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1. 发明申请

US20230113200A1 CATALYST AND PREPARATION THEREOF 有权
公开(公告)号：US20230113200A1
公开(公告)日：2023-04-13
申请号：US17908110
申请日：2021-03-02
申请人： BOREALIS AG
发明人： Frank Schröder , Timo Leinonen , Peter Denifl , Sascha Kaltenbacher , Bernhard Hagemann
IPC分类号： C08F4/646 , C08F116/20 , C08F4/654 , C08F4/657
摘要： The present invention relates to a process for producing a solid Ziegler-Natta catalyst component in the form of solid particles having a median particle size (D50vol) of 5 to 500 µm and the process comprising steps I. providing a solution of a Group 2 metal dihalide (1UPAC, Nomenclature of Inorganic Chemistry, 2005) by dissolving a solid Group 2 metal dihalide in an alcohol mixture comprising at least a monohydric alcohol (A1) of formula ROM, where R is selected from a hydrocarbyl group of 3 to 16 C atoms and an alcohol (A2) comprising in addition to the hydroxyl group another oxygen containing functional group not being a hydroxyl group, contacting the solution of the Group 2 metal dihalide of step I with a compound in a liquid form of a transition metal of Group 4 to 10, or of a lanthanide or actinide, preferably a transition metal of Group 4 to 6 of Periodic Table (1UPAC, Nomenclature of Inorganic Chemistry, 2005), and III. recovering the solid catalyst component, wherein the amount of Group 2 metal originating from Group 2 metal dihalide constitutes 100 % of the whole amount of the Group 2 metal used in the process for producing the solid Ziegler-Natta catalyst component.

2. 发明申请

US20220177686A1 POLYPROPYLENE-BASED RESIN COMPOSITION CONTAINING ULTRAHIGH MOLECULAR WEIGHT PROPYLENE (CO)POLYMER 有权
公开(公告)号：US20220177686A1
公开(公告)日：2022-06-09
申请号：US17619426
申请日：2020-06-12
申请人： SunAllomer Ltd. , SHOWA DENKO K.K.
发明人： Yutaka YOKOYAMA , Hiroshi KAJIOKA , Akihiro KAMIMURA , Shuji AKINAGA
IPC分类号： C08L23/16 , C08L23/12 , C08F4/654 , C08F4/657 , C08F10/06
摘要： A polypropylene-based resin composition contains: a component (A1) being a propylene homopolymer or a copolymer of propylene and a 30 wt % or less α-olefin having 2 or 4 to 8 carbon atoms, having a intrinsic viscosity of more than 20 dl/g, as measured in a tetralin solvent at 135° C.; and a component (A2) being a polymer selected from the group consisting of (A2-1) a propylene homopolymer, (A2-2) a random copolymer of propylene and an α-olefin having 2 or 4 to 8 carbon atoms, (A2-3) a block copolymer of propylene and an α-olefin having 2 or 4 to 8 carbon atoms, and a combination of the (A2-1), (A2-2), and (A2-3). The resin composition has a content of the component (A1) of 0.1 to 10 wt % and a content of the component (A2) of 99.9 to 90 wt % based on the total amount of the component (A1) and the component (A2). The component (A2) has a melt flow rate (MFR) (230° C., load: 2.16 kg) of 1 to 500 g/10 min.

3. 发明授权

US06872682B1 α-olefin polymerization catalyst system and its use for the polymerization of α-olefins 失效
标题翻译： α-烯烃聚合催化剂体系及其在α-烯烃聚合中的应用
公开(公告)号：US06872682B1
公开(公告)日：2005-03-29
申请号：US09890357
申请日：2000-02-11
申请人： Kauno Alastalo , Pauli Leskinen
发明人： Kauno Alastalo , Pauli Leskinen
IPC分类号： C08F4/655 , C08F4/44 , C08F4/657 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F10/00 , C08F2/44 , C08F4/6492 , C08F4/6491
摘要： A catalyst system for the polymerization of α-olefins prepared by a process which includes catalyst activation whereby a solid transitional metal compound is contacted with an organoaluminum compound and catalyst prepolymerization whereby a premonomer is prepolymerized in the presence of the activated catalyst. High activity, low fines polymerization can be achieved if in the first step of catalyst activation a first reaction mixture is prepared by contacting the solid transitional metal compound with a first organoaluminum compound in the presence of an oil and in the second step, the first reaction mixture is contacted with a second organoaluminum compound to give a second reaction mixture, the second organoaluminum compound being the same as or different from the first organoaluminum compound.
摘要翻译：用于通过包括催化剂活化的方法制备的α-烯烃聚合的催化剂体系，其中固体过渡金属化合物与有机铝化合物接触，催化剂预聚合，由此在活化催化剂存在下将预聚单体预聚合。如果在催化剂活化的第一步骤中，通过在油的存在下使固体过渡金属化合物与第一有机铝化合物接触来制备第一反应混合物，并且在第二步骤中，第一反应混合物与第二有机铝化合物接触，得到第二反应混合物，第二有机铝化合物与第一有机铝化合物相同或不同。

4. 发明授权

US6034023A Preparation of Ziegler-Natta catalyst systems 失效
标题翻译：齐格勒 - 纳塔催化剂体系的制备
公开(公告)号：US6034023A
公开(公告)日：2000-03-07
申请号：US943025
申请日：1992-09-10
申请人： Meinolf Kersting , Juergen Kerth , Klaus-Dieter Hungenberg , Peter Koelle
发明人： Meinolf Kersting , Juergen Kerth , Klaus-Dieter Hungenberg , Peter Koelle
IPC分类号： C08F4/654 , C08F4/60 , C08F4/642 , C08F4/646 , C08F4/648 , C08F4/651 , C08F4/657 , C08F10/00 , C08F4/64
CPC分类号： C08F10/00
摘要： A novel process for the preparation of Ziegler-Natta catalyst systems containing, as active components,a) a titanium-containing solid component which contains titanium, magnesium, halogen and a carboxylic ester and, as a cocatalyst,b) an aluminum compound andc) if required, a further electron donor is described. Ziegler-Natta catalyst systems which are obtainable by this process, the preparation of polymers of propylene with the aid of these catalyst systems, the polymers obtainable thereby and films and moldings of these polymers are also described.
摘要翻译：一种用于制备齐格勒 - 纳塔催化剂体系的新方法，其包含作为活性组分的a）含钛，镁，卤素和羧酸酯的含钛固体组分，并且作为助催化剂，b）铝化合物和c ）如果需要，描述另一电子给体。也可以通过该方法获得的齐格勒 - 纳塔催化剂体系，借助于这些催化剂体系制备丙烯的聚合物，由此得到的聚合物以及这些聚合物的膜和模制品。

5. 发明授权

US5369193A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US5369193A
公开(公告)日：1994-11-29
申请号：US967556
申请日：1992-10-27
申请人： Akira Sano , Takeichi Shiraishi , Kunihiro Suzuki , Mitsuo Okamoto , Kazuo Matsuura
发明人： Akira Sano , Takeichi Shiraishi , Kunihiro Suzuki , Mitsuo Okamoto , Kazuo Matsuura
IPC分类号： C08F4/60 , C08F4/657 , C08F4/658 , C08F4/685 , C08F10/00
CPC分类号： C08F10/00
摘要： Polyolefins exhibiting better particle properties are prepared by polymerizing an olefin or olefins in the presence of a catalyst comprising a solid catalyst component and an organometallic compound, the solid catalyst component being prepared by reacting the following components [I] and [II] at first and then reacting the reaction product thus obtained with the following component [III]:[I] a reaction product obtained by reacting:(1) a silicon oxide and/or an aluminum oxide, and(2) a titanium compound, or a titanium compound and a vanadium compound,[II] a reaction product obtained by the reaction of:(1) a magnesium halide,(2) a compound represented by the general formula Me(OR).sub.n X.sub.z-n wherein Me represents an element of J Groups I to IV in the Periodic Table, z represents the valence of the element Me, n is 0
摘要翻译：通过在包含固体催化剂组分和有机金属化合物的催化剂存在下聚合烯烃或烯烃制备出具有更好颗粒性能的聚烯烃，该固体催化剂组分通过首先使下列成分[I]和[II]反应而制备，然后将所得反应产物与以下组分[III]反应：[I]通过使（1）氧化硅和/或氧化铝反应获得的反应产物，和（2）钛化合物或钛化合物和钒化合物，[II]通过以下反应获得的反应产物：（1）卤化镁，（2）由通式Me（OR）n Xz-n表示的化合物，其中Me表示J组I 至IV元素，z表示元素Me的化合价，n为0

6. 发明申请

US20190055333A1 HETEROPHASIC PROPYLENE COPOLYMERS 审中-公开
公开(公告)号：US20190055333A1
公开(公告)日：2019-02-21
申请号：US15768875
申请日：2016-10-22
申请人： BASELL POLIOLEFINE ITALIA S.R.L.
发明人： PAOLA MASSARI , CAROLINE CATHELIN , GIAMPIERO MORINI , FABRIZIO PIEMONTESI , GIANNI VITALE , MARCO CIARAFONI , CLAUDIO CAVALIERI , ROBERTO PANTALEONI , MICHELE GRAZZI
IPC分类号： C08F210/06 , C08L23/16 , C08L23/12 , C08F4/657 , C08F4/659 , C08F2/00
摘要： A polypropylene composition made from or containing: A) from 50 wt % to 90 wt %; of a propylene homopolymer; B) from 10 wt % to 50 wt %; of a copolymer of propylene having from 30.0 wt % to 70.0 wt %, of ethylene derived units, based upon the total weight of the copolymer; the sum of the amount of component A) and B) being 100; the polypropylene composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 2.2 to 4.0 dl/g; ii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) from 0.5 to 100 g/10 min; iii) a xylene soluble fraction ranging from 20 wt % to 50 wt %, based upon the total weight of the polypropylene composition; wherein the polypropylene composition being obtained by a polymerization process wherein the catalyst system contains bismuth.

7. 发明申请

US20180265603A1 ZIEGLER-NATTA CATALYSTS DOPED WITH NON-GROUP IV METAL CHLORIDES 审中-公开
公开(公告)号：US20180265603A1
公开(公告)日：2018-09-20
申请号：US15918075
申请日：2018-03-12
申请人： FINA TECHNOLOGY, INC.
发明人： Lei Zhang , David Knoeppel
IPC分类号： C08F4/642 , C08F10/02 , C08F10/00 , C08F110/02 , C08F4/655 , C08F4/657
CPC分类号： C08F4/6421 , C08F10/00 , C08F10/02 , C08F110/02 , C08F2410/03 , C08F4/6557 , C08F4/6574 , C08F2500/04 , C08F2500/07 , C08F2500/11 , C08F2500/12 , C08F2500/17 , C08F2500/18 , C08F2500/20 , C08F2500/23 , C08F2500/26
摘要： A process may include contacting ethylene monomer with Ziegler-Natta catalyst to form polyethylene. The Ziegler-Natta catalyst may be formed by contacting an alkyl magnesium compound with an alcohol and a metal reagent to form a blend, and contacting the blend with a first agent to form a solution of reaction product “A”. The solution of reaction product “A” may be contacted with a second agent to form a solid reaction product “B”, and the solid reaction product “B” may be contacted with a third agent to form a solid reaction product “C”. The solid reaction product “C” may be contacted with a fourth agent to form a solid reaction product “D”, and the solid reaction product “D” may be contacted with a fifth agent to form a catalyst component.

8. 发明授权

US6136745A High activity polyethylene catalysts 失效
标题翻译：高活性聚乙烯催化剂
公开(公告)号：US6136745A
公开(公告)日：2000-10-24
申请号：US120113
申请日：1998-07-22
申请人： David John Ashton , Yury Viktor Kissin , Robert Ivan Mink
发明人： David John Ashton , Yury Viktor Kissin , Robert Ivan Mink
IPC分类号： C08F210/16 , C08F4/02 , C08F4/656 , C08F4/657 , C08F10/00 , C08F10/02 , B01J31/00 , B01J37/00 , C08F4/60
CPC分类号： C08F10/00 , C08F210/16 , Y02P20/52
摘要： The present invention relates to a high activity catalyst composition for the (co-)polymerisation of ethylene, optionally with an alpha olefin of 3 to 10 carbon atoms, comprising a catalyst precursor and an organoaluminium cocatalyst, wherein the catalyst precursor consists of:(i) a silica carrier material, having from 0.3 to 1.2 mmoles of OH groups per gram of silica,(ii) a dialkylmagnesium compound of the formula RMgR.sup.1, where R and R.sup.1 are the same or different C.sub.2 -C.sub.12 alkyl groups, in an amount comprised between 0.5 to 1.5 mmoles of dialkylmagnesium per gram of silica,(iii) a tetraalkyl orthosilicate, in which the alkyl groups contain from 2 to 6 carbon atoms, in an amount comprised between 0.2 to 0.8 mmoles per gram of silica,(iv) a chlorinated compound (X) having the formula R.sub.n SiCl.sub.4-n, wherein each R is the same or different and is hydrogen or an alkyl group and n is an integer from 0 to 3, in an amount comprised between 0.2 to 4 mmoles of X per gram of silica, and(v) a titanium compound in an amount comprised between 0.3 to 1.5 mmoles per gram of silica.
摘要翻译：本发明涉及一种用于（共）聚合乙烯（共聚）乙烯，含有3-10个碳原子的α-烯烃的高活性催化剂组合物，其包括催化剂前体和有机铝助催化剂，其中催化剂前体由以下组成：（i ）二氧化硅载体材料，每克二氧化硅具有0.3至1.2mmol的OH基团，（ii）式RMgR1的二烷基镁化合物，其中R和R 1是相同或不同的C 2 -C 12烷基，其量包括每克二氧化硅0.5至1.5毫摩尔二烷基镁，（iii）其中烷基含有2至6个碳原子的原硅酸四烷基酯，其含量为每克二氧化硅0.2至0.8毫摩尔，（iv）具有式RnSiCl4-n的氯化化合物（X），其中每个R相同或不同，为氢或烷基，n为0-3的整数，其含量为每克0.2至4毫摩尔X 的二氧化硅，和（v）钛酸盐 m化合物，其量为每克二氧化硅0.3至1.5毫摩尔。

9. 发明授权

US6051525A Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution 失效
标题翻译：用于制造具有宽或双峰分子量分布的聚乙烯的催化剂
公开(公告)号：US6051525A
公开(公告)日：2000-04-18
申请号：US892591
申请日：1997-07-14
申请人： Frederick Yip-Kwai Lo , Robert I. Mink , Thomas Edward Nowlin , Sandra Denise Schregenberger , Pradeep Pandurang Shirodkar
发明人： Frederick Yip-Kwai Lo , Robert I. Mink , Thomas Edward Nowlin , Sandra Denise Schregenberger , Pradeep Pandurang Shirodkar
IPC分类号： C08F10/02 , C08F4/22 , C08F4/64 , C08F4/646 , C08F4/657 , C08F4/659 , C08F4/6592 , C08F210/16
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/943
摘要： A catalyst composition is described for preparing a high activity catalyst in silica which produces, in a single reactor, polyethylene with a broad or bimodal molecular weight distribution. The catalyst is prepared from the interaction of silica, previously calcined at 600.degree. C., with dibutylmagnesium, 1-butanol and titanium tetrachloride and a solution of methylalumoxane and ethylenebis[1-indenyl]zirconium dichloride.
摘要翻译：描述了用于制备二氧化硅中的高活性催化剂的催化剂组合物，其在单个反应器中产生具有宽或双峰分子量分布的聚乙烯。催化剂由先前在600℃下煅烧的二氧化硅与二丁基镁，1-丁醇和四氯化钛的相互作用以及二甲基亚乙基双[1-茚基]二氯化锆的溶液制备。

10. 发明授权

US5348925A Catalyst for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US5348925A
公开(公告)日：1994-09-20
申请号：US20990
申请日：1993-02-22
申请人： Federico Milani , Luciano Luciani , Antonio Labianco
发明人： Federico Milani , Luciano Luciani , Antonio Labianco
IPC分类号： C08F4/658 , C08F4/60 , C08F4/657 , C08F10/00 , C08F110/00 , B01J31/00
CPC分类号： C08F10/00
摘要： A solid component of catalyst, active in the polymerization of propylene and other .alpha.-olefins in stereoregular polymers, is obtained:(i) by treating a non-activated silica support in particles with a tin tetrahalide, to at least partially block the hydroxylic groups of the silica and to obtain a blocked silica;(ii) by impregnating the blocked silica with magnesium dialkyl or magnesium alkyl halide to make the magnesium compound react with the tin compound and with possible residual hydroxylic groups of the silica and to obtain a support;(iii) by halogenating the support by contact with a halogenating agent selected from the halides of tin, antimonium or silicon to obtain a halogenated support;(iv) by titanating the halogenated support with an excess of a titanium tetrahalide to obtain a titanated support;(v) by putting the titanated support in contact with a Lewis base, to obtain a solid component of catalyst.
摘要翻译：获得在立体有规聚合物中丙烯和其它α-烯烃聚合中活性的催化剂的固体组分：（i）通过用四卤化锡处理颗粒中的未活化二氧化硅载体至少部分阻断羟基的二氧化硅，得到封闭的二氧化硅; （ii）通过用二烷基镁或烷基镁镁浸渍封闭的二氧化硅以使镁化合物与锡化合物反应，并与二氧化硅的可能的残余羟基反应并获得载体; （iii）通过与选自锡，锑或硅的卤化物的卤化剂接触来使载体卤化以获得卤化载体; （iv）通过用过量的四卤化钛钛酸化卤化载体以获得钛酸化的载体; （v）通过将钛酸盐载体与路易斯碱接触，得到催化剂的固体成分。

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