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    • 10. 发明授权
    • Method for the preparation of a polymeric shaped article containing an
electrically conductive polymer
    • 制备含有导电聚合物的聚合物成型制品的方法
    • US5338413A
    • 1994-08-16
    • US091715
    • 1993-07-15
    • Hans K. van DijkRonald M. A. M. Schellekens
    • Hans K. van DijkRonald M. A. M. Schellekens
    • C08G61/12C25B3/02C25D11/32
    • C08G61/124C08G61/126
    • Method for the preparation of a polymeric shaped article containing an electrically conductive polymer wherein a base shaped article possessing electrically conductive properties is moved along an anode, at least part of the article being in contact with the anode, in the presence of an electrolyte-containing medium containing monomer units, which on polymerization form an electrically conductive polymer and wherein a voltage is applied between the anode and a second electrode which is in contact with the electrolyte-containing medium. It has appeared that, in the method according to the invention, the shaped article does not adhere to the electrode so that the method may be practiced continuously. A further advantage of the shaped article failing to adhere to the electrode is that the method according to the invention generates very little waste. Furthermore, it has appeared that the method according to the invention allows a shaped article to be produced with a very short polymerization time, the electrically conductive polymer in which being homogeneously distributed. The applied base shaped article does not swell during wetting, so that the mechanical properties of the base shaped article do not deteriorate. As a result, if the method is applied, for instance, continuously, a higher rate of production can be applied.
    • 制备含有导电聚合物的聚合物成型制品的方法,其中具有导电性能的基底成型制品沿着阳极移动,至少部分制品与阳极接触,在含电解质的存在下 介质含有单体单元,其在聚合时形成导电聚合物,并且其中在阳极和与含电解质的介质接触的第二电极之间施加电压。 看来,在根据本发明的方法中,成形制品不粘附到电极上,使得可以连续地实施该方法。 成型制品未能粘附到电极的另一个优点是根据本发明的方法产生很少的浪费。 此外,似乎根据本发明的方法允许以非常短的聚合时间制造成形制品,其中均匀分布的导电聚合物。 所施加的基底成型制品在润湿期间不膨胀,使得基底成型制品的机械性能不劣化。 结果,如果例如连续地应用该方法,则可以应用更高的生产率。