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41. 发明授权

US5461115A Continuous production process of a propylene-ethylene block copolymer 失效
标题翻译：丙烯 - 乙烯嵌段共聚物的连续生产方法
公开(公告)号：US5461115A
公开(公告)日：1995-10-24
申请号：US309834
申请日：1994-09-21
申请人： Takahiro Oka
发明人： Takahiro Oka
IPC分类号： C08F4/658 , C08F2/38 , C08F4/60 , C08F297/08
CPC分类号： C08F2/38 , C08F297/083
摘要： A continuous process for producing a propylene-ethylene block copolymer having well-balanced properties of impact strength, stiffness, processability, etc. using a highly active catalyst, with a superior productivity is provided,which process comprisesa first polymerization step (I), carried out using a catalyst system consisting of [A] a solid catalyst component containing Ti, Mg, halogen and a polyvalent carboxylic acid ester as indispensable components, [B] an organoaluminum compound catalyst component and [C] an electron-donating compound,using two or more continuous polymerization vessels, andfeeding monomer(s) of ethylene/(ethylene+propylene) of 0 to 5% by weight, to carry out polymerization composed mainly of propylene, so as to give 60 to 95% of the total polymerized quantity;a continuous addition of a glycol compound (D) expressed by the formulaR.sup.1 --(OC.sub.m H.sub.2m).sub.n --OR.sup.2wherein m is an integer of 2 or more, n is an integer of 3 or more, R.sup.1 and R.sup.2 each are H atom, an alkyl group or a monovalent organic group containing a hetero atom of O, N, P, S, Si, etc., and may be same or different; so as to give a value of [D]/Ti in [A]=1 to 100 mols/atom; and successively,a polymerization step (II) carried out using one or more continuous polymerization vessels, andfeeding monomers of ethylene/(ethylene+propylene) of 10 to 100% by weight, to carry out a propylene-ethylene random copolymerization composed of ethylene in a relatively large quantity, so as to give 5 to 40% by weight of the total polymerized quantity.
摘要翻译：提供一种使用高活性催化剂具有良好平衡的冲击强度，刚度，加工性能等的丙烯 - 乙烯嵌段共聚物的连续制造方法，该方法具有优异的生产率，该方法包括第一聚合步骤（I），使用由[A]含有Ti，Mg，卤素和多价羧酸酯的固体催化剂组分作为不可或缺组分的催化剂体系[B]有机铝化合物催化剂组分和[C]给电子化合物进行的催化剂体系，使用两个或更多个连续聚合容器，并加入0-5重量％的乙烯/（乙烯+丙烯）单体以进行主要由丙烯组成的聚合物，从而得到总共聚合的聚合物的总量的60-95％数量; 连续加入由式R1-（OCmH2m）n-OR2表示的二醇化合物（D），其中m为2以上的整数，n为3以上的整数，R1和R2各自为H原子，烷基或含有O，N，P，S，Si等的杂原子的一价有机基团，可以相同或不同; 以得到[A] = 1〜100摩尔/原子的[D] / Ti值。依次使用一个或多个连续聚合容器进行聚合步骤（II），并且将进料乙烯/（乙烯+丙烯）单体为10-100重量％进行丙烯 - 乙烯无规共聚合，由乙烯以相当大的量使得总重量为5〜40重量％。

42. 发明授权

US5461018A Procatalyst composition for the polymerization of alpha-olefines, preparation and use 失效
标题翻译：用于α-烯烃聚合的主催化剂组合物，制备和使用
公开(公告)号：US5461018A
公开(公告)日：1995-10-24
申请号：US214656
申请日：1994-03-16
申请人： Sirpa Ala-Huikku , Marjaana Lommi , Eero Iiskola
发明人： Sirpa Ala-Huikku , Marjaana Lommi , Eero Iiskola
IPC分类号： C08F4/60 , C08F4/638 , C08F4/658 , C08F10/00 , B01J21/06 , B01J21/10
CPC分类号： C08F10/00
摘要： The present invention relates to a procatalyst composition for the polymerization of alpha-olefines, which has been prepared in steps, in which is arranged a carrier agent based on at least one inorganic oxide, having few or no hydroxyl groups on its surface, and the carier agent is reacted with the magnesium compound and one or more transition metal compounds of the groups IVB and VB of the periodic table. It has been observed that such a catalyst is most-advantageous when a) this carrier agent is impregnated with a mixture of the Mg compound and one or more compounds of a transition metal of the groups IVb or Vb of the periodic table, which dissolves the Mg compound, and b) by chlorinating with a compound that does not contain titanium so that 1) the carrier is first treated with a mixture in the form of a solution of the Mg compound and the transition metal compound and the product thus obtained is chlorinated, or 2) the carrier is first chlorinated and subsequently treated with the above mixture in the form of a solution, or 3) the Mg compound and the transition metal compound are impregnated into the carrier without any separate dissolving and the product thus obtained is chlorinated.
摘要翻译：本发明涉及一种用于α-烯烃聚合的主催化剂组合物，其已经按步骤制备，其中在其表面上布置有基于至少一种在其表面上具有很少或没有羟基的无机氧化物的载体剂，羧化剂与镁化合物和元素周期表IVB和VB族的一种或多种过渡金属化合物反应。已经观察到，当a）用Mg化合物和周期表IVb或Vb族的过渡金属的一种或多种化合物的混合物浸渍该载体时，这种催化剂是最有利的，其溶解了 Mg化合物，b）通过用不含钛的化合物进行氯化，使得1）载体首先用Mg化合物和过渡金属化合物溶液形式的混合物处理，并将得到的产物氯化，或2）首先将载体氯化并随后用溶液形式的上述混合物处理，或3）将Mg化合物和过渡金属化合物浸渍到载体中而不会单独溶解，并将得到的产物进行氯化。

43. 发明授权

US5420090A Silica supported transition metal catalysts 失效
标题翻译：二氧化硅负载的过渡金属催化剂
公开(公告)号：US5420090A
公开(公告)日：1995-05-30
申请号：US21705
申请日：1993-02-24
申请人： Lee Spencer , Brian W. S. Kolthammer
发明人： Lee Spencer , Brian W. S. Kolthammer
IPC分类号： C08J5/18 , B29C55/02 , B29K23/00 , B29L7/00 , C08F4/646 , C08F4/658 , C08F4/685 , C08F10/00 , C08F210/00 , C08F210/02 , C08F210/16 , B01J31/00
CPC分类号： C08F10/00 , Y10S428/91 , Y10T428/26 , Y10T428/31855
摘要： A transition metal containing catalyst useful for the polymerization of .alpha.-olefins is prepared by (A) forming in an inert atmosphere which excludes oxygen and moisture a slurry of (1) a porous inorganic oxide support material selected from the group consisting of silica, alumina, or a combination of silica and alumina, said support material containing not greater than about 5 millimoles of hydroxyl groups per gram of support material and a particle size not greater than about 10 microns and a surface area of from about 50 to about 800 m.sup.2 /g in an inert organic liquid medium; (B) mixing said slurry with (2) an alkoxide and stirring the resultant mixture at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to saturate the surface of the support material: (C) mixing the product form (B) with (3) a titanium compound or a combination of a titanium compound and (4) a vanadium compound and stirring the resultant mixture at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to allow complete reaction of the titanium compound and the vanadium compound with the organomagnesium moieties remaining on the solid support; (D) mixing the product from (C) with an inert organic solution of (5) a Group IIIA metal alkyl halide at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to complete the reduction of the titanium and vanadium, if present, compounds to their final oxidation state.
摘要翻译：用于α-烯烃聚合的含过渡金属的催化剂通过以下步骤制备：（A）在惰性气氛中形成不含氧和水分的淤浆（1）多孔无机氧化物载体材料，其选自二氧化硅，氧化铝，或二氧化硅和氧化铝的组合，所述载体材料每克载体材料含有不大于约5毫摩尔羟基，粒度不大于约10微米，表面积为约50至约800平方米/ g在惰性有机液体介质中; （B）将所述浆料与（2）醇盐混合并在约-20℃至约120℃的温度下搅拌所得混合物足以使载体材料表面饱和的时间：（C）将产品形式（B）与（3）钛化合物或钛化合物和（4）钒化合物的组合混合，并在约-20℃至约120℃的温度下搅拌所得混合物足以允许钛化合物和钒化合物与残留在固体载体上的有机镁部分完全反应的时间; （D）将来自（C）的产物与（5）IIIA族金属烷基卤的惰性有机溶液在约-20℃至约120℃的温度下混合足以完成还原的时间的钛和钒（如果存在）化合物达到其最终氧化态。

44. 发明授权

US5413979A Method for the preparation of a catalyst component for the polymerization of olefins, a polymerization catalyst component produced by the method and use of the same 失效
标题翻译：制备烯烃聚合用催化剂组分的方法，通过该方法制备的聚合催化剂组分及其用途
公开(公告)号：US5413979A
公开(公告)日：1995-05-09
申请号：US856967
申请日：1992-06-16
申请人： Arja Kostiainen , Bill Gustafsson , Pekka Sormunen
发明人： Arja Kostiainen , Bill Gustafsson , Pekka Sormunen
IPC分类号： C08F4/658 , C08F4/60 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00
摘要： The invention relates to a method for the preparation of a solid procatalyst composition for a catalyst system intended for the polymerization of olefins, wherein a magnesium halide, such as magnesium chloride, is dissolved and/or slurried in a mono-carboxylic acid alkyl ester, such as ethyl acetate, is impregnated into a support material, dried, treated with an organometallic compound or a silicon compound and thereafter with a transition metal compound. The invention also relates to such a procatalyst composition and its use together with a cocatalyst for the polymerization of olefins. According to the invention it has been possible to increase the activity of the catalyst composition by using a silanated support material, such as silanated silica, which is then treated with an organometallic or silicon compound before treatment with a transition metal compound. The silanated silica is preferably a silicon dioxide which has been heat-treated at 1000.degree.-200.degree. and thereafter treated with hexamethyldisilazane and contains 3-6% carbon. The organometallic compound is preferably an aluminum alkyl compound, such as triethylaluminum, and the transition metal compound is preferably titanium tetrachloride.
摘要翻译： PCT No.PCT / FI90 / 00279 Sec。 371日期：1992年6月16日 102（e）日期1992年6月16日PCT 1990年11月20日PCT PCT。公开号WO91 / 07443 日本1991年5月30日本发明涉及一种制备用于烯烃聚合的催化剂体系的固体前催化剂组合物的方法，其中卤化镁如氯化镁以单体形式溶解和/或浆化羧酸烷基酯如乙酸乙酯浸渍到载体材料中，干燥，用有机金属化合物或硅化合物处理，然后用过渡金属化合物处理。本发明还涉及这种前催化剂组合物及其与烯烃聚合用助催化剂的使用。根据本发明，可以通过使用硅烷化载体材料如硅烷化二氧化硅来提高催化剂组合物的活性，然后用过渡金属化合物处理之前用有机金属或硅化合物处理。硅烷化二氧化硅优选是在1000℃-200℃下热处理的二氧化硅，然后用六甲基二硅氮烷处理并含有3-6％的碳。有机金属化合物优选为烷基铝化合物，例如三乙基铝，过渡金属化合物优选为四氯化钛。

45. 发明授权

US5229476A Method for producing a stereospecific polyolefin 失效
标题翻译：生产立体聚烯烃的方法
公开(公告)号：US5229476A
公开(公告)日：1993-07-20
申请号：US749132
申请日：1991-08-23
申请人： Daiji Hara , Mitsuhiro Mori , Yozo Kondo
发明人： Daiji Hara , Mitsuhiro Mori , Yozo Kondo
IPC分类号： C08F4/60 , C08F4/658 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/903 , Y10S526/904
摘要： A method for producing a stereospecific polyolefin in the presence of a catalyst comprising a transition metal compound and an organometallic compound, wherein a catalyst system is used which comprises: (A) a solid catalyst component prepared by reacting a homogeneous solution containing (i-1) magnesium and a hydroxylated organic compound, (i-2) an oxygen-containing organic compound of titanium and/or (i-3) an oxygen-containing organic compound of silicon and an oxygen-containing organic compound of aluminum and/or a boron compound, with (ii) at least one aluminum halide compound to obtain a solid product, and further reacting to this solid product (iii) an electron-donative compound, (iv) a titanium halide compound, and (v) ethylene and/or an .alpha.-olefin having at least 3 carbon atoms, (B) at least one member selected from the group consisting of organometallic compounds of Groups IA, IIA, IIB, IIIB and IVB of the Periodic Table, and (C) an electron-donative compound. A highly stereospecific polymer having good configuration of particles can be obtained in good yield by the method of the present invention.

46. 发明授权

US5206197A Catalyst composition for preparation of syndiotactic vinyl aromatic polymers 失效
标题翻译：用于制备合成乙烯基芳族聚合物的催化剂组合物
公开(公告)号：US5206197A
公开(公告)日：1993-04-27
申请号：US664699
申请日：1991-03-04
申请人： Richard E. Campbell, Jr.
发明人： Richard E. Campbell, Jr.
IPC分类号： C08F4/658 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/657 , C08F4/6592 , C08F4/80 , C08F12/00 , C08F12/04
CPC分类号： C08F12/04 , Y10S526/943
摘要： A catalyst composition for preparation of polymers of vinyl aromatic monomers having high syndiotacticity comprising a cationic coordination complex and a metal hydrocarbyl.

47. 发明授权

US5189000A Supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds, and a (co)polymerization process which uses it 失效
标题翻译：用于烯烃不饱和化合物的聚合和共聚的支持催化剂和使用它的（CO）聚合方法
公开(公告)号：US5189000A
公开(公告)日：1993-02-23
申请号：US673272
申请日：1991-03-21
申请人： Francesco Masi , Renzo Invernizzi , Antonio Carbonaro , Lorenzo Costa , Angelo Moalli
发明人： Francesco Masi , Renzo Invernizzi , Antonio Carbonaro , Lorenzo Costa , Angelo Moalli
IPC分类号： C08F4/658 , B01J20060101 , C07F20060101 , C08F20060101 , C08F2/00 , C08F4/00 , C08F4/02 , C08F4/60 , C08F4/61 , C08F4/617 , C08F4/62 , C08F4/622 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F210/16
CPC分类号： C08F10/00
摘要： A supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds is described, comprising an organometallic compound of aluminium and a second component obtained by bringing a titanium, vanadium or chromium compound, at least one compound of a second metal chosen from V, Al, Zr, Hf, Mo and Nd and optionally a magnesium compound into contact with a porous support consisting of microbeads of aerogels of one or more inorganic oxides distinguished by low density, high porosity and the fact that at least 90% of the pores have a diameter lying within a very narrow range of values. The process for the polymerization or copolymerization of olefinically unsaturated compounds based on the use of said catalyst is also described.

48. 发明授权

US5177162A Polymerization of olefins 失效
标题翻译：烯烃的聚合
公开(公告)号：US5177162A
公开(公告)日：1993-01-05
申请号：US483997
申请日：1990-02-22
申请人： Mitsuyuki Matsuura , Takashi Fujita
发明人： Mitsuyuki Matsuura , Takashi Fujita
IPC分类号： C08F4/60 , C08F4/64 , C08F4/658 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/904
摘要： The present invention relates to an improvement of the known Ziegler catalyst which comprises a combination of a titanium-containing component and an organoaluminum component, and the present invention is characterized by a specific titanium-containing component. Namely, this titanium-containing component is obtained by contacting a known titanium-containing component of the Ziegler type catalyst which comprises Ti, Mg and a halogen, with an alkoxyalkylsilane compound which is characterized in that at least one of the alkyl groups has a branched structure. This catalyst does not require a so-called external electron donor, and no reduction of the polymerization velocity caused by the use of the electron donor is entailed. When this catalyst is used, a propylene/ethylene block copolymer in which the molecular weight of the propylene/ethylene copolymer portion and/or the polyethylene portion is increased, that is, the rigidity and impact strength are increased, can be prepared.

49. 发明授权

US5130284A Sold catalyst component for the polymerization of olefins and an olefin polymerization catalyst 失效
标题翻译：销售烯烃和烯烃聚合催化剂聚合催化剂组分
公开(公告)号：US5130284A
公开(公告)日：1992-07-14
申请号：US582415
申请日：1990-09-14
申请人： Minoru Terano , Hirokazu Soga , Masuo Inoue
发明人： Minoru Terano , Hirokazu Soga , Masuo Inoue
IPC分类号： C08F4/60 , C08F4/651 , C08F4/654 , C08F4/658 , C08F10/00
CPC分类号： C08F10/00
摘要： A solid catalyst component prepared under specific conditions by reacting with a reaction product which has been obtained by suspending diethoxymagnesium in an alkylbenzene and bringing the suspension into contact with titanium tetrachloride, phthaloyl dichloride at 80.degree.-125.degree. C., washing the resultant solid material with an alkylbenzene, reacting the solid material in the presence of an alkylbenzene with titanium tetrachloride to form a solid substance, and repeating the process of the following steps (1), (2), (3) and (4) 2-4 times for the solid substance:(1) washing the solid substance with an alkylbenzene,(2) suspending the solid substance in an alkylbenzene,(3) bringing the resultant suspension into contact with the titanium tetrachloride, and(4) eliminating a liquid substance from the reaction mixture as far as possible,as well as an olefin polymerization catalyst which comprises (A) the above specified solid catalyst component, (B) a specific silicon compound and (C) a specific organoaluminum compound. This catalyst exhibits, as compared with the existing olefin polymerization catalysts, an extremely high level of catalytic performance in polymerization activity, stereospecific performance and durability of the activity, and enables the production of stereoregular olefin polymers in an extremely high yield with a negligible residual ash content.

50. 发明授权

US5122492A Components and catalysts for the polymerization of olefins 失效
公开(公告)号：US5122492A
公开(公告)日：1992-06-16
申请号：US628526
申请日：1990-12-14
申请人： Enrico Albizzati , Giampiero Morini , Umberto Giannini
发明人： Enrico Albizzati , Giampiero Morini , Umberto Giannini
IPC分类号： C08F4/658 , C07F7/28 , C08F4/60 , C08F4/646 , C08F4/654 , C08F10/00
CPC分类号： C08F10/00
摘要： Catalyst components for the polymerization of olefins and catalysts obtained therefrom, said components comprising a porous metal oxide on which a magnesium dihalide, and a titanium halide or titanium halogen alcoholate and a compound containing two or more ether groups having specific reactivity properties towards MgCl.sub.2 and TiCl.sub.4 are supported.

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