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    • 31. 发明授权
    • Metalorganic vapor phase epitaxial growth of group II-VI semiconductor
materials
    • II-VI族半导体材料的金属有机气相外延生长
    • US4568397A
    • 1986-02-04
    • US649650
    • 1984-09-12
    • William E. HokeRichard TraczewskiPeter J. Lemonias
    • William E. HokeRichard TraczewskiPeter J. Lemonias
    • C30B25/02H01L21/365H01L31/00
    • H01L21/02395C30B25/02C30B29/48H01L21/02398H01L21/02411H01L21/0248H01L21/02562H01L21/0262Y10S148/063Y10S148/064Y10S148/08Y10S148/11
    • A method for growing a Group II-VI epitaxial layer on a substrate, said epitaxial layer having an electron mobility greater than 1.5.times.10.sup.5 cm.sup.2 /V-sec at 77.degree. K. and a carrier concentration less than 4.times.10.sup.15 (cm.sup.-3) is described. The method includes the steps of directing a plurality of vapor flows towards the substrate including a Group II metalorganic vapor having a mole fraction in the range of 3.0.times.10.sup.-4 to 4.5.times.10.sup.-4, a Group VI metalorganic vapor having a mole fraction in the range of 2.9.times.10.sup.-3 to 3.5.times.10.sup.-3 and a Group II elemental metal vapor having a mole fraction in the range of 2.6.times.10.sup.-2 to 3.2.times.10.sup.-2. The source of Group II metal is heated to at least 240.degree. C. while radiant energy is directed toward the reactor vessel to warm the zone of the reactor vessel between the Group II metal source and the substrate to at least 240.degree. C. The directed flows of Group II metalorganic vapor, Group VI metalorganic vapor and Group II metal vapor then chemically react to form the epitaxial layer.
    • 一种用于在衬底上生长II-VI族外延层的方法,所述外延层在77°K具有大于1.5×10 5 cm 2 / V·sec的电子迁移率,并且载流子浓度小于4×10 15(cm -3)) 。 该方法包括以下步骤:将多个蒸气流引向基材,包括摩尔分数在3.0×10 -4至4.5×10 -4范围内的第II族金属有机蒸汽,第VI族金属有机蒸气的摩尔分数在 范围为2.9×10 -3至3.5×10 -3,以及摩尔分数在2.6×10 -2至3.2×10 -2范围内的II族元素金属蒸气。 将II族金属的来源加热至至少240℃,同时将辐射能量指向反应器容器以将第II族金属源和基底之间的反应器容器区域加热至至少240℃。定向 第II族金属有机蒸气,第VI族金属有机蒸气和第II族金属蒸气的流动然后化学反应形成外延层。