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    • 11. 发明授权
    • Strong liquid-crystalline polymeric compositions
    • 强液晶聚合物组合物
    • US5268584A
    • 1993-12-07
    • US894752
    • 1992-06-05
    • Flonnie Dowell
    • Flonnie Dowell
    • C09K19/38C09K19/52C09K19/00C09K19/12C09K19/34
    • C09K19/3804C09K19/3823
    • Strong liquid-crystalline polymeric (LCP) compositions of matter. LCP backbones are combined with liquid crystalline (LC) side chains in a manner which maximizes molecular ordering through interdigitation of the side chains, thereby yielding materials which are predicted to have superior mechanical properties over existing LCPs. The theoretical design of LCPs having such characteristics includes consideration of the spacing distance between side chains along the backbone, the need for rigid sections in the backbone and in the side chains, the degree of polymerization, the length of the side chains, the regularity of the spacing of the side chains along the backbone, the interdigitation of side chains in sub-molecular strips, the packing of the side chains on one or two sides of the backbone to which they are attached, the symmetry of the side chains, the points of attachment of the side chains to the backbone, the flexibility and size of the chemical group connecting each side chain to the backbone, the effect of semiflexible sections in the backbone and the side chains, and the choice of types of dipolar and/or hydrogen bonding forces in the backbones and the side chains for easy alignment.
    • 物质的强液晶聚合物(LCP)组合物。 LCP骨架以液晶(LC)侧链与通过侧链交叉使分子排序最大化的方式组合,从而产生预测具有优于现有LCP的机械性能的材料。 具有这种特性的LCP的理论设计包括考虑沿着骨架的侧链之间的间隔距离,在主链和侧链中的刚性部分的需要,聚合度,侧链的长度,规则性 侧链沿着骨架的间距,亚分子条中侧链的交叉,侧链在它们所连接的主链的一侧或两侧上的包装,侧链的对称性,点 将侧链连接到骨架上,连接每个侧链与骨架的化学基团的柔性和尺寸,主链和侧链中的半柔性部分的作用以及偶极和/或氢的类型的选择 骨架和侧链中的粘结力易于对准。
    • 14. 发明授权
    • Wholly aromatic mesomorphic polyester amide imides and the preparation
thereof
    • 全芳族介晶聚酰胺酰亚胺及其制备方法
    • US4727129A
    • 1988-02-23
    • US937678
    • 1986-12-04
    • Bernd HisgenHans-Jakob Kock
    • Bernd HisgenHans-Jakob Kock
    • C08G73/16C09K19/38C08G69/44
    • C09K19/3823C08G73/16
    • Wholly aromatic mesomorphic polyester amide imides which form a liquid-crystalline fiber-forming melt below 320.degree. C. and are composed of(a) from 5 to 35 mol % of repeat units of the formula I and/or II ##STR1## where X can be identical or different, each X being --O--, --S--, --SO.sub.2 --, --CO--, --CH.sub.2 -- or .dbd.C(CH.sub.3).sub.2, and n is 0 or 1(b) from 0 to 30 mol % of repeat units of the formulae III and/or IV ##STR2## (c) a molar amount corresponding to the total amount of components (a) and (b) of one or more of the repeat units V, VI, VII, VIII, IX or X in an amount of(c1) from 3 to 35 mol % of units of the formula V ##STR3## (c2) from 0 to 10 mol % of units of the formula VI ##STR4## (c3) from 2 to 25 mol % of units of the formula VII ##STR5## (c4) from 2 to 20 mol % of units of the formula VIII ##STR6## (c5) from 0 to 20 mol % of the units of the formula IX ##STR7## (c6) from 2 to 20 mol % of units of the formula X ##STR8## the total of the mole percentages of components (c1), (c2), (c3), (c4), (c5) and (c6) equalling in each case the total of the mole percentages of components (a) and (b);(d) not less than 10 mol % of repeat units of the formula XI ##STR9## (e) from 0 to 25 mol % of one or more of the repeat units of the formula XII, XIII or XIV ##STR10## the mole percentages of components (a), (b), (c), (d) and (e) adding up to 100 mol % in each case, the preparation thereof and fibers, films and moldings prepared therefrom.
    • 全芳香族介晶聚酰胺酰亚胺,其在320℃以下形成液晶成纤熔体,由(a)5-35摩尔%的式I和/或II重复单元组成。 其中X可以相同或不同,每个X是-O - , - S - , - SO 2 - , - CO - , - CH 2 - 或= C(CH 3)2,n是 0或1(b)0至30摩尔%的式III和/或IV的重复单元(c)摩尔量对应于一种或多种组分(a)和(b)的总量 的重复单元V,VI,VII,VIII,IX或X的量为(c1)3至35摩尔%的式V(c2)的单元,为0至10摩尔%的单位 2至25摩尔%的式VII化合物VII(c4)的式VI VI(c3)2至20摩尔%的式VIII的单元VIII(c5)从0 至20摩尔%的式IX IX(c6)的单元,2至20摩尔%的式X单元X的总摩尔百分比 在各种情况下,组分(c1),(c2),(c3),(c4),(c5)和(c6)等于组分(a)和(b)的摩尔百分数的总和; (d)不少于10摩尔%的式XI XI(e)的重复单元,0至25摩尔%的一种或多种式XII,XIII或XIV的重复单元,1 HNcff / 135 OXIVC + RE组分(a),(b),(c),(d)和(e))的摩尔百分数在每种情况下加到100摩尔%,其制备和制备的纤维,膜和模制品 由此。