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1. 发明申请

US20180179304A1 ALDIMINES AND KETIMINES AS INITIATORS IN HARDENER SYSTEMS AND CORRESPONDING RESIN COMPOSITIONS INTER ALIA FOR FIXING TECHNOLOGY 审中-公开
公开(公告)号：US20180179304A1
公开(公告)日：2018-06-28
申请号：US15738092
申请日：2016-06-03
申请人： fischerwerke GmbH & Co. KG
发明人： Juergen GRUEN , Paul STEURER , Martin VOGEL , Christian SCHLENK , Christian WEINELT
IPC分类号： C08F4/26 , C09D4/00 , C08F4/10 , C08F4/20 , C09J4/00 , C04B41/48 , C09J5/00
CPC分类号： C08F4/26 , C04B41/483 , C08F4/10 , C08F4/20 , C09D4/00 , C09J4/00 , C09J5/00 , C09J2400/263 , C09J2433/00 , C08F2222/102 , C08F2222/1013 , C08F220/20 , C08F2220/343 , C08F2220/286
摘要： A hardener system for a synthetic resin composition having free-radical-polymerisable compounds, which includes the following constituents: a) at least one activator in the form of a metal salt, and as free-radical starter b1) (i) at least one aldehyde and/or ketone and at least one primary amine, and/or b2) (ii) at least one aldimine or (iii) at least one ketimine, or a mixture of two or more of constituents (i) to (iii). In addition, synthetic resin compositions having such a hardener system for application especially in fixing technology, and subject matters related thereto.

2. 发明授权

US07847043B2 Organic bismuth compound, method for producing same, living radical polymerization initiator, method for producing polymer using same, and polymer 有权
标题翻译：有机铋化合物，其制造方法，活性自由基聚合引发剂，使用其的聚合物的制造方法以及聚合物
公开(公告)号：US07847043B2
公开(公告)日：2010-12-07
申请号：US11792299
申请日：2005-12-09
申请人： Shigeru Yamago , Takashi Kameshima , Kazuhiro Kawano , Osamu Ito , Emiko Daimon , Ken Shu , Kunihiko Sugoh
发明人： Shigeru Yamago , Takashi Kameshima , Kazuhiro Kawano , Osamu Ito , Emiko Daimon , Ken Shu , Kunihiko Sugoh
IPC分类号： C08F4/20 , C08F9/94
CPC分类号： C08F4/42 , C07F9/94 , C08F212/08 , C08F257/02 , C08F291/06 , C08F297/02 , C08F226/10
摘要： An organobismuth compound represented by the formula (1) wherein R1 and R2 are C1-C8 alkyl, aryl, substituted aryl or an aromatic heterocyclic group, R3 and R4 are each a hydrogen atom or C1-C8 alkyl, and R5 is aryl, substituted aryl, an aromatic heterocyclic group, acyl, amido, oxycarbonyl or cyano.
摘要翻译：由式（1）表示的有机铋化合物，其中R 1和R 2为C 1 -C 8烷基，芳基，取代的芳基或芳族杂环基，R 3和R 4各自为氢原子或C 1 -C 8烷基，R 5为芳基，芳基，芳族杂环基，酰基，酰氨基，氧羰基或氰基。

3. 发明申请

US20090005522A1 Process for Preparing a Poly-1-Olefin in the Presence of a Ziegler Catalyst 有权
标题翻译：在齐格勒催化剂存在下制备聚-1-烯烃的方法
公开(公告)号：US20090005522A1
公开(公告)日：2009-01-01
申请号：US11658808
申请日：2005-07-27
申请人： Friedhelm Gundert
发明人： Friedhelm Gundert
IPC分类号： C08F4/22 , C08F4/10 , C08F4/52 , C08F4/20
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6548 , C08F4/6555 , C08F2500/12 , C08F2500/17 , C08F2500/18 , C08F2500/24
摘要： The invention relates to a process for preparing a poly-1-olefin by polymerization of a 1-olefin of the formula R4CH═CH2, where R4 is hydrogen or an alkyl radical having from 1 to 10 carbon atoms, in suspension, in solution or in the gas phase, at a temperature of from 20 to 200° C. and a pressure of from 0.5 to 50 bar, in the presence of a catalyst which comprises the reaction product of a magnesium alkoxide with a transition metal compound (=component a) and an organometallic compound (=component b) and whose component a has been prepared in a manner having the feature that a magnesium alkoxide powder having a mean particle size, expressed as the d50, in the range from 100 to 1000 μm is firstly processed by dry milling in a mill under inert conditions to produce magnesium alkoxide powder having a mean particle size, expressed as the d50, of less than 15 μm, then suspended in an inert hydrocarbon in which the magnesium alkoxide is insoluble, and is reacted immediately without further pretreatment with a transition metal compound of titanium, zirconium, vanadium or chromium.
摘要翻译：本发明涉及通过聚合式R 4 CH-CH 2的1-烯烃（其中R 4是氢或具有1至10个碳原子的烷基，在悬浮液中，在溶液中或溶液中）聚合制备聚-1-烯烃的方法，在气相中，在20〜200℃的温度和0.5〜50巴的压力下，在含有烷氧基镁与过渡金属化合物的反应产物（=组分a ）和有机金属化合物（=成分b），其成分a以具有以d50表示的平均粒径的烷氧基镁粉末在100〜1000μm的范围内的方式制备，首先被处理通过在惰性条件下在研磨机中干研磨以产生平均粒度（d50表示）小于15μm的烷氧基镁粉末，然后悬浮在惰性烃中，其中烷氧化镁不溶，并且立即反应而没有愤怒用钛，锆，钒或铬的过渡金属化合物预处理。

4. 发明授权

US07414101B2 Polymerization processes 有权
标题翻译：聚合工艺
公开(公告)号：US07414101B2
公开(公告)日：2008-08-19
申请号：US11805063
申请日：2007-05-22
申请人： Timothy Daniel Shaffer , Scott Thomas Milner , Michael Gerard Matturro , David Yen-Lung Chung , Michael Francis McDonald , Robert Norman Webb
发明人： Timothy Daniel Shaffer , Scott Thomas Milner , Michael Gerard Matturro , David Yen-Lung Chung , Michael Francis McDonald , Robert Norman Webb
IPC分类号： C08F2/14 , C08F4/20 , C08F10/10
CPC分类号： C08F210/12 , C08F2/06 , C08F10/00 , C08F4/06 , C08F4/52 , C08F2/002 , C08F4/00 , C08F4/12 , C08F2/14 , C08F236/08 , C08F2500/04 , C08F2500/03
摘要： The invention provides for a process to produce polymers utilizing a hydrofluorocarbon diluent.
摘要翻译：本发明提供了使用氢氟烃稀释剂制备聚合物的方法。

5. 发明申请

US20070265404A1 Organic Bismuth Compound, Method for Producing Same, Living Radical Polymerization Initiator, Method for Producing Polymer Using Same, and Polymer 有权
标题翻译：有机铋化合物，其制造方法，活性自由基聚合引发剂，使用其的聚合物的制造方法和聚合物
公开(公告)号：US20070265404A1
公开(公告)日：2007-11-15
申请号：US11792299
申请日：2005-12-09
申请人： Shigeru Yamago , Takashi Kameshima , Kazuhiro Kawano , Osamu Ito , Emiko Daimon , Ken Shu , Kunihiko Sugoh
发明人： Shigeru Yamago , Takashi Kameshima , Kazuhiro Kawano , Osamu Ito , Emiko Daimon , Ken Shu , Kunihiko Sugoh
IPC分类号： C08F4/20 , C07F9/94
CPC分类号： C08F4/42 , C07F9/94 , C08F212/08 , C08F257/02 , C08F291/06 , C08F297/02 , C08F226/10
摘要： An organobismuth compound represented by the formula (1) wherein R1 and R2 are C1-C8 alkyl, aryl, substituted aryl or an aromatic heterocyclic group, R3 and R4 are each a hydrogen atom or C1-C8 alkyl, and R5 is aryl, substituted aryl, an aromatic heterocyclic group, acyl, amido, oxycarbonyl or cyano.
摘要翻译：由式（1）表示的有机铋化合物，其中R 1和R 2均为C 1 -C 8烷基，烷基，芳基，取代的芳基或芳族杂环基，R 3和R 4各自为氢原子或C 1 -C 3 R 8是烷基，R 5是芳基，取代的芳基，芳族杂环基，酰基，酰氨基，氧羰基或氰基。

6. 发明授权

US5922632A Vanadium based components and catalysts for the polymerization of olefins and polymerization processes using the same 失效
标题翻译：用于烯烃聚合的钒基组分和催化剂以及使用其的聚合方法
公开(公告)号：US5922632A
公开(公告)日：1999-07-13
申请号：US936888
申请日：1997-09-25
申请人： Umberto Zucchini, deceased , Tiziano Dall'Occo , Antonella Angelini
发明人： Umberto Zucchini, deceased , Tiziano Dall'Occo , Antonella Angelini
IPC分类号： C08F4/68 , C08F4/20 , C08F4/60 , C08F4/62 , C08F10/00
CPC分类号： C08F10/00
摘要： Catalysts component of the (co)polymerization of alpha-olefins CH.sub.2 .dbd.CHR, wherein R is hydrogen or an alkyl radical having from 1 to 8 carbon atoms, comprising a product of the composition:VCL.sub.y.z(b)wherein (b) represents an organic compound selected from alkyl, aryl and acyl halides, y is a number higher than 2 and lower than 4, and preferably comprised between 2.5 and 3.5 and z is a number higher than zero and lower than or equal to 2, and preferably between 0.002 and 1. Components can be obtained as products of the reaction, carried out at temperatures higher than 10.degree. C., between VCl.sub.4 and the compound (b). Particularly preferred among compounds (b) are benzoyl chloride, p-methoxybenzoyl chloride and p-chloro benzoyl chloride. From the components of the invention, either supported or not, catalysts having high activity particularly useful for the production of ethylene polymers showing broad molecular weight distribution can be prepared.
摘要翻译： α-烯烃CH 2 = CHR（其中R为氢或具有1至8个碳原子的烷基）的（共）聚合的催化剂组分包含组成为VCLy.z（b）的产物，其中（b）表示选自烷基，芳基和酰基卤的有机化合物，y为高于2且低于4的数，优选为2.5至3.5，z为高于零且小于或等于2的数，并且优选为 0.002和1.可以在VCl 4和化合物（b）之间，在高于10℃的温度下进行反应的产物。化合物（b）中特别优选苯甲酰氯，对甲氧基苯甲酰氯和对氯苯甲酰氯。从本发明的组分，无论是否负载，可以制备具有高活性的催化剂，特别可用于生产显示宽分子量分布的乙烯聚合物。

7. 发明授权

US5627244A Process producing a polymer comprising an unsaturated carboxylic acid or a derivative thereof 失效
标题翻译：制备包含不饱和羧酸或其衍生物的聚合物的方法
公开(公告)号：US5627244A
公开(公告)日：1997-05-06
申请号：US427841
申请日：1995-04-26
申请人： Tsuneyuki Sato
发明人： Tsuneyuki Sato
IPC分类号： C08F4/16 , C08F4/20 , C08F4/42 , C08F4/76 , C08F20/00 , C08F20/10 , C08F20/12 , C08F20/14 , C08F120/14
CPC分类号： C08F4/76 , C08F20/12 , C08F220/14 , Y10S526/943
摘要： Disclosed is a process for producing a polymer of an unsaturated carboxylic acid or a derivative thereof, the process comprising polymerizing an unsaturated carboxylic acid or a derivative thereof in a water-soluble organic solvent-water mixture in the presence of at least one polymerization catalyst selected from the group consisting of a metal compound of the formulaL.sub.p.M.X.sub.q ( 1)wherein M is Ti, Zr, Hf or V, L is cyclopentazienyl, indenyl, fluorenyl or a derivative of these, X is halo, H, lower alkyl, lower alkoxyl, aryloxy, phenyl or benzyl, p and q each represents an integer including 0 and p+q is equal to the valence of M, and a metal compound of the formulaR.M.Y.sub.r ( 2)wherein M is defined above, R is a group formed by bonding, via a lower alkylene or di(lower alkyl)silylene group, two groups being cyclopentadienyl, indenyl, fluorenyl or a derivative of these, Y is halo, H, lower alkyl, lower alkoxyl, aryloxy, phenyl or benzyl, r is equal to the valence number of M minus 2.
摘要翻译：公开了一种制备不饱和羧酸或其衍生物的聚合物的方法，该方法包括在选自下列的至少一种聚合催化剂存在下，在水溶性有机溶剂 - 水混合物中使不饱和羧酸或其衍生物聚合由其中M是Ti，Zr，Hf或V的式Li.M.Xq（1）的金属化合物组成的组，L是环戊烯基，茚基，芴基或它们的衍生物，X是卤素，H，低级烷基，低级烷氧基，芳氧基，苯基或苄基，p和q各自表示包括0的整数，p + q等于M的化合价，以及式R.M.Yr（2）的金属化合物，其中M定义如上 R是通过低级亚烷基或二（低级烷基）亚甲硅基键合形成的基团，两个基团是环戊二烯基，茚基，芴基或它们的衍生物，Y是卤素，H，低级烷基，低级烷氧基，芳氧基，苯基或苄基，r等于M的价数减去2。

8. 发明授权

US5359017A Cationically polymerizable organic material compositions and method for the stabilization thereof 失效
标题翻译：阳离子聚合性有机材料组合物及其稳定化方法
公开(公告)号：US5359017A
公开(公告)日：1994-10-25
申请号：US108435
申请日：1993-08-18
申请人： Fumio Hamazu , Tatsuya Koizumi , Minoru Yokoshima , Masaki Fujimoto , Takeshi Endoh
发明人： Fumio Hamazu , Tatsuya Koizumi , Minoru Yokoshima , Masaki Fujimoto , Takeshi Endoh
IPC分类号： C08F4/00 , C08F2/38 , C08G59/68 , C08G65/10 , C08F4/20 , C08F4/80 , C08G59/18
CPC分类号： C08F2/38 , C08F4/00 , C08G59/68 , C08G65/10 , C08G65/105
摘要： The present invention provides a cationically polymerizable organic material composition comprising a composition which contains a cationic polymerization catalyst(s) and a cationically polymerizable organic material(s) as essencial ingredients, and one or more onium salts having a nucleophilic pair anion represented by halogenide, alkyl sulfate or p-toluenesulfonate ions, or one or more iron aromatic compound salts represented by the following formula (I): ##STR1## The composition of the present invention is a cationically polymerizable organic material composition capable of being cured by irradiation of a radiation or by heat, and it also has excellent storage stability at room temperature in the dark and a long pot life.
摘要翻译：本发明提供一种阳离子聚合性有机材料组合物，其包含含有阳离子聚合催化剂和阳离子聚合有机材料作为必需成分的组合物，以及一种或多种具有由卤化物表示的亲核对阴离子的鎓盐，烷基硫酸盐或对甲苯磺酸盐离子，或由下式（I）表示的一种或多种铁芳族化合物盐：本发明的组合物是能够通过照射而固化的阳离子聚合性有机材料组合物的辐射或热量，并且在黑暗中的室温下也具有优异的储存稳定性和适用期。

9. 发明授权

US5296567A Thermocurable compositions 失效
标题翻译：耐热组合物
公开(公告)号：US5296567A
公开(公告)日：1994-03-22
申请号：US863638
申请日：1992-04-06
申请人： Dieter Baumann , Werner Margotte , Beat Muller
发明人： Dieter Baumann , Werner Margotte , Beat Muller
IPC分类号： C08F2/40 , C08F2/38 , C08F4/06 , C08F4/42 , C08G59/00 , C08G59/18 , C08G59/68 , C08L63/00 , C09D201/00 , C09J201/00 , H01B3/40 , H05K1/03 , C08F4/20 , C08G8/04
CPC分类号： H05K1/0326 , C08G59/18 , C08G59/68 , C08G59/687 , H01B3/40
摘要： The present document describes the use of an inhibitor for cationic polymerization as an additive to a thermocurable composition based on at least one cationically polymerizable organic material and an initiator for cationic polymerization in the form of an onium compound or a compound of the formula (I)[M.sup.+n (L).sub.x ].sup.n+ nX.sup.- (I),in which n is 2 or 3, M is a metal cation selected from the group comprising Zn.sup.2+, Mg.sup.2+, Fe.sup.2+, Co.sup.2+, Ni.sup.2+, Cr.sup.2+, Ru.sup.2+, Mn.sup.2+, Sn.sup.2+, VO.sup.2+, Fe.sup.3+, Al.sup.3+ and Co.sup.3+, X.sup.- is an anion selected from the group comprising PF.sub.6.sup.-, AsF.sub.6.sup.-, SbF.sub.6.sup.-, BiF.sub.6.sup.-, derivatives of these anions in which at least one fluorine atom has been replaced by a hydroxyl group, and CF.sub.3 SO.sub.3.sup.-, or in which up to 50% of the anions X.sup.-, based on the total amount of anions, may be any desired anions, L is water or an organic .sigma.-donor ligand which contains, as bonding sites, one or more functional radicals selected from the group comprising --CO--, --CO--O--, --O--CO--O-- and --O-- and forms .sigma.-bonds with the central atom via the oxygen atom or atoms, and x is an integer from 0 to 6, and where the ligands L may be different within said definitions, or as an additive to components for the preparation of a composition of this type for avoiding initiator decomposition products which are formed due to moisture and reduce the thermal stability of the composition, and/or for increasing the thermal stability of the composition for a limited time before curing.
摘要翻译：本文件描述了用于阳离子聚合的抑制剂作为基于至少一种阳离子可聚合有机材料和以鎓化合物或式（I）化合物形式的阳离子聚合的引发剂的热可组合物的添加剂的用途，（M + n（L）x）n + nX-（I）其中n为2或3，M为选自Zn2 +，Mg2 +，Fe2 +，Co2 +，Ni2 +，Cr2 +，Ru2 +，Mn2 + ，Sn2 +，VO2 +，Fe3 +，Al3 +和Co3 +，X-是选自PF6-，AsF6-，SbF6-，BiF6-，这些阴离子的衍生物的阴离子，其中至少一个氟原子被羟基取代基团和CF 3 SO 3 - ，或其中最多50％的阴离子X-基于阴离子的总量可以是任何所需的阴离子，L是水或有机（Sigma） - 供体配体，其包含作为键合选自-CO - ， - CO-O-，-O-CO-O-和-O-的一个或多个官能团，并与中心a形成（Sigma） - 键通过氧原子或原子，x是0至6的整数，并且其中配体L在所述定义内可以不同，或作为用于制备用于避免引发剂分解产物的这种类型的组合物的组分的添加剂其由于水分而形成并降低组合物的热稳定性，和/或用于在固化前有限的时间提高组合物的热稳定性。

10. 发明授权

US4698385A Binder for high solids ambient cure coatings 失效
标题翻译：用于高固体含量环氧固化涂料的粘合剂
公开(公告)号：US4698385A
公开(公告)日：1987-10-06
申请号：US581766
申请日：1984-02-23
申请人： Frederick J. Schindler
发明人： Frederick J. Schindler
IPC分类号： C08F4/20 , C08G75/04 , C09D4/00 , C09D181/02
CPC分类号： C09D181/02 , C08G75/045 , C09D4/00 , Y10S525/92
摘要： Compositions suitable as binders for high solids, ambient cure coatings, and coating compositions which have high humidity resistance and good weatherability are disclosed herein.
摘要翻译：本文公开了适合作为高固体，环境固化涂料和涂料组合物的粘合剂的组合物，其具有高耐湿性和良好的耐候性。

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