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1. 发明授权

US07371890B2 Method for the continuous production of a compound that carries at least two functional groups 有权
标题翻译：连续生产携带至少两个官能团的化合物的方法
公开(公告)号：US07371890B2
公开(公告)日：2008-05-13
申请号：US10560740
申请日：2004-06-11
申请人： Wolfram Stüer , Jens Scheidel , Hartwig Voβ , Peter Baβler , Michael Röper
发明人： Wolfram Stüer , Jens Scheidel , Hartwig Voβ , Peter Baβler , Michael Röper
IPC分类号： C07C67/48 , C07C51/42 , C07C233/00 , C07C255/00
CPC分类号： C07C51/36 , C07C51/353 , C07C51/47 , C07C67/303 , C07C67/347 , C07C67/56 , C07C57/13 , C07C55/14 , C07C69/44 , C07C69/593
摘要： A process for continuously preparing a compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group and carboxamide group.
摘要翻译：连续制备具有至少两个各自独立地选自腈基，羧酸基，羧酸酯基和羧酰胺基的官能团的化合物的方法。

2. 发明授权

US07053239B2 Method for producing methyl formate 失效
标题翻译：甲酸甲酯的生产方法
公开(公告)号：US07053239B2
公开(公告)日：2006-05-30
申请号：US10511088
申请日：2003-04-15
申请人： Christoph Adami , Michael Slany , Jörn Karl , Gerd Kaibel , Martin Schäfer , Peter Zehner , Michael Röper
发明人： Christoph Adami , Michael Slany , Jörn Karl , Gerd Kaibel , Martin Schäfer , Peter Zehner , Michael Röper
IPC分类号： C07C67/36
CPC分类号： C07C67/36 , C07C69/06
摘要： The invention relates to a process for the preparation of methyl formate by reacting methanol with carbon monoxide at a pressure of from 0.5 to 10 MPa abs. and a temperature of from 50 to 150° C. in the presence of a metal alkoxide as catalyst in a reactor, in which a gas stream is withdrawn from the reactor, entrained methyl formate is removed from this gas stream by condensation, and all or some of the remaining gas stream is returned to the reactor as circulating-gas stream and a mean gas superficial velocity of from 1 to 20 cm/s is set in at least one region of the reactor in which the gas flows essentially in one direction.
摘要翻译：本发明涉及一种通过使甲醇与一氧化碳在0.5至10MPa abs的压力下反应制备甲酸甲酯的方法。在反应器中从作为催化剂的金属醇盐存在下的温度为50-150℃，其中将气流从反应器中排出，夹带的甲酸甲酯通过冷凝从该气流中除去，全部或一些剩余的气流作为循环气体流返回到反应器，并且在反应器的至少一个区域中设置1至20cm / s的平均气体空气速度，其中气体基本上在一个方向上流动。

3. 发明授权

US06906230B1 Method for producing alcohol surfactants and alcohol ether surfactants, the products obtained and their use 失效
标题翻译：制备醇类表面活性剂和醇醚表面活性剂的方法，获得的产品及其用途
公开(公告)号：US06906230B1
公开(公告)日：2005-06-14
申请号：US09926168
申请日：2000-03-17
申请人： Heiko Maas , Michael Röper , Marc Walter , Ralf Schulz , Jürgen Tropsch , Hans-Ulrich Jäger
发明人： Heiko Maas , Michael Röper , Marc Walter , Ralf Schulz , Jürgen Tropsch , Hans-Ulrich Jäger
IPC分类号： C07H15/04 , C07B61/00 , C07C2/06 , C07C2/08 , C07C2/10 , C07C11/00 , C07C11/02 , C07C27/22 , C07C29/132 , C07C29/16 , C07C29/36 , C07C29/38 , C07C29/40 , C07C29/44 , C07C29/46 , C07C31/02 , C07C31/125 , C07C41/03 , C07C43/13 , C07C45/50 , C07C303/24 , C07C305/06 , C07C305/10 , C07F9/09 , C07F9/11 , C07H1/00 , C07H13/04 , C08B1/00 , C08B37/00 , C11D1/72
CPC分类号： C07C45/50 , C07C2/10 , C07C11/02 , C07C29/141 , C07C41/03 , C07C43/11 , C07C303/24 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/755 , C07F9/091 , C07C31/125 , C07C305/10 , C07C305/06 , C07C47/02
摘要： The invention describes a process for the preparation of surfactant alcohols and surfactant alcohol ethers which are, inter alia, highly suitable as surfactants or for the preparation of surfactants. The process, starting from olefin mixtures having a defined minimum content of linear hexenes, gives mixtures having a predominant fraction of branched dodecenes, which are subsequently derivatized to give surfactant alcohols and then optionally alkoxylated.The surfactant alcohol mixture obtained in the process has a degree of branching of from 2.0 to 3.0 and in particular exhibits advantageous properties as regards ecotoxicity and biodegradability.A description is also given of the use of the surfactant alcohols and surfactant alcohol ethers as surfactants by glycosidation or polyglycosidation, sulfation or phosphation.
摘要翻译：本发明描述了制备表面活性剂醇和表面活性剂醇醚的方法，其特别是非常适合作为表面活性剂或用于制备表面活性剂。该方法从具有确定的最小含量的线性己烯的烯烃混合物开始，得到具有主要部分的支化十二碳烯的混合物，随后将其衍生化得到表面活性剂醇然后任选烷氧基化。本方法得到的表面活性剂醇混合物的支化度为2.0〜3.0，特别是在生态毒性和生物降解性方面表现出有利的特性。还给出了表面活性剂醇和表面活性剂醇醚通过糖基化或多糖苷化，硫酸化或磷酸化作为表面活性剂的用途。

4. 发明授权

US06906222B2 Preparation for production of formic acid formates 失效
标题翻译：甲酸甲酸盐的制备
公开(公告)号：US06906222B2
公开(公告)日：2005-06-14
申请号：US10494701
申请日：2002-10-29
申请人： Michael Slany , Martin Schäfer , Jörn Karl , Michael Röper
发明人： Michael Slany , Martin Schäfer , Jörn Karl , Michael Röper
IPC分类号： A23K1/16 , C07C27/02 , C07C51/09 , C07C51/41 , C07C53/02 , C07C53/06
CPC分类号： C07C51/09 , C07C53/08
摘要： A process is described for preparing acid formates in which methyl formate is reacted with water and a basic compound having a pKa of the conjugate acid of the corresponding dissociation state of ≧3 measured at 25° C. in aqueous solution, the methanol formed is separated off and, optionally, the desired acid content is set by adding formic acid.
摘要翻译：描述了一种制备酸甲酯的方法，其中甲酸甲酯与水反应，并且在25℃下测量的具有相应解离状态> = 3的共轭酸的pKαaα的碱性化合物。在水溶液中分离形成的甲醇，任选地，通过加入甲酸来设定所需的酸含量。

5. 发明授权

US06566566B1 Process for the preparation of surfactant alcohols and surfactant alcohol ethers, the prepared products and their use 有权
标题翻译：制备表面活性剂醇和表面活性剂醇醚的方法，制备的产品及其用途
公开(公告)号：US06566566B1
公开(公告)日：2003-05-20
申请号：US09936183
申请日：2001-09-10
申请人： Heiko Maas , Michael Röper , Marc Walter , Ralf Schulz , Jürgen Tropsch , Hans-Ulrich Jäger
发明人： Heiko Maas , Michael Röper , Marc Walter , Ralf Schulz , Jürgen Tropsch , Hans-Ulrich Jäger
IPC分类号： C07C210
CPC分类号： C07C303/24 , B01F17/0028 , C07C2/10 , C07C11/02 , C07C29/141 , C07C41/03 , C07C43/11 , C07C2521/06 , C07C2521/12 , C07C2523/755 , C07F9/091 , C07F9/11 , C07C305/06 , C07C31/125
摘要： The invention describes a process for the preparation of surfactant alcohols and surfactant alcohol ethers which are, inter alia, highly suitable as surfactants or for the preparation of surfactants. The process, starting from olefin mixtures which comprise less than 30% by weight of linear hexene isomers and utilizing a catalyst which contains nickel, prepares olefin mixtures having a predominant fraction of branched dodecenes, which are subsequently derivatized to give surfactant alcohols and then optionally alkoxylated. The invention further relates to the use of the surfactant alcohols and surfactant alcohol ethers for the preparation of surfactants by glycosidation or polyglycosidation, sulfation or phosphation.
摘要翻译：本发明描述了制备表面活性剂醇和表面活性剂醇醚的方法，其特别是非常适合作为表面活性剂或用于制备表面活性剂。该方法从包含小于30重量％的线性己烯异构体和利用含有镍的催化剂的烯烃混合物开始，制备具有主要部分的支化十二碳烯的烯烃混合物，随后将其衍生化得到表面活性剂醇，然后任选地烷氧基化本发明还涉及表面活性剂醇和表面活性剂醇醚用于通过糖基化或多糖苷化，硫酸化或磷酸化制备表面活性剂的用途。

6. 发明授权

US08362308B2 Process for preparing a C4-olefin mixture by selective hydrogenation and metathesis process for using this stream 有权
标题翻译：通过选择性氢化和复分解方法制备C4烯烃混合物的方法
公开(公告)号：US08362308B2
公开(公告)日：2013-01-29
申请号：US13042142
申请日：2011-03-07
申请人： Jürgen Stephan , Andreas Brodhagen , Markus Schubert , Frank Poplow , Michael Röper , Thomas Hill
发明人： Jürgen Stephan , Andreas Brodhagen , Markus Schubert , Frank Poplow , Michael Röper , Thomas Hill
IPC分类号： C07C5/02
CPC分类号： C07C11/08 , C07C6/04 , C07C2523/44 , C07C11/107 , C07C11/10
摘要： A C4-olefin mixture having a 1,3-butadiene content of from 100 to 500 ppm and a content of 1,2-dienes of less than 10 ppm is described. The present invention further provides a process for preparing this C4-olefin mixture and provides for its use in a metathesis reaction for preparing 2-pentene and/or 3-hexene.
摘要翻译：描述1,3-丁二烯含量为100-500ppm，1,2-二烯含量小于10ppm的C 4 - 烯烃混合物。本发明还提供了一种制备该C 4烯烃混合物的方法，并提供其在复分解反应中用于制备2-戊烯和/或3-己烯的用途。

7. 发明授权

US07923588B2 Process for preparing a C4-olefin mixture by selective hydrogenation and metathesis process for using this stream 有权
标题翻译：通过选择性氢化和复分解方法制备C4烯烃混合物的方法
公开(公告)号：US07923588B2
公开(公告)日：2011-04-12
申请号：US11665161
申请日：2005-10-13
申请人： Jürgen Stephan , Andreas Brodhagen , Markus Schubert , Frank Poplow , Michael Röper , Thomas Hill
发明人： Jürgen Stephan , Andreas Brodhagen , Markus Schubert , Frank Poplow , Michael Röper , Thomas Hill
IPC分类号： C07C7/167 , C07C11/08
CPC分类号： C07C11/08 , C07C6/04 , C07C2523/44 , C07C11/107 , C07C11/10
摘要： A C4-olefin mixture having a 1,3-butadiene content of from 100 to 500 ppm and a content of 1,2-dienes of less than 10 ppm is described. The present invention further provides a process for preparing this C4-olefin mixture and provides for its use in a metathesis reaction for preparing 2-pentene and/or 3-hexene.
摘要翻译：描述1,3-丁二烯含量为100-500ppm，1,2-二烯含量小于10ppm的C 4 - 烯烃混合物。本发明还提供了一种制备该C 4烯烃混合物的方法，并提供其在复分解反应中用于制备2-戊烯和/或3-己烯的用途。

8. 发明申请

US20100063320A1 METHOD FOR PRODUCING FORMIC ACID 审中-公开
标题翻译：生产形式酸的方法
公开(公告)号：US20100063320A1
公开(公告)日：2010-03-11
申请号：US12532642
申请日：2008-03-18
申请人： Nina Challand , Xavier Sava , Michael Röper
发明人： Nina Challand , Xavier Sava , Michael Röper
IPC分类号： C07C51/15
CPC分类号： C07C51/00 , B01J31/0202 , B01J31/0237 , B01J31/0271 , B01J31/2404 , B01J2231/625 , B01J2531/821 , C07C51/02 , C07C53/06 , C07C53/02
摘要： The invention relates to a process for preparing formic acid, in which catalytic hydrogenation of carbon dioxide with hydrogen over a catalyst which comprises a metal of groups 8 to 10 of the Periodic Table in the presence of a primary, secondary and/or tertiary amine generates the corresponding ammonium formate and the ammonium formate is split by heating into formic acid and the amine, which comprises selecting the primary, secondary or tertiary amine from the amines of the formula I or mixtures thereof where R1 to R3 are the same or different and are each hydrogen, linear or branched alkyl radicals having from 1 to 18 carbon atoms, cycloaliphatic radicals having from 5 to 7 carbon atoms, aryl radicals and/or arylalkyl radicals, and at least one of the R1 to R3 radicals bears a hydroxyl group, and performing the hydrogenation in a solvent which has a boiling point of 105° C. at standard pressure, and obtaining the formic acid in the reaction mixture from the hydrogenation comprising the high-boiling solvent by thermally splitting the ammonium formate and distilling off the formic acid.
摘要翻译：本发明涉及一种制备甲酸的方法，其中二氧化碳与氢在催化剂上催化氢化，所述催化剂在初级，仲和/或叔胺存在下包含元素周期表第8至10族的金属产生相应的甲酸铵和甲酸铵通过加热分解成甲酸和胺，其包括从式I的胺或其混合物中选择伯胺，仲胺或叔胺，其中R 1至R 3相同或不同，并且是每个氢，具有1至18个碳原子的直链或支链烷基，具有5至7个碳原子的脂环族基团，芳基和/或芳基烷基，并且至少一个R 1至R 3基团具有羟基，并且在标准压力下在沸点为105℃的溶剂中进行氢化，并从氢化得到反应混合物中的甲酸，包括高沸点溶剂通过热分解甲酸铵并蒸馏除去甲酸。

9. 发明授权

US06844463B2 Method for the carbonylation of pentenoic acid and its derivatives thereof 失效
标题翻译：戊烯酸及其衍生物的羰基化方法
公开(公告)号：US06844463B2
公开(公告)日：2005-01-18
申请号：US10433034
申请日：2001-12-03
申请人： Michael Slany , Martin Schäfer , Michael Röper
发明人： Michael Slany , Martin Schäfer , Michael Röper
IPC分类号： C07B61/00 , C07C51/14 , C07C67/38 , C07C69/44 , C07C253/30 , C07C255/19 , C07C255/00 , C07C57/02 , C07C69/34
CPC分类号： C07C253/30 , C07C51/14 , C07C67/38 , C07C55/02 , C07C69/44
摘要： Process for the carbonylation of n-pentenoic acid or its derivatives of the formula (I) C4H7—R1 (I) where R1 is —CN or COOR2 where R2 is hydrogen, alkyl or aryl by reaction of a compound of the formula (I) with carbon monoxide and a compound (II) containing a hydroxyl group in the presence of a catalyst system, wherein the catalyst system is obtainable by reaction of a) a source for a metal ion of a metal (III) of the 8th subgroup of the Periodic Table of the Elements with b) a bidentate phosphine ligand of the formula (IV) (R3R4R5C)(R6R7R8C)P-L1-X-L2-P(CR9R10R11) (CR12R13R14) (IV) where R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14 independently of one another is an organic radical which in each case contains a carbon atom, via which the respective radical is linked to the relevant tertiary carbon atom mentioned in formula (IV); L1, L2 independently of one another are a lower alkylene group; X is an arylene group.
摘要翻译：羰基化式（I）的正戊烯酸或其衍生物的方法，其中R 1是-CN或COOR 2，其中R 2是氢，烷基或芳基，通过式（I）与一氧化碳和含有羟基的化合物（II）在催化剂体系的存在下反应，其中催化剂体系可通过以下方法获得：a）第8族金属（III）的金属离子源的元素周期表b）一种式（Ⅳ）的二齿膦配体，其中R 3，R 4，R 5，R 6，R 7，R 8，R 8， R 9，R 10，R 11，R 12，R 13，R 14彼此独立地是有机基团，其在每种情况下均含有碳原子，通过该有机基团，各自的基团与式（IV）中所述的相关叔碳原子连接; L 1，L 2彼此独立地为低级亚烷基; X为亚芳基。

10. 发明授权

US06737553B1 Method for producing surfactant alcohols and surfactant alcohol ethers, the resulting products and their use 有权
标题翻译：生产表面活性剂醇和表面活性剂醇醚的方法，得到的产品及其用途
公开(公告)号：US06737553B1
公开(公告)日：2004-05-18
申请号：US09868340
申请日：2001-06-18
申请人： Heiko Maas , Michael Röper , Marc Walter , Ralf Schulz , Jürgen Tropsch , Hans-Ulrich Jäger , Peter Schwab , Michael Schulz
发明人： Heiko Maas , Michael Röper , Marc Walter , Ralf Schulz , Jürgen Tropsch , Hans-Ulrich Jäger , Peter Schwab , Michael Schulz
IPC分类号： C07C2720
CPC分类号： C07F9/11 , C07C11/02 , C07C29/16 , C07F9/091 , C07C31/125
摘要： The invention describes a process for the preparation of novel surfactant alcohols and surfactant alcohol ethers by derivatization of olefins having from about 10 to 20 carbon atoms or of mixtures of such olefins to give alkanols, and optional subsequent alkoxylation, which comprises subjecting a C4-olefin mixture to metathesis, dimerizing the resulting olefins, and then derivatizing them to give surfactant alcohols, and optionally alkoxylating said alcohols. The olefin mixture obtained in the dimerization has a high proportion of branched components and less than 10% by weight of compounds which contain a vinylidene group. The invention further describes the use of the surfactant alcohols and surfactant alcohol ethers to give surfactants by glycosylation or polyglycosylation, sulfation or phosphation.
摘要翻译：本发明描述了通过衍生具有约10至20个碳原子的烯烃或这些烯烃的混合物来制备新的表面活性剂醇和表面活性剂醇醚的方法，以产生链烷醇，以及任选的随后的烷氧基化，其包括使C4-烯烃混合物对所得烯烃进行二聚，然后将其衍生化得到表面活性剂醇，并任选地使所述醇烷氧基化。二聚中获得的烯烃混合物具有高比例的支链组分，并且含有少于10重量％的含有亚乙烯基本发明还描述了表面活性剂醇和表面活性剂醇醚通过糖基化或多糖基化，硫酸化或磷酸化来提供表面活性剂的用途。

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