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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
181	Carbon fibrils, method for producing same and compositions containing same	US678701	1984-12-06	US4663230A	1987-05-05	Howard G. Tennent
This invention concerns an essentially cylindrical discrete carbon fibril characterized by a substantially constant diameter between about 3.5 and about 70 nanometers, e.g. between about 7 and 25 nanometers, length greater than about 10.sup.2 times the diameter, an outer region of multiple essentially continuous layers of ordered carbon atoms and a distinct inner core region, each of the layers and core disposed substantially concentrically about the cylindrical axis of the fibril. Preferably the entire fibril is substantially free of thermal carbon overcoat. The invention further concerns a plurality of such fibrils.The fibril or plurality of fibrils of this invention may be produced by contacting for an appropriate period of time and at suitable pressure a suitable metal-containing particle with a suitable gaseous, carbon-containing compound, at a temperature between about 850.degree. C. and 1200.degree. C., the ratio on a dry weight basis of carbon-containing compound to metal containing particle being at least about 100:1.The fibrils are useful in composites having a matrix of e.g., an organic polymer, an inorganic polymer or a metal. In one embodiment the fibrils are incorporated into structural materials in a method of reinforcement. In other embodiments the fibrils may be used to enhance the electrical or thermal conductivity of a material, to increase the surface area of an electrode or capacitor plate, to provide a support for a catalyst, or to shield an object from electromagnetic radiation.
182	Process for modifying the surface characteristics of carbon substrates and composite articles produced from the treated substrates	US35052173	1973-04-12	US3865705A	1975-02-11	RIEUX JEAN-PHILIPPE; LEHUREAU JEAN
Disclosed is a method for modifying and improving the surface characteristics of a carbon substrate which comprises subjecting the carbon substrate to alternating treatment as an anode and a cathode by passage of current in an electrolytic cell wherein the carbon substrate acts as one electrode and there is provided a second electrode, both in an aqueous electrolyte solution. The modified carbon substrates impart improved mechanical properties to composite articles produced using same as reinforcing elements.
183	Flexible activated carbon fibers manufactured from salt impregnated cellulosic fibers	US22378272	1972-02-04	US3847833A	1974-11-12	BAILEY A; MAGGS F
1. A PROCESS FOR THE PRODUCTION OF A STRONG, FLEXIBLE, HIGHLY ACTIVATED FIBROUS CARBON HAVING A BREAKING STRENGTH OF AT LEAST 30,000 P.S.I., A CARBON TETRACHLORIDE SORBENCY OF AT LEAST 50% BY WEIGHT AND SUFFICIENTLY FLEXIBLE TO FOLD BACK UPON ITSELF WITHOUT FRACTURE AROUND A RADIUS OF CURVATURE OF 0.5 MM., FROM A FIBROUS CELLULOSIC MATERIAL, SAID PROCESS COMPRISING: CONTACTING THE SAID FIBROUS CELLULOSIC MATERIAL WITH AN AQUEOUS SOLUTION CONTAINING BETWEEN 1-30% BY WEIGHT OF AT LEAST ONE IMPREGNATED SELECTED FROM THE GROUP CONSISTING OF HALIDES OF ZINC, ALUMINUM, BARIUM, CALCIUM, MAGNESIUM AND IRON TO IMPREGNATE THE FIBROUS CARBOHYDRATE MATERIAL WITH BETWEEN 0.1 AND 10% BY WEIGHT OF THE SAID IMPREGNANT CATIONS, DRYING THE IMPREGNATED FIBROUS CELLULOSIC MATERIAL AT A TEMPERATURE IN THE RANGE OF 100* TO 140C., FLEXING THE FIBERS OF THE DRIED MATERIAL TO RESTORE A MAJOR PROPORTION OF ANY FLEXIBILITY LOST DURING THE IMPREGNATION AND DRYING OF THE FIBROUS CELLULOSIC MATERIAL, CARBONIZING THE MATERIAL BY HEATING IN AN INERT ATMOSPHERE TO A CARBONIZING TEMPERATURE THROUGH THE CRITICAL DECOMPOSITION TEMPERATURE RANGE WHICH EXTENDS FOR BETWEEN 40C. AND 80C. WITHIN THE TEMPERATURE LIMITS 70C. AND 300C. AND MAINTAINING THE TEMPERATURE WITHIN THE SAID CRITICAL TEMPERATURE RANGE FOR A TIME WHICH IS AT LEAST FIFTEEN MINUTES FOR A CRITICAL TEMPERATURE RANGE OF 40C. INCREASING PROGRESSIVELY TO AT LEAST THIRTY MINUTES FOR A CRITICAL TEMPERATURE RANGE OF 80C., AND ACTIVATING THE CARBONIZED MATERIAL BY CONTACT AT AN ACTIVATION TEMPERATURE BETWEEN 600C. AND 1000*C. WITH AN ACTIVATING GAS SELECTED FROM THE GROUP CONSISTING OF STEAM AND CARBON DIOXIDE UNTIL THE ACTIVATE HAS A CARBON TETRACHLORIDE SORBENCY OF AT LEAST 50% BY WEIGHT.
184	Treatment of carbon or graphite fibers and yarns for use in fiber reinforced composites	US3671411D	1970-03-03	US3671411A	1972-06-20	RAY JAMES D; STEINGISER SAMUEL; CASS ROBERT A
Carbon fiber or yarn as used in fiber reinforced composites is electrolytically treated to improve the surface characteristics and thereby to improve its bonding or adhesion to the matrix material. By this improved bonding, shear strengths of resultant fiber resin or plastic composites have been more than doubled. The electrolytic treatment is conducted by using the fiber or yarn as the anode and using en electrolyte such as an aqueous caustic solution.
185	Production of high temperature resistant continuous filaments	US3495940D	1967-09-28	US3495940A	1970-02-17	STUETZ DAGOBERT E

186	一种电石墨烯复合纤维的制备方法	PCT/CN2014/072689	2014-03-03	WO2015014124A1	2015-02-05	高超; 胡晓珍; 周晓松; 徐焰
本发明实施例提供了一种石墨烯复合纤维，包括石墨烯片以及将所述石墨烯片聚合在一起的聚合物，所述聚合物包括超支化聚合物以及聚乙烯醇中的一种或两种，所述石墨烯片与聚合物形成相互堆叠的层状结构且所述石墨烯片沿所述石墨烯复合纤维的轴向规整排列。上述石墨烯复合纤维的制作方法选用氧化石墨烯作为原料，大大提高了石墨烯复合纤维的拉伸强度；所述聚合物的加入为复合纤维提供了良好的韧性；纺丝过程采用旋转的凝固剂，给凝胶纤维增加了拉伸力，使其具有高取向和规整度，大大提高了所得固体纤维的强度；最后的还原过程很好的恢复了石墨烯的导电性能。
187	EQUIPMENT FOR THE MANUFACTURE OF TEXTILE THREADS COATED WITH A LAYER OF A PRECIOUS METAL, IN PARTICULAR GOLD	PCT/IB2012/053026	2012-06-15	WO2012172514A1	2012-12-20	PEPE, Guglielmo; GUERRA, Giovanni
The equipment (1) comprises a creel (2) with a plurality of bobbins (3) onto which is wound base threads (4) of natural or synthetic yarn (5) provided with a coating (6) of electroconducting material, in particular silver, a gathering structure (7), with a plurality of motor-driven winding bobbins (8) intended to draw and receive the coated threads (9); distribution and guidance devices (12, 13) intended to arrange the base yarn (4) in at least one essentially horizontal group (14) of parallel threads along a defined route between the creel (2) and the gathering structure (7), and electroplating equipment (15) in which there is a plurality of successive galvanic baths along the route containing a solution of a noble or precious metal salt. The arrangement is such that in operation at least one group (14) of threads is successively immersed in the bath present in the vats (17-23) of the electroplating equipment (15) and the threads therein are galvanically coated with a layer (9a) of noble or precious material of progressively increasing thickness.
188	FLUOROPOLYMER FINE FIBER	PCT/US2008/071800	2008-07-31	WO2009018463A3	2009-02-05	FERRER, Ismael; YANG, Chuanfang
A layer of fluoropolymer fine fiber can be made. The fine fiber can be made by electrospinning from a solvent or a solvent blend. The layers of the invention are useful in general filtration of fluid streams including gaseous and liquid streams. The fine fiber layers are also useful as hydrophobic filtration layers that can be used to separate water from a hydrocarbon stream.
189	METHOD FOR ELECTROCHEMICALLY PRODUCING CARBON MATERIAL WITH ITS SURFACE MODIFIED BY FUNCTIONALISED GROUPS, NOVEL CARBON MATERIAL WITH MODIFIED SURFACE AND ITS APPLICATION	PCT/FR1998/000437	1998-03-05	WO98040540A1	1998-09-17
The invention concerns a method for electrochemically producing carbon material with its surface modified by functionalised groups, characterised in that it consists in contacting said carbon material with a solution in a protic or aprotic solvent, of a functionalised organic radical carboxylate salt (R) capable of being subjected to Kolbe's test, optionally containing a electrolyte, in positively polarising the carbon material with respect to a cathode also in contact with said salt solution and recuperating the modified carbon material. The invention also concerns the carbon materials modified at the surface with arylmethyl groups and the use of these modified materials, for example for producing composite materials.
190	MOLECULAR SELF-ASSEMBLY OF ELECTRICALLY CONDUCTIVE POLYMERS	PCT/US9407182	1994-06-24	WO9502251A3	1995-03-02	RUBNER MICHAEL F; CHEUNG JOSEPHINE HO-WAH
A molecular self-assembly process based on the alternating deposition of a p-type doped electrically conductive polycationic polymer and a conjugated or nonconjugated polyanion or water soluble, non-ionic polymer has been developed. In this process, monolayers of electrically conductive polymers are spontaneously adsorbed onto a substrate from dilute solutions and subsequently built-up into multilayer thin films by alternating deposition with a soluble polyanion or water soluble, non-ionic polymer. In contrast to a deposition process involving the alternate self-assembly of polycations and polyanions, this process is driven by non-covalent bonded attractions (for example, ionic and hydrogen bonds) developed between a p-type doped conducting polymer and a polymer capable of forming strong secondary bonds. The net positive charge of the conducting polymer can be systematically adjusted by simply varying its doping level. Thus, with suitable choice of doping agent, doping level and solvent, it is possible to manipulate a wide variety of conducting polymers into exceptionally uniform multilayer thin films with layer thicknesses ranging from a single monolayer to multiple layers.
191	一种热化学气相沉积制备三维石墨烯纤维的方法及其应用	PCT/CN2018/080267	2018-03-23	WO2019095602A1	2019-05-23	于杰; 曾杰
一种热化学气相沉积制备三维石墨烯纤维的方法及其应用，在这种纤维中石墨烯片固定在纤维上，片的厚度、密度、生长速率可通过改变生长气氛和温度来调控，解决了石墨烯团聚的问题，石墨烯片边缘层数可达单层，片与片彼此接触形成了良好的三维的导电网络，电导率高达1.2×10 ⁵Sm ^-1。这种三维石墨烯纤维材料具有超疏水的功能，接触角达到165 ^。，同时对有机物有良好的吸附作用，接触角接近0 ^。。此外，三维石墨烯纤维具有出色的电磁屏蔽功能，3μm厚的自支撑三维石墨烯纤维材料的比电磁屏蔽效能高达60932dBcm ²/g。由于三维石墨烯纤维材料独特的结构和性质，其在功能复合材料、水处理、电磁屏蔽、传感器和能源领域具有多方面的应用潜力。
192	СПОСОБ СТАБИЛИЗАЦИИ УГЛЕРОДСОДЕРЖАЩЕГО ВОЛОКНА И СПОСОБ ПОЛУЧЕНИЯ УГЛЕРОДНОГО ВОЛОКНА	PCT/RU2010/000421	2010-07-28	WO2011014105A1	2011-02-03	СОБОЛЕВА, Марина Владимировна; УСОВ, Виталий Викторович; ШМЫРЕВ, Владислав Васильевич
Группа изобретений относится к области получения высокопрочных углеродных волокон, преимущественно изготавливаемых из органического исходного материала (предшественника). Заявлен способ стабилизации углеродсодержащего волокна (предшественника), в котором волокно, помещенное в газовую среду, подвергают обработке микроволновым излучением с одновременным нагревом газовой среды. Волокно в частном случае помещают в рабочую камеру с расположенной внутри нее газовой средой, нагрев газовой среды осуществляют путем нагрева камеры (например, ее стенок) одновременно с обработкой волокна микроволновым излучением. Согласно второму аспекту изобретения заявлен способ получения углеродного волокна, который включает в себя по крайней мере этапы стабилизации и карбонизации волокна, в котором стабилизацию предшественника осуществляют вышеописанным способом путем воздействия на волокно микроволновым излучением с одновременным нагревом среды, в которой помещено волокно. После карбонизации волокна, как вариант, возможно его дополнительная графитация. При необходимости карбонизация и/или графитация стабилизированного волокна также может осуществляться путем его комплексной обработки микроволновым излучением с одновременным нагревом среды, в которую волокно помещено для карбонизации/графитации. В результате снижается время стабилизации волокон предшественников, что влечет за собой снижение энергозатрат и повышение производительности процесса получения углеродного волокна.
193	WRINKLE REDUCTION IN UNCURED COMPOSITE LAMINATES	PCT/US2009/058688	2009-09-29	WO2010039665A1	2010-04-08	GUZMAN, Juan C; MCCARVILLE, Douglas A; ROTTER, Daniel M.; WASHBURN, Todd J; WILLDEN, Kurtis S; DARROW, Donald C
Wrinkles are removed from fiber reinforced resin plies of an uncured composite layup by subjecting the wrinkles to vibration and pressure.
194	STRUCTURE FIBREUSE TRIDIMENSIONNELLE EN FIBRES REFRACTAIRES, PROCEDE POUR SA REALISATION ET APPLICATION AUX MATERIAUX COMPOSITES THERMOSTRUCTURAUX.	PCT/FR0302692	2003-09-11	WO2004025003A3	2004-05-06	OLRY PIERRE; BRETON YANNICK CLAUDE; BONNAMY SYLVIE; NICOLAUS NATHALIE; ROBIN-BROSSE CHRISTIAN; SION ERIC
Des nanotubes de carbone sont incorporés à la structure fibreuse par croissance sur les fibres réfractaires du substrat, de manière à obtenir une structure tridimensionnelle en fibres réfractaires enrichie en nanotubes de carbone.
195	CONDUCTIVE NONWOVEN	PCT/EP0111194	2001-09-27	WO0231841A3	2002-06-27	JOERDER KURT; SCHAEFER WERNER; RETTIG HANS; SALAMA KARIM; BOCK ACHIM; WAGENER SILKE; HELMBOLD AXEL
The invention relates to a conductive nonwoven, which is carbonized and/or graphitized and has a flexural strength of < 8 Taber, a density of between 0.1 g/cm<3> and 0.5 g/cm<3>, a thickness of between 80 mu m and 500 mu m and an electric conductivity of between 10 and 300 S/cm in the nonwoven web and between 30 and 220 S/cm<2> perpendicular to the nonwoven web.
196	一种褶皱的石墨烯纤维和石墨烯纤维无纺布及其制备方法	PCT/CN2018/084334	2018-04-25	WO2019029191A1	2019-02-14	高超; 李拯
本发明公开了一种具有褶皱结构的石墨烯纤维和石墨烯纤维无纺布及其制备方法，该石墨烯纤维表面含有大量褶皱的微结构，且可用于构成多褶皱结构石墨烯纤维无纺布，使得无纺布的比表面积得到显著增加，而石墨烯纤维及由纤维构成的连通网络结构同时具有较高的导电性能和柔韧性，因此可作为柔性电极材料在可穿戴储能器件中得到应用。
197	DEVICE AND METHOD FOR CONTINUOUS COATING OF CARBON FIBRES WITH AN ELECTROCHEMICAL METHOD	PCT/TR2017/050028	2017-01-18	WO2017138899A1	2017-08-17	SARAC, A. Sezai; SAYINLI, Burcu
The invention is related to a continuous system for coating carbon fibre materials and a device developed carry out said method. The coating of carbon fibre with both an electrochemical method following the polymerization (polyethylenedioxythiophene, polypyrrole, polythiophene, polyaniline and derivates thereof) of the conductive monomer and coating with an insulating sizing material (thickening material) is carried out in a single step.
198	FREESTANDING ULTRA THIN MEMBRANES AND TRANSFER-FREE FABRICATION THEREOF	PCT/US2014/067280	2014-11-25	WO2015077751A1	2015-05-28	WADUGE, Pradeep; LARKIN, Joseph; UPMANYU, Moneesh; KAR, Swastik; WANUNU, Meni
Devices contain freestanding, ultra thin (< 10 nm thick) membranes and methods of making such devices. Methods of using devices contain freestanding ultra thin membranes for determining the sequence of a polynucleotide and for desalination of aqueous solutions. A device containing: a substrate having an upper surface, a lower surface, and an aperture, the aperture having one or more walls connecting the upper and lower surfaces and forming a well; and a membrane attached to the lower surface of the substrate and forming a floor of the well, the membrane having a thickness of less than 10 nm. The electrical conductance across the membrane is less than 1 nS/?m2.
199	FLUOROPOLYMER FINE FIBER	PCT/US2008071800	2008-07-31	WO2009018463A2	2009-02-05	FERRER ISMAEL; YANG CHUANFANG
A layer of fluoropolymer fine fiber can be made. The fine fiber can be made by electrospinning from a solvent or a solvent blend. The layers of the invention are useful in general filtration of fluid streams including gaseous and liquid streams. The fine fiber layers are also useful as hydrophobic filtration layers that can be used to separate water from a hydrocarbon stream.
200	METHOD FOR PRODUCING BY ELECTROCHEMICAL PROCESS A CARBON-CONTAINING MATERIAL WITH ITS SURFACE MODIFIED BY ORGANIC GROUPS, USE OF THE MODIFIED MATERIAL	PCT/FR1998/000594	1998-03-25	WO98044172A1	1998-10-08
The invention concerns a method for producing by electrochemical reduction a carbon-containing material with its surface modified by organic groups, in particular functionalised, comprising contacting the carbon-containing material with an organic diazonium salt in solvent, optionally in the presence of an electrolyte; negative polarisation of the carbon-containing material relative to an anode also in contact with an electrolytic solution separate from said diazonium salt solution, said method being characterised in that the electrochemical reduction is carried out on an organic diazonium salt in protic solvent in an acid medium. The invention also concerns the carbon-containing materials with surface modified by organic groups and the use of these modified materials, for example for producing composite materials or for fixing molecules of biological interest.

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