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    • 8. 发明授权
    • Articles having a polymeric shell and method for preparing same
    • 具有聚合物外壳的制品及其制备方法
    • US5443727A
    • 1995-08-22
    • US122807
    • 1993-09-16
    • David R. Gagnon
    • David R. Gagnon
    • A23L3/3436A61K9/70A61K47/48B01D67/00B01D69/14B01D71/38B01J20/32B41M5/52B41M7/00B65D65/38B65D81/26C04B41/48C04B41/83C09D129/04C12N11/08H01M2/16
    • C04B41/83A23L3/3436A61K47/48007A61K9/7023B01D67/0088B01D69/141B01D71/38B01J20/3204B01J20/321B01J20/3212B01J20/3272B01J20/3291B41M5/5254B41M7/00B65D65/38B65D81/267C04B41/4869C09D129/04C12N11/08H01M2/1653H01M2/1666H01M2/1686Y10T428/1341
    • Articles having a complex geometric configuration have hydrophilicity imparted to at least a portion of surfaces of the articles while substantially retaining the complex geometric configuration. The hydrophilicity is imparted by an extremely thin, self-interlocking shell of tactic, hydrophilic poly(vinyl alcohol) enveloping the surfaces. A tactic poly(vinyl alcohol) precursor applied to surfaces of the supporting structure is reacted in situ on the surfaces with a hydrolysis reagent to prepare the tactic, hydrophilic poly(vinyl alcohol) shell. The article having the hydrophilic shell is highly resistant to solvent washout. Hydrophilicity and hydrophobicity can be reversibly provided on regio-specific surfaces of the article. Articles in the form of membranes useful as filters, residue barriers for electroplating devices, separators for electrochemical cells, and drug delivery device components are also described. Membranes to form permanent and undistorted images, and methods of preparing such images from image-forming substances in receptive media are also provided. Hydrophilic porous supporting structures loaded with an enzyme system which catalyzes a reaction of a substrate, oxygen, and if necessary, water or moisture to consume oxygen are also described for oxygen scavenging in packages containing oxygen sensitive products.
    • 具有复杂几何构型的制品具有赋予制品表面的至少一部分的亲水性,同时基本保持复杂的几何构型。 亲水性通过非常薄的自相互作用的外壳(包括表面的亲水性聚(乙烯醇))赋予。 施加到支撑结构表面的策略性聚(乙烯醇)前体在表面上与水解试剂原位反应,制备了亲水性的聚(乙烯醇)壳。 具有亲水壳的制品对溶剂冲洗具有高度抗性。 亲水性和疏水性可以在制品的区域特异性表面上可逆地提供。 还描述了可用作过滤器的膜形式的制品,用于电镀装置的残留屏障,用于电化学电池的隔板和药物递送装置部件。 还提供了形成永久和未失真图像的膜以及从接受介质中的成像物质制备这种图像的方法。 还描述了负载催化底物,氧气和必要时的水或水分消耗氧气的酶系统的亲水性多孔支持结构,用于在含有氧敏感产物的包装中进行氧清除。