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序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
101 AMMONIUM LIGNOSULFONATES GB8524193 1985-10-01 GB2168970A 1986-07-02 DILLING PETER
A method of producing ammonium salts of sulfomethylated lignins suited for use as dyestuff and coal-water slurry additives comprising of the steps of ionizing the phenol component of a lignin material by-product of the black liquor of a kraft paper-making process in an alkaline liquid medium, methylolating the lignin material, lowering the pH of the liquid medium to an acid pH to precipitate the methylolated lignin material, washing the precipitated lignin material with water to remove inorganic salts and residual reactants therefrom, and sulfonating the washed, purified methylolated lignin material with an ammonium salt of a sulphur-oxygen containing compound in a liquid medium. The washed, purified methylolated lignin material is preferably sulfonated at an acid pH level to minimize the production of electrolytes when the lignin is to be used for dyeing at low pH. Lignin products produced by the method, as well as dye and coal-water slurry compositions containing such products are also disclosed.
102 NO802235 1980-07-24 NO153732C 1986-05-14 LIN STEPHEN Y
Dispersants particularly useful for insoluble dyes such as disperse and vat dyes are lignin adducts made from sulfonated lignin materials, which include spent sulfite liquors, sulfonated lignin and lignosulfonates, by reaction with mono or polyhydroxyl benzyl alcohol compounds, and are characterised by high levels of heat stability, desirable dye reduction, staining, foaming, milling and viscosity-reducing properties. Dyestuffs, dye pastes and dye baths, as well as methods utilizing them, are disclosed.
103 UN PROCEDIMIENTO PARA PREPARAR UN FUELOLEO PRE-ATOMIZADO COMBUSTIBLE. ES537272 1984-10-31 ES8605569A1 1986-03-16
PROCEDIMIENTO PARA LA PREPARACION DE UN FUELOLEO PRE-ATOMIZADO COMBUSTIBLE A PARTIR DE UN HIDROCARBURO VISCOSO. COMPRENDE LAS SIGUIENTES OPERACIONES: PRIMERA, SE DISUELVE O DISPERSA EN UNA FASE ACUOSA UNA CANTIDAD ADECUADA DE UN PAQUETE DE AGENTES TENSIOACTIVOS, QUE COMPRENDE AL MENOS UN AGENTE TENSIOACTIVO SOLUBLE EN AGUA, CAPAZ DE FORMAR UNA EMULSION DE HIDROCARBURO EN AGUA, Y AL MENOS UN BIOEMULSIFICADOR SOLUBLE EN AGUA, CAPAZ DE ESTABILIZAR UNA EMULSION DE HIDROCARBURO EN AGUA; SEGUNDA, SE PONE EN CONTACTO LA FASE ACUOSA QUE CONTIENE EN PAQUETE DE AGENTES TENSIOACTIVOS CON UN HIDROCARBURO VISCOSO; Y POR ULTIMO, SE MEZCLA EL HIDROCARBURO Y LA FASE ACUOSA CON SUFICIENTE AGITACION, PARA FORMAR UNA EMULSION DE HIDROCARBURO EN AGUA.
104 DISPERSING AGENTS FOR DISPERSE AND VAT DYES GB8509743 1985-04-16 GB2157719A 1985-10-30 DILLING PETER
Improved dyestuff compositions are disclosed herein comprising, as dispersants, sulfonated lignins prepared by selectively isolating lignins having molecular weights greater than 5,000 and subsequently reacting the lignin with sodium sulfite and an aldehyde.
105 PREPARING LIGNOSULFONATES GB8503314 1985-02-08 GB2157681A 1985-10-30 DILLING PETER
Disclosed herein is a process for preparing sulfonated lignins by selectively isolating lignins having molecular weights greater than 5,000 and subsequently reacting the lignin with sodium sulfite and an aldehyde. The resulting sulfonated lignins are useful as dispersants for disperse dyes and vat dyes.
106 DE3511627 1985-03-29 DE3511627A1 1985-10-17 DILLING PETER
Improved dyestuff compositions are disclosed herein comprising, as dispersants, sulfonated lignins prepared by selectively isolating lignins having molecular weights greater than 5,000 and subsequently reacting the lignin with sodium sulfite and an aldehyde.
107 DE3506601 1985-02-25 DE3506601A1 1985-10-17 DILLING PETER
Disclosed herein is a process for preparing sulfonated lignins by selectively isolating lignins having molecular weights greater than 5,000 and subsequently reacting the lignin with sodium sulfite and an aldehyde. The resulting sulfonated lignins are useful as dispersants for disperse dyes and vat dyes.
108 BR8404548 1984-09-12 BR8404548A 1985-08-06 DILLING PETER
Non-sulfonated lignin color reductions of over 90 percent, and in some cases as high as 95 percent, are achieved by a three-step process involving (1) methylolating or crosslinking the lignin, (2) the blocking of phenolic groups on the lignin molecule with blocking agents followed by (3) oxidation with chlorine dioxide. The light colored lignin dispersants produced by the invention process exhibit very low staining and low azo dye reduction, good heat stability, dye grinding efficiency, and dispersion stability.
109 ZPUSOB VYROBY DISPERGATORU ZE SULFITOVYCH VYLUHU A NEBO SULFITOVYCH VYPALKU CS657584 1984-08-31 CS657584A1 1985-06-13 SESTAUBER KAREL ING; KUDRNA STANISLAV ING CSC; LORENC JOSEF; MACA KAREL ING; MAXA MILAN INGSESTAUBER KAREL; MAXA MILAN ING; RUZICKA KAREL ING; SVOBODA EDUARD
110 BIOEMULSIFIER-STABILIZED HYDROCARBOSOLS AU3556584 1984-10-15 AU3556584A 1985-05-22 EDWARD HAYES MICHAEL; ROBERT HREBENAR KEVIN; LORD MURPHY PATRICIA
Methods and compositions are provided to facilitate the transportation and combustion of highly viscous hydrocarbons by forming reduced viscosity hydrocarbon-in-water emulsions, and in particular, bioemulsifier-stabilized hydrocarbon-in-water emulsions.
111 FR7911121 1979-05-03 FR2424952B1 1985-04-26
A drilling fluid additive effective as a viscosity controlling agent is composed of water-soluble complex titanium, zlrconium, titanium-iron or zirconium-iron lignosulfonate. The lignin component of the lignosulfonate may be in either oxidized or unoxidized form.
112 SE7706992 1977-06-16 SE437842B 1985-03-18 DETROIT W J
Valuable new and widely useful compositions of matter are comprised of products having enhanced solubility and increased dispersant and the like surfactant activity which products are ozonated (so as to be oxidized) lignosulfonate derivatives beneficially including ozonated units of alkaline oxidized, hydrolyzed, partially desulfonated lignosulfonates.
113 DD25325983 1983-07-21 DD219395A1 1985-03-06 NOLL BERND; SCHREINER GERD; HILLE GERT; HARTMANN MARLIES; DREISSIG WALTER; KEHRER UDO; KNOP PETER; EBELING HARRY
114 PROCESS FOR PRODUCING A SUSPENSION OF SOLID FUEL/WATER YU292876 1976-12-01 YU39374B 1984-10-31 COLE E L; HESS H V; GUPTILL F E
Preparation of a solid fuel-water slurry suitable for use as feed to a partial oxidation zone for the production of synthesis gas by forming a mixture of finely-divided solid fuel and water, heating the mixture to a temperature above 300 DEG F. under pressure sufficient to maintain water in the liquid phase, cooling the mixture and adding a surface active agent and sufficient water to form a mixture having a water content between 40 and 50 weight %.
115 NO771082 1977-03-28 NO150962B 1984-10-08 DETROIT WILLIAM JOHN; SANFORD MICHAEKL ELLIOT
Valuable new and widely used compositions of matter are comprised of products having enhanced solubility and increased dispersant and the like surfactant activity which products are resulfonated units of alkaline oxidized, hydrolyzed, partially desulfonated lignosulfonates.
116 OA57816 1982-10-06 OA07224A 1984-04-30 DELESCLUSE CHARLES
The wettable powders contain, mixed with one or more hydrophobic solid substances, a) at least one dispersing agent chosen from lignosulphonates and condensates of the naphthalenesulphonic acid-formaldehyde type, and b) at least one surface-active agent chosen from phosphoric esters, converted into salts or otherwise, of a branched or unbranched C2-C10 aliphatic alcohol, the total quantity of dispersing agent(s) and of surface-active agent(s) being between 1 and 6 parts by weight per 100 parts by weight of hydrophobic solid substances and it being possible for the proportion of dispersing agent(s) in this total quantity to range from 35 to 85% by weight. These powders have excellent wettability and dispersibility in water properties and a very low foamability.
117 BR8300948 1983-02-23 BR8300948A 1984-04-03 GROOTE ROBERT A M C DE; NEUMANN MIGUEL G; CERQUEIRA MIRABEL; MENDONCA JOSE EDUARDO DE; BERNARDO REINALDO LUIS
118 PROCESS FOR THE EXTRACTION OF ZINC FORM ZINC BEARING SULFUR CONTAINING MINERAL SULFIDES YU292573 1973-11-13 YU36542B 1984-02-29 PAUL KAWULKA; KAWULKA PAUL; WALTER HAFFENDEN J; HAFFENDEN J WALTER; VLADIMIR MACKIW N; MACKIW N VLADIMIR
Rapid and substantially complete extraction of zinc from zinc and iron containing sulphides is obtained by leaching the sulphides under oxidizing conditions at a temperature above the melting point of sulphur with an aqueous sulphuric acid solution containing at least the stoichiometric amount of acid required to combine with the zinc content of the sulphides as zinc sulphate and, also, containing an additive which is effective to prevent or at least substantially inhibit the molten sulphur from occluding unleached zinc sulphide particles thereby enabling the leaching reaction to continue until substantially all zinc values are extracted. Additives which are suitable for the process include lignins, lignosulphonates, tannin compounds, particularly quebracho, and other tree bark extracts, and alkylaryl sulphonates.
119 DE2357280 1973-11-16 DE2357280C2 1984-01-26 KAWULKA, PAUL; HAFFENDEN, WALTER J., FORT SASKATCHEWAN, ALBERTA, CA; MACKIW, VLADIMIR N., ISLINGTON, ONTARIO, CA
Rapid and substantially complete extraction of zinc from zinc and iron containing sulphides is obtained by leaching the sulphides under oxidizing conditions at a temperature above the melting point of sulphur with an aqueous sulphuric acid solution containing at least the stoichiometric amount of acid required to combine with the zinc content of the sulphides as zinc sulphate and, also, containing an additive which is effective to prevent or at least substantially inhibit the molten sulphur from occluding unleached zinc sulphide particles thereby enabling the leaching reaction to continue until substantially all zinc values are extracted. Additives which are suitable for the process include lignins, lignosulphonates, tannin compounds, particularly quebracho, and other tree bark extracts, and alkylaryl sulphonates.
120 NO791429 1979-04-27 NO148036C 1983-07-27 JAVORA PAUL HENRY; GREEN BETHEL QUINTON
A drilling fluid additive effective as a viscosity controlling agent is composed of water-soluble complex titanium, zlrconium, titanium-iron or zirconium-iron lignosulfonate. The lignin component of the lignosulfonate may be in either oxidized or unoxidized form.