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    • 4. 发明授权
    • Molecular spacer layer for semiconductor oxide surface and high-K dielectric stack
    • 用于半导体氧化物表面和高K电介质叠层的分子间隔层
    • US08124485B1
    • 2012-02-28
    • US13032909
    • 2011-02-23
    • Dario L. GoldfarbHemanth N. JagannathanDirk Pfeiffer
    • Dario L. GoldfarbHemanth N. JagannathanDirk Pfeiffer
    • H01L21/00
    • B82Y30/00H01L21/02112H01L21/02282H01L21/0271H01L21/31144H01L21/76224
    • A process for defining a functional area in a semiconductor device comprising a semiconductor substrate contiguous with a gate dielectric layer whose dielectric constant is higher than silicon oxide and an oxide capping layer positioned on the gate dielectric layer that reduces gate leakage comprises applying an organo phosphorous SAM to the oxide capping layer, adhering an organic photoresist layer to the organo phosphorous SAM, defining the functional area by imaging the photoresist layer with a functional area image, developing and removing the functional area image in the photoresist to form a functional area image on the organo phosphorous SAM, and removing the functional area image on the organo phosphorous SAM to form a functional area image on the oxide capping layer. In various embodiments, the gate dielectric layer comprises a HfO2 dielectric layer, the oxide capping layer comprises a La2O3 layer, and the organo phosphorous acid comprises an alkyl phosphonic acid, a carboxylic acid-terminated alkyl phosphonic acid, and mixtures thereof.
    • 一种用于限定半导体器件中的功能区域的方法,包括与其介电常数高于氧化硅的栅极电介质层邻接的半导体衬底以及位于栅极电介质层上的减少栅极泄漏的氧化物覆盖层的方法包括施加有机磷SAM 将有机光致抗蚀剂层粘合到有机磷SAM上,通过用功能区域图像对光致抗蚀剂层进行成像来限定功能区域,在光致抗蚀剂中显影和去除功能区域图像,以形成功能区域图像 有机磷SAM,去除有机磷SAM上的功能区图像,以在氧化物覆盖层上形成功能区图像。 在各种实施例中,栅介质层包括HfO 2电介质层,氧化物覆盖层包含La 2 O 3层,有机亚磷酸包括烷基膦酸,羧酸封端的烷基膦酸及其混合物。