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    • 6. 发明授权
    • Polyacrylate esters with ammonium salt groups
    • 具有氨基酸盐的聚丙烯酸酯
    • US5145914A
    • 1992-09-08
    • US665778
    • 1991-03-07
    • Eberhard EsselbornJurgen FockHelmut Lammerting
    • Eberhard EsselbornJurgen FockHelmut Lammerting
    • B01F17/52C08F8/44C08F20/34D06M13/02D06M13/322D06M13/467D06M13/47D06M13/477D06M15/267
    • C08F8/44
    • Polyacrylate esters with ammonium salt groups obtained by the transesterification of alkyl polyacrylates produced by free radical polymerization are disclosed, wherein the alkyl groups of the acrylate esters have 1 to 8 carbon atoms, up to 50% of the acrylate esters can be replaced by the corresponding methacrylate esters and the transesterification is carried out witha) compounds of the formula ##STR1## b) saturated or unsaturated aliphatic alcohols having 8 to 22 carbon atoms or alkoxylated alkylphenols having 9 to 27 carbon atoms in the alkylphenol group,wherein the molar ratio of component a) to component b) is 1:9 to 9:1, in such amount that 5 to 70% of the ester groups are transesterified and subsequently, the transesterification product is transformed into a salt. The new polyacrylate esters with ammonium salt groups are distinguished by containing a lesser amount of low molecular weight compounds than products obtained through copolymerization and can be used as cationic surfactants and particularly, as active ingredients of metal adjuvants.
    • 公开了通过通过自由基聚合制备的烷基聚丙烯酸酯的酯交换获得的具有铵盐基团的聚丙烯酸酯,其中丙烯酸酯的烷基具有1至8个碳原子,至多50%的丙烯酸酯可以被相应的 甲基丙烯酸酯和酯交换是用下列化合物进行的:a)下式化合物:b)烷基酚基中具有8-22个碳原子的饱和或不饱和脂族醇或具有9至27个碳原子的烷氧基化烷基酚,其中摩尔比 组分a)至组分b)为1:9至9:1,其用量为5至70%的酯基酯交换,随后将酯交换产物转化为盐。 具有铵盐基团的新的聚丙烯酸酯通过含有比通过共聚获得的产物更少量的低分子量化合物来区分,并且可以用作阳离子表面活性剂,特别是作为金属助剂的活性成分。