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1. 发明申请

US20110028741A1 Novel Platensimycin Derivatives, Their Intermediates, and Process for Preparing the Same, and New Process for Preparing Platensimycin 有权
标题翻译：新型普拉霉素衍生物，其中间体及其制备方法，以及制备普拉霉素的新工艺
公开(公告)号：US20110028741A1
公开(公告)日：2011-02-03
申请号：US12936856
申请日：2009-03-31
申请人： Eun Lee , Ki Po Jang , Chan Hyuk Kim , Seong Wook Na , Dong Seok Jang
发明人： Eun Lee , Ki Po Jang , Chan Hyuk Kim , Seong Wook Na , Dong Seok Jang
IPC分类号： C07D311/78 , C07C255/06
CPC分类号： C07D307/77 , C07D307/93 , C07D307/94 , C07D493/18
摘要： The present invention relates to novel platensimycin derivatives, their intermediates and preparing methods of the same. Platensimycin is known as an effective antibiotic material having a broad antimicrobial spectrum and its derivatives are also expected to be effective antibiotic candidates. The present invention also relates to a novel preparing method of platensimycin. The intermediates used for the production of platensimycin and its derivatives of the present invention are tricyclo ketone derivatives and tetracyclo derivatives. Tetracyclo derivatives are prepared from tricyclo ketone derivatives prepared by carbonyl ylide [3+2] cycloaddition of dia-zoketone derivative.
摘要翻译：本发明涉及新颖的拉米霉素衍生物及其中间体及其制备方法。普拉霉素被称为具有广谱抗菌谱的有效的抗生素材料，其衍生物也预期是有效的抗生素候选物。本发明还涉及一种新型的铂霉素的制备方法。用于生产本发明的扁柏霉素及其衍生物的中间体是三环酮衍生物和四环衍生物。四环衍生物由通过二氮杂酮衍生物的羰基内酰胺[3 + 2]环加成制备的三环酮衍生物制备。

2. 发明授权

US4921872A Acaricidal agents based on azomethines of 2,3-diaminomaleic acid nitrile 失效
标题翻译：基于2,3-二氨基马来酸腈的偶氮甲碱的杀螨剂
公开(公告)号：US4921872A
公开(公告)日：1990-05-01
申请号：US149244
申请日：1988-01-27
申请人： Holger Heidenreich , Benedikt Becker
发明人： Holger Heidenreich , Benedikt Becker
IPC分类号： A01N37/34 , A01N35/10 , A01N37/40 , A01N37/42 , A01N37/44 , A01N37/48 , A01N37/50 , A01N41/10 , A01N47/02 , A01N47/04 , C07C20060101 , C07C67/00 , C07C253/00 , C07C253/18 , C07C255/06 , C07C255/30 , C07C255/32 , C07C255/61 , C07C313/00 , C07C317/32 , C07C317/36 , C07C317/44 , C07C317/46 , C07C317/48 , C07C323/45 , C07C323/62
CPC分类号： C07C255/00 , A01N37/44 , A01N37/50 , A01N47/04
摘要： A method of combating acarids which comprises applying to such acarids or to an acarid habitat an acaricidally effective amount of an azomethine of 2,3-diaminomaleic acid nitrile of the formula ##STR1## in which X represents halogen, halogenoalkyl or CN and R.sup.1, R.sup.2, R.sup.3 and R.sup.4 can be identical or different and represent hydrogen, optionally substituted alkyl, optionally substituted alkoxy, halogen, CN, NO.sub.2, optionally substituted dialkylamino, alkoxycarbonyl, optionally substituted alkylthio, optionally substituted alkylthionyl, optionally substituted alkylsulphonyl, OH, SH or NH.sub.2. The compounds other than the 2-chloro-and 2,6-dichloro-toluylideneamino-compounds are new.
摘要翻译：一种抗螨剂的方法，其包括向所述螨或螨栖息地施用杀螨有效量的式（I）的2,3-二氨基马来酸腈的偶氮甲碱，其中X表示卤素，卤代烷基或CN， R 1，R 2，R 3和R 4可以相同或不同，表示氢，任选取代的烷基，任选取代的烷氧基，卤素，CN，NO 2，任选取代的二烷基氨基，烷氧基羰基，任选取代的烷硫基，任选取代的烷基硫酰基，任选取代的烷基磺酰基， SH或NH2。除2-氯 - 和2,6-二氯 - 甲苯亚甲基氨基化合物以外的化合物是新的。

3. 发明授权

US4330482A Process for the preparation of halogenoalkenes 失效
标题翻译：卤代烯烃的制备方法
公开(公告)号：US4330482A
公开(公告)日：1982-05-18
申请号：US218394
申请日：1980-12-18
申请人： Hellmut Hoffmann
发明人： Hellmut Hoffmann
IPC分类号： C07C69/743 , C07B31/00 , C07B37/04 , C07C17/00 , C07C17/263 , C07C45/00 , C07C45/68 , C07C49/567 , C07C67/00 , C07C253/00 , C07C255/06 , C07C255/48 , C07F9/38 , C07F9/40 , C07C21/19 , C07C121/48
CPC分类号： C07F9/4065 , C07C45/68 , C07C49/567 , C07F9/4018 , C07F9/4056
摘要： In the process for the production of a halogenoalkene of the formula ##STR1## in which R.sup.1 is an optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, aralkyl, aralkenyl or aryl radical or an optionally substituted heterocyclic radical,R.sup.2 represents a halogen atom, a cyano group, an optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, aralkenyl, aryl, alkylcarbonyl, arylcarbonyl, alkoxycarbonyl or aminocarbonyl radical or an optionally substituted heterocyclic radical, andX is a halogen atom,in which an .alpha.-hydroxy-phosphonic acid ester of the formula ##STR2## in which R.sup.3 each independently is an alkyl or phenyl radical, or the two radicals R.sup.3 together are an alkanediyl (alkylene) radical,is reacted with a phosphorus-containing olefinating agent of the formula ##STR3## in which Z.sup.1 is the phosphorus-containing radical ##STR4## R.sup.4 and R.sup.5 each independently is an alkyl, phenyl, alkoxy or phenoxy radical or together are an alkanedioxy radical, andR.sup.6 is an alkyl or phenyl radical,in the presence of a base at a temperature between about -70.degree. and +150.degree. C., the improvement which comprises effecting the reaction in the presence of a halogen carrier. The end products are useful as intermediates such as in synthesizing pyrethroid-like insecticides.
摘要翻译：在制备其中R 1为任选取代的烷基，烯基，炔基，环烷基，环烯基，芳烷基，芳烯基或芳基或任选取代的杂环基团的式IMAMA的卤代烯烃的方法中，R 2表示卤素原子，氰基，任选取代的烷基，烯基，炔基，环烷基，芳烯基，芳基，烷基羰基，芳基羰基，烷氧基羰基或氨基羰基或任选取代的杂环基，X是卤素原子，其中α-羟基膦酸其中R 3各自独立地是烷基或苯基，或者两个基团R 3一起是烷二基（亚烷基）基团的式“IMAGE”的酸酯与式“IMAGE”的含磷烯烃化合物在其中Z 1是含磷基团R 4和R 5各自独立地是烷基，苯基，烷氧基或苯氧基，或者一起是烷二氧基，R 6是烷基 1或苯基，在碱存在下，温度在约-70℃至+ 150℃之间，其改进包括在卤素载体存在下进行反应。最终产物可用作合成拟除虫菊酯类杀虫剂的中间体。

4. 发明授权

US06924345B2 Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions 有权
标题翻译：含磷组合物及其在氢化，异构化和加氢甲酰化反应中的应用
公开(公告)号：US06924345B2
公开(公告)日：2005-08-02
申请号：US10659205
申请日：2003-09-10
申请人： Michel R. Gagne , Kenneth G. Moloy , Nora S. Radu , Brian P. Santora , Wilson Tam
发明人： Michel R. Gagne , Kenneth G. Moloy , Nora S. Radu , Brian P. Santora , Wilson Tam
IPC分类号： B01J31/16 , B01J31/18 , B01J31/22 , B01J31/26 , C07B61/00 , C07C45/49 , C07C45/50 , C07C47/02 , C07C253/10 , C07C253/30 , C07C255/02 , C07C255/06 , C07C255/09 , C07C255/17 , C07F9/46 , C07F9/48 , C07F15/00 , C07F15/04 , C07F15/06 , C08F8/00 , C08F12/00 , C08F20/30 , C08F22/20 , C08F30/02 , C08F130/02
CPC分类号： B01J31/1658 , B01J31/185 , B01J31/1865 , B01J31/1875 , B01J31/1885 , B01J31/2291 , B01J31/2295 , B01J31/26 , B01J31/30 , B01J2531/0266 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , C07C45/49 , C07C45/50 , C07C253/10 , C07C253/30 , C07F15/0066 , C07F15/045 , C07F15/065 , C08F12/24 , C08F30/02 , C08F212/08 , C08F212/14 , C08F212/32 , C08F212/36 , C08F230/02 , C07C47/19 , C07C255/06 , C07C255/09 , C07C255/17 , C07C47/02
摘要： A polymeric, phosphorus-containing composition made by heating, in the presence of an initiator, preferably a free radical initiator, and optionally in the presence of one or more comonomers, at least one substituted phosphonylated 2,2′-dihydroxyl-1,1′-binaphthalene or at least one substituted 2,2′-dihydroxyl-1,1′-biphenylene.
摘要翻译：通过在引发剂存在下，优选自由基引发剂和任选在一种或多种共聚单体存在下，加入至少一种取代的膦酰化的2,2'-二羟基-1,1 ' - 联萘或至少一个取代的2,2'-二羟基-1,1'-联亚苯基。

5. 发明授权

US6150304A 2-aryl-cyclopentane-1,3-dione derivatives 失效
标题翻译： 2-芳基 - 环戊烷-1,3-二酮衍生物
公开(公告)号：US6150304A
公开(公告)日：2000-11-21
申请号：US131043
申请日：1998-08-06
申请人： Reiner Fischer , Jacques Dumas , Thomas Bretschneider , Christoph Erdelen , Ulrike Wachendorff-Neumann , Hans-Joachim Santel , Markus Dollinger , Andreas Turberg , Norbert Mencke
发明人： Reiner Fischer , Jacques Dumas , Thomas Bretschneider , Christoph Erdelen , Ulrike Wachendorff-Neumann , Hans-Joachim Santel , Markus Dollinger , Andreas Turberg , Norbert Mencke
IPC分类号： C07D333/38 , A01N35/06 , A01N37/02 , A01N37/10 , A01N45/02 , A01N47/06 , A01N47/18 , A01N57/12 , C07C45/45 , C07C49/657 , C07C49/675 , C07C49/697 , C07C49/747 , C07C49/753 , C07C59/84 , C07C59/86 , C07C62/38 , C07C69/013 , C07C69/738 , C07C69/96 , C07C205/45 , C07C271/32 , C07D213/80 , C07D307/68 , C07F9/09 , A01N37/34 , C07C255/06
CPC分类号： C07C205/45 , A01N35/06 , A01N37/02 , A01N37/10 , A01N45/02 , A01N47/06 , C07C45/455 , C07C49/657 , C07C49/675 , C07C49/697 , C07C49/747 , C07C49/753 , C07C59/84 , C07C59/86 , C07C62/38 , C07C69/013 , C07C69/738 , C07C69/96
摘要： The present invention relates to novel 2-aryl-3-hydroxy-cyclopent-2-en-1-one derivatives of the formula (I) ##STR1## in which X represents halogen, nitro, cyano, alkyl, alkoxy, alkenyloxy, alkylthio, alkylsulphinyl, alkylsulphonyl, halogenoalkyl or halogenoalkoxy,Y represents hydrogen, halogen, nitro, cyano, alkyl, alkoxy, alkenyloxy, alkylthio, alkylsulphinyl, alkylsulphonyl, halogenoalkyl or halogenoalkoxy,Z represents halogen, nitro, cyano, alkyl, alkoxy or halogenoalkoxy andA, B, D.sup.1, D.sup.2, G and n have the meaning given in the description,several processes for their preparation and their use as compositions for controlling pests and as herbicides.
摘要翻译：本发明涉及式（I）的新的2-芳基-3-羟基 - 环戊-2-烯-1-酮衍生物，其中X表示卤素，硝基，氰基，烷基，烷氧基，烯氧基，烷硫基，烷基亚磺酰基，烷基磺酰基，卤代烷基或卤代烷氧基，Y代表氢，卤素，硝基，氰基，烷基，烷氧基，烯氧基，烷硫基，烷基亚磺酰基，烷基磺酰基，卤代烷基或卤代烷氧基，Z代表卤素，硝基，氰基，烷基，烷氧基或卤代烷氧基，A， D1，D2，G和n具有说明书中给出的含义，其制备方法及其用作防治害虫和除草剂的组合物。

6. 发明授权

US5892092A Preparation of aliphatic, unsaturated nitriles 失效
标题翻译：脂肪族不饱和腈的制备
公开(公告)号：US5892092A
公开(公告)日：1999-04-06
申请号：US144478
申请日：1998-08-31
申请人： Andreas Kramer , Wolfgang Siegel , Michael Henningsen , Georg Heinrich Grosch
发明人： Andreas Kramer , Wolfgang Siegel , Michael Henningsen , Georg Heinrich Grosch
IPC分类号： B01J23/02 , C07B61/00 , C07C253/00 , C07C255/06 , C07C255/07 , C07C255/31
CPC分类号： C07C253/00
摘要： A process for preparing unsaturated nitriles of the formula I ##STR1## where R, R.sup.1 and R.sup.2 are each independently of one another alkyl or alkenyl each having 1-20 carbon atoms or cycloalkyl or cycloalkenyl each having 3-12 carbon atoms and any two of the radicals R, R.sup.1 and R.sup.2 may be part of a saturated or unsaturated ring and R.sup.1 and R.sup.2 may also be hydrogen and n is 0 or 1-20, by dehydration of oximes of the formula II ##STR2## where R, R.sup.1, R.sup.2 and n are as defined above, comprises dehydrating in the gas or liquid phase at from 150.degree. to 300.degree. C. over a heterogeneous catalyst consisting of an oxidic, carbidic or nitridic support doped with basic oxides and/or hydroxides or compounds which are converted into said oxides or hydroxides under the reaction conditions, or of said basic oxides.
摘要翻译：制备式I的不饱和腈的方法，其中R，R 1和R 2各自独立地为各自具有1-20个碳原子的烷基或链烯基或各自具有3-12个碳原子的环烷基或环烯基，任何两个的基团R 1，R 2和R 2可以是饱和或不饱和环的一部分，R 1和R 2也可以是氢，n是0或1-20，通过式II的肟脱水，其中R，R 1 R2和n如上定义，包括在气相或液相中在150-300℃下脱水，所述非均相催化剂由掺有碱性氧化物和/或氢氧化物或化合物的氧化，碳化或氮化载体组成，在反应条件下或所述碱性氧化物中转化为所述氧化物或氢氧化物。

7. 发明授权

US5460927A Activated propenes as color couplers and a method for production of photographic elements therewith 失效
标题翻译：作为彩色成色剂的活性丙烯和用于生产照相元件的方法
公开(公告)号：US5460927A
公开(公告)日：1995-10-24
申请号：US175395
申请日：1994-01-03
申请人： Hugh M. Williamson
发明人： Hugh M. Williamson
IPC分类号： C07B37/04 , C07C209/04 , C07C211/45 , C07C211/52 , C07C253/30 , C07C255/06 , C07C255/30 , C07C303/30 , C07C309/65 , C07C309/76 , G03C7/36 , G03C7/32
CPC分类号： G03C7/36 , C07C255/30 , C07C303/30
摘要： The invention provides a novel and economic method for the production of an activated propene from a malonitrile dimer which comprises reacting a compound of the formula (I) ##STR1## with a nucleophile D to provide a compound of the formula (II) ##STR2## wherein substituents A, B and E each individually represent hydrogen, a substituted or unsubstituted alkyl acyl carboxyl or aryl group or an electron withdrawing group, and X is a group capable of displacement via a substitution reaction.
摘要翻译： PCT No.PCT / EP92 / 01476 Sec。 371日期1994年1月3日 102（e）日期1994年1月3日PCT提交1992年6月29日PCT公布。出版物WO93 / 01523 日本1993年1月21日。本发明提供了一种用于从丙二腈二聚体制备活化丙烯的新型和经济方法，其包括使式（I）化合物（I）与亲核试剂D反应，式（II）的化合物其中取代基A，B和E各自独立地表示氢，取代或未取代的烷基酰基羧基或芳基或吸电子基团，X是能够通过替代反应。

8. 发明授权

US10696848B2 Fluorinated ether compound, coating liquid, article and novel compounds 有权
公开(公告)号：US10696848B2
公开(公告)日：2020-06-30
申请号：US16152450
申请日：2018-10-05
申请人： AGC Inc.
发明人： Taiki Hoshino , Kazue Toda , Eiichiro Anraku , Masahiro Itoh
IPC分类号： C09D5/00 , C07C211/22 , C09D171/00 , C08G65/336 , C23C14/24 , C07C255/06 , C08G65/00 , C08G65/323 , C07C255/07 , C07F7/18 , B05D1/00 , B05D5/08 , B05D1/02 , C23C14/12
摘要： The present invention provides: a fluorinated ether compound and a coating liquid capable of forming a surface layer excellent in water/oil repellency, abrasion resistance, fingerprint stain removability and lubricity and an article having a surface layer excellent in water/oil repellency, abrasion resistance, fingerprint stain removability and lubricity. Provided is a fluorinated ether compound represented by [Rf-G-]aZ[—(O—R2)c—SiR3nL3−n]b wherein Rf: a linear polyfluoroalkyl group having at least two carbon atoms, which has at least one etheric oxygen between carbon-carbon atoms, G: —R1—O—, —R1—CONH—, —CONH— or a single bond, R1: an alkylene group, Z: a hydrocarbon group having a valence of (a+b) or the like, R2: an alkylene group, R3: a monovalent hydrocarbon group or the like, L: a hydrolyzable group, n: from 0 to 2, a: an integer of at least 1, b: an integer of at least 1, (a+b): at least 3, when a is 1, b is at least 4, and when a is at least 2, b is at least 1, and c: 0 or 1.

9. 发明授权

US09057084B2 Method for producing aqueous acrylamide solution 有权
标题翻译：丙烯酰胺水溶液的制备方法
公开(公告)号：US09057084B2
公开(公告)日：2015-06-16
申请号：US14117754
申请日：2012-05-21
申请人： Makoto Kanou , Norifumi Hagiya
发明人： Makoto Kanou , Norifumi Hagiya
IPC分类号： C07C255/06 , C07C231/00 , C12P13/02 , C07C231/06
CPC分类号： C12P13/02 , C07C231/06 , C07C233/09
摘要： There is provided a method for producing an aqueous acrylamide solution by reacting a composition including acrylonitrile with water to produce acrylamide, in which the composition including acrylonitrile includes 3 to 15 mg of propionitrile per 1 kg of the total weight of the composition including acrylonitrile. According to the present invention, a production method with which it is possible to suppress acrylamide polymerization without lowering quality and thereby obtain a stable aqueous acrylamide solution can be provided.
摘要翻译：提供了一种通过使包含丙烯腈的组合物与水反应生成丙烯酰胺来制备丙烯酰胺水溶液的方法，其中包含丙烯腈的组合物包括每1kg包括丙烯腈的组合物总重量的3至15mg丙腈。根据本发明，可以提供可以抑制丙烯酰胺聚合而不降低品质从而得到稳定的丙烯酰胺水溶液的制备方法。

10. 发明申请

US20030181751A1 4, 8-dodecadienedinitrile and process for its production 失效
标题翻译： 4,8-十二烷基二腈及其生产方法
公开(公告)号：US20030181751A1
公开(公告)日：2003-09-25
申请号：US10363415
申请日：2003-03-03
申请人： UBE INDUSTRIES
发明人： Katsumasa Harada , Yasuhisa Fukuda , Yoshinori Yamanaka , Tadashi Murakami , Kenji Hirotsu
IPC分类号： C07C255/06
CPC分类号： C07C255/09
摘要： The present invention relates to a novel compound 4,8-dodecadienedinitrile represented by the following formula (1): 1 wherein 2 nullmeans a cis or trans bond, and a process for preparing 4,8-dodecadienedinitrile which comprises reacting a 2-alkoxy-5,9-cyclododecadienone oxime or a 2-halogeno-5,9-cyclododecadienone oxime with formic acid and hydroxylamine.
摘要翻译：本发明涉及一种由下式（1）表示的新型化合物4,8-十二烷二腈：其中是指顺式或反式键，以及制备4,8-十二烷基二腈的方法，包括使2-烷氧基-5， 9-环十二碳烯酮肟或2-卤代-5,9-环十二碳二烯肟与甲酸和羟胺。

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