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    • 9. 发明申请
    • COMPOSITE PAPER HAVING OIL RESISTANCE
    • 具有耐油性的复合纸
    • US20160130763A1
    • 2016-05-12
    • US14894797
    • 2014-05-30
    • KURARAY CO., LTD.
    • Masako KAWAGOEYosuke KUMAKI
    • D21H19/12
    • D21H19/12D21H19/00D21H19/20D21H19/22D21H19/38D21H19/40D21H19/60D21H19/76D21H21/16D21H27/10C08F216/06C08F210/02
    • The present invention addresses the problem of providing a composite paper which exhibits excellent oil resistance, water vapor permeability, and water resistance even when hot and oily food is wrapped therein. The above problem can be solved by using a composite paper comprising an oil-resistant layer formed on at least one surface of a base paper, wherein the oil-resistant layer comprises a vinyl alcohol polymer (A) having a content of ethylene units of 2 to 10 mol %, a viscosity-average degree of polymerization of 300 to 2000, a saponification degree of 95 to 99.5 mol %, a total content of carboxyl groups and lactone rings of 0.02 to 3 mol %, a melting point of 180 to 230° C., a content of 1,2-glycol bonds of 1.2 to 2 mol %, and a molar fraction of central hydroxyl groups in chains of three consecutive hydroxyls by a triad expression relative to vinyl alcohol units of 65 to 98 mol %, the base paper has an air permeability resistance of 1000 seconds or less and a bulk density of 0.5 to 1.0 g/cm3, and the oil-resistant layer is formed in an amount of 0.1 to 10.0 g/m2 in terms of dry mass. The oil-resistant layer may also contain a fluorine compound (B), a layered inorganic compound (C) having an average aspect ratio of 20 to 1000, a fatty acid sizing agent (D), or a cross-linking agent (E).
    • 本发明解决了提供一种复合纸的问题,该复合纸即使在热油和油性食品被包裹时也显示出优异的耐油性,水蒸气透过性和耐水性。 上述问题可以通过使用包含在原纸的至少一个表面上形成的耐油层的复合纸来解决,其中耐油层包含乙烯单元含量为2的乙烯醇聚合物(A) 至10摩尔%,粘均聚合度为300〜2000,皂化度为95〜99.5摩尔%,羧基和内酯环的总含量为0.02〜3摩尔%,熔点为180〜230 ℃,1,2-二醇键的含量为1.2〜2摩尔%,三个连续羟基的链中的中心羟基的摩尔分数相对于乙烯醇单元为65〜98摩尔%,通过三联体表示, 原纸的透气阻力为1000秒以下,堆密度为0.5〜1.0g / cm 3,耐油层的干燥质量为0.1〜10.0g / m 2。 耐油层还可以含有氟化合物(B),平均长径比为20〜1000的层状无机化合物(C),脂肪酸上浆剂(D)或交联剂(E) 。