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    • 10. 发明授权
    • Cationic electrodeposition using aqueous dispersions of quaternary
ammonium carbonate-containing polymers
    • 阳离子电沉积使用含季铵碳酸盐的聚合物的水分散体
    • US4102863A
    • 1978-07-25
    • US744533
    • 1976-11-24
    • Stephen L. BuchwalterJoseph F. BossoRoger M. Christenson
    • Stephen L. BuchwalterJoseph F. BossoRoger M. Christenson
    • C08G59/00C08G59/14C09D5/44C25D13/06C08G65/26
    • C09D5/4434C09D5/4423
    • A method of cationic electrodeposition on an electroconductive substrate is disclosed. The method of the invention employs as the electrocoating vehicle an aqueous dispersion of a quaternary ammonium carbonate-containing resin. Electrodeposition of the resin is accomplished without generating harmful acid from the counter ion. The carbonate counter ion is continuously evolved from the electrodeposition bath at the anode as carbon dioxide.The quaternary ammonium carbonate-containing polymers are also useful as feed resins for controlling the pH of aqueous dispersions of acidified cationic resins used in electrodeposition. Upon electrodeposition, these resins generate acid which can build up to undesirable levels in the electrodeposition bath. The quaternary ammonium carbonate-containing polymers are relatively basic and when fed into the bath react with the acid to form the corresponding quaternary ammonium salt of the acid releasing carbon dioxide. This controls the pH of the bath and provides additional cationic resin for electrodeposition.Utilizing the polymeric quaternary ammonium carbonates in this manner minimizes the need for controlling acid build-up in the electrodeposition bath by conventional techniques such as by treating the bath with ultrafiltration or electrodialysis.
    • 公开了一种阳离子电沉积在导电基底上的方法。 本发明的方法使用含有季铵碳酸盐树脂的水性分散体作为电泳载体。 实现树脂的电沉积而不从抗衡离子产生有害的酸。 碳酸盐反离子从阳极的电沉积池连续放出,作为二氧化碳。