-10-12
申请人： Sudip Mukhopadhyay , Cheryl L. Bortz , Barbara A. Light , Cheryl L. Cantlon , Robert C. Johnson
发明人： Sudip Mukhopadhyay , Cheryl L. Bortz , Barbara A. Light , Cheryl L. Cantlon , Robert C. Johnson
IPC分类号： C07C17/20
CPC分类号： C07C17/21 , C07C17/23 , C07C17/25 , C07C21/18 , C07C19/08
摘要： Disclosed is a process for the synthesis of fluorinated olefins, and in particularly preferred embodiments tetrafluorinated olefins having F on an unsaturated, non-terminal carbon, such as 2,3,3,3-tetrafluoropropene. The preferred processes of the present invention in accordance with one embodiment generally comprise: (a) reacting a compound of formula (I) X1X2 (I) with a compound of formula (II) CX1X2X3CX1═CX1X2 (II) to produce a reaction product comprising a compound of formula (III) CF3CHX1CH2X2 (III), and (b) exposing said compound of formula (III) to reaction conditions effective to convert said compound of formula (III) to a compound of formula (IV) CF3CZ=CH2 (IV) wherein X1, X2, and X3 are each independently selected from the group consisting of hydrogen, chlorine, bromine, fluorine and iodine, provided that X1 and X2 in formula (I) are not both hydrogen and Z is Cl, I, Br, or F.
摘要翻译：公开了用于合成氟化烯烃的方法，特别优选的实施方案中，在不饱和的非末端碳上具有F的四氟化烯烃如2,3,3,3-四氟丙烯。根据一个实施方案的本发明的优选方法通常包括：（a）使式（I）化合物<？in-line-formula description =“In-Line Formulas”end =“lead”→> X1X2 I）<？in-line-formula description =“In-line formula”end =“tail”？>与式（II）的化合物<？in-line-formula description =“In-line Formulas”end =“ 引线“→CX1X2X3CX1-CX1X2（II）<？在线公式描述=”内联式“末端=”尾“→产生包含式（III）化合物的反应产物 -formulae description =“In-line Formulas”end =“lead”？> CF3CHX1CH2X2（III）和<？in-line-formula description =“In-line Formulas”end =“tail”？>（b）式（III）化合物与有效将所述式（III）化合物转化成式（IV）化合物的反应条件<β在线式描述=“在线式”末端=“铅”→CF 3 CZ = CH2（IV）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中X1，X2和X3各自独立式（I）中的X 1和X 2不同时为氢，Z为Cl，I，Br或F时，选自氢，氯，溴，氟和碘组成的组。

7. 发明授权

US09079818B2 Process for synthesis of fluorinated olefins 有权
标题翻译：合成氟化烯烃的方法
公开(公告)号：US09079818B2
公开(公告)日：2015-07-14
申请号：US12249958
申请日：2008-10-12
申请人： Sudip Mukhopadhyay , Cheryl L. Bortz , Barbara A. Light , Cheryl L. Cantlon , Robert C. Johnson
发明人： Sudip Mukhopadhyay , Cheryl L. Bortz , Barbara A. Light , Cheryl L. Cantlon , Robert C. Johnson
IPC分类号： C07C21/00 , C07C17/00 , C07C17/21 , C07C17/23 , C07C17/25 , C07C21/18
CPC分类号： C07C17/21 , C07C17/23 , C07C17/25 , C07C21/18 , C07C19/08
摘要： Disclosed is a process for the synthesis of fluorinated olefins, and in particularly preferred embodiments tetrafluorinated olefins having F on an unsaturated, non-terminal carbon, such as 2,3,3,3-tetrafluoropropene. The preferred processes of the present invention in accordance with one embodiment generally comprise: (a) reacting a compound of formula (I) X1X2 (I) with a compound of formula (II) CX1X2X3CX1═CX1X2 (II) to produce a reaction product comprising a compound of formula (III) CF3CHX1CH2X2 (III), and (b) exposing said compound of formula (III) to reaction conditions effective to convert said compound of formula (III) to a compound of formula (IV) CF3CZ═CH2 (IV) wherein X1, X2, and X3 are each independently selected from the group consisting of hydrogen, chlorine, bromine, fluorine and iodine, provided that X1 and X2 in formula (I) are not both hydrogen and Z is Cl, I, Br, or F.
摘要翻译：公开了用于合成氟化烯烃的方法，特别优选的实施方案中，在不饱和的非末端碳上具有F的四氟化烯烃如2,3,3,3-四氟丙烯。根据一个实施方案的本发明的优选方法通常包括：（a）使式（I）X1X2（I）化合物与式（II）化合物CX1X2X3CX1 = CX1X2（II）反应以产生反应产物，其包含式（III）化合物，CF 3 CHX 1 CH 2 X 2（III）的化合物，和（b）将式（III）化合物暴露于有效将式（III）化合物转化成式（IV）化合物的反应条件：CF 3 CZ = CH 2 ）其中X1，X2和X3各自独立地选自氢，氯，溴，氟和碘，条件是式（I）中的X1和X2不同时为氢，Z为Cl，I，Br，或F.

8. 发明授权

US08071825B2 Method for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US08071825B2
公开(公告)日：2011-12-06
申请号：US12185042
申请日：2008-08-01
申请人： Robert C. Johnson , Hsueh S. Tung , Daniel C. Merkel
发明人： Robert C. Johnson , Hsueh S. Tung , Daniel C. Merkel
IPC分类号： C07C17/00
CPC分类号： C07C17/25 , C07C17/04 , C07C17/087 , C07C17/204 , C07C17/206 , C07C17/21 , C07C17/23 , C07C21/18 , C07C19/01 , C07C19/10 , C07C19/08 , C07C21/073
摘要： Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF═CH2 (1234yf). In certain preferred embodiments the processes comprise first exposing a compound of Formula (IA) C(X)2═CClC(X)3 (IA) where each X is independently F, Cl or H, preferably CCl2═CClCH2Cl, to one or more sets of reaction conditions, but preferably a substantially single set of reaction conditions, effective to produce at least one chlorofluoropropane, preferably in accordance with Formula (IB): CF3CClX′C(X′)3 Formula (IB) where each X′ is independently F, Cl or H, and then exposing the compound of Formula (IB) to one or more sets of reaction conditions, but preferably a substantially single set of reaction conditions, effective to produce a compound of Formula (II) CF3CF═CHZ (II) where Z is H, F, Cl, I or Br.
摘要翻译：公开了用于生产氟化烯烃的方法，优选适于CF 3CF≡CH2（1234yf）的商业化。在某些优选实施方案中，方法包括首先将式（IA）C（X）2 = CClC（X）3（IA）的化合物暴露于其中每个X独立地为F，Cl或H，优选CCl 2 = CClCH 2 Cl，反应条件，但优选基本上单一组反应条件，有效产生至少一种氯氟丙烷，优选按照式（IB）：CF 3 CClX'C（X'）3式（IB）其中每个X'独立地为 F，Cl或H，然后将式（IB）化合物暴露于一组或多组反应条件，但优选基本上单组的反应条件，有效产生式（II）化合物CF 3 CF = CHZ（II ）其中Z是H，F，Cl，I或Br。

9. 发明申请

US20090030247A1 METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 有权
标题翻译：生产氟化有机化合物的方法
公开(公告)号：US20090030247A1
公开(公告)日：2009-01-29
申请号：US12185042
申请日：2008-08-01
申请人： Robert C. Johnson , Hsueh S. Tung , Daniel C. Merkel
发明人： Robert C. Johnson , Hsueh S. Tung , Daniel C. Merkel
IPC分类号： C07C21/18
CPC分类号： C07C17/25 , C07C17/04 , C07C17/087 , C07C17/204 , C07C17/206 , C07C17/21 , C07C17/23 , C07C21/18 , C07C19/01 , C07C19/10 , C07C19/08 , C07C21/073
摘要： Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF═CH2 (1234yf). In certain preferred embodiments the processes comprise first exposing a compound of Formula (IA) C(X)2═CClC(X)3 (IA) where each X is independently F, Cl or H, preferably CCl2═CClCH2Cl, to one or more sets of reaction conditions, but preferably a substantially single set of reaction conditions, effective to produce at least one chlorofluoropropane, preferably in accordance with Formula (IB): CF3CClXC(X)3 Formula (IB) where each X′ is independently F, Cl or H, and then exposing the compound of Formula (IB) to one or more sets of reaction conditions, but preferably a substantially single set of reaction conditions, effective to produce a compound of Formula (II) CF3CF═CHZ (II) where Z is H, F, Cl, I or Br.
摘要翻译：公开了用于生产氟化烯烃的方法，优选适于商业化CF 3 CF-CH 2（1234yf）。在某些优选实施方案中，所述方法包括首先将式（IA）化合物<？在线公式描述=“在线式”中的结束=“铅”→C（X）2 -CClC（X）3 IA）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中每个X独立地为F，Cl或H，优选为CCl 2 -CClCH 2 Cl，一个或多个反应条件，但优选基本上单组的反应条件，有效地产生至少一种氯氟丙烷，优选根据式（IB）：<？in-line-formula description =“In-line formula”end =“lead”？> CF 3 CClXC（ X）3式（IB）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中每个X'独立地为F，Cl或H，然后将式）至一组或多组反应条件，但优选基本上单一组的反应条件，有效产生式（II）化合物<？在线公式描述=“在线式”末端=“铅” > CF 3 CF-CHZ（II）<αin-li ne-formula description =“In-line Formulas”end =“tail”？>其中Z是H，F，Cl，I或Br。

10. 发明授权

US08455704B2 Method for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US08455704B2
公开(公告)日：2013-06-04
申请号：US13287199
申请日：2011-11-02
申请人： Robert C. Johnson , Hsueh S. Tung , Daniel C. Merkel
发明人： Robert C. Johnson , Hsueh S. Tung , Daniel C. Merkel
IPC分类号： C07C17/00
CPC分类号： C07C17/25 , C07C17/04 , C07C17/087 , C07C17/204 , C07C17/206 , C07C17/21 , C07C17/23 , C07C21/18 , C07C19/01 , C07C19/10 , C07C19/08 , C07C21/073
摘要： Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF═CH2 (1234yf). In certain preferred embodiments the processes comprise first exposing a compound of Formula (IA) C(X)2═CClC(X)3 (IA) where each X is independently F, Cl or H, preferably CCl2═CClCH2Cl, to one or more sets of reaction conditions, but preferably a substantially single set of reaction conditions, effective to produce at least one chlorofluoropropane, preferably in accordance with Formula (IB): CF3CClX′C(X′)3 Formula (IB) where each X′ is independently F, Cl or H, and then exposing the compound of Formula (IB) to one or more sets of reaction conditions, but preferably a substantially single set of reaction conditions, effective to produce a compound of Formula (II) CF3CF═CHZ (II) where Z is H, F, Cl, I or Br.
摘要翻译：公开了用于制备氟化烯烃的方法，优选适于商业化CF 3 CF = CH 2（1234yf）。在某些优选实施方案中，该方法包括首先将式（IA）C（X）2 = CClC（X）3（IA）的化合物暴露于其中每个X独立地为F，Cl或H，优选CCl 2 = CClCH 2 Cl，反应条件组，但优选基本上单一组的反应条件，有效产生至少一种氯氟丙烷，优选按照式（IB）：CF 3 CClX'C（X'）3式（IB），其中每个X'独立地为F ，然后将式（IB）化合物暴露于一组或多组反应条件，但优选基本上单一组的反应条件，有效地制备式（II）化合物，CF 3 CF = CHZ（II）其中Z是H，F，Cl，I或Br。

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