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    • 3. 发明申请
    • NONVOLATILE SEMICONDUCTOR MEMORY DEVICE AND METHOD FOR MANUFACTURING THE SAME
    • 非易失性半导体存储器件及其制造方法
    • US20080116507A1
    • 2008-05-22
    • US11857722
    • 2007-09-19
    • Tsunehiro INOKouichi Muraoka
    • Tsunehiro INOKouichi Muraoka
    • H01L29/792
    • H01L21/28282H01L29/513H01L29/792
    • A nonvolatile semiconductor memory device includes: a source region and a drain region formed at a distance from each other in a semiconductor substrate; a tunnel insulating film formed on the semiconductor substrate between the source region and the drain region; a charge storage film formed on the tunnel insulating film; a first alumina layer formed on the charge storage film, and having a first impurity element added thereto, the first impurity element having an octacoordinate ion radius of 63 pm or greater, the first impurity element having a concentration distribution in a layer thickness direction of the first alumina layer that becomes the largest in a region close to the side of the charge storage film; a second alumina layer formed on the first alumina layer, and not having the first impurity element added thereto; and a control gate electrode formed on the second alumina layer.
    • 非易失性半导体存储器件包括:在半导体衬底中形成为彼此间隔一定距离的源极区域和漏极区域; 在所述源极区域和所述漏极区域之间形成在所述半导体衬底上的隧道绝缘膜; 形成在隧道绝缘膜上的电荷存储膜; 形成在所述电荷存储膜上的第一氧化铝层,并且具有添加了第一杂质元素的第一杂质元素,所述第一杂质元素的八面体离子半径为63μm以上,所述第一杂质元素具有层厚度方向的浓度分布 在靠近电荷存储膜的一侧的区域中成为最大的第一氧化铝层; 形成在第一氧化铝层上的第二氧化铝层,并且不具有添加第一杂质元素的第二氧化铝层; 以及形成在第二氧化铝层上的控制栅电极。
    • 4. 发明申请
    • NONVOLATILE SEMICONDUCTOR MEMORY DEVICE
    • 非易失性半导体存储器件
    • US20090057753A1
    • 2009-03-05
    • US12193251
    • 2008-08-18
    • Tsunehiro INO
    • Tsunehiro INO
    • H01L29/792
    • H01L29/792H01L21/28282H01L27/11568H01L29/513
    • A nonvolatile semiconductor memory device includes a source region and a drain region spaced from each other in a surface of a semiconductor layer, a tunnel insulating film provided on the semiconductor layer between the source region and the drain region, a charge storage film provided on the tunnel insulating film, a block insulating film provided on the charge storage film, and a control gate electrode provided on the block insulating film. The block insulating film is made of (Rm1−xLnx)2−yAlyO3+δ, where Ln is one or more selected from Pr, Tb, Ce, Yb, Eu, and Sm, Rm is one or more selected from La, Nd, Gd, Dy, Ho, Er, Tm, Lu, Y, and Sc, 0
    • 非易失性半导体存储器件包括在半导体层的表面中彼此间隔开的源极区域和漏极区域,设置在源极区域和漏极区域之间的半导体层上的隧道绝缘膜,设置在源极区域和漏极区域之间的电荷存储膜 隧道绝缘膜,设置在电荷存储膜上的块绝缘膜,以及设置在块绝缘膜上的控制栅电极。 块绝缘膜由(Rm1-xLnx)2-yAlyO3 + delta制成,其中Ln是选自Pr,Tb,Ce,Yb,Eu和Sm中的一种或多种,​​Rm是选自La,Nd, Gd,Dy,Ho,Er,Tm,Lu,Y和Sc,0
    • 7. 发明申请
    • LANTHANOID ALUMINATE FILM FABRICATION METHOD
    • 兰蔻酸铝薄膜制造方法
    • US20110284365A1
    • 2011-11-24
    • US13192687
    • 2011-07-28
    • Tsunehiro INOAkira Takashima
    • Tsunehiro INOAkira Takashima
    • C23C14/34
    • C23C14/3464C23C14/08
    • A method of fabricating by co-sputtering deposition a lanthanoid aluminate film with enhanced electrical insulativity owing to suppression of deviation in composition of the film is disclosed. Firstly within a vacuum chamber, hold two separate targets, one of which is made of lanthanoid aluminate (LnAlO3) and the other of which is made of aluminum oxide (Al2O3). Then, transport and load a substrate into the vacuum chamber. Next, introduce a chosen sputtering gas into this chamber. Thereafter, perform sputtering of both the targets at a time to thereby form a lanthanoid aluminate film on the substrate surface. This film is well adaptable for use as ultra-thin high dielectric constant (high-k) gate dielectrics in highly miniaturized metal oxide semiconductor (MOS) transistors.
    • 公开了一种通过共溅射沉积制造具有增强的电绝缘性的镧系铝酸盐膜的方法,这是因为抑制了膜的组成偏差。 首先在真空室内保持两个独立的靶,其中一个靶由铝酸镧(LnAlO3)制成,另一个由氧化铝(Al2O3)制成。 然后,将基板输送并加载到真空室中。 接下来,将选择的溅射气体引入该室。 此后,一次进行两个靶的溅射,从而在基板表面上形成镧系铝酸盐膜。 该薄膜适用于高度小型化的金属氧化物半导体(MOS)晶体管中的超薄高介电常数(高k)栅极电介质。