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1. 发明授权

US5329026A Process for preparation of 2-substituted 1,4-naphthoquinone 失效
标题翻译： 2-取代的1,4-萘醌的制备方法
公开(公告)号：US5329026A
公开(公告)日：1994-07-12
申请号：US618941
申请日：1990-11-28
申请人： Noboru Sugishima , Noriaki Ikeda , Yasushi Fujii , Ryuji Aoki , Yumi Hatta
发明人： Noboru Sugishima , Noriaki Ikeda , Yasushi Fujii , Ryuji Aoki , Yumi Hatta
IPC分类号： C07C46/02 , C07C46/04 , C07C46/10 , C07C49/675 , C07C49/697 , C07C50/10 , C07C50/24 , C07C66/02 , C07C205/46 , C07C205/47 , C07C323/22 , C07C50/18
CPC分类号： C07C323/22 , C07C201/12 , C07C303/32 , C07C46/02 , C07C46/04 , C07C46/10 , C07C49/675 , C07C49/697 , C07C50/10 , C07C50/24 , C07C51/353 , C07C66/02 , C07C2102/10 , C07C2103/22 , C07C2103/24
摘要： A process for preparation of a 2-substituted-1,4-naphthoquinone which comprises oxidizing a 2-substituted naphthalene to obtain reaction products comprising a 2-substituted-1,4-naphthoquinone and a 6-substituted-1,4-naphthoquinone; adding a diene compound to the reaction products and heating the mixture to form a Diels-Alder reaction adduct between the diene compound and the 6-substituted-1,4-naphthoquinone in the reaction products; and separating the 2-substituted-1,4-naphthoquinone from the adduct.
摘要翻译：一种2-取代-1,4-萘醌的制备方法，其包括将2-取代萘氧化得到包含2-取代-1,4-萘醌和6-取代-1,4-萘醌的反应产物; 向反应产物中加入二烯化合物并加热混合物以在反应产物中的二烯化合物和6-取代的-1,4-萘醌之间形成Diels-Alder反应加合物; 并从加合物中分离2-取代的-1,4-萘醌。

2. 发明授权

US4892686A Process for the preparation of 1-nitroanthraquinone 失效
标题翻译：制备1-硝基蒽醌的方法
公开(公告)号：US4892686A
公开(公告)日：1990-01-09
申请号：US275238
申请日：1988-11-22
申请人： Walter Fischer , Tibor Somlo
发明人： Walter Fischer , Tibor Somlo
IPC分类号： B01J21/02 , B01J27/236 , B01J31/04 , C07B61/00 , C07C67/00 , C07C201/00 , C07C201/12 , C07C205/47
CPC分类号： C07C205/47 , C07C201/12 , C07C201/16 , C07C2103/24
摘要： A process for the preparation of 1-nitroanthraquinone by oxidising 1-nitro-5,8,11,12-tetrahydroanthraquinone with oxygen, inorganic peroxo compounds or metal oxides.
摘要翻译：通过用氧，无机过氧化合物或金属氧化物氧化1-硝基-5,8,11,12-四氢蒽醌来制备1-硝基蒽醌的方法。

3. 发明授权

US4259248A Process for the preparation of mixtures of dinitroanthraquinones with a high content of 1,5- and 1,8- dinitroanthraquinone 失效
标题翻译：制备二硝基蒽醌与高含量1,5-和1,8-二硝基蒽醌的混合物的方法
公开(公告)号：US4259248A
公开(公告)日：1981-03-31
申请号：US49708
申请日：1979-06-18
申请人： Walter Hohmann , Klaus Wunderlich
发明人： Walter Hohmann , Klaus Wunderlich
IPC分类号： C07C205/47 , C07C20060101 , C07C67/00 , C07C201/00 , C07C97/12
CPC分类号： C07C225/34
摘要： A process has been developed for the preparation of mixtures of dinitroanthraquinones with a high content of 1,5- and 1,8- dinitroanthraquinone by nitration with nitric acid in the presence of sulphuric acid with heating wherein anthraquinone, 1-nitroanthraquinone or a mixture of them is treated with about 1.5 to about 2.5 times the amount by weight of nitric acid, relative to the feed material, in the presence of about 0.75 times to twice the amount by weight, relative to nitric acid, of sulphuric acid, the temperature first being kept in the range from room temperature to about 50.degree. C. until at least 50% of the starting material or materials has been dinitrated, then adjusting the temperature to about 50.degree. C. to about 70.degree. C. to complete the dinitration.
摘要翻译：已经开发了一种通过硝酸在硫酸存在下通过加热制备二硝基蒽醌与高含量1,5-和1,8-二硝基蒽醌的混合物的方法，其中蒽醌，1-硝基蒽醌或在相对于原料的硝酸的量的约1.5至约2.5倍的条件下，相对于硝酸，硫酸的重量的约0.75倍至2倍的量处理它们，温度先保持在室温至约50℃的范围内，直到起始材料或材料的至少50％已被硝化，然后将温度调节至约50℃至约70℃以完成二硝化。

4. 发明授权

US4065478A Process for the manufacture of .alpha.,.alpha.'-aminonitroanthraquinones 失效
标题翻译：制备{60，{60 {40-氨基四氢蒽醌
公开(公告)号：US4065478A
公开(公告)日：1977-12-27
申请号：US640372
申请日：1975-12-15
申请人： Zdenek Seha
发明人： Zdenek Seha
IPC分类号： C09B1/22 , C07C20060101 , C07C67/00 , C07C205/47 , C07C225/34 , C07C227/04 , C07C229/74 , C07C313/00 , C09B51/00 , C07C97/24
CPC分类号： C07C225/34
摘要： A process for the manufacture of .alpha.,.alpha.'-aminonitroanthraquinones, from .alpha.,.alpha.'-dinitroanthraquinones, wherein the .alpha.,.alpha.'-dinitroanthraquinones are reacted with ammonia in dipolar aprotic solvents which are inert to ammonia, the reaction substrates and reaction products.
摘要翻译：用于从α，α'-二硝基蒽醌生产α，α'-氨基三氟蒽醌的方法，其中所述α，α'-二硝基蒽醌与氨反应，其对氨惰性的偶极非质子溶剂，反应底物和反应产物。

5. 发明授权

US4042604A Isolation of dinitroanthraquinone having a high content of .alpha.,.alpha.- d 失效
标题翻译：具有高含量{60，{60-二硝基化合物的二硝基蒽醌的分离
公开(公告)号：US4042604A
公开(公告)日：1977-08-16
申请号：US686365
申请日：1976-05-14
申请人： Heinz Eilingsfeld , Dietrich Lach
发明人： Heinz Eilingsfeld , Dietrich Lach
IPC分类号： C07C205/47 , C07C67/00 , C07C201/00 , C09B1/00 , C07C79/37
CPC分类号： C07C225/34
摘要： A process for the isolation of mixtures of 1,5-dinitroanthraquinone and 1,8-dinitroanthraquinone which have a high content of .alpha.,.alpha.'-dinitroanthraquinones by heating a suspension of the crude dinitroanthraquinone mixture in certain organic liquids at from 60.degree. to 200.degree. C until solution equilibrium has been set up, and separating the undissolved material from the solution. The undissolved material contains more than 90% and as a rule more than 95% by weight of 1,5-dinitroanthraquinone and 1,8-dinitroanthraquinone. The pure mixture of 1,5-dinitroanthraquinone and 1,8-dinitroanthraquinone may be used for the manufacture of dyes.
摘要翻译：通过在60°至200°的某些有机液体中加热粗二硝基蒽醌混合物的悬浮液，分离具有高α，α'-二硝基蒽醌含量的1,5-二硝基蒽醌和1,8-二硝基蒽醌的混合物的方法直到溶液平衡已经建立，并将未溶解的材料与溶液分离。未溶解的材料含有超过90％且通常超过95重量％的1,5-二硝基蒽醌和1,8-二硝基蒽醌。 1,5-二硝基蒽醌和1,8-二硝基蒽醌的纯混合物可用于制备染料。

6. 发明授权

US4021498A Adiabatic process for nitration of nitratable aromatic compounds 失效
标题翻译：硝化硝化芳香族化合物的绝热方法
公开(公告)号：US4021498A
公开(公告)日：1977-05-03
申请号：US639019
申请日：1975-12-09
申请人： Verner Alexanderson , James Bryant Trecek , Cornelius Marsden Vanderwaart
发明人： Verner Alexanderson , James Bryant Trecek , Cornelius Marsden Vanderwaart
IPC分类号： C07B43/02 , C07B31/00 , C07C67/00 , C07C201/00 , C07C201/08 , C07C205/06 , C07C205/11 , C07C205/12 , C07C205/47 , C07C79/10 , C07C79/12
CPC分类号： C07C201/08
摘要： An adiabatic process for the mononitration of nitratable aromatic hydrocarbons and halo substituted aromatic hydrocarbons which yield a mononitration product containing less than 500 ppm. of dinitrated product is disclosed.
摘要翻译：产生含有小于500ppm的单硝化产物的可硝化芳族烃和卤代烃芳族烃单硝化的绝热方法。的硝酸盐产品被公开。

7. 发明授权

US3960903A Process for preparing 1-nitro-anthraquinone 失效
标题翻译： 1-硝基 - 蒽醌的制备方法
公开(公告)号：US3960903A
公开(公告)日：1976-06-01
申请号：US501017
申请日：1974-08-27
申请人： Karl Linhart , Reinold Schmitz
发明人： Karl Linhart , Reinold Schmitz
IPC分类号： C07C205/47 , C07C20060101 , C07C67/00 , C07C201/00 , C07C49/68
CPC分类号： C07C205/47
摘要： 1-Nitro-anthraquinone is separated from an anthraquinone nitration mixture in concentrated nitric acid by adding to the nitration mixture sulpholan and separating off the insoluble 1-nitro-anthraquinone. The quantity of sulpholan added is such that the mixture contains 10-90% by weight nitric acid and from 90-10% by weight sulpholan.
摘要翻译：将1-硝基蒽醌与浓硝酸中的蒽醌硝化混合物分离，加入到硝化混合物溶液中，分离出不溶性的1-硝基蒽醌。所添加的sulpholan的量使得混合物含有10-90重量％的硝酸和90-10重量％的sulpholan。

8. 发明授权

US3959318A Process for preparing highly pure 5-nitro-1,4,4a,9a-tetrahydroanthraquinone 失效
标题翻译：制备高纯度5-硝基-1,4,4a，9a-四氢蒽醌的方法
公开(公告)号：US3959318A
公开(公告)日：1976-05-25
申请号：US610778
申请日：1975-09-05
申请人： Yasuyoshi Torisu , Seishichiro Kaba , Ken Mukai
发明人： Yasuyoshi Torisu , Seishichiro Kaba , Ken Mukai
IPC分类号： C07C205/47 , C07C67/00 , C07C201/00 , C07C205/45 , C07C49/68
CPC分类号： C07C201/12 , C07C205/47 , C07C221/00 , C07C2103/24
摘要： Highly pure 5-nitro-1,4,4a,9a-tetrahydroanthraquinone can be obtained by subjecting 6-nitronaphthoquinone-containing crude 5-nitro-1,4-naphthoquinone to Diels-Alder condensation reaction with 1,3-butadiene in a solvent including benzene, an alkylated aromatic hydrocarbon such as toluene, xylene or the like, a halogenated aromatic hydrocarbon such as chlorobenzene, dichlorobenzene, or the like, or a halogenated aliphathic hydrocarbon such as trichloroethylene, perchloroethylene or the like, cooling the resulting reaction solution to crystallize the reaction product, and separating the thus crystallized product by filtration. 5-nitro-1,4,4a,9a-tetrahydroanthraquinone has a relatively small solubility in the above-mentioned solvents, while the solubility of 6-nitro-1,4,4a,9a-tetrahydroanthraquinone in the solvents is rather great, thus the above-mentioned solvents being effective for the separation of these compounds from each other. The oxidation and the subsequent reduction of the thus obtained 5-nitro-1,4,4a,9a-tetrahydroanthraquinone yields 1-aminoanthraquinone with a purity above 98 wt% and a 2-aminoanthraquinone content below 1 wt%. The above-mentioned solvents are also effective for purification of 6-nitro-1,4,4a,9a-tetrahydroanthraquinone-containing 5-nitro-1,4,4a,9a-tetrahydroanthraquinone by recrystallization.
摘要翻译：通过使6-硝基萘醌的粗5-硝基-1,4-萘醌与溶剂中的1,3-丁二烯进行狄尔斯 - 阿尔德缩合反应，可以得到高纯度的5-硝基-1,4,4a，9a-四氢蒽醌包括苯，烷基化芳烃如甲苯，二甲苯等，卤代芳烃如氯苯，二氯苯等，或卤代脂族烃如三氯乙烯，全氯乙烯等，将所得反应溶液冷却至使反应产物结晶，并通过过滤分离如此结晶的产物。 5-硝基-1,4,4a，9a-四氢蒽醌在上述溶剂中的溶解度相对较小，而6-硝基-1,4,4a，9a-四氢蒽醌在溶剂中的溶解度相当大，因此上述溶剂对于将这些化合物彼此分离是有效的。由此得到的5-硝基-1,4,4a，9a-四氢蒽醌的氧化和随后的还原得到纯度高于98wt％，2-氨基蒽醌含量低于1wt％的1-氨基蒽醌。上述溶剂对于通过重结晶纯化含有6-硝基-1,4,4a，9a-四氢蒽醌的5-硝基-1,4,4a，9a-四氢蒽醌也是有效的。

9. 发明授权

US3932473A Process for the manufacture of 1-nitro-anthraquinone 失效
标题翻译：制备1-硝基 - 蒽醌的方法
公开(公告)号：US3932473A
公开(公告)日：1976-01-13
申请号：US353001
申请日：1973-04-20
申请人： Erich Klauke , Reinhold Schmitz , Hans-Samuel Bien
发明人： Erich Klauke , Reinhold Schmitz , Hans-Samuel Bien
IPC分类号： C07C205/47 , C07C20060101 , C07C67/00 , C07C201/00 , C09B1/00 , C07C79/37
CPC分类号： C07C205/47
摘要： Pure 1-nitro-anthraquinone is produced by nitrating anthraquinone in aqueous hydrogen fluoride containing about 5 - 30 weight percent of water with nitric acid as nitrating agent at about 0.degree. - 150.degree.C preferably 20.degree. - 70.degree.C.
摘要翻译：通过在约0-150℃，优选20-70℃下，用硝酸作为硝化剂，将含有约5-30重量％水的氟化氢水溶液中的蒽醌硝化作为硝基化蒽醌。

10. 发明授权

US1810011A 2-nitro-7-chloro-anthraquinone and process of making the same 失效
标题翻译： 2-硝基-7-氯 - 蒽醌及其制备方法
公开(公告)号：US1810011A
公开(公告)日：1931-06-16
申请号：US20326227
申请日：1927-07-02
申请人： NEWPORT CHEMICAL CORP
发明人： IVAN GUBELMANN , WEILAND HENRY J , OTTO STALLMANN
IPC分类号： C07C205/47
CPC分类号： C07C205/47 , C07C201/12 , C07C2603/24

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