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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
1	一种氯化蓝蒽酮、紫蒽酮或异紫蒽酮的方法	CN202110013918.X	2021-01-06	CN112778789A	2021-05-11	贺潇寒
本发明公开了一种氯化蓝蒽酮、紫蒽酮或异紫蒽酮的方法，采用阴离子为过渡金属卤化物的Lewis酸类离子液体作为反应溶剂，磺酰氯、氯化亚砜或三光气中的任一种为氯化剂，在不低于室温且不高于120℃的氯化温度下，反应2～40小时，再经后处理得到目标产品。该技术方案从根源上切断了二噁英及其衍生物等有害物质的生成路线，产物中无二噁英类物质生成，且反应的原子利用率高、能耗低，填补了国内外化工技术领域的空白。利用本发明的技术方案制备得到的产品，在不使用硝基苯、氯苯等毒性较大的溶剂的前提下，质量也达到了国际先进水平，甚至质量更好，所得紫蒽酮、蓝蒽酮、异紫蒽酮的氯化物更亮、更艳。
2	一种还原蓝6的工业化合成方法	CN201911365680.6	2019-12-26	CN111087833A	2020-05-01	周坚彪; 汤学斌; 熊俊
本发明涉及染料技术领域，具体涉及一种还原蓝6的工业化合成方法，包括如下步骤：还原蓝4固体加入芳香惰性溶剂中，得到还原蓝4溶液或混悬液；向还原蓝4溶液或混悬液加入磺酰氯，加入过程中控制溶液温度为20~40℃；添加完成后，加热反应；反应完成后，向反应液中加入水稀释物料，并加入碱调节反应液pH为7~10；反应液pH调节完毕后，加热蒸馏反应液，溶剂蒸馏完毕后，将物料转到压滤机压滤，再用热水吹洗至pH值为5~8卸料，得到还原蓝6成品。本发明提供的还原蓝6的工业化合成方法使用的溶剂的热稳定性好而易于再生，物料质量能得到进一步的保证，同时溶剂可用物理方法水汽蒸馏回收套用循环套用，更好的利用资源，减少废酸、废盐的排放。
3	一种氯化蓝蒽酮、紫蒽酮或异紫蒽酮的方法	CN202110013918.X	2021-01-06	CN112778789B	2021-11-12	贺潇寒
本发明公开了一种氯化蓝蒽酮、紫蒽酮或异紫蒽酮的方法，采用阴离子为过渡金属卤化物的Lewis酸类离子液体作为反应溶剂，磺酰氯、氯化亚砜或三光气中的任一种为氯化剂，在不低于室温且不高于120℃的氯化温度下，反应2～40小时，再经后处理得到目标产品。该技术方案从根源上切断了二噁英及其衍生物等有害物质的生成路线，产物中无二噁英类物质生成，且反应的原子利用率高、能耗低，填补了国内外化工技术领域的空白。利用本发明的技术方案制备得到的产品，在不使用硝基苯、氯苯等毒性较大的溶剂的前提下，质量也达到了国际先进水平，甚至质量更好，所得紫蒽酮、蓝蒽酮、异紫蒽酮的氯化物更亮、更艳。
4		DEI0048872	1934-01-27	DE615535C	1935-07-06	MUELLER DR JOACHIM; KOEBERLE DR KARL

5		JP3440584	1984-02-27	JPH0257095B2	1990-12-04	KATO KIMITOSHI; AIGA HIROSHI; MIKOTA TAMIO; SAKAI TSUNEHIRO

6	VERFAHREN ZUR HERSTELLUNG VON 6,15-DIHYDRO-5,9,14,18-ANTHRAZINTETRON UND CHLORIERUNGSPRODUKTEN DAVON.	CH292284	1984-06-15	CH661738A5	1987-08-14	KATO KIMITOSHI; AIGA HIROSHI; MIKODA TAMIO; SAKAI TUNEHIRO

7		FR718154D	1930-06-04	FR718154A	1932-01-20

8		CS221071	1971-03-26	CS149077B1	1973-05-24

9	Colouration of materials made of or containing cellulose esters or ethers	GB41331	1931-01-05	GB374839A	1932-06-06
Cellulose esters or ethers, dyeing; vat dyes, dyeing with; printing.--Cellulose ester or ether materials, whether alone or in admixture with other fibres, are dyed, printed, stencilled, or otherwise coloured with dyestuffs containing a single anthraquinone nucleus linked to a second cyclic residue through a heterocyclic grouping. Suitable dyestuffs are the anthraquinonexanthones, -acridones, -thioxanthones, -oxazines, -azines, -thiazines, -dioxides, -carbazoles, and -thiazoles which may be substituted in the anthraquinone residue and/or the aryl residue or residues, e.g. by amino, alkylamino, oxyalkylamino, acylamino, alkyl, hydroxy, or alkoxy groups, or by halogen atoms. The dyestuffs may be applied by any convenient methods, e.g. (1) from vats containing hydrosulphite or other reducing agent and ammonia or an organic base such as methylamine, ethylamine, propylamine, mono-, di-, or triethanolamine, cyclohexylamine, pyridine, or piperidine; (2) as aqueous suspensions or dispersions such as are obtainable by the processes described in Specifications 219,349, 224,925, 242,393, 242,711, 269,960, 273,819, 273,820, 322,737, and 323,788, [all in Class 2 (iii), Dyes &c.]. The dyestuffs may also be used to produce coloured discharges, e.g. by the process of Specification 351,457. The following examples are specified. (1) A cellulose acetate knit fabric is dyed orange-yellow by vatting at temperatures rising to 75 DEG C. in an aqueous liquor containing the dyestuff 3<1> : 4<1> - dichlor - 1 : 2 - anthraquinonethioxanthone, turkey red oil, sodium hydrosulphite, and methylamine, and thereafter oxidizing in a bath containing sodium perborate and soap. (2) A cellulose acetate woven fabric is dyed reddish violet by vatting at temperatures rising to 80 DEG C. in an aqueous liquor containing the dyestuff 1 : 2 : 5 : 6-anthraquinone-diacridone, monopol soap, sodium hydrosulphite, and mono-ethanolamine, and thereafter oxidizing in a bath containing hydrogen peroxide and soap. (3) Cellulose acetate yarn is dyed pink by treatment at 75-80 DEG C. in an aqueous bath containing the dyestuff 1 : 2-anthraquinone-acridone dispersed with pyridine and turkey red oil. The following additional dyestuffs are specified, viz. 3<1> : 4<1>-dichlor-1(NH) : 2(CO)-anthraquinone - acridone, anthraquinone - 1(NH) : 2(CO) - 2<1> : 1<1> - naphthacridone and 2<1> : 5<1>-dichlor-1 : 2-anthraquinone-thioxanthone. The use of the processes of Specifications 262,506, 263,473, [both in Class 15 (ii), Dyeing, Processes &c. for], and 341,408, and the use of anthraquinone-naphthacridones obtained by replacing one or more halogens in a 5 : 8 - dihalogenanthraquinone - 2 : 1(b )-naphthacridone by amino, alkylamino, or acyclic or monocyclic acylamino or acylimino groups are disclaimed. Specifications 197,281, 227,183, 284,376, and 285,104, [all in Class 15 (ii), Dyeing, Processes &c. for], also are referred to. The Provisional Specification describes also the use of dyestuffs in general in which two adjacent carbon atoms of an anthraquinone residue form part of a carbocyclic or heterocyclic ring, and specifies the use of 1 : 2 - benzanthraquinone, 1 - oxy - 2 : 3 - benzanthraquinone, anthraquinone-quinolines, and anthraquinone-thiazines such as 1 : 2-anthraquinone-keto-dihydrothiazine.
10		FR37890D	1930-01-11	FR37890E	1931-02-04

11	HALOGENATION OF POLYCYCLIC VAT DYEING DYE OR ITS POLYCYCLIC PRECURSOR	JP8647191	1991-04-18	JPH04227764A	1992-08-17	HERUMUUTO HOTSUHO; HAINRITSUHI KOBUARUSHIYU

12	PRODUCTION OF VAT DYE	JP3440584	1984-02-27	JPS60179462A	1985-09-13	KATOU KIMITOSHI; AIGA HIROSHI; MIKOTA TAMIO; SAKAI TSUNEHIRO
PURPOSE:To obtain a vat dye of good quality in a high yield, by chlorinating a specified condensation product obtd. by a reaction in the presence of 1,3-dimethyl-2-imidazolidinone. CONSTITUTION:0.1-10pts.wt. alkaline condensing agent such as KOH and optionally a wetting agent such as an alkali metal naphthalenesulfonate are added to one pt. 1-aminoanthraquinone in the form of a powder or a slurry while introducing an oxidizing agent such as air. A condensation reaction is conducted in the presence of 0.1-10pts.wt. 1,3-dimethyl-2-imidazolidinone at 80-150 deg.C to obtain a condensation reaction product. The product is slurried in water and reduced with hydrotalcite in the presence of an alkali metal hydroxide. The resulting crystal is recovered by filtration and slurried in water. The resulting dianthraquinone-N,N-dihydroamine or the above product is chlorinated in sulfuric acid. The product is recovered by filtration and the filter cake is completely dissolved in 98% sulfuric acid and reduced with Al powder to obtain a vat dye of the formula, wherein n is 1, 2.
13	Manufacture of chlorinated indanthrone compounds	US70851834	1934-01-26	US2035459A	1936-03-31	EDWARD BURGOINE; WILLIAM SOUTAR CHARLES

14		DE4014172	1990-05-02	DE4014172A1	1991-11-07	HOCH HELMUT DR; KOWARSCH HEINRICH DR

15		DEI0048926	1934-02-02	DE605939C	1934-11-22
Chorinated indanthrones are obtained by heating b -aminoanthraquinone with antimony pentachloride and selenium or a selenium chloride in nitrobenzene with, if desired a copper catalyst. The formation of flavanthrone in this reaction is prevented or hindered. According to examples, the reaction is performed in presence of selenium, and selenium with varying small quantities of copper acetate at temperatures of 120 to 170 DEG C.
16	Verfahren zur Herstellung eines gechlorten Indanthrens.	CH172374D	1934-01-26	CH172374A	1934-10-15	INDUSTRIES LIMITED IMPERIAL CH

17	Verfahren zur Herstellung eines chlorierten Derivats des 1.2.2'.1'-anthrachinonazins.	CH85230D	1917-02-27	CH85230A	1920-06-01	BASEL GESELLSCHAFT FUER CHEMIS

18		DE4217954	1992-05-30	DE4217954A1	1993-12-02	SCHMITT MICHAEL DR

19	Manufacture of indanthrone compounds	GB324833	1933-02-02	GB414136A	1934-08-02
Chorinated indanthrones are obtained by heating b -aminoanthraquinone with antimony pentachloride and selenium or a selenium chloride in nitrobenzene with, if desired a copper catalyst. The formation of flavanthrone in this reaction is prevented or hindered. According to examples, the reaction is performed in presence of selenium, and selenium with varying small quantities of copper acetate at temperatures of 120 to 170 DEG C.
20		FR768093D	1934-02-02	FR768093A	1934-07-31
Chorinated indanthrones are obtained by heating b -aminoanthraquinone with antimony pentachloride and selenium or a selenium chloride in nitrobenzene with, if desired a copper catalyst. The formation of flavanthrone in this reaction is prevented or hindered. According to examples, the reaction is performed in presence of selenium, and selenium with varying small quantities of copper acetate at temperatures of 120 to 170 DEG C.

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