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    • 57. 发明授权
    • Copper interconnect barrier layer structure and formation method
    • 铜互连屏障层结构和形成方法
    • US06607976B2
    • 2003-08-19
    • US09964108
    • 2001-09-25
    • Ling ChenSeshadri GanguliChristophe MarcadalWei CaoRoderick C. MoselyMei Chang
    • Ling ChenSeshadri GanguliChristophe MarcadalWei CaoRoderick C. MoselyMei Chang
    • H01L214763
    • H01L21/76843H01L21/28556H01L21/28562H01L21/76846H01L21/76876H01L23/53238H01L2924/0002H01L2924/00
    • A method for forming a tungsten-containing copper interconnect barrier layer (e.g., a tungsten [W] or tungsten-nitride [WXN] copper interconnect barrier layer) on a substrate with a high (e.g., greater than 30%) sidewall step coverage and ample adhesion to underlying dielectric layers. The method includes first depositing a thin titanium-nitride (TiN) or tantalum nitride (TaN) nucleation layer on the substrate, followed by the formation of a tungsten-containing copper interconnect barrier layer (e.g., a W or WXN copper interconnect barrier layer) overlying the substrate. The tungsten-containing copper interconnect barrier layer can, for example, be formed using a Chemical Vapor Deposition (CVD) technique that employs a fluorine-free tungsten-containing gas (e.g., tungsten hexacarbonyl [W(CO)6]) or a WF6-based Atomic Layer Deposition (ALD) technique. The presence of a thin TiN (or TaN) nucleation layer facilitates the formation of a tungsten-containing copper interconnect barrier layer with a sidewall step coverage of greater than 30% and ample adhesion to dielectric layers. A copper interconnect barrier layer structure includes a thin titanium-nitride (TiN) (or tantalum nitride [TaN]) nucleation layer disposed directly on the dielectric substrate (e.g., a single or dual-damascene copper interconnect dielectric substrate). The copper interconnect barrier layer structure also includes a tungsten-containing copper interconnect barrier layer (e.g., a W or WXN copper interconnect barrier layer) formed on the thin TiN (or TaN) nucleation layer using, for example, a CVD technique that employs a fluorine-free tungsten-containing gas (e.g., [W(CO)6]) or a WF6-based ALD technique.
    • 在具有高(例如,大于30%)侧壁台阶覆盖的基板上形成含钨铜互连势垒层(例如,钨[W]或氮化钨[WXN]铜互连势垒层)的方法,以及 充足的粘附到底层电介质层。 该方法包括首先在衬底上沉积薄的氮化钛(TiN)或氮化钽(TaN)成核层,随后形成含钨的铜互连屏障层(例如W或WXN铜互连阻挡层) 覆盖基板。 含钨铜互连阻挡层例如可以使用使用无氟含钨气体(例如六羰基钨[W(CO)6])或WF 6的化学气相沉积(CVD)技术来形成 的原子层沉积(ALD)技术。 薄TiN(或TaN)成核层的存在有助于形成具有大于30%的侧壁台阶覆盖率和对电介质层的充分粘合性的含钨铜互连屏障层。 铜互连势垒层结构包括直接设置在电介质基板(例如,单镶嵌铜互连电介质基板)上的薄氮化钛(TiN)(或氮化钽[TaN])成核层。 铜互连阻挡层结构还包括使用例如CVD技术在薄TiN(或TaN)成核层上形成的含钨铜互连势垒层(例如,W或WXN铜互连势垒层),其采用 无氟含钨气体(例如[W(CO)6])或基于WF6的ALD技术。
    • 59. 发明授权
    • Contact clean by remote plasma and repair of silicide surface
    • 通过远程等离子体接触清洁并修复硅化物表面
    • US09147578B2
    • 2015-09-29
    • US13004740
    • 2011-01-11
    • Xinliang LuChien-Teh KaoChiukin Steve LaiMei Chang
    • Xinliang LuChien-Teh KaoChiukin Steve LaiMei Chang
    • H01L21/00H01L21/285H01L21/02H01L21/28H01L21/321H01L29/66
    • H01L21/28518H01L21/0206H01L21/02063H01L21/02068H01L21/28061H01L21/321H01L29/665H01L29/6659Y10S438/906
    • Embodiments provide methods for treating a metal silicide contact which includes positioning a substrate having an oxide layer disposed on a metal silicide contact surface within a processing chamber, cleaning the metal silicide contact surface to remove the oxide layer while forming a cleaned silicide contact surface during a cleaning process, and exposing the cleaned silicide contact surface to a silicon-containing compound to form a recovered silicide contact surface during a regeneration process. In some examples, the cleaning of the metal silicide contact surface includes cooling the substrate to an initial temperature of less than 65° C., forming reactive species from a gas mixture of ammonia and nitrogen trifluoride by igniting a plasma, exposing the oxide layer to the reactive species to form a thin film, and heating the substrate to about 100° C. or greater to remove the thin film from the substrate while forming the cleaned silicide contact surface.
    • 实施例提供了处理金属硅化物接触的方法,其包括将具有设置在处理室内的金属硅化物接触表面上的氧化物层的衬底定位,在金属硅化物接触表面中清洁金属硅化物接触表面以除去氧化物层同时形成清洁的硅化物接触表面 清洁工艺,以及将清洁的硅化物接触表面暴露于含硅化合物,以在再生过程中形成回收的硅化物接触表面。 在一些实例中,金属硅化物接触表面的清洁包括将衬底冷却至低于65℃的初始温度,通过点燃等离子体从氨和三氟化氮的气体混合物形成反应物质,将氧化物层暴露于 反应性物质形成薄膜,并将衬底加热至约100℃或更高以在形成清洁的硅化物接触表面的同时从衬底移除薄膜。