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    • 6. 发明授权
    • Method and apparatus for microwave assisted high throughput high pressure chemical synthesis
    • 微波辅助高通量高压化学合成方法和装置
    • US07816633B2
    • 2010-10-19
    • US11853102
    • 2007-09-11
    • Wyatt P. Hargett, Jr.James E. Thomas
    • Wyatt P. Hargett, Jr.James E. Thomas
    • H05B6/64B01J19/08
    • H05B6/806B01J19/0046B01J19/126B01J2219/00162B01J2219/002B01J2219/00231B01J2219/0024B01J2219/00283B01J2219/0034B01J2219/00353B01J2219/00477B01J2219/00495B01J2219/00601B01J2219/00689B01J2219/00691B01J2219/0869B01J2219/1215B01J2219/1239B01J2219/1275C40B60/14H05B6/6408
    • A method and associated instrument are disclosed for increasing the sequential rate at which a series of microwave assisted chemical reactions that potentially generate high pressure can be carried out. The method includes the steps of opening a pressure-resistant valve on a microwave-transparent pressure-resistant vessel to define a unpressurized pathway through the valve into the vessel, inserting a tube through the pathway in the valve and into the vessel, transferring at least one composition into the vessel through the tube, removing the tube from the vessel and from the pathway in the valve, closing the valve to seal the vessel against pressure release, and exposing the vessel and its contents to microwave radiation. The instrument includes a source of microwave radiation, a cavity in microwave communication with the source, an attenuator that forms at least a portion of the cavity, a pressure-resistant microwave-transparent reaction vessel having portions in the cavity and portions in the attenuator, a pressure-resistant valve on the mouth of the vessel, a reciprocating tube for passing through the valve and into the vessel when the valve is open, and means for mechanically inserting and retracting the tube through the valve and into the vessel when the vessel is in the cavity and the attenuator.
    • 公开了一种方法和相关联的仪器,用于增加可以进行可能产生高压的一系列微波辅助化学反应的顺序速率。 该方法包括以下步骤:在微波透明耐压容器上打开耐压阀,以限定通过阀进入容器的非加压路径,将管穿过阀中的通道插入容器中,至少转移 一个组合物通过管子进入容器,从容器中取出管子并从阀门中的通道中取出管子,关闭阀门以密封容器以抵抗压力释放,并将容器及其内容物暴露于微波辐射。 仪器包括微波辐射源,与源极微波连通的空腔,形成空腔的至少一部分的衰减器,具有空腔中的部分和衰减器中的部分的耐压微波透明反应容器, 容器口上的耐压阀,当阀打开时通过阀门并进入容器的往复式管,以及用于当管是容器时通过阀机械地插入和收回管并进入容器的装置 在腔和衰减器中。