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    • 8. 发明授权
    • Cobalt bearing polymeric compositions
    • 含钴聚合物组合物
    • US08425997B2
    • 2013-04-23
    • US13063275
    • 2009-09-14
    • Eddy ClauwaertBert-Jan Kamphuis
    • Eddy ClauwaertBert-Jan Kamphuis
    • B32B1/08B32B1/00C08G79/00C08L85/00
    • C08K5/55C08J5/10C08J2321/00C08K5/098C08K5/42C08L7/00C08L9/00C08L21/00C08L59/00C08L85/00Y10T428/1352Y10T428/139C08L87/00C08L2666/14
    • The invention relates to polymeric cobalt bearing compounds, in particular for use as metal-rubber adhesion promoters (RAPs) in tires, belts and hoses. Known active substances are a.o. cobalt stearates, naphthenates, resinates, decanoates, boro-decanoates and many other forms of acylates. While these substances appear to enhance the metal-rubber adhesion, all of them also come with significant drawbacks, a.o. linked to the relatively high bioavailability of cobalt in these substances. The invention concerns more particularly a polymer comprising Co-carboxylate sequences, with a Co content of at least 3% by weight, and with a mean molecular weight of more than 2000. Several synthesis methods, allowing to reach relatively high Co concentrations in the polymer, illustrate the invention. The invented polymers show a strongly reduced bioavailability of Co compared to currently available products, as demonstrated by aqueous leaching tests. As RAPs, they perform similarly to commercial products, as shown by pullout tests.
    • 本发明涉及聚合钴载体化合物,特别是用作轮胎,带和软管中的金属橡胶粘合促进剂(RAP)。 已知的活性物质是a.o. 硬脂酸钴,环烷酸盐,树脂酸盐,癸酸盐,硼酸癸酯和许多其它形式的酰化物。 虽然这些物质似乎增强了金属 - 橡胶的附着力,但它们都具有显着的缺点。 与这些物质中钴的相对高的生物利用度有关。 本发明更具体地涉及包含Co-羧酸酯序列的聚合物,Co含量为至少3重量%,平均分子量大于2000.几种合成方法允许在聚合物中达到较高的Co浓度 说明本发明。 与目前可获得的产品相比,本发明的聚合物显示出强烈降低的Co的生物利用度,如通过含水浸出试验所证实的。 作为RAP,它们与商业产品类似,如拉出测试所示。
    • 10. 发明授权
    • Coating compositions containing ethylene-acrylic acid copolymers with polyamide grafts as rheology modifiers
    • 含有乙烯 - 丙烯酸共聚物与聚酰胺接枝物作为流变改性剂的涂料组合物
    • US06310127B1
    • 2001-10-30
    • US08572193
    • 1995-12-14
    • Michael Jablon
    • Michael Jablon
    • C08K504
    • C08G81/028C08L87/00C09D5/04C09D7/45C09D7/47C09D7/65
    • An improved coating composition having one or more polymeric binders dispersed in a liquid medium, wherein the improvement comprises an anti-sag and anti-settling effective amount of a copolymer comprising a polymeric backbone comprising recurring monomeric units derived from monomers selected from the group consisting of one or more &agr;-olefins and one or more unsaturated carboxylic acids, said backbone having grafted thereto, by a covalent amide linkage, one or more polymeric grafts comprising at least one recurring monomeric unit selected from the group consisting of: —NHC(O)RC(O)NHR1 and —NH—R—C(O)— or a combination thereof, wherein R is an alkylene group of at least about 2 carbon atoms, and R1 is R or aryl.
    • 一种改进的涂料组合物,其具有分散在液体介质中的一种或多种聚合物粘合剂,其中所述改进包括抗流挂和抗沉降有效量的共聚物,所述共聚物包含聚合物主链,其包含衍生自选自以下的单体的重复单体单元: 一种或多种α-烯烃和一种或多种不饱和羧酸,所述骨架通过共价酰胺键接枝到其上,一个或多个聚合物接枝物包含至少一个选自以下的重复单体单元:-NHC(O) RC(O)NHR1和-NH-RC(O) - 或其组合,其中R是至少约2个碳原子的亚烷基,R 1是R或芳基。